Environmental Fate Of Sulfur In Sulphur Creek, Valles Caldera, Nm: Implications For Metal Transport And Water Quality, Daniel Lavery

Earth and Planetary Sciences ETDs

The 1.2 Ma Valles Caldera in north-central New Mexico hosts a young igneous volcanic hydrothermal system after the model proposed in Goff and Janik (2000). The Sulphur Springs area within Valles Caldera is an acid-sulfate area typical of this model, discharging acidic waters (pH 1.5-3) formed by oxidation of magmatic H₂S at the surface. We report on samples obtained from springs and streams collected between October 2021 and May 2023 in the Sulphur Creek and Alamo watersheds. Sulphur Creek receives input from Sulphur Springs and exhibits low pH (2-4) and high concentrations of Al (≤110 mg/L), Fe (≤60 …

Volumetric Imaging Using The Pupil-Matched Remote Focusing Technique In Light-Sheet Microscopy, Sayed Hassan Dibaji Foroushani

Optical Science and Engineering ETDs

ABSTRACT

The dissertation explores innovative techniques in light sheet microscopy, a pivotal tool in biomedical imaging, to enhance its speed, resolution, and efficiency in capturing dynamic biological processes. Light sheet microscopy allows for quick 3D imaging of biological specimens ranging from cells to organs with high spatiotemporal resolution, large field-of-view, and minimal damage, making it vital for in vivo imaging.

The first project introduces a novel optical concept designed to optimize Axially Swept Light Sheet Microscopy (ASLM). This technique is crucial for imaging specimens ranging from live cells to chemically cleared organs due to its versatility across different immersion media. …

Smart Applications And Resource Management In Internet Of Things, Zeinab Akhavan

Computer Science ETDs

Internet of Things (IoT) technologies are currently the principal solutions driving smart cities. These new technologies such as Cyber Physical Systems, 5G and data analytic have emerged to address various cities' infrastructure issues ranging from transportation and energy management to healthcare systems. An IoT setting primarily consists of a wide range of users and devices as a massive network interacting with different layers of the city infrastructure resulting in generating sheer volume of data to enable smart city services. The goal of smart city services is to create value for the entire ecosystem, whether this is health, education, transportation, energy, …

Computational Study Of The Effect Of Geometry On Molecular Interactions, Sarika Kumar

Computer Science ETDs

The specificity and predictability of DNA make it an excellent programmable material and have allowed bio-programmers to build sophisticated molecular circuits. These molecular devices should be precise, correct, and function as intended. In order to implement these circuits, the challenge is to build a robust, reliable, and scalable logic circuit with ideally minimum unwanted signal release. Performing experiments are expensive and time-consuming, so modeling and analyzing these bio-molecular systems become crucial in designing molecular circuits. This dissertation aimed to develop algorithms and build computational tools for automated analysis of molecular circuits that incorporate the molecular geometry of nanostructures. Molecular circuits …

Transport And Mixing Of Water Masses Across The Southeast Caribbean Ocean Imaged By Seismic Reflection Data, Joseph Renzaglia

Earth Sciences Theses and Dissertations

The Caribbean Sea serves as a major pathway for global thermohaline circulation (THC), which is a complex and vital component of the Earth’s climate system, influencing global heat distribution and oceanic circulation. Though relatively stratified, it is the boundary layer that distributes mass and temperature between the surface waters and the deep ocean where we observe various multiscale mixing processes from mesoscale to fine-scale. In regions where bathymetry is shallower and mechanical mixing forces, such as winds and tides, are more dominant, diapycnal diffusivity is typically stronger, driving vertical mixing. This type of mixing occurs at small scales, typically as …

Radio Insights Into Gamma-Ray Mysteries, Seth M. Bruzewski

Physics & Astronomy ETDs

In the time since its launch, the \textit{Fermi Gamma-Ray Space Telescope} has provided new and unparalleled views of the $\gamma$-ray sky, dramatically increasing our understanding of sources of high-energy radiation. During that same time, however, its ``unassociated'' sources have provided a consistent mystery: approximately one third of the modern gamma-ray sky remains completely unaccounted for in other electromagnetic regimes. While some of the fainter sources simply pose challenges in achieving the necessary signal-to-noise ratio, others are well constrained and have resisted traditional investigations for years, and in some cases, for over a decade. Radio astronomy has traditionally been the best …

