Physical Sciences and Mathematics Commons^™

Bromination Of 1,2-Cyclononadiene And 1,3-Dimethylallene, Edward Benny Samuel

University of the Pacific Theses and Dissertations

Much information has been obtained on the orientation of unsymmetrical reagents about substituted allenes. Although hydrogen halide addition to 1,2-propadiene yields 2-halopropenes,^20,31 it has been ample demonstrated, at least in the case of halogenation and oxymercuration of the 1,2-alkyl substituted allenes, that the attacking electrophile ends up in the product attached to the central carbon of the original allenic system. ^{20,22,31,34,38,39,40} Using optically active 1,3-dimethylallene(15) it has been shown that the bromination and oxymercuration of 15 is stereospecific. ^22,39Knowledge of the absolute configurations of the optically active addition products have made it possible to propose a plausible mechanism …

The Effects Of Indomethacin On A Strain Of Fibroblasts Cultivated In Vitro, John Thomas Mccloskey

University of the Pacific Theses and Dissertations

Man has always searched for greater understanding of himself and his environment. As a result, much scientific investigation has been directed towards the understanding of the life process. In recent years, such scientific inquiry has become increasingly focused on the fundamental biochemical events taking place at the cellular, subcellular, and molecular levels. In the course of investigation into the nature of living things, research has often necessitated the development of new techniques and investigational tools to serve as experimental systems. Very often such new methods have made possible the discovery of previously unknown processes. One very interesting and useful investigational …

The Effects Of Divalent Metal Ions On The Micellar Properties Of Sodium Dodecyl Sulfate, Michael U. Oko, Raymond L. Venable

Chemistry Faculty Research & Creative Works

Critical micelle concentrations and micellar molecular weights have been determined for sodium dodecyl sulfate in the presence of nitrates of copper, lead, zinc, and magnesium and critical micelle concentrations have been determined with sodium nitrate and silver nitrate as the added electrolytes. The thickness of the ionic atmosphere at the critical micelle concentration has been found to be 34.1 Å with no electrolyte present and 33.6 Å with 9.66 x 10-6 M sodium or silver nitrate and was found to increase upon addition of the 2:1 electrolytes. This is explained in terms of molecular and ionic interactions. Micellar molecular weights …

Metal Salt Catalyzed Carbenoids, Billy W. Peace

Doctoral Dissertations

"The interaction of diazomalonic esters with olefins in the presence of homogeneous copper(I) and copper(II) catalyst has been examined as a function of olefin structure, solvent media, ionic strength, catalyst structure and catalyst concentration, using partial rate data. It has been possible to determine the fine mechanistic details of the cycloproponation, C-H insertion and "dimer" forming reactions. The initial step is displacement of a ligand from copper by diazo compound in a pre-equilibrium, loss of nitrogen in the rate determining step, return of the ligand, displacement of metal from the carbenoid by olefin, followed by collapse to products. Studies revealed …

A Study Of Productivity In Drosophila Immigrans, Lalita Helen Shenoy Waterman

University of the Pacific Theses and Dissertations

In this study it has been demonstrated that Drosophila immigrans females begin laying fertile eggs on the third or fourth day following eclosion, with productivity reaching a peak between the fifth and sixth days of adult life. A delay in mating of even four days decreases the rate as well as the volume of productivity. Based on the evidence in the literature, it is suggested that the stimulus to oviposition may be mechanical or chemical on the corpora allata via the ventral nerve cord.

Tungsten Carbonyl Complexes Containing Positively Charged Phosphorus Ligands, Dilip Poonamchand Shah

Masters Theses

Two positively charged complexes, (CO)₅WP(C₆H₅)₂CH₂CH₂-⁺P(C₆H₅)₂(CH₂C₆H₅) Br^- and (CO)₅W(C₆H₅)₂PCH₂⁺P(C₆H₅)₂CH₃ I^-, were synthesized, and their carbonyl stretching frequencies and force constants were compared to those of the uncharged complexes, (CO)₅WP(C₆H₅)₂CH₂CH₂P(C₆H₅)₂ and (CO)₅WP(C₆H₅) …

Studies In The Preparation Of Metal Enolates Of 3,3,5,5-Tetramethylcyclohexanone And Their Reactions With Lead(Iv) And Mercury(Ii) Acetates, Donald Robert Paveska

Masters Theses

No abstract provided.

