Physical Sciences and Mathematics Commons^™

Monte Carlo Simulations Of Photoemission Characteristics From Gaas And Diamond, Abhishek Srivastava

Electrical & Computer Engineering Theses & Dissertations

Monte Carlo based numerical simulations were performed to study photoemission from GaAs and diamond. The central goal was to assess the potential for NEA photoemission from diamond, and to predict its characteristics. The GaAs material system was also included in the simulation study to provide: (i) calibration and validation of the numerical model developed by carefully matching the simulation results with available experimental data, and (ii) quantitative comparisons between the response characteristics of diamond and the better known GaAs system.

Predictions of the energy distribution, temporal response and angular distribution of emitted electrons were obtained. Effects of various parameters, such …

Resource/Dataflow Graph Operating System Development, Sriram J. Coimbatore

Electrical & Computer Engineering Theses & Dissertations

Implementation of a new dataflow schedule model is the objective of this thesis. The dataflow model algorithm called the resource/dataflow graph model is implemented on a peer-to-peer communication network comprising of six personal computers. This dataflow model is implemented making use of an earlier dataflow model called ATAMM (Algorithm to Architecture Mapping Model) developed by ODU and National Aeronautics and Space Administration (NASA). Development issues include modification of the RDFG testbed operating system and a scheme to transfer data buffers using the ethernet channel from one processor to another processor. This, in turn, equips each sub-module of an application with …

Nlo Waveguide "And" Switch And Method Therefor, John J. Kester, Iyad A. Dajani, Peter M. Ranon, Thomas G. Alley

AFIT Patents

Method and apparatus are provided for NLO switching by first providing a phase-matched SHG grating which outputs a reinforced SHG beam only when two input beams of frequency (ω) are present in two modes of such wg. The so encoded NLO switch is operated by directing at least two input pulsed laser beams of frequency (ω) into the two modes of the wg to generate a reinforced pulsed output SHG beam and output same from the wg in an NLO switching process. The two input beams desirably have a separate pulse train and the spatial and temporal overlap of the …

An Empirical Comparison Of Area-Universal And Other Parallel Computing Networks, Ronald I. Greenberg, Lee Guan

Computer Science: Faculty Publications and Other Works

This paper provides empirical comparison of the communication capabilities of two area-universal networks, the fat-tree and the fat-pyramid, to the popular mesh and hypercube networks for parallel computation. While area-universal networks have been proven capable of simulating, with modest slowdown, any computation of any other network of comparable area, prior work has generally left open the question of how area-universal networks compare to other networks in practice. Comparisons are performed using techniques of throughput and latency analysis that have previously been applied to k-ary n-cube networks and using various existing models to equate the hardware cost of the networks being …

Study On The Growth Process Of Lead Dioxide On Lead-Antimony Electrodes By Impedance Tracing Method, Guolin Wei, Hongxin Yang, Jiarong Wang

Journal of Electrochemistry

The growth process of PbO2 formed by the oxidation of PbSO4 in the anodic film on lead-(1,3,5,7)wt%antimony electrodes was investigated with impedance tracing method of single frequency and the current-time transient method. The influence of antimony on this process was studied.The simulation curves obtained for capacity-time transients fit the experimental results very well.It has been shown that the mentioned growth process is a two-dimentional instantaneous nucleation and growth process,Antimony will inhibit the growth of PbO2 nucleus but enhance its nucleation.

A Study On Electrochemical Oxidation Of Reduced Nicotinamide Coenzyme Nadh In Organic Media, Fangzu Yang, Wuhuihuang Wuhuihuang, Xushukai Xushukai, Zhoushsomin Zhoushsomin

Journal of Electrochemistry

The behaviour of electrochemical oxidation of the reduced nicotinamide coenzyme NADH on glassy carbon was studied and some kinetic parameters were measured by means of voltammometry in the N-dimethylformamide(DMF)and 1,4-dioxane media respectively. The eletrochemical oxidation of NADH shows completely irriversable both in the two solvents,and the diagnostic experiments support that the process involves a fast chemical step.The oxidation rate and the diffusion coefficient of N ADH in DMP are smaller than those in 1,4-dioxane,but the response current is more stable in DMF. The experimental results are discussed by solvent effects.