Modeling Lithographic Quantum Dots And Donors For Quantum Computation And Simulation, Mitchell Ian Brickson

Physics & Astronomy ETDs

Our first focus is on few-hole quantum dots in germanium. We use discontinous Galerkin methods to discretize and solve the equations of a highly detailed k·p model that describes these systems, enabling a better understanding of experimental magnetospectroscopy results. We confirm the expected anisotropy of single-hole g-factors and describe mechanisms by which different orbital states have different g-factors. Building on this, we show that the g-factors in Ge holes are suciently sensitive to details of the device electrostatics that magnetospectroscopy data can be used to make a prediction of the underlying confinement potential. The second focus is on designing quantum …

Comparative Lineament And Geomorphic Analysis Of Chaotic Terrains And Noctis Labyrinthus, Mars, Sarah A. Walton

Electronic Theses and Dissertations

Noctis Labyrinthus (NL) is an extensional trough network connecting the Tharsis rise and Valles Marineris on Mars. Chaotic terrains are a group of polygonally-fractured surface features commonly associated with subsidence due to rapid fluid loss within the subsurface. Polygonal surface patterns are seen at both sites, where geometric topographic highs are bounded by low troughs. Lineaments, topography, and geomorphology of NL and chaotic terrains were analyzed to determine tectonics and fluid influence in the formation and evolution of both sites. NL shows preferential fracture patterns associated with regional extension. Lineaments within chaotic terrains do not show cumulative preferential trends but …

Dryland Vegetation Mapping Using High Spatial-Temporal Resolution Satellite Imagery In New Mexico: A Comparison Of Phenological Time-Series Transformation Methods, Pratistha Sharma

Geography ETDs

New Mexico's drylands are undergoing notable vegetation changes due to rising aridity, higher temperatures, and shifts in precipitation with changing climate. Mapping drylands through remote sensing is challenging compared to mesic systems due to the irregular patterns of rainfall-driven phenology and weaker vegetation absorption signals. This study aims to enhance vegetation mapping in New Mexico, utilizing a high-resolution, frequently revisited PlanetScope dataset with multispectral capabilities, specifically chosen for its suitability for time-series analysis. The challenge with high spatial and temporal data lies in the overwhelming volume, leading to issues like the curse of dimensionality, overfitting, data redundancy, collinearity, and visualization …

Interpretable Word-Level Sentiment Analysis With Attention-Based Multiple Instance Classification Models, Chenyu Yang

Statistical Science Theses and Dissertations

In this study, our main objective is to tackle the black-box nature of popular machine learning models in sentiment analysis and enhance model interpretability. We aim to gain more insight into the decision-making process of sentiment analysis models, which is often obscure in those complex models. To achieve this goal, we introduce two word-level sentiment analysis models.

The first model is called the attention-based multiple instance classification (AMIC) model. It combines the transparent model structure of multiple instance classification and the self-attention mechanism in deep learning to incorporate the contextual information from documents. As demonstrated by a wine review dataset …

Rolling The Crypto Dice: The Interplay Of Legal Environments, Market Uncertainty, And Gambling Attitudes On Users’ Behavioral Intentions, Ayman Abdalmajeed Alsmadi, Ahmed Shuhaiber, Khaled Saleh Al-Omoush

All Works

The high volatility and inherent high-risk nature of cryptocurrency investments promote the study of the determinants of value perception and the various factors influencing individuals’ intentions regarding whether to adopt, abstain from, or continue their investments in these dynamic cryptocurrency markets. The main aim of this study is to examine the determinants of behavioral intention to continue using cryptocurrencies. In addition, it is aimed at exploring the effect of gambling attitudes on the perceived benefits and legal environment in the cryptocurrency context. An online questionnaire was developed in order to gather data from 258 respondents in the United Arab Emirates …

Adaptation Reshapes The Distribution Of Fitness Effects, Diego Tenoch Morales Lopez

Electronic Thesis and Dissertation Repository

The process of adaptation has been of interest since the XIX century, when Darwin first proposed the idea of natural selection. Since then, there has been a myriad of theoretical and empirical works that have expanded the field. From the many evolutionary insights these works have produced, a foundational idea is that spontaneous mutations in the genome of organisms can produce changes to their reproductive success that might confer an advantage for the mutant organisms with respect to their peers. Therefore, mutations drive adaptive evolution by virtue of their heritable effects on fitness. Empirical measures of the distribution of these …

