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Articles 5641 - 5670 of 7943
Full-Text Articles in Physical Sciences and Mathematics
Virtual Fencing Predictable For Cattle? A Simple Method To Test Whether And How Fast Cattle Can Learn The Association Between Acoustic Signal And Electric Pulse, D. Hamidi, M. Komainda, N. Grinnell, L. Wilms, F. Reisch, J. Horn, M. Hamidi, J. Isselstein
Virtual Fencing Predictable For Cattle? A Simple Method To Test Whether And How Fast Cattle Can Learn The Association Between Acoustic Signal And Electric Pulse, D. Hamidi, M. Komainda, N. Grinnell, L. Wilms, F. Reisch, J. Horn, M. Hamidi, J. Isselstein
IGC Proceedings (1993-2023)
Virtual fencing (VF) offers promising future prospects for improved grazing management as it has the potential to simplify fencing. VF lines are easily drawn and shifted via GPS coordinates. A VF collar emits an acoustic signal when the animal approaches the VF line. The signal stops immediately when the animal turns around. If the animal continues to move towards the VF line, a short electric pulse is emitted. A teaching and an operating mode are provided by the VF collars. The animals automatically change mode when they respond correctly to 20 consecutive acoustic signals without receiving an electric pulse. A …
More Than A Fencing System? Testing The Validity Of Virtual Fencing Collars For Animal Monitoring On Pasture, D. Hamidi, M. Komainda, N. Grinnell, F. Reisch, J. Horn, M. Hamidi, I. Traulsen, J. Isselstein
More Than A Fencing System? Testing The Validity Of Virtual Fencing Collars For Animal Monitoring On Pasture, D. Hamidi, M. Komainda, N. Grinnell, F. Reisch, J. Horn, M. Hamidi, I. Traulsen, J. Isselstein
IGC Proceedings (1993-2023)
High labour requirements for fencing and animal monitoring appear to be general obstacles for the wider use of pastureland for grazing livestock. Virtual fencing (VF) enables a less laborious pasture management. Fence lines can be easily drawn and moved using GPS data. The advantages of VF for reducing the labour inherent to controlled grazing management are obvious. Potential additional animal monitoring opportunities arising from such a VF system that uses real-time GPS data have not yet been studied. Lying is seen as an indicator for assessing comfort or restlessness of cattle. Therefore, we focus on lying behavior in this evaluation. …
Forage And Grazinglands Extension: Training The Next Generation Of Specialists, D. W. Hancock
Forage And Grazinglands Extension: Training The Next Generation Of Specialists, D. W. Hancock
IGC Proceedings (1993-2023)
This invited talk provides a perspective on what is required to excel in the role as an Extension Specialist. In the USA, most such Extension Specialists are tenure-track faculty, and have state-wide or even multi-state responsibilities. Advice is given on how to balance the high expectations of such a faculty appointment while providing appropriate recommendations to farmers/ranchers and service providers in the forage and grazinglands industry. This talk will offer one former Extension Specialist’s perspective on the skills, experience, and persona required to begin a successful career as a Forage and Grazinglands Extension Specialist. Additional exposition will be given on …
An Assessment Of Young Cattle Behaviour And Welfare In A Virtual Fencing System, C. Holohan, A. Gordon, R. Palme, S. Buijs, F. Lively
An Assessment Of Young Cattle Behaviour And Welfare In A Virtual Fencing System, C. Holohan, A. Gordon, R. Palme, S. Buijs, F. Lively
IGC Proceedings (1993-2023)
Virtual fencing is a novel technology which uses a combination of audio and electrical stimuli to contain grazing livestock within a GPS boundary. There are however some concerns around the use of such a technology and its potential effects on the behaviour and welfare of animals. To investigate this, 64 dairy-origin calves were assigned to one of two treatments in a randomised complete block design, with 4 groups of 8 calves per treatment. The two treatments were virtual fencing (VF) and electric fencing (EF). The experimental period lasted 31 days in total, consisting of a 10 day training period and …
Herding Livestock – The Phoenix Rises From The Ashes? Digital Herding As A Future Tool For Grazing Livestock, J. Horn, R. Reisch, M. Komainda, P. Riedel, J. Isselstein
Herding Livestock – The Phoenix Rises From The Ashes? Digital Herding As A Future Tool For Grazing Livestock, J. Horn, R. Reisch, M. Komainda, P. Riedel, J. Isselstein
IGC Proceedings (1993-2023)
