Physical Sciences and Mathematics Commons^™

Exploring Colonial Identity And A Growing Ecoconsciousness On The Great Plains, Charles Hiebner

Department of English: Dissertations, Theses, and Student Research

This thesis is an exploration of my journey from an unapologetic industrial agriculturalist to a more environmentally sensitive citizen. I now recognize the inescapable relationship between colonialism and environmental issues surrounding water resources on the Great Plains and how these intertwined issues affect both the planet and its inhabitants. Specifically, I look at literature as both the catalyst and sustainer of my still-growing environmental and social consciousness. From important literary works encountered as a youth to the ecocriticism and explorations of social justice of the readings I engage in today, I examine how these literary choices have led me to …

A Fishery, A Sanctuary, A Sink, And A Disaster: The Often Hapless Management Of California's Salton Sea, William M. Mclaren

Will McLaren

Over a century ago, a series of questionable management decisions and water-diversion engineering mistakes in Southern California produced an “unnatural” waterbody called the Salton Sea. Since then, the Sea has served as a recreational destination with fluctuating popularity, a sanctuary for migratory birds, a sink for agricultural runoff and urban wastewater, and one of the most productive tilapia and corvina fisheries in the United States. However, the Sea’s resources and associated uses have steadily deteriorated since its formation.

The contrast between the ethics that drove resource management decisions at the time of the Salton Sea’s formation to those employed in …

Size-Dependent Chemical Reactivity Of Silicon Nanocrystals With Water And Oxygen, Melanie L. Mastronardi, Kenneth K. Chen, Kristine Liao, Gilberto Casillas, Geoffrey A. Ozin

Australian Institute for Innovative Materials - Papers

A detailed investigation examines how the size of allylbenzene-capped silicon nanocrystals (ncSi:AB) affects their chemical reactivity with gaseous O₂, H₂O, and O₂/H₂O as probed by in situ luminescence spectroscopy. Specifically, changes in the photoluminescence (PL) of size-separated ncSi:AB are monitored through alterations of their PL absolute quantum yield (AQY) as well as the wavelength and intensity of their PL spectra over time. These experiments, conducted under both continuous and intermittent illumination, help elucidate the roles of O₂, H₂O, and mixtures of O₂/H₂O, with respect …

San Diego’S Options For Alternate Sources Of Water: A Comparative Analysis Of Water Recycling And Desalination As Alternative Methods To Importing Water, Alana O. Pokorny

Scripps Senior Theses

This paper describes the processes, methods, backgrounds, and economic challenges, of Desalination and Water Recycling and provide current examples of both. To create a baseline with which to compare the two methods, I will also delve into the history of California water policy. This complicated past is the reason water importation into Southern California remains the main method of obtaining water. Yet, as the current drought continues and technology advances, the need for imported water will become obsolete as the methods for recycling and desalinating water become less expensive, more convenient and more equitable. In the conclusion, all the methods …

Stakeholder Perceptions Of Sustainable Value And Water Conservation: A Case Study Of Social, Environmental, And Economic Concerns In The Rookery Bay Estuary, Bruce Victor Lilyea

Department of Conflict Resolution Studies Theses and Dissertations

Stakeholders’ perceptions of social, environmental, and economic concerns in the Rookery Bay Estuary were examined through this research. The purpose of this study was to discover the shared value and common resolution responses for the people of the Rookery Bay area that can extend to other local environmental management scenarios. Using Stakeholder Theory, Rational Choice Theory, Symbolic Interactionism, and Systems Theory as theoretical foundation, the following research questions were considered: RQ1) What are the points of shared value of community stakeholders facing environmental management issues? RQ2) How do the perspectives of the community stakeholders toward the social, environmental, and economic …

Hierarchical Heteroaggregation Of Binary Metal-Organic Gels With Tunable Porosity And Mixed Valence Metal Sites For Removal Of Dyes In Water, Asif Mahmood, Wei Xia, Nasir Mahmood, Qingfei Wang, Ruqiang Zou

