Physical Sciences and Mathematics Commons^™

Homework 2: Intro To Data Science ( Week Two), Grant Long, Nyc Tech-In-Residence

Open Educational Resources

Homework assignment for the course "CSC 59970: Intro to Data Science" (Week Two) delivered at the City College of New York in Fall 2018 by Grant Long as part of the Tech-in-Residence Corps program.

Intro To Data Science - Guest Lecture On Deep Learning (Week Thirteen), Grant Long, Nyc Tech-In-Residence Corps

Open Educational Resources

Lecture for the course "CSC 59970: Intro to Data Science" (Week Thirteen) delivered at the City College of New York in Fall 2018 by Grant Long as part of the Tech-in-Residence Corps program.

Intro To Data Science - Ml 1 (Week Nine), Grant Long, Nyc Tech-In-Residence Corps

Open Educational Resources

Lecture for the course "CSC 59970: Intro to Data Science" (Week Nine) delivered at the City College of New York in Fall 2018 by Grant Long as part of the Tech-in-Residence Corps program.

Homework 5: Intro To Data Science (Week Five), Grant Long, Nyc Tech-In-Residence Corps

Open Educational Resources

Homework Assignment for the course "CSC 59970: Intro to Data Science" (Week Five) delivered at the City College of New York in Fall 2018 by Grant Long as part of the Tech-in-Residence Corps program.

Homework 7: Intro To Data Science (Week Eleven), Grant Long, Nyc Tech-In-Residence Corps

Open Educational Resources

Homework Assignment for the course "CSC 59970: Intro to Data Science" (Week Eleven) delivered at the City College of New York in Fall 2018 by Grant Long as part of the Tech-in-Residence Corps program.

Test: Intro To Data Science - Midterm Review, Grant Long, Nyc Tech-In-Residence Corps

Open Educational Resources

Test for the course "CSC 59970: Intro to Data Science" (Midterm Review) delivered at the City College of New York in Fall 2018 by Grant Long as part of the Tech-in-Residence Corps program.

A Tool For Optimizing Java 8 Stream Software Via Automated Refactoring, Raffi T. Khatchadourian, Yiming Tang, Mehdi Bagherzadeh, Syed Ahmed

Publications and Research

Streaming APIs are pervasive in mainstream Object-Oriented languages. For example, the Java 8 Stream API allows for functional-like, MapReduce-style operations in processing both finite and infinite data structures. However, using this API efficiently involves subtle considerations like determining when it is best for stream operations to run in parallel, when running operations in parallel can be less efficient, and when it is safe to run in parallel due to possible lambda expression side-effects. In this paper, we describe the engineering aspects of an open source automated refactoring tool called Optimize Streams that assists developers in writing optimal stream software in …

The Role Of Proton Transport In Gating Current In A Voltage Gated Ion Channel, As Shown By Quantum Calculations, Alisher M. Kariev, Michael E. Green

Publications and Research

Over two-thirds of a century ago, Hodgkin and Huxley proposed the existence of voltage gated ion channels (VGIC) to carry Na⁺ and K⁺ ions across the cell membrane to create the nerve impulse, in response to depolarization of the membrane. The channels have multiple physiological roles, and play a central role in a wide variety of diseases when they malfunction. The first channel structure was found by MacKinnon and coworkers in 1998. Subsequently the structure of a number of VGIC was determined in the open (ion conducting) state. This type of channel consists of four voltage sensing domains …

Observed Differences Between Near-Surface Air And Skin Temperatures Using Satellite And Ground-Based Data, Satya Prakash, Farjana Shati, Hamidreza Norouzi, Reginald Blake

Publications and Research

Accurate estimates of long-term land surface temperature (T_s) and near-surface air temperature (T_a) at finer spatio-temporal resolutions are crucial for surface energy budget studies, for environmental applications, for land surface model data assimilation, and for climate change assessment and its associated impacts. The Atmospheric Infrared Sounder (AIRS) and Moderate Resolution Imaging Spectroradiometer (MODIS) sensors onboard the Aqua satellite provide a unique opportunity to estimate both temperatures twice daily at the global scale. In this study, differences between T_a and T_s were assessed locally over regions of North America from 2009 to 2013 …

Preparation And Characterization Of Chemically-Modified Biomaterials And Their Application As Adsorbents Of Penicillin G, Jesie Silva, Lizebel Morante, Tesfamichael Demeke, Jacqueline Baah-Twum, Abel E. Navarro

Publications and Research

The prevalence of antibiotics in water creates microbial resistance and has a negative impact on the ecosystem. Biomaterials such as spent tea leaves are rich in functional groups and are suitable for chemical modification for diverse applications. This research proposes the use of spent tea leaves of chamomile (CM), green tea (GT), and peppermint (PM) as structural scaffolds for the incorporation of carboxyl, sulfonyl, and thiol groups to improve the adsorption of Penicillin G (Pe). Adsorbents characterization reported a higher number of acidic functional groups, mainly in thiolated products. Scanning electron microscopy (SEM) analysis showed changes on the surfaces of …

The Diverse Magneto-Optical Selection Rules In Bilayer Black Phosphorus, Jhao-Ying Wu, Szu-Chao Chen, Thi-Nga Do, Wu-Pei Su, Godfrey Gumbs, Ming-Fa Lin