A Study On Solid Polymer Electrolyte Fuel Cell, Hongfeng Xu, Ming Han, Baolian Yi, Xinge Zhang, Shanhai Ge

Journal of Electrochemistry

Solid polymer electrolyte fuel cell(SPEFC)show promise of a high level of performance in the present fuel cell.In this paper,we report the method of SPEFC electrode preparation,and the effects of temperature,pressure and gas flow rate on the performance.

Studies On The Charge And Discharge Reaction Of Li/Lini_(0.3)Co_(0.7)O_2 Battery, Fupjng Zhang

Journal of Electrochemistry

The charge and discharge reaction of Li/LiNi0.3Co0.7O2 battery have been studied by using CV,CT,XRD and GCP.It is shown that the discharge capacity of the cell reaches 120-140 mA·h·g(-1) in the 4.30-3.00 V in 1 mol/L LiClO4/PC electrolyte system. The discharge mechanism involve a two-step Li+ intercalation reaction. The thermodynamic data such as △G,△S,△H,of the reaction are given. Furthermore,the changes of the Dor σi of Li+ with its composition have been discussed.

An Esr Study Of Free Radicals In Electroreduction Process Of Allyl Alcohol, Jindong Zhang, Yafei Kuang, Shukun Huang, Naixian Xie

Journal of Electrochemistry

Electrochemical-ESR technique with spin trap phenyl-t-butyl nitrone(PBN)was used to study the intermediates of electroreduction of allyl alcohol at platinized platinum electrode in acidic alcohol-aqua solution. Hydrogen and allyl group and(or)propyl group radicals were identified by a hyperfine spectrum of the radical adducts,and that provided a direct evidence for the presence of these radicals in the electroreduction of allyl alcohol.

Single-Layer Channel Routing And Placement With Single-Sided Nets, Ronald I. Greenberg, Jau-Der Shih

Computer Science: Faculty Publications and Other Works

This paper considers the optimal offset, feasible offset, and optimal placement problems for a more general form of single-layer VLSI channel routing than has usually been considered in the past. Most prior works require that every net has exactly one terminal on each side of the channel. As long as only one side of the channel contains multiple terminals of the same net, we provide linear-time solutions to all three problems. Such results are implausible if the placement of terminals is entirely unrestricted; in fact, the size of the output for the feasible offset problem may be Ω(n^2). The linear-time …

Two-Dimensional Drift-Diffusion Simulations Of Silicon Avalanche Shaper (Sas) Devices For High Power Applications, Hamid Jalali

Electrical & Computer Engineering Theses & Dissertations

Silicon Avalanche Shaper devices have been projected as being important components of an inexpensive, semiconductor-based technology for high power switching applications. The primary advantage of this technology is that it is based on Silicon material which is easy to fabricate and has a well established processing technology. Unlike other high power technologies, the SAS devices do not rely on external optical triggering which eliminates the need for lasers and related optical circuitry.

The SAS based high power switching technology has been pioneered and tested by a Russian group. Though preliminary results have been very encouraging, the device reliability and its …

Neural Generalized Predictive Control For Real-Time Control, Donald I. Soloway

Electrical & Computer Engineering Theses & Dissertations

In this thesis a computationally efficient Generalized Predictive Control (GPC) algorithm is presented and implemented. The algorithm is more efficient than others because the number of iterations needed for convergence is significantly lower with Newton-Raphson. The main additional cost with Newton-Raphson algorithm is the calculation of the Hessian. This overhead is not a problem because of the reduced number of iterations, making the algorithm suitable for real-time control. For nonlinear control applications, a neural network is used as a dynamical system predictor leading to a Neural Generalized Predictive Control (NGPC) algorithm which is presented in detail in this thesis. An …

Visual Speech Recognition Using Multiple Deformable Lip Models, Devi Chandramohan

