Physical Sciences and Mathematics Commons^™

Chemical Shift Parameters For Shallow Donors In Semiconductors, Edward Boyd Hale

Physics Faculty Research & Creative Works

A model for a shallow donor impurity in a semiconductor is used to calculate two relationships and several conditions involving the chemical shift parameters. The model is based on the standard effective mass form for the donor electron wave function, the existence of a potential in the chemical cell which may be real, pseudo, or rather general in nature, and a few somewhat restrictive approximations. The parameters, Δ, δ and Λ are theoretically calculated and are shown to be related if the approximations are valid. These parameters determine the 1S multiplet level structure and it is shown how properties of …

Projected Hartree Product Wavefunctions. Viii. Relationship Of Dods And Scf Orbitals For Be, Gordon A. Gallup

Gordon Gallup Publications

Projected Hartree product wavefunctions. VIII. Relationship of DODS and SCF orbitals for Be

Branchiobdellids (Annelida: Clitellata) From Some Eastern North American Caves, With Descriptions Of New Species Of The Genus Cambarincola, Perry C. Holt

International Journal of Speleology

Branchiobdellids are found as epizoites on crustaceans of the orders Isopoda and Decapoda (cambarine crayfishes) in caves of eastern North America. Species that may be considered as troglobites, since they are not known from epigean waters, appear to be confirmed to truly troglobitic isopods and possibly a few troglobitic crayfishes from Florida and the Tennessee-Kentucky Highland Rim cave belt. The majority of the records of branchiobdellids from caves are of representatives of common epigean forms epizootic un crayfishes. Cross-referenced lists of branchiobdellids, their hosts and cave localities are presented. Some of the new species described are apparently troglobitic or troglophilic, …

Petrogenesis Of The Granitic Rocks Of Part Of The Upper Granite Gorge, Grand Canyon, Arizona, Michael B. Walen

WWU Graduate School Collection

The study area extends from Phantom Creek to Crystal Creek, a distance of approximately 10 miles along the Colorado River. The units exposed are the Precambrian Vishnu Schist granitic to granodioritic units in Phantom Canyon, Trinity Canyon, and near Crystal Creek, and pegmatites and aplites. The Vishnu Schist is composed mostly of quartzo-feldspathic schists. The assemblage quartz-oligoclase-muscovite-biotite-sillimanite-K-feldspar indicates metamorphic conditions in the upper amphibolite facies between Phantom Creek and Mile 95. Between Mile 95 and Crystal Creek, assemblages indicate lower amphibolite to greenschist facies conditions.

The Phantom Granitic Complex consists of granodioritic and quartz monzonitic units. The presence of a …

Geology Of The Older Precambrian Rocks In The Vicinity Of Clear Creek And Zoroaster Canyon, Grand Canyon, Arizona, William S. Lingley Jr.

WWU Graduate School Collection

The Clear Creek-Zoroaster Canyon area is located in the east- central section of the Bright Angel Quadrangle (Maxson, 1968) roughly seven miles east northeast of Grand Canyon Village, Arizona. The boundaries of the present study area are shown in Figure 1. The study area extends from Mile 83.7 to Mile 86 on the Colorado River below Lee's Ferry, Arizona.

Older Precambrian rocks are exposed along the Inner Gorge of the Colorado River. They also crop out at Zoroaster Canyon, Clear Creek, and Cremation Creek. There are over 450 m of vertical exposure. Many outcrops are inaccessible due to steepness of …

Imbedding Problems In Graph Theory, William Goodwin

Honors Theses

For some years there has been interest among mathematicians in determining the different ways in which certain graphs can be imbedded in given surfaces. M.P. VanStraten in 1948, determined that it is possible to imbed the graph K_3,3 (which is the graph representing the famous three houses, three utilities problem) in the torus in only two ways. She then used this fact to show that the graph representing the configuration of Desargues (containing K_3,3 as a subgraph) has genus two. One major source of motivation for the work on imbedding problems has been their relation to coloring problems …

Adsorption Of Water On Gold, Jean-Marc Louis Deschanel

Masters Theses

"Water adsorption isotherms on gold films were measured with a quartz crystal microbalance. Two gold films were studied: a "dirty" gold film contaminated by approximately one monolayer of carbon, and a "clean" gold film prepared by evaporating gold from a heated tungsten wire under high vacuum.

Water was found to chemisorb on both films according to a Freundlich type adsorption isotherm. Isosteric heats of adsorption were computed from the isotherm data. On the "clean" gold surface the isosteric heat showed a logarithmic decrease with increasing water coverage. The highest measured value for the heat of adsorption was 35 kcal mole …

Heavy Metal Analysis Of Stream Sediments In The James River Basin, Missouri, William J. Head

Masters Theses

"A reconnaissance survey of stream sediments using the minus 80 mesh sieve fraction was made at 53 sites throughout the James River basin, Missouri. Sample sites within the 1460 square miles of the basin were chosen at tributary confluences, suspected contamination sources, and known areas of mineralization. Replicates and stream profiles were taken to check for analytical variation and reproducibility of results. Sediment samples were prepared by a hot nitric acid leach method. The sediments were analyzed using an atomic absorption unit to determine Cu, Pb, Zn, and Cd trace metal contents.

