Physical Sciences and Mathematics Commons^™

The Kinetics And Mechanism Of The Reaction Of Chromium(Ii) With Pentaaquodiiodomethyl Chromium(Iii) And Pentaaquomonoiodomethyl Chromium(Iii) Ions., Ronald Sinclair Nohr

University of the Pacific Theses and Dissertations

Transition metal ions, in low oxidation states, have gained increasing use as versatile reducing agents for a number of organic compounds. The ability of metal ion to act as reducing agents in organic reactions is frequently thought to be due to the formation of intermediates which contain an organic species bound to a metal, although the identy of these organo-metallic intermediates has been determined in relatively few cases.

The purpose of this research was to investigate the kinetics and mechanism of one such reaction: the reduction of iodoform to methane by chromium(II). Two air stable organochromium(III) intermediates were separated and …

The Preparation And Characterization Of The Palladium(Ii) And Platinum(Ii) Chelates Of Three Cyclic Tertiary Amino Acids., Floyd Michael Hogue

University of the Pacific Theses and Dissertations

The purpose of this study was to prenare and characterize the palladium (II) and platinum (II) chelates of 1-pyrrolidineacetic acid, 1-piperidineacetic acid, and hexahydro-1-azepineacetic acid.

The ligands were prepared by reacting the cyclic secondary arnines (pyrrolidine, piperidine, and hexahydroazepine) with sodium chloroacetate. The resulting cyclic tertiary amino acids were saponified and, finally, converted to the hydrochloride salts by neutralization with hydrochloric acid.

The chelates were prepared by adding 1.0 millimole of K₂PdC1₄ or K₂PtC1₄ to a solution made by dissolving 2.0 Millimoles of amino acid hydrochloride in 25 ml. of water. The pH was …

A Comparison Of The Effects Of Aspirin, Sodium Salicylate, And Acetate On Cells In Vitro, Roger Scott Barron

University of the Pacific Theses and Dissertations

Salicylic acid and its concern have long been used for the management of pain, fever, and inflammation. Of this group, acetyl-salicylic acid, or aspirin (ASA) has proved to be the most potent in each case. Although hydrolysis, the first step in biotransformation of aspirin takes place very rapidly, many workers feel that the greater effectiveness is due to a unique action of the intact molecule; however, others disagree. In this study, the effects of aspirin and in vitro were compared in order to obtain a greater amount of information relating to the problem.

The Complexes Of Palladium (Ii) And Nickel (Ii) With Cycloalkanecarboxylic Acid, Thaimos E. T. Yeh

University of the Pacific Theses and Dissertations

Although some organic hydroxy acid complexes of palladium(II) and nickel(II) have been described (1-9), crystalline palladium(II) and mickel(II) dicycloalkanecarboxylates have not been reported.

The interaction of a palladium salt such as NA₂PdCl₄ or a nickel salt such as NiCl₂·6H₂ with cycloalkane carboxylic acids which contain 3, 4, 5, 6, and 7 carbons produces deep green carboxylates with palladium(II) and yellowish green carboxylates with nickel(II).

Generalization Of Lie's Counting Theorems For Second And Third Order Ordinary Differential Equations, Suzanne Marie Davison

University of the Pacific Theses and Dissertations

This work concerns two new theorems which count the maximum possible number of independent generators of a certain form which leave an ordinary differential equation of second or third order covariant. Sophus Lic has derived such theorems for a particular class of transformations. The new theorems contain Lic’s theorems as a suboase, and are therefore called ‘generalized” theorems.

La Colonisation De Quelques Grottes Du Jura Par Niphadobota Alpina Bezzi (Dipt. Tipulidae), M. J. Turquin

International Journal of Speleology

Three new localities of Niphadobota (=Chionea) alpina in the French southern Jura allow the author to state that this insect’s climatic requirements explain the biogeography of the species; the origin of the colonization of caves by this dipteran is considered.

Les Populations Naturelles De Stanasellus Virei Dollfus (Crustacé Asellote Troglobie), Guy Magniez

International Journal of Speleology

Many cavernicolous and phreatic localities are known for the species Stenasellus virei. Some of these, which harbor a rather abundant population have been studied for several years. The endemic populations from permanent waters of some fossil karstic systems seem to have an abnormal composition. They include especially large individuals (juvenile stages being rare). They differ from the phreatic populations, which exhibit a normal distribution in size groups with a normal percentage of juveniles. These differences in the structure of populations may result from physical differences between the habitat in free waters of caves and in phreatic water, and from …

Biotope Et Description De Niphargus Altagahizi N. Sp., Amphipode Gammaridé Souterrain Du Liban, N. Alouf

International Journal of Speleology

Description of a small warm cave situated along the Mediterranean shore; the temperature of water varies from 14 to 19°C. Inhabiting this cave is Niphargus altagahizi, a new species related to orcinus s.l. group. Description of this species and comparison with the other Lebanese species, N. nadarini.