Today, sustainable management of grazing livestock requires high efforts in management and fencing. Nowadays, several developments in digital technologies for herding grazing animals are arising. We conducted a systematic review on current developments in digital technologies for managing grazing animals within the landscape. We mainly focused on cattle (Bos taurus) and sheep (Ovis aries). We highlight the most promising developments of virtual fencing used in recent research to evaluate effectiveness, animal behaviour and welfare. Moreover, we highlight current research in digital herding by drones and robots. We discuss the potential and current limitations of digital tools …
Development Of Megathyrsus Maximus Genotypes For Intensification Of Cattle Rearing In Brazil, Liana Jank, M. F. Santos, Sanzio Carvalho Barrios, Cacilda Borges Do Valle, Rosangela Maria Simeão
Development Of Megathyrsus Maximus Genotypes For Intensification Of Cattle Rearing In Brazil, Liana Jank, M. F. Santos, Sanzio Carvalho Barrios, Cacilda Borges Do Valle, Rosangela Maria Simeão
IGC Proceedings (1993-2023)
Megathyrsus maximus is a forage species used over 30 million hectares in Brazil and in the surrounding countries for intensification of the cattle production systems. Due to the large area and distinct biomes in which it is used, there is a need to continuously develop more productive and adapted cultivars to each biome and use. Three apomictic accessions were crossed with five sexual plants at Embrapa Beef Cattle in Campo Grande, MS, Brazil in 2014. More than 1100 hybrids were planted in a spaced-plant field and evaluated visually for regrowth after cuts and for disease and pest damage. In 2016, …
Scaled Datasets Through Leveraging Technology Better Represent Plant Communities Classified Within National Land Cover Database (Nlcd), D. M. Johnston, D. B. Murray, Y. Y. Tsang
Scaled Datasets Through Leveraging Technology Better Represent Plant Communities Classified Within National Land Cover Database (Nlcd), D. M. Johnston, D. B. Murray, Y. Y. Tsang
IGC Proceedings (1993-2023)
Technological advances in remote sensing have allowed for access to and application of large- scale datasets of plant communities using cover classification and chlorophyll content measurement with the use of multispectral sensors and vegetation indices. The United States’ primary remote sensing platform Landsat Thematic Mapper is a series of satellites providing 30-meter resolution imagery of the Earth’s surface. Efforts have been made to best utilize Landsat derivative National Land Cover Database (NLCD) datasets and provide spatial resolution commensurate with the needs of plant ecologists and range managers. However, usage of 30-meter spatial resolution imagery and indices does not allow detection …
Heavy Grazing Significantly Reduced The Temporal Stability Of Aboveground Biomass, X. Ju, T. T. Shen, Q. Wu, G. D. Han
Heavy Grazing Significantly Reduced The Temporal Stability Of Aboveground Biomass, X. Ju, T. T. Shen, Q. Wu, G. D. Han
IGC Proceedings (1993-2023)
The stability of a plant community is the embodiment of the dynamic balance achieved by the interaction between populations in the form of competition or mutual benefit. Temporal stability refers to the ratio of the average value to the variance of the biomass of the population or community. For grassland ecosystems, the stability of the grassland plant community is the basis for its survival and functional performance, and is the key factor affecting its structure and function. In order to study the impact of grazing on the temporal stability of aboveground biomass of desert steppe, this study used a completely …
Migration And Colonization Characteristics Of Endophytic Tracer Rhizobia To The Reproductive Organs Of Alfalfa, W. J. Kang, S. L. Shi, Y. T. Zhang, L. Y. Chen
Migration And Colonization Characteristics Of Endophytic Tracer Rhizobia To The Reproductive Organs Of Alfalfa, W. J. Kang, S. L. Shi, Y. T. Zhang, L. Y. Chen
IGC Proceedings (1993-2023)
Legume seeds are the product of long-term natural selection and the co-evolution of rhizobia and seeds. They are more competitive than the native rhizobia in constructing symbiotic nitrogen-fixing systems with host plants. However, the paths and impact factors of rhizobia invasion and migration in plants, as well as colonization in seeds, are unclear. Here, alfalfa cultivars WL343HQ and Gannong 5, and three cyan fluorescent protein-tagged rhizobia (FTR), 3436f, 12531f and gn5f were used as materials. The effects of potassium dihydrogen phosphate (KH2PO4) and fulvic acid (FA) on the migration and colonization of FTR in the reproductive organs of field plants …