Electrical & Computer Engineering Theses & Dissertations

Motivated by the fact that human speech perception is a bimodal process (auditory and visual), several researchers have designed and implemented automatic speech recognition (ASR) systems consisting of both audio and visual subsystems, and shown improved performance relative to traditional purely auditory systems. Several visual speech reading approaches have used deformable templates to model the shape of a speaker's lips. Deformable templates are models of image objects, which can be deformed by adjusting a set of parameters to match the object in some optimal way, as defined by a cost function. Using a single deformable lip model has disadvantages such …

Investigation Of Radio Wave Propagation In The Martian Ionosphere Utilizing Hf Sounding Techniques, Robert J. Yowell

Theses and Dissertations

This thesis presents a preliminary design of an ionospheric sounder to be carried aboard one or more of NASA's Mars Surveyor landers. Past Russian and American probes have indicated the existence of an ionosphere, but none of these missions remotely sensed this atmospheric layer from the surface. The rationale for utilizing a surface-based Martian ionospheric sounder is discussed. Based on NASA's choice of launch vehicle and power source, a low-weight, low-powered Chirp sounder using a horizontally-polarized dipole antenna is recommended for the sounder experiment. The sounder experiment should be conducted for at least one Martian year, in order to investigate …

Status Of The Research And Development For Fuel Cell Technology Abroad, Naichao Li, Baolian Yi

Journal of Electrochemistry

Status of the research and development for fuel cell technology abroad was overviewed,and at the aim of accelerating the research and development for fuel cell technology in China, the corresponding stategy for our country was recommended.

Electrocatalytic Oxidation Of Some C 2 Compounds(Alcohols, Aldehydes, And Carboxylic Acids) On A Pt/Sb Ad Electrode, Hong Li, Lincai Jiang, Xiong Jiang

Journal of Electrochemistry

The electrocatalytic oxidation behavior of some C 2 compounds(alcohols, aldehydes and carboxylic acids) on a Pt/Sb ad electrode prepared in situ or ex situ UPD was investigated using pontential sweep and rotating disc electrode methods. It is confirmed that Pt/Sb ad electrode show the most electrocatalytical active to the oxidation of aldehyde functional group and only a little activity to the oxidation of hydroxyl group, but no activity for the oxidation of carboxyl group. The experimental results show that the activity of the Pt/Sb ad electrode prepared by ex situ UPD is higher than that prepared by in situ UPD. …

Problems On The Study Of Anodic Films On Pb In Sulfuric Acid Solution(Ⅱ), Houtian Liu, Qunzhou Wang, Yongqin Wan, Weifang Zhou

Journal of Electrochemistry

The conditions for the growth of the different phases in the anodic Pb(Ⅱ) film on Pb in sulfuric acid solution were discussed.

Electrocatalytic Reduction Of Nitrite In The Presence Of Complex Of Cobalt(Ⅱ) And 1,10 Phenanthroline, Jian Tong, Xiaojun Dang, Hulin Li

Journal of Electrochemistry

The electrochemistry of cobalt(Ⅱ) 1,10 phenanthroline Co(Phen) 2+ 2 complex and its ability to electrocatalyze the reduction of nitrite were studied , we found that this complex could act as a catalyst in alkaline or neutral solution for nitrite reduction. We have investigated the effect of the complex composition on electrocatalytic ability. The effects of pH value, complex concentration, regeneration and activation of electrocatalyst on the catalytic current have been studied and discussed.