Values of selected streams within the basin were …

Heavy Metals In The Main Streams Of The James River Basin, Missouri, Richard Jerome Lance

Masters Theses

"Demands on water resources in the James River basin have greatly increased. Industrial plants and lead-zinc prospects in the basin are potential sources of heavy metal additions to the waters of the area. The study determines the heavy metal content and distribution in the streams of the basin.

Approximately 50 water samples were collected each season and analyzed by atomic absorption techniques. Field determinations of temperature, specific conductance, pH, and effective alkalinity were also made.

Ranges of heavy metal content were: (1) mercury- <0. 1 to 0.3 ppb (summer only); (2) zinc-

The urban areas of Springfield contribute dissolved heavy metals to the surface streams. The Southwest Springfield Sewage …

Regional Hydrothermal Alteration Of The Leadville Limestone (Mississippian) Of Central Colorado, L. V. Benson

United States Geological Survey: Staff Publications

Massive metallic-sulfide deposits were implaced in the Leadville Limestone {Mississippian) of Central Colorado less than 70 million years ago. The thermal fluids which precipitated ore at Gilman, Colorado have regionally altered the Leadville Limestone. The sequence of alteration began with the recrystallization of limestone to a dark medium~grained dolomite containing a homogeneous distribution of Fe. This Was followed by partial recrystallization of the medium-grained dolomite to coarse-clear dolomite which contains an inhomogeneous distribution of Fe. The resulting banded rock is known as "zebra rock" . Precipitation of Si0 2 (jasperoid) occurred next. The jaspe=oid formed prior to the deposition of …

Seismicity Preceding Moderate Earthquakes In California, Robert L. Wesson, William L. Ellsworth

United States Geological Survey: Staff Publications

Regional seismicity data have been examined to determine the nature of seismicity in the years preceding these moderate earthquakes in California: 1952 Kern County (M = 7.7), 1963 Watsonville (M = 5.4), 1964 and 1967 Corralitos (M = 5.0, 5.3), 1966 Parkfield-Cholame (M = 5.1, 5.5), 1968 Borrego Mountain (M = 6.4), 1969 Santa Rosa (M = 5.6, 5.7), and 1971 San Fernando (M = 6.4). In each instance the moderate earthquakes occurred in areas characterized by a relatively high level of small earthquake activity. In most cases the preceding activity in the area immediately surrounding the epicenter was high …

Production And Decay Of Double L Vacancies In Argon And Phosphorus, M. Eugene Rudd, B. Fastrup, P. Dahl, F. D. Schowengerdt

M. Eugene Rudd Publications

Measurements have been made at two laboratories which indicate that the structure reported at 450-550eV in the electron spectrum from Ar⁺-Ar collisions by Ogurtsov, Flaks, and Avakyan is spurious. It is argued that the double L vacancies which they invoke to explain the structure are more likely to decay by the two-step Auger process L ²→LM²→M⁴ than by the one-step process L²→M³ suggested by these authors. Evidence supporting this is found in our electron spectra from P⁺-Ar collisions, where it is known from energy-loss and charge-state measurements that double …

Autoionization Of He And Autodetachment Of He- Following Bombardment By H+, H2+, He+, And He Atoms, F. D. Schowengerdt, S. R. Smart, M. Eugene Rudd

M. Eugene Rudd Publications

Presented here are experimental results of a study of the systematics of electron emission from discrete states of He and He- as produced by H⁺, H₂⁺, He⁺, and He impacts. The results were obtained by energy analysis of the electrons emitted at angles of 10° to 160°. Projectile energies ranged from 20 to 150 keV. Differential and integrated cross sections are presented for emission of electrons from the 2s² (¹S), 2s2p(³P), the sum of the 2p² (¹D) and 2s2p(¹P) autoionizing levels of He, …

Synthesis And Chemistry Of Thione-Iron Carbonyl Complexes, Albert Shil-Kwan Chan

Graduate Dissertations and Theses

The first examples of sulfur-donor ligand ortho-metallated complexes were obtained in good to excellent yields by reaction of various thiobenzophenones and a thiobenzoate with diiron enneacarbonyl in benzene at room temperature. The known trinuclear complex S₂Fe₃(CO)₉ was a by-product of these reactions, and complexes of the type (Ar₂C)S₂Fe₂(CO)₆ were formed in several instances. The structures of these complexes were established on the basis of microanalytical and spectral data as well as by reductive cleavage experiments. Oxidative or photolytic cleavage of the ortho-metallated complexes provides a convenient …

A Novel Method Of Constructing Sorting Networks, Robert M. Keller

All HMC Faculty Publications and Research

The construction of sorting networks has been a topic of much recent discussion. In view of the apparent difficulty of verifying whether a reasonably large proposed sorting network actually does sort, the most useful approach for constructing large networks seems to be to devise a recursive scheme which constructs a network which is guaranteed to sort, obviating the verification phase. In this note, another such approach is presented.

