Physical Sciences and Mathematics Commons^™

High-Capacity Anode For Sodium-Ion Batteries Using Hard Carbons Derived From Polyurea-Cross-Linked Silica Xerogel Powders, Santhoshkumar Sundaramoorthy, Rushi U. Soni, Stephen Yaw Owusu, Sutapa Bhattacharya, A. B.M.Shaheen Ud Doulah, Vaibhav A. Edlabadkar, Chariklia Sotiriou-Leventis, Amitava Choudhury

Chemistry Faculty Research & Creative Works

In this article, we demonstrated carbon aerogel-silica composites derived from polyurea-cross-linked silica xerogel powders (C-PUA@silica) as anodes for Na-ion batteries. These xerogel-derived hard carbons with embedded silica showed a stable high capacity. Of the several hard carbon samples derived at different temperatures, the pyrolyzed sample at 800 °C (C-PUA@silica-800) showed a high capacity of 236 mAh/g at a current density of 10 mA/g and a stable cycle-life at 200 mAh/g. The galvanostatic charge-discharge curves displayed a sloping voltage profile reminiscent of the adsorption mechanism of Na+ storage. On the other hand, higher temperature-pyrolyzed samples at 1300 °C (C-PUA@silica-1300) displayed a …

Tailored (La0.2pr0.2nd0.2tb0.2dy0.2)2ce2o7 As A Highly Active And Stable Nanocatalyst For The Oxygen Evolution Reaction, Sreya Paladugu, Ibrahim Munkaila Abdullahi, Palani Raja Jothi, Bo Jiang, Manashi Nath, Katharine Page

Chemistry Faculty Research & Creative Works

Designing highly active and robust catalysts for the oxygen evolution reaction is key to improving the overall efficiency of the water splitting reaction. It has been previously demonstrated that evaporation induced self-assembly (EISA) can be used to synthesize highly porous and high surface area cerate-based fluorite nano catalysts, and that substitution of Ce with 50% rare earth (RE) cations significantly improves electrocatalyst activity. Herein, the defect structure of the best performing nano catalyst in the series are further explored, Nd₂Ce₂O₇, with a combination of neutron diffraction and neutron pair distribution function analysis. It is …

A Comparative Study Of Cationic Copper(I) Reagents Supported By Bipodal Tetramethylguanidinyl-Containing Ligands As Nitrene-Transfer Catalysts, Suraj Kumar Sahoo, Brent Harfmann, Himanshu Bhatia, Harish Singh, Srikanth Balijapelly, Amitava Choudhury, Pericles Stavropoulos

Chemistry Faculty Research & Creative Works

The Bipodal Compounds [(TMG2biphenN-R)CuI-NCMe](PF6) (R = Me, Ar (4-CF3Ph-)) And [(TMG2biphenN-Me)CuI-I] Have Been Synthesized With Ligands That Feature A Diarylmethyl- And Triaryl-Amine Framework And Superbasic Tetramethylguanidinyl Residues (TMG). The Cationic Cu(I) Sites Mediate Catalytic Nitrene-Transfer Reactions Between The Imidoiodinane PhI = NTs (Ts = Tosyl) And A Panel Of Styrenes In MeCN, To Afford Aziridines, Demonstrating Comparable Reactivity Profiles. The Copper Reagents Have Been Further Explored To Execute C-H Amination Reactions With A Variety Of Aliphatic And Aromatic Hydrocarbons And Two Distinct Nitrene Sources PhI = NTs And PhI = NTces (Tces = 2,2,2-Trichloroethylsulfamate) In Benzene/HFIP (10:2 V/v). Good Yields …

Integration Of 3d Structural Modelling And Well Logging Analysis In The Evaluation Of October Oil Field, Gulf Of Suez, Egypt, Lamiaa Yahia, Mostafa Toni, Farouk I. Metwalli, M. H. Mansour, Amir Ismail

Trends in advanced sciences and technology

An extensive study of the NUBIA and MAT reservoirs, incorporating numerous data sources, enhances the accuracy of production forecasts for hydrocarbon exploration and development. This study aims to integrate seismic and well data for re-assessment and to delineate the geological and petrophysical characteristics of the October oil field which is one of the most productive in the central Gulf of Suez, but it has recently witnessed a drop in output in some regions, and some wells have begun to depletion. While facies modeling enabled the spatial distribution of lithologic facies inside the constructed 3D structural model, which reflected two types …

Estimating Soil Texture By Hand, Department Of Primary Industries And Regional Development, Western Australia

Natural resources factsheets

Estimating or measuring soil texture provides valuable information about soil properties affecting crop and pasture growth. Soil texture affects the movement and availability of air, nutrients, and water in soil. A simple and quick measure of soil texture is the way a soil feels when manipulated by hand.

The department recommends laboratory testing of soil texture (and other factors) for all critical soil uses, including farm dam construction and claying.