Comparison Of Diffusion Coefficients Measured Electrochemically And Non-Electrochemically, Terry Dick Rotsch

Masters Theses

Diffusion coefficients of Co(en)₃I₃⋅H₂O, FeCl₃, and K₃Fe(CN)₆ were measured using the methods of polarography, chronopotentiometry, and diaphragm cell for the purpose of determining any relationships which may exist between these values. A major objective of the present study was to relate diffusion coefficients obtained by a simple non-electrotrochemical method to diffusion coefficients used in electrochemical techniques.

It was found that the polarographically determined diffusion coefficients were all 1.04 times larger than the chronopotentiometric values. This constant factor is probably due to viscosity differences tn the polarographic and chronopotentiometric solutions …

Reactions Of The Tin Tetrahalides With 2,4-Pentanedione In The Presence Of Organic Amines, Kwai-Sam Wong

Dissertations, Theses, and Masters Projects

No abstract provided.

Palladium(Ii) And Platinum(Ii) Complexes Of 2-Cyanophenyl Diphenylphosphine, David Harrison Payne

University of the Pacific Theses and Dissertations

There has been no successful chelation of any phosphorus-acetylenic or phosphorous-nitrile ligand. The objectives of this study were to synthesize such ligands and to study their chemistry and chelating tendencies. The best choice appeared to be the preparation of ortho-substituted triphenylphosphines similar to the chelating ligand allylphenyldiphenylphosphine. The Grignard reactions utilized in the preparation of the olefinic compound could not be used in most cases due to the high reactivity of the acetylene and nitrile function Bromobenzene and iodobenzene have been reacted with alkali metal phosphines under conditions that were probably too drastic for the acetylenic and nitrile functions. There …

Fluorescence Lifetimes And Quantum Efficiencies Of Some 1,10-Phenanthrolines, Paul John Tabakian

University of the Pacific Theses and Dissertations

Fluorescence properties of fourteen substituted 1,10-Phenanthrolines were determined using two different solvent systems. Hour different sets of experiments were performed in order to measure fluorescence lifetimes, quantum efficiencies, absorption and corrected fluorescence spectra, oscillator strengths, and Stoke’s shifts. Two of the phenanthrolines, the 5-Nitro-1,10-Phenanthroline and the 1,10-Phenanthroline-5,6-Dione, did not fluoresce.

A new equation was developed in order to extract the true fluorescence lifetimes τ from the observed fluorescence output f(t), and the lamp decay function I(t). This equation was [see PDF] where “A” was the weight factor or the normalization constant for the appropriate functions. A test of this equation …

Mössbauer Studies Of Bifeo₃-Pbtio₃ Perovskite-Type Solid Solutions, C. M. Yagnik, Robert Gerson, William Joseph James

Physics Faculty Research & Creative Works

The Mössbauer spectra of the ferroelectric solid solutions (BiFeO₃)_x(PbTiO)1-x have been studied as a function of temperature, mainly between room temperature and 600°C, using ⁵⁷Fe in the solutions as an absorber. The quadrupole splitting increased and the isomer shift decreased between x = 0.05 and x = 0.70, a range in which the solutions are tetragonal and paramagnetic, and in which the unit cell volume increases with increasing x. The isomer shift, in particular, was primarily determined by the unit cell volume. Data are presented on the internal magnetic field of the antiferromagnetic …

The Solvolysis Of Triaryhaloallenes, Henry Wayne Moran

Dissertations, Theses, and Masters Projects

No abstract provided.

The Mechanism Of Solvolysis Of Tri-Tert-Butylchloroallene, Whitney Ann Boynton

Dissertations, Theses, and Masters Projects

No abstract provided.