A New Troglohyphantes From Bulgarian Caves (Araneae, Linyphiidae), Ch. Deltshev

International Journal of Speleology

A new species Troglohyphantes drenskii is described, which was collected in the cave “Suchata pestera” near Velingrad, Bulgaria. Troglohyphantes drenskii n.sp. belongs to the group of T. orpheus and is related to T.salax and T.pademontanus.

Ragni Delle Filippine, 1. Un Nuovo Althepus Cavernicolo Dell'isola Di Mindanao (Araneae, Ochyroceratidae), Paolo Marcello Brignoli

International Journal of Speleology

Althepus noonadanae n.sp. is described (female; male unknown; loc. typ.: Latuan Cave, Curuan district, Mindanao, Philippines); it can be distinguished from the other known species by the morphology of the chelicerae and of the female genitalia. It is not related to any of the very few described species. A key for the female Althepus is given.

Redescription Of Centromerus Bulgarianus (Drensky 1931) And Centromerus Lakatnikensis (Drensky 1931), (Araneae, Linyphiidae), Ch. Deltshev

International Journal of Speleology

The type specimens (lectotypes) of Centromerus bulgarianus and C. lakatnikensis, preserved in the collection of the Zoological Institut — BAN, Sofia, are redescribed. The redescription is necessary, because the original description is superficial and the drawings are inexact. Moreover, the male of C. lakatnikensis was unknown.

Description Du Mâle De Mexistenasellus Parzefalli (Crustacea Isopoda Asellota Cavernicole Du Mexique) Et Observations Sur Cette Espèce, Guy Magniez

International Journal of Speleology

Description of the male of the Mexican cavernicolous Stenasellid Mexistenasellus parzefalli Magniez, 1972, from Huizache Cave, San-Luis Potosi State, Mexico. In the female with a brood pouch, the coxopodit of the maxilliped contains two provisional, oostegit-like plates, whereas the ovigerous female of european Stenasellids have only the inner one. This temporary sexual female character is known in other Isopods, such as the cavernicolous Caecosphaeroma burgundum Dollfus.

Temperature Preference Responses Of Some Aquatic, Cave-Adapted Crustaceans From Central Texas And Northeastern México, William R. Elliott, Robert W. Mitchell

International Journal of Speleology

The temperature preference responses of five species of troglobite crustaceans were studied in a 15°-30°C gradient. Stygonectes hadenoecus, S. russelli and Asellus reddelli had no discernible temperature preferenda. Speocirolana bolivari had a weak preference for 20-30°C. Cirolanides texensis had a pronounced preference for 20-30°C, temperatures much warmer than that of its habitat. The lack of temperature preferenda in three species agrees with the hypothesis that imprisoned troglobites tend to lose responses to those environmental variables which are constant in caves. S. bolivari may retain its temperature selectivity because of a slow rate of cave-adaptation. It is hypothised that C. …

Le Deuxième Colloque International Sur Les Genres Niphargus Et Gammarus - Lyon, 1973 Compte-Rendu De Travail Pour Niphargus, R. Ginet

International Journal of Speleology

Following the First Colloquium held at Verona in 1969, it was planned to hold at Lyon in July, 1973, the Second International Colloquium dealing with the genus Niphargus and also with the genus Gammarus. As subject matter in discussions dealing with the first of these genera, the meeting was devoted mainly the balancing the various viewpoints (based on the European approach) and initiating a collective study of the systematics of these hypogean Amphipoda. The systematics are currently quite confused. Several modifications of the propositions of the Colloquium at Verona (published in 1972) were discussed. A third Colloquium, with the same …

A New Troglobitic Isopod Of The Genus Lirceus (Asellidae) From Southwestern Virginia, With Notes On Its Ecology And Additional Cave Records For The Genus In The Appalachians, John R. Holsinger, Thomas E. Bowman

International Journal of Speleology

Lirceus usdagalun new species, the first known troglobitic species of the genus, is described from three caves in Lee County, Virginia. The potential taxonomic value of the endopod tip of the male second pleopod, heretofore dismissed as a diagnostic character in this genus, is pointed out. Some general ecological data for the new species are presented, and cave records for other populations of Lirceus spp. from the Appalachians are given.