A Preliminary Study On Floating Flexible Otec Cold Water Pipe, Nai Kuang Liang, Hai Kuan Peng

Journal of Marine Science and Technology

Ocean Thermal Energy Conversion (OTEC) requires a large amount of cold seawater. The traditional rigid pipe, semi-rigidly fixed onto the ship bottom is not easy to install and disassemble, so the Floating Flexible Cold Water Pipe (FFCWP) flexibly connected to the ship is proposed. A small FFCWP was designed, fabricated, and successfully installed and recovered in the sea. The flexible pipe adopts commercially available fire ventilation snake pipe. The pipe wall material strength must be improved in the future. Assuming that the drag coefficient Cd value is 1.5, a numerical calculation is employed to simulate the FFCWP attitude from the …

Machine Learning With Multi-Source Data To Predict And Explain Marine Pilot Occupational Accidents, Gokhan Camliyurt, Youngsoo Park, Daewon Kim, Won Sik Kang, Sangwon Park

Journal of Marine Science and Technology

Marine pilot occupational accidents during transfer to/from ships are the primary concern of the International Marine Pilots’ Association (IMPA) and industry professionals. There are multiple transfer methods for marine pilots, with the most common being the pilot boat. To reach the mother ship bridge, the following stages must be safely completed: car transfer, walking on the pier, pier to pilot boat, pilot transfer by boat, cutter to pilot ladder, mother ship freeboard climbing, and ship deck to the bridge. Each stage has its own risk. Previous accident records and expert opinions are commonly used to conduct a risk analysis and …

Evaluation Of Operational Performance Of Wusongkou Cruise Port Through Network Data Envelopment Analysis, Qian-Feng Wang, Guo-Ya Gan, Xin-Liang Ye, Hsuan-Shih Lee

Journal of Marine Science and Technology

As major hubs for cruise berthing and passenger transfers, cruise ports in China were developing rapidly in the years before the COVID-19 pandemic because of an ever-growing regional market. Wusongkou Cruise Port is the most important port for cruise ships in China, and this study evaluated the operational performance of this port during 2011–2020. To this end, two-stage network data envelopment analysis was conducted to evaluate the port’s operation performance; subsequently, the change trajectory of the port’s operational efficiency during 2011–2020 was determined, and the potential reasons for the identified changes are discussed. Finally, suggestions for improving the operational performance …

Interactive Effects Of Sublethal Concentrations Of Fracking Biocides And Abandoned Mine Drainage On Amphipod Behavior, Kelly Lenhart

Electronic Theses and Dissertations

This thesis examined the sublethal effects of three pollutants, namely glutaraldehyde, 4,4-dimethyloxazolidine (DMO), and abandoned mine drainage (AMD), on amphipods. The primary objective was to investigate their combined effects on amphipods. The three pollutants, despite having the potential to combine in the environment, have not been studied to determine their potential for detrimental interactive effects which could result in unexpected environmental damage.

The research employed a series of experimental setups involving controlled exposure of amphipods to varying, putatively sublethal, concentrations of the chemicals of interest. Subsequently, effects were assessed via both behavioral and feeding assessments. To facilitate this analysis, novel …

Clean Energy Transition Threatens Indigenous Land Rights, Jonnathan M. Pulla

Capstones

Indigenous communities in Jujuy, Argentina are protesting a constitutional reform that could lead to their displacement without consultation or exposure to contamination from extractive projects. The story is told from the perspective of Milagros Lamas, a 19-year-old indigenous woman who joined the movement known as the Third Malón de la Paz.

Synthesis Of Poly(Styrene-Co-Butyl Acrylate) Pickering Emulsion With Montmorillonite Nanoparticles And Its Comparison With Sodium Dodecyl Sulfate Surfactant On Affecting The Water Barrier Properties Of Coated Paper, Chidubem H. Uchefuna

Electronic Theses and Dissertations

Water-borne barrier dispersion coatings on paper have emerged as an alternative to extrusion coatings on paper due to improved recycling, high application speed, and other end of life attributes. Pigments are often added to improve the performance of dispersion coatings. The use of pigments to form a Pickering emulsion during the polymerization step for the production of a barrier coating on paper has not been discussed in the literature.