Spring Grass Availability And Silage Supplementation Impact On Dry Matter Intake And Enteric Methane Emissions In Grazing Dairy Cattle, M. Kennedy, S. Walsh, T. M. Boland, M. Egan
Spring Grass Availability And Silage Supplementation Impact On Dry Matter Intake And Enteric Methane Emissions In Grazing Dairy Cattle, M. Kennedy, S. Walsh, T. M. Boland, M. Egan
IGC Proceedings (1993-2023)
Enteric methane (CH4) emissions were measured in forty spring calving cows offered one of two (n=20) contrasting diets (High Grass; HG, Low Grass; LG) over 10 weeks in early lactation (8th February – 18th April 2021). All cows were blocked for breed and parity and balanced on milk production, economic breeding index (EBI), bodyweight and body condition score and randomly allocated to treatments. The HG grazing treatment cows were offered their full daily nutrient requirement from grazed grass and concentrate with no silage supplementation. The LG grazing treatment cows were offered a restricted (~60%) amount of their daily nutrient requirement …
Role Of Social Media And Digital Resources In Extension, L. L. Baxter
Role Of Social Media And Digital Resources In Extension, L. L. Baxter
IGC Proceedings (1993-2023)
Social media and digital resources can be powerful tools for Extension personnel as they can enable forage-livestock researchers and Extension specialists to connect with a wide audience of producers, Extension personnel, colleagues, and industry partners. Online platforms that provide a space for Extension personnel to deliver timely information and digital resources have been critical for continuing producer education in today’s environment. This presentation in the thematic session on “Understanding the role of social media and digital resources in forage education and promotion” will focus on the role social media and digital resources play in Extension. There are a host of …
Creating An Educational Experience That Fosters Diversity And Inclusion, M. M. Kohmann
Creating An Educational Experience That Fosters Diversity And Inclusion, M. M. Kohmann
IGC Proceedings (1993-2023)
Demographic, intellectual, and individual diversity have been linked to increase in innovation, problem-solving, critical thinking, and economic gains. However, there are multiple challenges associated with recruiting, retaining, and advancing underrepresented groups in Science, Technology, Engineering, and Mathematics (STEM). Studies have indicated negative implicit bias against women and minorities in terms of their perceived competence, worthiness to be hired, and payment irrespective to their qualification. Additionally, lack of mentoring and access to personal capital often hinder students’ academic advancement in STEM. However, there have been multiple intentional, recent efforts to increase and foster diversity in sciences. Some of the most effective …
Modeling The Biomass Production Of Grasslands Of Wallonia According To Their Functional Type, U. Kokah Essomandan, D. Knoden, B. Dumont, J. Bindelle
Modeling The Biomass Production Of Grasslands Of Wallonia According To Their Functional Type, U. Kokah Essomandan, D. Knoden, B. Dumont, J. Bindelle
IGC Proceedings (1993-2023)
Permanent grasslands are complex ecosystems which respond with a great variability - in terms of specific richness - to soil type and management strategies. Modelling is a valuable tool to explore these relationships. Our work consisted in adapting the Moorepark St Gilles grass growth model (MoSt GG) designed to model Lolium perenne plant functional type (PFT) pastures (PFT A) to a different PFT (Dactylis glomerata, PFT B) through literature-based parametrization. The model was evaluated under Walloon (Belgium) conditions using growth trials from 2014 to 2018 in two sites with contrasting pedo-climatic conditions. Three to five cuts were performed …
Assessment Of Soil Structure And Root Patterns By Means Of Micro-X-Ray Computed Tomography In Temperate Grassland Sites, K. Kuka, M. Joschko
Assessment Of Soil Structure And Root Patterns By Means Of Micro-X-Ray Computed Tomography In Temperate Grassland Sites, K. Kuka, M. Joschko
IGC Proceedings (1993-2023)
Grassland sites are important ecosystems delivering essential ecosystem services such as carbon storage and filtering of water. Adequate management necessitates a better understanding of soil ecological processes in grassland ecosystems. Of special interest is the relationship between soil structure and root development. In a project within the Biodiversity Exploratory Initiative (http://www.biodiversity-exploratories.de), undisturbed soil cores from 31 grassland plots from Swabian Alb Biodiversity exploratory in Germany were investigated by means of X-ray micro computed tomography. This allows the simultaneous determination of soil physical and root parameters in one sample. VG StudioMax® version 2.1 was used to apply a combination of histogram …