Australian Institute for Innovative Materials - Papers

Hierarchical heteronuclear metal-organic gels (MOGs) based on iron (Fe) and aluminium (Al) metal-organic framework (MOF) backbones bridged by tri-carboxylate ligands have firstly been synthesized by simple solvothermal method. Monometallic MOGs based on Fe or Al give homogenous monoliths, which have been tuned by introduction of heterogeneity in the system (mismatched growth). The developed gels demonstrate that surface areas, pore volumes and pore sizes can be readily tuned by optimizing heterogeneity. The work also elaborates effect of heterogeneity on size of MOG particles which increase substantially with increasing heterogeneity as well as obtaining mixed valence sites in the gels. High surface …

My Water, My Rights: Ethics And Implications Of Water Privatization, Rachel Vandermyde

Augustana Center for the Study of Ethics Essay Contest

No abstract provided.

Electronic Structure And Photocatalytic Water Oxidation Activity Of Rtino2 (R = Ce, Pr And Nd) Perovskite Nitride Oxides, Spencer H. Porter, Zhenguo Huang, S X. Dou, Samantha Brown-Xu, Md. Golam Mahabub Sarwar, Roberto C. Myers, Patrick M. Woodward

Australian Institute for Innovative Materials - Papers

Three perovskite nitride oxides CeTiNO₂, PrTiNO₂, and NdTiNO₂ have been synthesized and their electronic structures and photocatalytic activities characterized and compared to LaTiNO₂. All three compounds have band gaps that fall in the range 2.0 − 2.1 eV, very similar to LaTiNO₂, which enables them to absorb a significant fraction of the visible spectrum. Photocatalytic oxygen evolution studies under visible light irradiation in the presence of a sacrificial electron acceptor (Ag⁺) show that the activity of NdTiNO₂ (16 μmol/g/hr) is comparable to that of LaTiNO₂ (17 μmol/g/hr), …

Palladium-Catalyzed Ligand-Free And Efficient Suzuki--Miyaura Reaction Of $N$-Methyliminodiacetic Acid Boronates In Water, Chun Liu, Xinmin Li, Xinnan Wang, Jieshan Qiu

Turkish Journal of Chemistry

A green and efficient protocol has been developed for the Pd(OAc)$_{2}$-catalyzed ligand-free Suzuki--Miyaura reaction of $N$-methyliminodiacetic acid (MIDA) boronates in water. In the presence of Pd(OAc)$_{2}$ as a catalyst and ($i$-Pr)$_{2}$NH as a base, the cross-coupling reactions of aryl bromides with aryl MIDA boronates proceeded smoothly in water without any surfactant, and various functional groups were tolerated under the optimized conditions.

Ensuring Our Future Or Sowing The Seeds Of Our Own Destruction? Crop Insurance And Water Use In Texas, Michael Shapiro

Pomona Senior Theses

Agriculture is the largest consumer of water in the United States. Policies that affect agriculture therefore have the potential to have a large effect on the overall use of water. Crop insurance is one such policy, which was found to significantly increase water use in the state of Texas. Much, but not all of this effect can be explained by an increase in planting density, and results vary widely by crop and by region.

Decision Support Tools To Address Climate Change: Climate Model - Land Surface Models, Zea Mays L. (Corn) Phenology And Evapotranspiration-Yield Sensitivity Models For Nebraska, Usa., Jane A. Okalebo

School of Natural Resources: Dissertations, Theses, and Student Research

Nebraska's climate is highly variable and is expected to change in the future with anthropogenic global warming (AGW), resulting in warmer spring and summer temperatures coupled with more erratic rainfall events. This has strong implications for agriculture in the region, yet it is not clear that current modeling and decision-support tools are adequate to address these looming changes and provide planning, mitigation and adaptation strategies. To address climate change and its implications to agriculture in Nebraska, a set of robust decision support tools are very crucial. This study herein are divided into three chapters, with each chapter addressing a specific …

Catechol Oxidation By Ozone And Hydroxyl Radicals At The Air-Water Interface, Elizabeth A. Pillar, Robert C. Camm, Marcelo I. Guzman