In this study, montmorillonite (MMT) pigment varied from 0-6 % pigment volume concentration (PVC) was used to synthesize dispersion coatings consisting of poly(styrene-co-butylacrylate) latex and compared with sodium dodecyl …

Introduction To Physics, Kalani Hetti

Open Educational Resources

Introduction to physics, class code PHY 114 at college of Staten Island covers general physics concepts by using very simple algebraic calculations. Topics may include scientific measurements, significant figures, estimation, units, linear and rotational motion, vectors, forces, energy, momentum, collision, impulse, projectile motion, circular motion, thermodynamics, oscillating waves, electricity and magnetism, properties of lights, reflection, refraction, atomic nuclei, and radioactivity. This course is designed to teach general concepts and laws of physics to everyday life enforcing student’s critical thinking, logical patterns, organization, and everyday life applications. In this document, all the class materials including lectures, worksheets, homework assignments, quizzes, and …

Quantifying Tidewater Glacier-Fjord Environments In The Rapidly Changing Regions Of West And South Greenland, Sydney Baratta

Electronic Theses and Dissertations

The Greenland Ice Sheet has undergone rapid mass loss over the last four decades, primarily through solid and liquid discharge at marine-terminating outlet glaciers. The acceleration of these glaciers is in part due to the increase in temperature of ocean water in contact with the glacier terminus. However, quantifying meltwater injection and heat transport can be challenging due to iceberg abundance, which threatens instrument survival and fjord accessibility. Additionally, acceleration and eventual retreat of tidewater glaciers onto land can change glacier forcing, completely altering fjord water-meltwater dynamics. Here, we couple in situ and remote sensing methods to quantify the upper-layer …

An Empirical Study Of Machine Learning Techniques For Accurate Stock Price Forecasting, Daniel Paliulis, Hari Patchigolla

Honors Scholar Theses

This paper presents a comprehensive approach to predicting future stock prices of companies using machine learning and time series analysis. The research problem is centered around addressing the complexity and emotion-driven nature of stock investment decisions. To create an objective determinant in stock decisions, we propose a machine learning model utilizing time series data from major companies, including Amazon, Apple, Google, Nvidia, Meta, Tesla, Salesforce, Intel, and Microsoft. We explore the use of Long Short-Term Memory (LSTM) neural networks, to capture the temporal dynamics of stock prices. These models are designed to process sequential data, maintaining short term and long …

Elucidating The Pd Active Sites Of Bimetallic Gold-Palladium Catalysts Using Chemisorption And Titration Techniques, Andrew T. Boucher

Electronic Theses and Dissertations

A bimetallic nanoparticle catalyst combines two different metals on an oxide support, which can increase the selectivity towards useful products that may be too tightly bound to a monometallic catalyst. To explore the surface properties of such a system, we made a group of four PdAu bimetallic catalysts with varying gold mass loadings to compare with a parent Pd catalyst. The parent catalyst was synthesized using ion exchange, and gold was added to this parent Pd catalyst using incipient wetness impregnation (IWI) to create four bimetallic catalysts. All catalysts were characterized using H₂ and CO chemisorption in tandem with …

Enhanced Mechanical Strength Of Soybean Oil-Based Non-Isocyanate Polyurethane Adhesive For Wood Application By Introducing Nanofillers, Vatsal Chaudhari

Electronic Theses & Dissertations

Polyurethane (PU) is a versatile material that finds extensive use in various industries including bedding, construction, automotive, and packaging. Historically, this particular polymer relied significantly on petrochemical resources, a practice that was considered to have negative environmental impacts. The conventional method for preparing PU involves the use of isocyanate, which is a disadvantage due to its negative impact on the environment and human health. The resolution of this problem entails identifying an appropriate substitute for petroleum-derived products that minimize their impact on both the environment and human health. The researchers earlier utilized soybean oil, for the formulation of PUs in …

Exploring Soybean Oil-Based Polyol And Effect Of Non-Halogenated Flame Retardants In Rigid Polyurethane Foam, Sahithi Kondaveeti

Electronic Theses & Dissertations

To address the increasing demand for sustainable biomaterials due to the depletion of fossil fuel resources and growing environmental concerns, a new type of biodegradable and environmentally friendly rigid polyurethane foam (RPUF) has been synthesized. These foams are derived from chemically modified soybean oil-based polyol obtained from soybean oil by epoxidation followed by a ring-opening reaction. Polyurethane foam is generally used in construction, furniture, and automobile industries but is highly flammable and releases toxic gases and smoke during combustion. In this study, a highly efficient synergistic effect halogen-free flame-retardant (FR) melamine salt, 2-carboxyethyl(phenyl)phosphinic acid melamine salt (CMA) was synthesized from …