Benzyl Glycosides Of 2-Amino-2-Deoxy Alpha-D-Mannopyranoside And 2-Amino-2-Deoxy Alpha-D-Mannopyranuronic Acid, Tony Man-Kuen Chiu

University of the Pacific Theses and Dissertations

No abstract provided.

The Oxidative Decarboxylation Of Aminopolycarboxylic Acids With Cerium (Iv) In Sulfuric Acid, Rita Kathleen Hessley

Masters Theses

"The rates of oxidation of four chelating agents, NTA, EDTA CDTA, and DTPA with Ce(IV), in sulfuric acid media, were determined spectrophotometrically by a stopped-flow technique. The reductive ability is in the order CDTA>EDTA>DTPA>NTA. The influence of varying the acidity of the medium was studied, and in each case a maximum in the rate constant [H +] plot was observed. A possible interpretation of the reactivities and the influence of acidity is advanced"--Summary, page 1.

The Measurement Of Flame Temperatures With Coated, Electrically Heated Thermocouples, Irvin Milton Miller

Dissertations, Theses, and Masters Projects

No abstract provided.

Reactions Of Tin (Iv) Lewis Acids With -Diketones In The Presence Of Pyridine, Diana Deane Carr

Dissertations, Theses, and Masters Projects

No abstract provided.

Potential Five-Coordinate Titanium-Diketonate Complexes, Pamela Bowen Barrett

Dissertations, Theses, and Masters Projects

No abstract provided.

The Halogen And Uranium Content Of Sedimentary Rocks, Tektites, Impact Glasses, And Obsidians, Victor J. Becker Jr.

Masters Theses

"The iodine and uranium concentrations in sedimentary rocks were measured by irradiating the samples in a neutron flux, radiochemically separating iodine, and ß-counting the resulting activity. The values obtained for uranium are in good agreement with previous estimates of the uranium content in sedimentary rocks. The values obtained for iodine define a distribution pattern similar to that reported for chlorine and bromine, in contrast with the distribution pattern previously reported for iodine in sedimentary rocks. The concentrations of chlorine, bromine, iodine and uranium were determined in tektites, obsidians and impact glasses by neutron activation. The uranium content found in tektites …

A Kinetic Study Of The Reductive Abilities Of Four Polyaminocarboxylic Acids (Edta, Cdta, Dtpa And Nta) Towards Cerium(Iv) In Perchloric Acid Media, Salem Ahmed Attiga

Masters Theses

"The reduction of Ce(IV) in HC10₄ solutions by four polyaminocarboxylic acids, which are commonly used as chelating agents, has been studied by the stopped-flow technique. The rates of reduction first increase with increasing acidity, reach maxima which are characteristic of the chelating agent and the medium, then progressively decrease with increasing the acid concentration in the media. At their maximum reactivities, trans-1,2-diaminocyclohexane tetraacetic acid (CDTA) shows the highest reductive ability; this is followed by ethylenedinitrilotetraacetic acid (EDTA), diethylenetriaminepentaacetic acid (DTPA), and finally nitrilotriacetic acid (NTA). The observed maxima can be qualitatively explained in terms of a mechanism which involves unhydrolyzed …

Mass Fraction And The Isotopic Anomalies Of Xenon And Krypton In Ordinary Chondrites, Edward W. Hennecke

Masters Theses

"The abundance and isotopic composition of all noble gases are reported in the Wellman chondrite, and the abundance and isotopic composition of xenon and krypton are reported in the gases released by stepwise heating of the Tell and Scurry chondrites. Major changes in the isotopic composition of xenon result from the presence of radiogenic Xe¹²⁹ and from isotopic mass fractionation. The isotopic composition of trapped krypton in the different temperature fractions of the Tell and Scurry chondrites also shows the effect of isotopic fractionation, and there is a covariance in the isotopic composition of xenon with krypton in the manner …

Ua66/7/2 Newsletter, Wku Chemistry

WKU Archives Records

Newsletter created by and about the WKU Chemistry department.