The Reduction Of Oxygen To Hydrogen Peroxide In An Acidic Trickle Bed Cell Using Graphite Chip Cathode, Zhaoe Lu, Guanyong Zhang, Tiangeng Zhong, Guonu Fang

Journal of Electrochemistry

The authors investigated the electrochemical reduction of oxygen to hydrogen peroxide in 0.05 mol/L H 2SO 4 solution by the trickle bed electrode using graphite chip. The bed dimension was 14×5×0.6 cm. The current efficiency and the concentration of H 2O 2 in the catholyte were determined at various current strengths and various rates of adding the electrolyte. The proper current was 0.15 A. i.e. the current density was 2.1 mA/cm 2 vertical cross section area of the bed. The concentration of H 2O 2 reached 7×10 -3 mol/L with the current efficiency of 0.2. If the concentration of H …

A Comparative Analysis Of Viable Solar Thermal Technologies For Solar Field Development And Commercialization, Sean M. Crawford

UNLV Theses, Dissertations, Professional Papers, and Capstones

Diminishing fossil fuels and concerns about the quality of the environment has lead the recent drive to establish a commercialized solar field in Southern Nevada. The competing solar thermal technologies for the Solar Enterprise Zone (SEZ) are Parabolic Dish-Stirling, Central Receiver Power Towers, and Parabolic Trough Systems. It is important to compare the technologies based on the guidelines set by the Corporation for Solar Technology and Renewable Resources. The variables weighted are solar conversion performances, initial capital investment, operation and maintenance costs, water and land use, and electricity production costs. All technologies have been proven to viable power sources and …

An Electroabsorption Study Of Porous Silicon, Melanie Fewings

WWU Honors College Senior Projects

Bulk silicon is an indirect band gap material. When carriers are injected into bulk silicon, electron-hole recombination takes place thermally via phonon exchange, and not by emission of photons. Porous silicon, on the other hand, is a fairly efficient emitter of light in the visible region. Much research is currently under way to find out what makes porous silicon able to emit light. One main theory suggests that the energy bands of bulk silicon may be "squeezed" by being quantum confined, and porous silicon is just an array of quantum silicon wires. Another possibility is that defects in the huge …

Electron Beam Emission From A Ferroelectric Cathode, Crystal Briana Garland

Electrical & Computer Engineering Theses & Dissertations

The electron beam emission from a LTZ-2 (lead titanate-zirconate) ferroelectric cathode was characterized. The purpose was to determine the operation range for this type of electron emitter. The experimental apparatus consisted of a high voltage driving circuit with a charging voltage up to 30kV. A solid-state SCR switch is used to generate the high voltage pulse which induces a polarization change. Current densities on the order of 80A/cm² 30kV were achieved. The electron beam profile is Guassian. At long anode-cathode distances the measured current densities were found to be above Child-Langmuir space charge limits. The large current densities and …

Wavelength Modulation Spectroscopy With Diode Lasers, Ying Lu

Electrical & Computer Engineering Theses & Dissertations

Wavelength Modulation Spectroscopy is a non-intrusive technique which enables several parameters such as concentration, velocity, and temperature of a target specie to be measured. The method involves a modulation of a probe laser beam and detection at the fundamental, or any harmonic frequency, by a phase-sensitive apparatus. The theory of wavelength modulation is discussed. Effects of the finite value of the wavelength modulation index, together with the effects of any residual amplitude modulation that often occurs simultaneously in a diode laser, are included. It is shown that there are several advantages in using detection harmonics orders greater than the second. …

Adaptive Integration Of Audio And Visual Information Using Discrete And Semi-Continuous Hidden Markov Models In Audiovisual Automatic Speech Recognition, Qin Su

Electrical & Computer Engineering Theses & Dissertations

An audiovisual semi-continuous hidden Markov model (HMM)-based Automatic Speech Recognition (ASR) system and an improved method of integrating audio and visual information in an audiovisual discrete HMM-based ASR system are investigated.

In the audiovisual discrete HMM, an adaptive integration formulation is employed, which incorporates the integration into the HMM at a pre-categorical stage. A visual weighting parameter is determined automatically, which allows the relative contribution of audio and visual information to be adjusted adaptively. Using an adaptive weight, the accuracy increased by 13% compared to the same model with no adaptive weight.