Targeting Macrophytes: Increased Water Quality Through Optimized Vegetation Considerations For Constructed Wetlands, Austin Mcbrady

Masters Theses

This study of constructed wetland design investigated relationships between macrophyte species selection and planting density for water quality improvement. A lab-scale wetland was compared against a pilot-scale wetland in San Antonio, Texas at Mitchell Lake to measure differences in effluent water quality improvement using three native macrophyte species. Using a novel, two-phase method, a targeting macrophyte was identified from among other species based on its marked capability for improving water quality factors, then was planted in varied majority densities to compare differences in treatment effectiveness. The results of this study showed that this complimentary approach to wetland design displayed significant …

Investigation Of Zinc And Iron In Wildflower Honey, Savannah Simpson

Honors Theses

Honey acts as a valuable food source for both animals and humans. When found in contaminated environments, there is an increased likelihood that honey samples will have high metal concentrations. It has been discovered that honey concentrations in metals can be different based on location. This experiment aims to determine the amount of two valuable metals, zinc, and iron, in various honey sources. These metals can be important to the human body because they help boost immunity and allow the body to carry out the functions required for survival. However, if these elements are present in copious quantities, then it …

Novel Integrated Sachs-Wolfe Effect From Early Dark Energy, Tristan L. Smith, J. T. Giblin Jr., M. Amin, M. Gerhardinger, E. Florio, M. Cerep, S. Daniels

Physics & Astronomy Faculty Works

We study the nonlinear effects of minimally coupled, massless, cosmological scalar fields on the cosmic microwave background (CMB). These fields can exhibit postrecombination parametric resonance and subsequent nonlinear evolution leading to novel contributions to the gravitational potential. We compute the resulting contributions to the CMB temperature anisotropies through the time variation of the gravitational potential (i.e., the integrated Sachs-Wolfe (ISW) effect). We find that fields that constitute 5% of the total energy density and become dynamical at z_c ≃ 10⁴ can produce marginally observable ISW signals at multipoles ℓ ≃ 2000. Fields that become dynamical at earlier times …

Comparative Analysis Of Interacting Stepped Dark Radiation, N. Schöneberg, G. F. Abellán, T. Simon, A. Bartlett, Y. Patel, Tristan L. Smith

Physics & Astronomy Faculty Works

Models that address both the Hubble and S₈ tensions with the same mechanism generically cause a prerecombination suppression of the small scale matter power spectrum. Here we focus on two such models. Both models introduce a self-interacting dark radiation fluid scattering with dark matter, which has a step in its abundance around some transition redshift. In one model, the interaction is weak and with all of the dark matter whereas in the other it is strong but with only a fraction of the dark matter. The weakly interacting case is able to address both tensions simultaneously and provide a …

Advances In Cellulose Nanomaterial-Based Foams For Environmental Applications, Md Musfiqur Rahman

Electronic Theses and Dissertations

The use of metal-oxide nanoparticles adsorbents is limited to fixed-bed columns in industrial-scale water treatment applications. This limitation is commonly attributed to the tendency of nanoparticles to aggregate, the use of non-sustainable and inefficient polymeric resins as supporting materials, or a lack of adsorption capacity. Foams and aerogels derived from cellulose nanomaterials have unique characteristics, such as high porosity and low density, which enables their use in a variety of environmental applications, including water treatment. However, the overall use of cellulose nanomaterial-based foams in various environmental sectors is limited due to the high cost of production associated with time- and …

The Impact Of Conservation Land On Property Taxes And Municipal Budgets In Maine: A Mixed-Methods Study, Abigail Bennett

Electronic Theses and Dissertations

This study is an interdisciplinary project done in collaboration with the Municipal Budget and Conservation Working group, a group of stakeholders that formed in 2018 to study conservation and town budgets. We use mixed methods to explore the impacts of conservation and municipal budgets in Maine. We use regression analysis on 21 years of panel data to identify causal relationships between conservation and mill rates, controlling for economic and town budget factors. We found statistically significant but small effects on average, with a 1% increase in conserved acres in a town associated with average tax bill increases of $1 or …