Chemistry Faculty Publications

Anthropogenic emissions of aromatic hydrocarbons promptly react with hydroxyl radicals undergoing oxidation to form phenols and polyphenols (e.g., catechol) typically identified in the complex mixture of humic-like substances (HULIS). Because further processing of polyphenols in secondary organic aerosols (SOA) can continue mediated by a mechanism of ozonolysis at interfaces, a better understanding about how these reactions proceed at the air–water interface is needed. This work shows how catechol, a molecular probe of the oxygenated aromatic hydrocarbons present in SOA, can contribute interfacial reactive species that enhance the production of HULIS under atmospheric conditions. Reactive semiquinone radicals are quickly produced upon …

Vernal Pool: A Participatory Art Project About Place + Precipitation, Karen Miranda Abel, Jessica Marion Barr

The Goose

Produced by Karen Miranda Abel with Jessica Marion Barr, Vernal Pool is an immersive, elemental water installation created as a participatory, contemplative inquiry into our transitory interrelationships with water and landscape. From November 2013 to April 2014, 114 individuals across Canada and abroad gathered snow samples as a form of extrinsic artistic practice about place and precipitation. With the arrival of spring, the reservoir of melted snow was convened for four days at Toronto’s historic Gladstone Hotel to create Vernal Pool.

Irrigation Tips To Conserve Water And Grow A Healthy Lawn, Gregg Munshaw, Brad Lee

Agriculture and Natural Resources Publications

Turfgrasses are composed of thousands of cells, all containing water, in which metabolic processes such as photosynthesis and respiration take place. Water makes up 80 to 90 percent of the total plant mass. If this level drops below 60 percent, these processes may slow and wilting will occur. Water is critically important for:

• Maintaining turgidity, which keeps plants standing upright
• Transporting nutrients and sugars through the plant
• Chemical reactions
• Transpirational cooling when water moves out of the leaves and evaporates

The Potlib Library Of Potential Energy Functions And A New Global Analytic Pes For The H + O2 Reaction, Ronald Duchovic

Ronald J. Duchovic

No abstract provided.

The Barriers To Adopting Composting Toilets Into Use In Urban And Suburban Locations In The United States, Julia Branstrator

Open Access Theses

The amount of fresh water available in the world is a finite resource. Large quantities of the fresh water are located in remote locations, while more accessible sources of fresh water are disproportionately distributed around the world. Some populations lack reliable access to clean water for daily life, making the routine use of potable water in toilets of upper-income countries a questionable practice in terms of resource responsibility, energy use, and sustainable infrastructure. The innovative nature of composting toilets offers potential solutions to the downfalls of conventional, waterborne toilets. However, the path to adoption of composting toilets has encountered barriers …

Long-Term Protection Of Freshwater Resources Following Co2 Storage, University Of North Dakota. Energy And Environmental Research Center

EERC Brochures and Fact Sheets

Fact sheet about mechanisms used to protect freshwater resources following CO₂ injection. Outlines U.S. Department of Energy’s (DOE’s) research on water safety.

Experiments On Tracer Diffusion In Aqueous And Non-Aqueous Solvent Combinations, Duncan M. Frasch, Daniel Spiegel

Physics and Astronomy Faculty Research

Forced Rayleigh scattering is used to study the tracer diffusion of an azobenzene in binary combinations of polar solvents, including water. In the absence of water, the tracer diffusion coefficient D in the mixture lies between the diffusion coefficients within the pure solvents, on a curve that is reasonably close to the prediction of free-volume theory. If water is present, on the other hand, the diffusion coefficient displays a minimum that is less than the smaller of the two pure-solvent values. We attempt to understand the different behavior in water by concentrating on the fairly hydrophobic nature of the solute, …

Polyol Induced Extraction (Pie) Of Water From Organic Solvents, Mithilesh Deshpande

Seton Hall University Dissertations and Theses (ETDs)

Acetonitrile (ACN) is used in huge quantities for Reversed Phase High Performance Liquid Chromatography (RP-HPLC) experiments. For most of the part, these results in waste that is only contaminated with large amounts of water, buffer and trace organic impurities. It would seem worthwhile to purify the ACN from water using a mass separating agent (MSA). In a quest for an MSA, our investigation reveals polyols as a new class of MSAs. It is observed that when a polyol such as glycerol, sorbitol, erythritol, xylitol, Isomalt® or maltitol is added to a mixture of ACN-water, the ACN separates out of the …

Effects Of Ether Vs. Ester Linkage On Lipid Bilayer Structure And Water Permeability., S. Deren Guler, D. Dipon Ghosh, Jianjun Pan, John Mathai, Mark Zeidel, John Nagle, Stephanie Tristram-Nagle

Prof. Stephanie Tristram-Nagle Ph.D.