The semi-continuous HMM is a class of models …

Variable Step Size Lms Adaptive Filters With Delayed Coefficient Updating, Guixian Xu

Electrical & Computer Engineering Theses & Dissertations

A new approach to delayed LMS adaptive filtering is presented, which uses a variable step size for coefficient updating to increase convergence speed and improve tracking characteristics. The new algorithm, called delayed variable step size LMS (DVLMS), is explained, analyzed, and simulated to experimentally determine performance characteristics. Three different strategies for adjusting the step size are examined, and their performance is compared. Also, simulation results are presented to show that the proposed DVLMS systems provide faster convergence and lower mis-adjustment than previously proposed DLMS systems.

Speech Feature Computation For Visual Speech Articulation Training, Stefan Auberg

Electrical & Computer Engineering Theses & Dissertations

A new version of the Visual Speech Articulation Training Aid was implemented which provides real-time visual feedback for speech articulation training. This version was migrated to a Windows Multimedia PC from a previous version which used a Personal Computer (PC) system and additional specialized and expensive custom hardware. This new version will make the system more available to schools and private users. A new method was developed for computing spectral/temporal features which characterize the speech sounds. In addition to the typical frame-based spectral analysis parameters, the new method represents temporal changes of the spectrum with a small number of features. …

Frequency Response Enhancement Of A Flow Sensor Using Diamond Thin Films Synthesized By Plasma Cvd, John Curren Hagwood

Electrical & Computer Engineering Theses & Dissertations

Theoretical modeling conducted previously in our Microelectronics Laboratory has shown that a layer of diamond film inserted between a metal film and a substrate will enhance the frequency response of a conventional thin film flow sensor. This thesis involved fabricating and testing a conventional thin film sensor of nickel on quartz (Ni/Q) and a diamond enhanced sensor (Ni/D/Q) for comparative frequency response analysis to validate the theory. Diamond films were grown onto quartz substrates using a microwave plasma enhanced chemical vapor deposition process. Conditions were established to synthesize continuous diamond films on quartz substrates. These films were characterized by scanning …

Gamma-Ray Optical Studies Of ⁷³Ge And ⁵⁷Fe, Walter Carlton Mcdermott Iii

Physics Theses & Dissertations

The research described herein is among the first attempts to test one of the more popular theories for development of a gamma-ray laser. This work is a "marriage" between the Borrmann effect, which is a consequence of the dynamical theory of x-ray diffraction, and time-filtering which comes from time-domain Mossbauer spectroscopy.

Our experiments involved the search for a nuclear Borrmann effect and the subsequent time-filtering effect using ⁵⁷Fe and ⁷³Ge. In both cases, no nuclear Borrmann effect was observed; however, the methodology and criteria necessary for such an observation with any isotope were documented. The procedures necessary for …

Generalized Hidden Filter Markov Models Applied To Speaker Recognition, John M. Colombi

Theses and Dissertations

Classification of time series has wide Air Force, DoD and commercial interest, from automatic target recognition systems on munitions to recognition of speakers in diverse environments. The ability to effectively model the temporal information contained in a sequence is of paramount importance. Toward this goal, this research develops theoretical extensions to a class of stochastic models and demonstrates their effectiveness on the problem of text-independent (language constrained) speaker recognition. Specifically within the hidden Markov model architecture, additional constraints are implemented which better incorporate observation correlations and context, where standard approaches fail. Two methods of modeling correlations are developed, and their …

An Indirect Electrochemical Oxidation Of Toluene─Catalytic Effects Of Ag(Ⅰ) On Mn(Ⅱ)/Mn(Ⅲ) Couple Transition At Pt Electrode, Zhonghua Wang, Yunan Qu, Xingguo Yan, Qngmin Hua, Guacai Chen, Zhongquan Wang

Journal of Electrochemistry

The Catalytic effects of Ag(Ⅰ) on toluene oxidation by Mn(Ⅲ) as well as the anodic generation of Mn(Ⅲ) were investigated. The rates of toluene oxidation were first order with respect to both Ag(Ⅰ) and Mn(Ⅲ). Ag(Ⅱ) formed on the surface of the platinum anode when Ag(Ⅰ) was present in the anolyte, which catalyic the Mn(Ⅱ) to Mn(Ⅲ) in solution.