Spatio-Temporal Dynamics Of The Dual-Purpose Cattle Value Chain In The Colombian Amazonas, A. Leinert, S. Burkart
Spatio-Temporal Dynamics Of The Dual-Purpose Cattle Value Chain In The Colombian Amazonas, A. Leinert, S. Burkart
IGC Proceedings (1993-2023)
The cattle sector plays an important role in the economy of the Caquetá department, located in the Colombian Amazon. However, the predominantly extensive production system is associated with low productivity and negative environmental impacts, such as land degradation, greenhouse gas emissions, and deforestation. Efforts to introduce improved practices (e.g., improved forages or silvopastoral systems) have been made over the last decades, but adoption rates remain low. Though several studies have analyzed the cattle value chain (VC) to enhance the understanding of adoption barriers, the heterogeneity of farmers has been considered only marginally when trying to explain their adoption behavior. To …
Predicting Forage Provision Of Grasslands Across Climate Zones By Hyperspectral Measurements, F. A. Männer, J. Muro, J. Ferner, S. Schmidtlein, A. Linstädter
Predicting Forage Provision Of Grasslands Across Climate Zones By Hyperspectral Measurements, F. A. Männer, J. Muro, J. Ferner, S. Schmidtlein, A. Linstädter
IGC Proceedings (1993-2023)
The potential of grasslands’ fodder production is a crucial management measure, while its quantification is still laborious and costly. Remote sensing technologies, such as hyperspectral field measurements, enable fast and non-destructive estimation. However, such methods are still limited in transferability to other locations or climatic conditions. With this study, we aim to predict forage nutritive value, quantity, and energy yield from hyperspectral canopy reflections of grasslands across three climate zones. We took hyperspectral measurements with a field spectrometer from grassland canopies in temperate, tropical and semi-arid grasslands, and analyzed corresponding biomass samples for their quantity (BM), metabolizable energy content (ME) …
Themeda Triandra As A Perennial Seed Crop In South-Eastern Australia: What Are The Agronomic Possibilities And Constraints, And Future Research Needs?, D. Male, J. Hunt, C. Celestina, J. Morgan, D. Gupta, Dja Dja Wurrung People
Themeda Triandra As A Perennial Seed Crop In South-Eastern Australia: What Are The Agronomic Possibilities And Constraints, And Future Research Needs?, D. Male, J. Hunt, C. Celestina, J. Morgan, D. Gupta, Dja Dja Wurrung People
IGC Proceedings (1993-2023)
In Australia, the development of native perennial seed crops is an area of increasing interest. Reasons for this include the production of high-value seed, the significance of native plants to Aboriginal people and the importance of diversified cropping in building more resilient farming systems. One species of interest is Themeda triandra, a C4 perennial tussock grass that dominated grasslands and woodlands across Australia prior to European invasion. Djaara, the traditional owner group representing the Dja Dja Wurrung people of Djandak (Dja Dja Wurrung country in central Victoria), is one group who seek to return T. triandra to the landscape …
Quality Of Life In Orthodontics, Claudia Eisenhuth, Gabriel Eisenhuth, Connor Schwartz, Amir Mohajeri, Man Hung, Tiffany Nelson, Ryann Glenn
Quality Of Life In Orthodontics, Claudia Eisenhuth, Gabriel Eisenhuth, Connor Schwartz, Amir Mohajeri, Man Hung, Tiffany Nelson, Ryann Glenn
Annual Research Symposium
Orthodontic treatment goes beyond mere cosmetic enhancement; it significantly impacts various aspects of an individual's quality of life. Beyond the physical benefits of improved oral function and prevention of dental issues, orthodontics also yields profound psychological benefits. Aligned teeth enhance self-confidence, reduce social anxiety, and contribute to better relationships and professional opportunities. Moreover, addressing dental concerns through orthodontic treatment reduces psychological distress and promotes overall happiness and satisfaction. Real-life case studies vividly illustrate the transformative effects of orthodontic interventions, emphasizing the importance of considering quality of life outcomes in dental care.