Un Nouvel Asellide Cavernicole D'Espagne Centrale: Bragaselius Lagari N.Sp. (Crustacea Isopoda Asellota), Jean-Paul Henry, Guy Magniez

International Journal of Speleology

Description of a new, unpigmented and eyeless Asellid, belonging to the Iberian Genus Bragasellus Henry et Magniez, 1968. The new species lives in the underground stream of the Cueva del Tornero (Checa, province of Guadalajara, central Spain).

Breeding And Fecundity In A Subterranean Mysid, Lepidomysis Longipes (Pillai And Mariamma), C. N. Nath

International Journal of Speleology

The hypogean mysid, Lepidomysis longipes has a breeding period extending from December to April with the peak period in March. A secondary breeding period appears in August and September. The females have low fecundity and carry a maximum of nine eggs. Development is delayed due to lack of nourishment in the environment. The mysids breed only once a year.

Ii Popolamento Di Ragni Nelle Grotte Tropicali (Araneae), Paolo Marcello Brignoli

International Journal of Speleology

The so called “tropical” caves (most of which are also geographically “tropical”) are distinguished from the “temperate” caves by the much larger trophic resources. Spiders are common in both kinds of caves, but the groups present in one kind are mostly absent in the other (notwithstanding that many families are distributed over at least one temperate and one tropical region). As in all temperate caves more or less the same groups of spiders can be found, so the tropical caves have a typical spider fauna, composed of different groups (often also more than those present in the temperate caves). In …

A Study To Improve Dissolved Oxygen Analysis Techniques To Facilitate Water Quality Field Survey Applications, R. W. Raible, M. K. Testerman

Arkansas Water Resources Center Technical Reports

This report describes studies made of the temperature characteristics of dissolved oxygen electrodes having a large surface area. Large area electrodes proved to have much longer lifetime between rejuvenations. Many measurements of dissolved oxygen in water need to be made in field situations where recalibration techniques would be difficult and where making temperature corrections is time consuming for operators who may be making numerous measurements. This study was directed toward design of a compensation circuit for a dissolved oxygen electrode which will give the best possible measurement over a large water temperature range of 5° - 35°C without the necessity …

A Eutrophication Model Of The White River Basin Above Beaver Reservoir In Northwest Arkansas, Robert A. Gearhart, Dee Mitchell, Louis Thibodeaux, Richard Meyers

Arkansas Water Resources Center Technical Reports

With national interest focused on man’s ever increasing degradation of the waters in this nation, it is clearly evident that an accurate assessment of all parameters influencing water quality needs to be made. Moreover, nutrient levels and budgets reflecting eutrophication trends are important parameters in the overall factors effecting water quality in lakes and reservoirs. The ability to predict future eutrophication levels will greatly enhance the retardation of the eutrophication process. Through mathematical simulation of this process, eutrophication can be analyzed and intelligent decisions regarding water quality management can be made.

Feeding Efficiency In The Cave Salamander Haideotriton Wallacei, Stewart B. Peck

International Journal of Speleology

Selection for efficiency in food capture may be a dominant influence in the evolutionary biology of predaceous cave animals. A sample of 8 Haideotriton wallacei from a natural population contained 21 feeding boluses in their digestive tracts. Fourteen of these boluses contained food, demonstrating success in at least 67% of the feeding attempts.

Beobachtungen An Markierten Und Unmarkierten Köcherfliegen (Trichoptera) In Der Bärenhöhle Im Lonetal (Schwäbischer Jura), Klaus Dobat

International Journal of Speleology

1.The Bärenhöhle, one of the ten caves situated in the episodically water-bearing valley of the Lone (Swabian Jura), serves as summer quarters for the total of ten species of Trichoptera, most of which are Micropterna nycterobia and Stenophylax permistus. 2.Counts carried out in this cave from 1967-1972 and observations of flood and dry-periods of the Lone during the same years make evident that the number of Trichoptera flying into the cave seems to depend in a large measure on the seasonal activity of the creek: a steady flow of water makes the undisturbed development of larvae possible and results …

A New Cavernicolous Species Of The Pseudoscorpion Genus Roncus L. Koch, 1873 (Neobisiidae, Pseudoscorpiones) From The Balkan Peninsula, Božidar P. M. Ćurčić

International Journal of Speleology

Roncus (Parablothrus) pljakici, a new species of cave living pseudoscorpions, is described from the cave ‘Pecina u selu Vrelo’ on Mt. Stara Planina, East Serbia. The problem of its taxonomic position in the subgenus is discussed. The new species is the first representative of Parablothrus to be found in Serbia. It seems possible that R. (P.) pljakici represents an endemic species, specialized for a cavernicolous way of living. The analogies of this and other species of the subgenus point to some similar phenomena which occur in other genera of Balkan false scorpions (Ćurčić 1972). In all these cases, a …

Sur Un Nouvel Amphipode Souterrain De Bulgarie Niphargus Kochianus Melticensis N. Ssp., Dan Dancau, Stoitze Andreev

International Journal of Speleology

A new subspecies of Amphipode is described, being the first representative of the Niphargus kochianus group in Bulgaria. The new subspecies resembles N. k. tamanini Ruffo, N. k. petrosani Dobr. et Manolache, N. k. labacensis Sket, N. k minor Sket, for the maxille I having one single hair on the internal lobe and a single combed spine on the external lobe. However, it differs neatly from all other subspecies by the length of the nails on the dactyl and by the peculiar form and the chetotaxia of the telson.