The structure and water permeability of bilayers composed of the ether-linked lipid, dihexadecylphosphatidylcholine (DHPC), were studied and compared with the ester-linked lipid, dipalmitoylphosphaditdylcholine (DPPC). Wide angle X-ray scattering on oriented bilayers in the fluid phase indicate that the area per lipid A is slightly larger for DHPC than for DPPC. Low angle X-ray scattering yields A=65.1A(2) for DHPC at 48 degrees C. LAXS data provide the bending modulus, K(C)=4.2x10(-13)erg, and the Hamaker parameter H=7.2x10(-14)erg for the van der Waals attractive interaction between neighboring bilayers. For the low temperature phases with ordered hydrocarbon chains, we confirm the transition from a tilted …

Structure And Water Permeability Of Fully Hydrated Diphytanoylpc., Stephanie Tristram-Nagle, Dong Joo Kim, Nadia Akhunzada, Norbert Kucerka, John Mathai, John Katsaras, Mark Zeidel, John Nagle

Prof. Stephanie Tristram-Nagle Ph.D.

Diphytanoylphosphatidylcholine (DPhyPC) is a branched chain lipid often used for model membrane studies, including peptide/lipid interactions, ion channels and lipid rafts. This work reports results of volume measurements, water permeability measurements P(f), X-ray scattering from oriented samples, and X-ray and neutron scattering from unilamellar vesicles at T=30 degrees C. We measured the volume/lipid V(L)=1426+/-1A(3). The area/lipid was found to be 80.5+/-1.5A(2) when both X-ray and neutron data were combined with the SDP model analysis (Kucerka, N., Nagle, J.F., Sachs, J.N., Feller, S.E., Pencer, J., Jackson, A., Katsaras, J., 2008. Lipid bilayer structure determined by the simultaneous analysis of neutron and …

Structure Of Fully Hydrated Fluid Phase Lipid Bilayers With Monounsaturated Chains., Norbert Kucerka, Stephanie Tristram-Nagle, John Nagle

Prof. Stephanie Tristram-Nagle Ph.D.

Quantitative structures are obtained at 30 degrees C for the fully hydrated fluid phases of palmitoyloleoylphosphatidylcholine (POPC), with a double bond on the sn-2 hydrocarbon chain, and for dierucoylphosphatidylcholine (di22:1PC), with a double bond on each hydrocarbon chain. The form factors F(qz) for both lipids are obtained using a combination of three methods. (1) Volumetric measurements provide F(0). (2) X-ray scattering from extruded unilamellar vesicles provides /F(qz)/ for low q(z). (3) Diffuse X-ray scattering from oriented stacks of bilayers provides /F(qz)/ for high q(z). Also, data using method (2) are added to our recent data for dioleoylphosphatidylcholine (DOPC) using methods …

Volunteered Geographic Information For Water Management: A Prototype Architecture, Maria Antonia Brovelli, Luca Dotti, Marco Minghini, Massimo Pancaldi, Giorgio Zamboni

International Conference on Hydroinformatics

Driven by Web 2.0 technology and the almost ubiquitous presence of mobile devices, Volunteered Geographic Information (VGI) is knowing an unprecedented growth. These notable technological advancements have opened fruitful perspectives also in the field of water management and protection, raising the demand for a reconsideration of policies which also takes into account the emerging trend of VGI. This research investigates the opportunity of leveraging such technology to involve citizens equipped with common mobile devices (e.g. tablets and smartphones) in a campaign of report of water-related phenomena. The work is carried out in collaboration with ADBPO - Autorità di bacino del …

Development And Applications Of The Expanded Equivalent Fluid Method, Bharath Kumar Kandula