Subaqueous Carbonate Speleothems As Paleotemperature Archives – Clumped Isotope Thermometry And Stable Isotope Compositions Of Inclusion-Hosted Water, Attila Demeny, Ágnes Berentés, László Rinyu, Ivett Kovács, Gergely Surányi, Magdolna Virág
Subaqueous Carbonate Speleothems As Paleotemperature Archives – Clumped Isotope Thermometry And Stable Isotope Compositions Of Inclusion-Hosted Water, Attila Demeny, Ágnes Berentés, László Rinyu, Ivett Kovács, Gergely Surányi, Magdolna Virág
International Journal of Speleology
Clumped isotope measurements of carbonates and stable isotope analyses of water trapped in fluid inclusions are both promising techniques to determine carbonate formation temperatures. Cave-hosted carbonate deposits (speleothems) are excellent targets for such studies, but kinetic fractionations and diagenetic influences frequently deteriorate the temperature data obtained from these methods. However, subaqueous carbonate deposits may provide reliable data, as kinetic fractionations are less significant in underwater environments. In this study, subaqueous speleothems, whose formation temperatures were directly measured in the water, were investigated. Additionally, temperatures calculated from the oxygen isotope fractionations between calcite and fluid inclusion-hosted water were compared with clumped …
The Role Of Humor In Sustainability: Well-Being, (In)Equity, And Community, Mia Ocean
The Role Of Humor In Sustainability: Well-Being, (In)Equity, And Community, Mia Ocean
Sustainability Research & Practice Seminar Presentations
Professor Mia Ocean, Graduate Social Work, shares an interactive presentation on The Role of Humor in Sustainability: Focusing on Well-Being, (In)equity, and Community
Electrocatalytic Asymmetric Nozaki-Hiyama-Kishi Decarboxylative Coupling: Scope, Applications, And Mechanism, Yang Gao, Baiyang Jiang, Nathan C. Friede, Arianne C. Hunter, Dylan G. Boucher, Shelley D. Minteer, Matthew S. Sigman, Sarah E. Reisman, Phil S. Baran
Electrocatalytic Asymmetric Nozaki-Hiyama-Kishi Decarboxylative Coupling: Scope, Applications, And Mechanism, Yang Gao, Baiyang Jiang, Nathan C. Friede, Arianne C. Hunter, Dylan G. Boucher, Shelley D. Minteer, Matthew S. Sigman, Sarah E. Reisman, Phil S. Baran
Chemistry Faculty Research & Creative Works
The first general enantioselective alkyl-Nozaki-Hiyama-Kishi (NHK) coupling reactions are disclosed herein by employing a Cr-electrocatalytic decarboxylative approach. Using easily accessible aliphatic carboxylic acids (via redox-active esters) as alkyl nucleophile synthons, in combination with aldehydes and enabling additives, chiral secondary alcohols are produced in a good yield with high enantioselectivity under mild reductive electrolysis. This reaction, which cannot be mimicked using stoichiometric metal or organic reductants, tolerates a broad range of functional groups and is successfully applied to dramatically simplify the synthesis of multiple medicinally relevant structures and natural products. Mechanistic studies revealed that this asymmetric alkyl e-NHK reaction was enabled …
Comment On “Photons Can Tell ‘Contradictory’ Answer About Where They Have Been”, Gregory Reznick, Carlotta Versmold, Jan Dziewior, Florian Huber, Harald Weinfurter, Justin Dressel, Lev Vaidman
Comment On “Photons Can Tell ‘Contradictory’ Answer About Where They Have Been”, Gregory Reznick, Carlotta Versmold, Jan Dziewior, Florian Huber, Harald Weinfurter, Justin Dressel, Lev Vaidman
Mathematics, Physics, and Computer Science Faculty Articles and Research
Yuan and Feng (Eur. Phys. J. Plus 138:70, 2023) recently proposed a modification of the nested Mach–Zehnder interferometer experiment performed by Danan et al. (Phys. Rev. Lett. 111:240402, 2013) and argued that photons give “contradictory” answers about where they have been, when traces are locally imprinted on them in different ways. They concluded that their results are comprehensible from what they call the “three-path interference viewpoint,” but difficult to explain from the “discontinuous trajectory” viewpoint advocated by Danan et al. We argue that the weak trace approach (the basis of the “discontinuous trajectory” viewpoint) provides a consistent explanation of the …
A Case For Hope In A Warming World, Noreen L. Herzfeld
A Case For Hope In A Warming World, Noreen L. Herzfeld
Reuter Professorship of Science and Religion Publications
It is difficult to feel hopeful in a rapidly warming world. But hope is not just a feeling. It is an active verb, one that calls for courage, solidarity, a clear vision, and hard work. First, knowing that each fraction of a degree counts, humanity is called not to despair but to use every technology and means, technologies we already have. Second, we can be encouraged by a vision of a new world and society that works for everyone. Third, we can be heartened by nature’s resilience and an evolutionary theology that looks toward the future.