Part A: Some Reactions Of Norbornene Oxide: Part B: Arylnorbornene Oxides, Thomas J. Gerteisen

Doctoral Dissertations

Part A: In this thesis research on the action of Grignard reagents with with norbornene oxide has been initiated and found to be of possible synthetic utility.

Part B: The structure of the product of the acid catalyzed dehydration of 2-p-anisylnorbornane-2, 3-cis-exo-diol in hydrochloric acid-tetrahy-drofuran has been reassigned. It was discovered, on the basis of further data, that the structure of the high melting solid was that of the dimer of the epoxide, a p-dioxane, rather than the epoxide itself. This change was proposed for many reasons. A near total nmr analysis of the compound …

The Reaction Of Ethylenediamine With Tetradentate Cobalt(Iii) Complexes, Laura H. C. Huang

Masters Theses

No abstract provided.

Cell-Free Amino Acid-Incorporating Systems From Mesofhilic And Thermophilic Species Of The Genus Bacillus, Nisson Schechter

Dissertations

No abstract provided.

Synthesis And Structure Proof Of Cis-6,6-Dichloro-2-Diphenylmethylene- Bicyclo [3.2.0] Hept-3-Ene-7-One And Cis-2,2- Dichloro- 1,2,2a,7a-Tetrahydro- 7-Diphenylmethylene-Cyclobut (A) Inden-1-0ne, William Douglas Barta

Masters Theses

Introduction

The purpose of this research endeavor was to determine the structures of the adducts of dichloroketene with diphenylfulvene and benzodiphenylfulvene. Structure elucidation was attempted by chemical degradation and nmr analysis.

The structures of the adducts of dichloroketene with cyclopentadiene^1,2 and indene^3,4 have been determined by previous workers. The influence of the exocyclic double bond on the mode of cycloaddition is unknown.

Cobalt(Iii) Complexes With 1,2-Propanediaminediacetic Acid, Paul John Magnell

Masters Theses

Introduction

Aminocarboxylic acid cobalt(III) complexes have been of interest to inorganic chemists since 1909 when Ley and Winkler isolated violet and rose colored geometric isomers of tris amino acid complexes of glycine and alanine.¹ More recently, considerable interest has been shown in the study of the stereochemistry and optical activity arising from configurational and vicinal interactions of these complexes. Nuclear magnetic resonance of the methylene protons on the carboxylate portion of the coordinated ligand has also been studied.

Of immediate interest to this study is the stereo-chemistry of complexes containing flexible tetradentate ligands. A tetradentate ligand may be constructed …

Perturbation Theory Of The Hooke's Law Model For The Two‐Electron Atom, Ronald White, W. Byers Brown

Center for Advanced Mineral and Metallurgical Processing (CAMP)

The Hooke model for the two‐electron atom replaces the electron–nuclear interaction by a harmonic oscillator potential, but retains the Coulomb repulsion of the electrons. The first‐order perturbation equation for the electron repulsion is solved analytically, and the exact first‐, second‐, and third‐order perturbation energies are obtained. A similar Z^-1 perturbation treatment is carried out for the Hartree–Fock equation and other variational approximations. The Z^-1 of the correlation energy is compared with that for helium-like atoms and found to be similar.

Algal Growth And Decomposition: Effects On Water Quality, Phase Ii, Edward G. Foree, Ronald L. Barrow

KWRRI Research Reports

The decomposition and associated nutrient regeneration of three unialgal cultures and one mixed culture containing an indigenous population of bacteria and microscopic animals were studied under dark, constant temperature laboratory conditions. After periods of nutrient-deficient growth ranging from O to 30 days, these cultures were inoculated with decomposer populations and subjected to anaerobic and aerobic environments for the decomposition studies. The extend of decomposition was determined from the percentage volatile suspended solids and percentage particulate COD remaining after 200 days of decomposition. The average extent of decomposition was greater for aerobic than for anaerobic conditions. However, significant portions of the …