Dissertations

Ocean acoustics is the study of sound in the oceans. Electromagnetic waves attenuate rapidly in the water medium. Sound is the best means to transmit information underwater. Computational numerical simulations play an important role in ocean acoustics. Simulations of acoustic propagation in the oceans are challenging due to the complexities involved in the ocean environment. Different methods have been developed to simulate underwater sound propagation. The Parabolic-Equation (PE) method is the best choice in several ocean acoustic problems. In shallow water acoustic experiments, sound loses some of its energy when it interacts with the bottom. An equivalent fluid technique was …

Development Of A Public Education Website: Building Bridges Over Water, Angelina Mckee

Agricultural Education and Communication

Website created by Angelina McKee to educate the public about water resource issues. Water is the basic unit of life, water resources are the basis for what societies and ecosystems are founded upon. Water shortages and droughts are more prevalent in our ever-changing world. It is no shock that there are discrepancies between various stockholders on either sides of the dry riverbed. This senior project resulted in the development of a website that addresses global water resources, water use in California, water conservation, and water allocation. The website informs the public on water resources and related issues and will hopefully …

Liming Kentucky Lawns, Gregg Munshaw, Edwin L. Ritchey

Agriculture and Natural Resources Publications

Most homeowners desire an aesthetically pleasing landscape and will take steps to ensure success. Proper fertilizing, watering, and pest control are all steps that will lead to a quality lawn. However, some confusion surrounds when and why lime should be applied to a lawn. Many homeowners believe that lime needs to be applied on an annual basis for a quality lawn. The purpose of this publication is to explain why lime is needed and whether it is required on your lawn.

How Dry Seasons Affect Woody Plants, Nicole Ward Gauthier, Susan Fox, Kathy Wimberley

Agriculture and Natural Resources Publications

Pattern, frequency, and amounts of rainfall are important components to plant health. Water is an essential plant component, making up 70 percent to 90 percent of plant mass. Growth, photosynthesis (manufacture of food), nutrient transport, important chemical reactions, and the production of secondary metabolites are all dependent upon water uptake from roots. Water expands and enlarges new cells within stems and leaves, which holds them upright (turgor pressure).

During dry seasons and drought conditions, plants become stressed (Figure 1). Growth ceases, nutrient transport slows, and plants wilt as cells become water-deficient. Severe, long-term, or consecutive drought events may cause permanent …

2014 Martz Summer Conference Poster Session, University Of Colorado Boulder. Getches-Wilkinson Center For Natural Resources, Energy, And The Environment, University Of Colorado Boulder. Airwatergas Sustainability Research Network

Water and Air Quality Issues in Oil and Gas Development: The Evolving Framework of Regulation and Management (Martz Summer Conference, June 5-6)

1 page.

This Conference is presented by the Getches-Wilkinson Center for Natural Resources, Energy, and the Environment, in conjunction with the Air-Water-Gas Sustainability Research Network. Technological advances for extracting oil and gas from shale deposits have ushered in a new era of energy development in key resource-rich pockets throughout the US. In this event, we review the ongoing efforts of governments and industry to develop the regulatory and management practices necessary to protect water and air resources, drawing on the latest scientific research to tackle areas of uncertainty and to inform future action.

Water In The 21st Century, Grayson Michael Shor

Social Sciences

The aim of this research project is to provide a comprehensive and global analysis of water use in order to provide the reader with a comprehensive grasp of current and impending issues. The included five (5) chapters discuss water distribution, conservation, purification, law, international development, economic debates, ethical consideration, as well as educated estimations of the effects water related issues may cause in the next one-hundred years.

3d Flowerlike Micro/Nanocomposite Ceria To Remove Arsenic And Chromium In Drinking Water, Taera Kim

Honors Theses

Ceria has received great attention for the removal of water contaminants due to its high oxygen storage capacity, marked oxygen ion conductivity, and tunable catalytic activity. Zhong et al. suggested that ceria (cerium oxide) microspheres with nanoscale 3D flowerlike morphology represent a promising inorganic synthetic material to remove water contaminants such as As(V) and Cr(VI) from drinking water. The 3D flowerlike micro/nanocomposite ceria offer key advantages over other nanoparticle based remediation systems as they can be easily removed via conventional microfiltration. The goals of this thesis project were to test the reproducibility of the synthesis of the 3D flowerlike ceria, …