Heavy Metal Movement Through Insect Food Chains In Pristine Thermal Springs Of Yellowstone National Park, Braymond Adams, John Bowley, Monica Rohwer, Erik Oberg, Kelly Willemssens, Wendy Wintersteen, Robert K.D. Peterson, Leon G. Higley
Heavy Metal Movement Through Insect Food Chains In Pristine Thermal Springs Of Yellowstone National Park, Braymond Adams, John Bowley, Monica Rohwer, Erik Oberg, Kelly Willemssens, Wendy Wintersteen, Robert K.D. Peterson, Leon G. Higley
School of Natural Resources: Faculty Publications
Yellowstone National Park thermal features regularly discharge various heavy metals and metalloids. These metals are taken up by microorganisms that often form mats in thermal springs. These microbial mats also serve as food sources for invertebrate assemblages. To examine how heavy metals move through insect food webs associated with hot springs, two sites were selected for this study. Dragon-Beowulf Hot Springs, acid-sulfate chloride springs, have a pH of 2.9, water temperatures above 70 oC, and populations of thermophilic bacterial, archaeal, and algal mats. Rabbit Creek Hot Springs, alkaline springs, have a pH of up to 9, some water temperatures …
Inferring Binary Parameters With Dual-Line Gravitational Wave Detection From Tight Inspiraling Double Neutron Stars, Wen-Fan Feng, Jie-Wen Chen, Tan Liu, Yan Wang, Soumya D. Mohanty
Inferring Binary Parameters With Dual-Line Gravitational Wave Detection From Tight Inspiraling Double Neutron Stars, Wen-Fan Feng, Jie-Wen Chen, Tan Liu, Yan Wang, Soumya D. Mohanty
Physics and Astronomy Faculty Publications and Presentations
Neutron star (NS) binaries can be potentially intriguing gravitational wave sources, with both high- and low-frequency radiation from the possibly aspherical individual stars and the binary orbit, respectively. The successful detection of such a dual-line source could provide fresh insights into binary geometry and NS physics. In the absence of electromagnetic observations, we develop a strategy for inferring the spin-orbit misalignment angle using the tight dual-line double NS system under the spin-orbit coupling. Based on the four-year joint detection of a typical dual-line system with the Laser Interferometer Space Antenna and Cosmic Explorer, we find that the misalignment angle and …
Recent Advances And Applications Of Nanostructured Membranes In Water Purification, Didem Aydin, İlkay Hilal Gübbük, Mustafa Ersöz
Recent Advances And Applications Of Nanostructured Membranes In Water Purification, Didem Aydin, İlkay Hilal Gübbük, Mustafa Ersöz
Turkish Journal of Chemistry
In recent years, water pollution caused by hazardous materials such as metals, drugs, pesticides, and insecticides has become a very serious environmental and health problem that needs to be addressed urgently. The nutritional needs associated with the increasing population also increase the demand for water use and rapidly increase the rate of freshwater consumption. Since most of the water in the universe is in the form of sea water, which cannot be directly used, freshwater resources are limited ,compared to the existing available water. When addressing the purification of all kinds of pollution in environmental research, nanostructured membranes attract attention …
Chromium Speciation In Water Using Magnetic Polyaniline Nanoparticles Coupled With Microsampling Injection-Flame Atomic Absorption Spectroscopy, Osman Çaylak
Turkish Journal of Chemistry