Canonical Analysis Of Several Sets Of Variables, Chong S. Kim

All Graduate Plan B and other Reports, Spring 1920 to Spring 2023

Many procedures have been proposed for analyzing and describing multivariate dependence structure.

Partial correlation, multiple correlation, canonical correlation, principal component and factor analysis are used to analyze the dependence structures of a multinormal population.

For a partial correlation analysis it is necessary to decide which variables are to be correlated and which of the remaining variables must be held constant.

Multiple correlation demands that one variable be dependent upon some or all of the remaining variates.

For a canonical correlation, the variables must be collected into two or more sets. The factor analysis technique is for explaining the covariances of …

Quasifree (P,Pα) Scattering On ⁶Li, ²⁴Mg, ²⁸Si, ⁴⁰Ca, ¹⁴⁰Ce, And ²³²Th At 156 Mev, D. Bachelier, M. Bernas, Oleksa-Myron Bilaniuk, J. L. Boyard, J. C. Jourdain, P. Radvanyi

Physics & Astronomy Faculty Works

Knockout of α particles by 156-MeV protons from ⁶Li, ²⁴Mg, ²⁸Si, ⁴⁰Ca, ¹⁴⁰Ce, and ²³²Th has been used to investigate the A dependence of α clustering in nuclei. Protons and α particles were detected in coincidence under conditions of quasifree scattering. Corresponding reaction cross sections were measured. Cross sections for ²⁴Mg and ⁴⁰Ca were found to be about 2 orders of magnitude lower than for ⁶Li. The cross section for ²⁸Si was found to be about 3 times lower than that for ²⁴Mg and ⁴⁰Ca. Upper limits of the integrated cross sections for ¹⁴⁰Ce and ²³²U are still compatible with …

Chronic Toxicity Of A Copper, Cadmium And Zinc Mixture To The Fathead Minnow (Pimephales Promelas Rafinesque), John G. Eaton

United States Environmental Protection Agency: Publications

Fathead minnows were exposed to a series or concentrations of a copper, cadmium and zinc mixture during a 12.5 month chronic test in water of 200 mg 1^-1 total hardness. The metal concentrations in the mixture were selected on the basis of results obtained during previous chronic exposures to each of the metals individually in the same water. Strict summation of the chronic toxicities of the metals was not indicated when they were tested in combination. Toxic effects of the mixture attributable to copper appeared to be increased, but that attributable to cadmium was reduced. The effects thought to …

Chronic Effect Of Low Ph On Fathead Minnow Survival, Growth And Reproduction, Donald I. Mount

United States Environmental Protection Agency: Publications

Fathead minnows (Pimephales promelas Rafinesque) were continuously exposed to reduced pH levels of 4.5, 5.2, 5.9, 6.6 and 7.5 (control) during a 13-month, one-generation test. Survival was not affected, even at the lowest pH tested. Fish behavior was abnormal, and fish were deformed at pH 4.5 and 5.2. Egg production and egg hatchability were reduced at pH 5.9 and lower, and all eggs were abnormal. A pH of 6.6 was marginal for vital life functions, but safe for continuous exposure. Free carbon dioxide, liberated by the addition of sulfuric acid to reduce the pH, may have had an unknown …

Captan Toxicity To Fathead Minnows (Pimephales Promelas), Bluegills (Lepomis Macrochirus), And Brook Trout (Salvelinus Fontinalis), Roger O. Hermanutz, Leonard H. Mueller, Kenneth D. Kempfert

United States Environmental Protection Agency: Publications

The toxic effects of capt an on survival, growth, and reproduction of fathead minnows (Pimephales promelas) and on survival of bluegiIIs (Lepomis macrochirus) and brook trout (Salvelinus fontinalis) were determined in a flow-through system. In a 45-week exposure of fathead minnows, survival and growth were adversely affected at 39.5 μLg/Iiter. Adverse effects on spawning were suspected but not statisticaIly demonstrated at 39.5 and 16.5 μLg/Iiter. The maximum acceptable toxicant concentration (MATC), based on survival and growth, lies between 39.5 and 16.5 μLg/liter. The lethal threshold concentration (LTC) derived from acute exposures was 64 μLg/liter, …

Appendix A: The Use Of The Personalized System Of Instruction (Psi)