Xlix Contribution To The Knowledge Of The Amphipoda. On Three Niphargus Species (Fam. Gammaridae) From The Balkans, Gordan S. Karaman

International Journal of Speleology

Three Niphargus species from the Balkans are studied. Niphargus adbiptus, n. sp. is described from Ravanica cave in Serbia. Niphargus stygius ravanicanus S. Kar. 1943 from the same cave (Ravanica) is redescribed. N. valachicus Dobr. Man. 1933, is newly recorded from Bulgaria (Devnja).

Fluorescent Dye Determination Of Groundwater Movement And Contamination In Permeable Rock Strata, Charles P. Giammona

International Journal of Speleology

A preliminary inquiry to the extent and boundaries of subterranean waterways within the Mystery Cave System was explored. Rhodamine WT dye in 500 ml quantities was used in fluormetry determinations of surface flow to ground water basins. A Turner Model 111 fluorometer was utilized for detection purposes powered by a portable 12 volt, 220 amp hour battery-inverter system. It was shown that water entered underground passageways through sinkholes or highly creviced limestone/dolomite rock strata and reappeared several kilometres downstream. The outflow appears in the form of “springs”. The possibility exists that contaminated surface water may seep through the soil for …

Observations Sur La Faune Aquatique Souterraine De Cuba, L. Botosaneanu

International Journal of Speleology

A short account on some achievements of the cubano-romanian biospeleological expeditions to Cuba in the study of the aquatic subterranean faunas. The following divisions of the aquatic subterranean realm are reviewed together with their most characteristic faunal elements: “guano pools” and rimstone pools in the vadose zone of the caves; underground streams; water table (and other) lakes in the caves; “pozzos” carved in the limestone, and “grietas” which are vertical clefts in the limestone of marine terraces, giving access to fresh- or to brackish water; the interstitial of the marine beaches; the underflow of running waters. At present, thorough biospeleological …

Note Sulla Distribuzione Dei Trichoniscidae In Sardegna (Crustacea, Isopoda, Oniscoidea), Roberto Argano, Mauro Rampini

International Journal of Speleology

The study of the biogeography of the eight species of Isopoda Trichoniscidae from Sardegna brings to consider the faunistic relationships happened in the past between the island and the Pyrenees. Two of the species are eutroglophilous and rather widespread; the other six are troglobic and endemic to Sardinia. Five of the latter show strong affinity to Pyrenees forms. A detailed description is given of the distribution of the various species. This distribution makes possible some observations on the history of the fauna of the island.

The Evolution Of The Eastern North American Isopods Of The Genus Asellus (Crustacea: Asellidae) Part Ii, Laurence E. Fleming

International Journal of Speleology

This paper is the second in the three part series dealing with the evolution of the North American isopods of the genus Asellus. The generic status of Asellus is discussed with emphasis placed on the newly proposed genera of Henry and Magniez (1968). Use is made of comparative anatomical and where feasible statistical methods during this investigation. The first, shorter portion of the study deals with the presentation of evidence supporting the viewpoint that if "Pseudobaicalasellus” is to be considered a valid genus then it must include the members of the Cannulus Group of Steeves (1965). The …

Aspetti Ecologici Ed Evolutivi Del Popolamento Di Grotte Temperate E Tropicali: Osservazioni Sul Ciclo Biologico Di Alcune Specie Di Ptomaphagus (Coleoptera Catopidae), Valerio Sbordoni, Marina Cobolli-Sbordoni

International Journal of Speleology

Differences between tropical and temperate cave communities are an important topic in the actual biospeleological thinking. Among the most striking differences is the paucity of terrestrial troglobites in tropical caves. This fact may depend on the higher energy input into tropical caves which lessens the selection pressures for energy-economizing troglobite adaptations. Consequently evolutionary rates would be slowed in tropical caves and, in a date group, troglobites would appear later in such caves than in temperate ones with lower energy input. In order to investigate this point the authors studied the degree of adaptation to the cave environment in two species …