The chromium speciation procedure was optimized using magnetic polyaniline nanoparticles (Fe3O4@PANI NPs) solid-phase extraction coupled with microsampling injection-flame atomic absorption spectrometry (MIS-FAAS). Chromium speciation was successfully achieved by Fe3O4@PANI NPs at pH 8.0. The recoveries obtained for Cr(III) and Cr(VI) were above 95% and under 5%, respectively. Recoveries of over 95% for Cr(III) from 40.0 mL of the sample were obtained using 25 mg Fe3O4@PANI NPs and 500 µL of 0.2% (w/v) thiourea (TU) solution prepared in 2 mol L–1 HCl as eluent. Total chromium as Cr(III) was extracted quantitatively after reducing the Cr(VI) to Cr(III). The linear range, detection …
The Effect Of Partial Substitution Of Noble Metal (Pd) At The B Site Of La0.6sr0.4feo3 As A Supercapacitor Electrode Material, Nagihan Deli̇baş, Turgut Süleymanoğlu
The Effect Of Partial Substitution Of Noble Metal (Pd) At The B Site Of La0.6sr0.4feo3 As A Supercapacitor Electrode Material, Nagihan Deli̇baş, Turgut Süleymanoğlu
Turkish Journal of Chemistry
Sol-gel combustion was used to produce the perovskite-type La0.6Sr0.4FeO3 (LSF) and La0.6Sr0.4Fe0.9Pd0.1O3 (LSFP) materials and assessed as supercapacitor electrodes. The synthesized materials’ crystal structure, morphology, and electrochemical performance were thoroughly analyzed. The partial substitution of Pd in the B site of the LSF structure affected the electrochemical properties of this compound and improved its performance. In fact, the greatest effect of Pd substitution was on the content of oxygen vacancies, which are known as the active sites of the perovskite surface in the supercapacitor cell. The specific capacitance obtained for the sample containing Pd was about 80 F.g–1 at a …
N-(2-Aminobenzoyl)Benzotriazole Mediated Synthesis Of 3- Acyl-2-Alkyl(Aryl)-4-Hydroxyquinolines And 3-Acylamino-4(3h) Quinazolinones, İlbilge Merve Şenol, Sevtem Gökbulut Satioğlu, İlhami Çeli̇k
N-(2-Aminobenzoyl)Benzotriazole Mediated Synthesis Of 3- Acyl-2-Alkyl(Aryl)-4-Hydroxyquinolines And 3-Acylamino-4(3h) Quinazolinones, İlbilge Merve Şenol, Sevtem Gökbulut Satioğlu, İlhami Çeli̇k
Turkish Journal of Chemistry
New methods have been developed for the synthesis of the substituted quinolines and quinazolinones derivatives by utilizing N-(2-aminobenzoyl)benzotriazoles under mild reaction conditions. 3-Acyl-2-alkyl(aryl)-4-hydroxyquinolines were obtained in modarete yields by the reaction of N-(2-aminobenzoyl)benzotriazoles and diketones in the presence of tert-BuOK. 3-Acylamino-4(3H) quinazolinones were obtained in good yields via N-(2-aminobenzoyl)benzotriazoles, orthoester and hyrazides in one-pot.
Low Fine-Tuning With Heavy Higgsinos In Yukawa Unified Susy Guts, Cem Salih Ün
Low Fine-Tuning With Heavy Higgsinos In Yukawa Unified Susy Guts, Cem Salih Ün
Turkish Journal of Physics
The work presented considers a class of minimally constructed Yukawa unified SUSY GUTs - NUHM2 - and explores their implications when their soft supersymmetry breaking Lagrangian is generalized by the nonholomorphic terms which provide extra contributions to the Higgsino mass and couple the supersymmetric scalar fields to the wrong Higgs doublets. With such a simple extension, it can be found several regions with interesting implications which cannot be realized in the usual restricted models. It is observed that the Yukawa unification solutions can be compatible with a relatively light mass spectrum and acceptable low fine-tuning measurements. In the restricted models …