Calculus-Based General Physics

STUDY MODULES FOR THE USE OF THESE CBP MODULES

Recommended

1. What is the Philosophy of PSI?

2. How Do I Manage This System?

3. The Care and Feeding of Student Tutors

Optional

4. How to Plan the Content of a Keller Plan Course

5. How to Design a Study Module

6. How to Write Learning Objectives

The Auditor And Statistical Sampling Techniques, Marilyn Metcalf

Honors Theses

"The auditor's overall objective is to determine whether the accounting process is free from material error." To complete his objective, the auditor must thoroughly analyze all aspects of the financial statements used in the accounting process in order to satisfy himself that they fairly represent the results of activity for the period under audit and of the financial position at the end of that period. If the volume of the transactions is great, time and economic factors may keep the auditor from making a 100 percent examination. Since a complete examination cannot be made, the auditor must choose a portion …

Radiation Problem, Gerald L. Fuller

Honors Theses

A sphere of radius 'a' which is radioactive and which has an average range 'b' in the sphere. What fraction of total radiation will escape the sphere?

Modern Art Through Geometric Eyes, Janice M. West

Honors Theses

When tourists--even homefolks--go through a modern art museum, many opinions are accumulated. Some people may have chills when they see a certain painting, while others get a sick feeling of dizziness when they see the same one. In fact, if there were an opinion box at the exit of an art show, I imagine you could almost accurately count the different opinions by counting the total number of people who viewed the show. Yet, there is one opinion that most 'ole foggies' (and I use the term loosely) would agree upon, and that is this: "Why that's nothing but a …

A Numerical And Spatial Study Of The Meadow Vole, Microtus Pennsylvanicus, Margaret Whitney Higgins Bowker

Dissertations, Theses, and Masters Projects

No abstract provided.

Finite Dimensional Group Rings, Ralph W. Wilkerson

Computer Science Faculty Research & Creative Works

A Ring is Right Finite Dimensional If It Contains No Infinite Direct Sum of Right Ideals. We Prove that If a Group G is Finite, Free Abelian, or Finitely Generated Abelian, then a Ring R is Right Finite Dimensional If and Only If the Group Ring RG is Right Finite Dimensional. a Ring R is a Self-Injective Cogenerator Ring If Rn is Injective and RR is a Cogenerator in the Category of Unital Right /{-Modules; This Means that Each Right Unital A-Module Can Be Embedded in a Direct Product of Copies of R. Let G Be a Finite Group Where …

A Computer-Oriented Course In Chemical Spectroscopy, D. (Donald) W. Beistel

Chemistry Faculty Research & Creative Works

No abstract provided.

The Synthesis And Spectroscopic Properties Of Vanadium(Iii) Squarate Trihydrate, S. M. Condren, Hector O. Mcdonald

Chemistry Faculty Research & Creative Works

Vanadium(III) squarate trihydrate has been prepared; and the infrared, X-ray diffraction, and electronic spectra of the complex indicate that the central metal atom is in a slightly distorted octahedral field. A thermogravimetric study has shown that the complex loses three water molecules upon heating. A hydroxy-bridged, dimeric structure has been proposed from these data. © 1973, American Chemical Society. All rights reserved.

Geology Of The Country East Of The Santa Rita Mining District, Grant County, New Mexico: The San Lorenzo Area, Raymond S. Lambert Jr.

Earth and Planetary Sciences ETDs

The settlement of San Lorenzo is approximately 19 miles east of Silver City, New Mexico. The area consists of rolling hills, relatively steep slopes and the broad Mimbres River Valley. The land surface reflects partial erosion of Basin and Range fault blocks. The maximtun elevation is 7,170 feet, with relief of 1,400 feet.

The main structural feature is a northwest trending mountain range, which is a west-southwest-dipping fault block bounded on the northeast by the Mimbres fault. Vertical displacement ranges from 150 meters (500 feet) to 1,200 meters (4,000 feet). Rocks exposed along the steep northeastern escarpment range in age …

Pleistocene Stratigraphy Of The Red Lake Falls Area, Minnesota, Kenneth L. Harris

Theses and Dissertations

Seven formations are present along a 50-mile stretch of the Red Lake River in Pennington, Red Lake, and Polk Counties, Minnesota. Five formations are largely glacial, sediment, and two are largely lacustr1ne sediment deposited during phases of Lake Agassiz.

The Gervais Formation (pre-Wisconsinan or early Wisconsinan) is mostly fluvial or lacustrine sediment modified by glacial ice of unknown source. The Marcoux Formation (pre Wisconsinan or Wisconsinan) is largely sediment deposited by glacial ice that advanced from the northeast over the Canadian Shield. The St. Hilaire. Formation (Wisconsinan) is mainly sediment deposited by glacial ice that advanced from a western or …