Publications and Research

The magneto-optical properties of bilayer phosphorene is investigated by the generalized tight-binding model and the gradient approximation. The vertical inter-Landau-level transitions, being sensitive to the polarization directions, are mainly determined by the spatial symmetries of sub-envelope functions on the distinct sublattices. The anisotropic excitations strongly depend on the electric and magnetic fields. A uniform perpendicular electric field could greatly diversify the selection rule, frequency, intensity, number and form of symmetric absorption peaks. Specifically, the unusual magneto-optical properties appear beyond the critical field as a result of two subgroups of Landau levels with the main and side modes. The rich and …

Rationality And Efficient Verifiable Computation, Matteo Campanelli

Dissertations, Theses, and Capstone Projects

In this thesis, we study protocols for delegating computation in a model where one of the parties is rational. In our model, a delegator outsources the computation of a function f on input x to a worker, who receives a (possibly monetary) reward. Our goal is to design very efficient delegation schemes where a worker is economically incentivized to provide the correct result f(x). In this work we strive for not relying on cryptographic assumptions, in particular our results do not require the existence of one-way functions.

We provide several results within the framework of rational proofs introduced by Azar …

Linear Progress With Exponential Decay In Weakly Hyperbolic Groups, Matthew H. Sunderland

Dissertations, Theses, and Capstone Projects

A random walk w_n on a separable, geodesic hyperbolic metric space X converges to the boundary ∂X with probability one when the step distribution supports two independent loxodromics. In particular, the random walk makes positive linear progress. Progress is known to be linear with exponential decay when (1) the step distribution has exponential tail and (2) the action on X is acylindrical. We extend exponential decay to the nonacylindrical case. We give an application to random Heegaard splittings.

Nmr Characterizations Of Candidate Battery Electrolytes, Stephen A. Munoz

Dissertations, Theses, and Capstone Projects

Enormous strides have been made in next-generation power sources to build a more sustainable society. Energy storage has become a limiting factor in our progress, and there are huge environmental and financial incentives to find the next step forward in battery technology. This work discusses NMR methods for characterizing materials for use in battery application, with a special focus on relaxometry and diffusometry. Examples are provided of various recent investigations involving novel candidate electrolyte materials with different collaborators. Works discussed in this thesis include: the characterization of a new disruptive solid polymer electrolyte technology, investigations of the dynamics of super …

Supercharged Models Of Intrinsically Disordered Proteins And Their Utility In Sensing, Peter J. Schnatz

Dissertations, Theses, and Capstone Projects

In this thesis I show that greatly increasing the magnitude of a protein’s net charge using surface supercharging transforms that protein into a ligand-gated or counterion-gated conformational molecular switch. To demonstrate this I first modified the designed helical bundle hemoprotein H4 using simple molecular modeling, creating a highly charged protein which both unfolds reversibly at low ionic strength and undergoes the ligand-induced folding transition commonly observed in signal transduction by intrinsically disordered proteins in biology. Due to the high surface charge density, ligand binding to this protein is allosterically activated by low concentrations of divalent cations and the polyamine spermine. …

Regulation Of Dissolved Arsenic Using Zero-Valent Iron With Gypsum And Sulfate Reducing Bacteria: Laboratory Microcosm And Column Studies, Ying Liu

Dissertations, Theses, and Capstone Projects

Bench scale microcosm incubation was first conducted in two stages to examine the removal of arsenic (As) by zero-valent iron (ZVI) in the presence of sulfate reducing bacteria, gypsum as well as organic substrates under anaerobic condition. About 98% of dissolved As was removed from solution within 20 days with concurrent decrease of dissolved sulfate and growth of bacterial population. Mineralogy analysis using SEM-EDS found the formation of iron sulfide and Fourier-transformed infrared (FTIR) spectroscopy analysis indicates that some As is associated with pyrite. The main iron corrosion product was found as ferrihydrite with traces of lepidocrocite. Sequential leaching shows …

Galois Groups Of Differential Equations And Representing Algebraic Sets, Eli Amzallag

Dissertations, Theses, and Capstone Projects

The algebraic framework for capturing properties of solution sets of differential equations was formally introduced by Ritt and Kolchin. As a parallel to the classical Galois groups of polynomial equations, they devised the notion of a differential Galois group for a linear differential equation. Just as solvability of a polynomial equation by radicals is linked to the equation’s Galois group, so too is the ability to express the solution to a linear differential equation in "closed form" linked to the equation’s differential Galois group. It is thus useful even outside of mathematics to be able to compute and represent these …

Fundamental Chemistry Related To The Separations And Coordination Of Actinium-225, Thorium-227, And Technetium-99, Jasmine L. Hatcher

Dissertations, Theses, and Capstone Projects

This work explores the fundamental chemistry of actinium, thorium, and technetium in an effort to develop methodologies which help to address complications specific to each of these elements. Developing fundamental knowledge in inorganic chemistry has the power to meaningfully address a number of real world problems. By using simple systems and experiments like following an electron or changing the solvent system, we are able to gain invaluable information which can be used to address major issues.

Actinium-225 (t_½: 9.92 d) is an alpha-emitting radionuclide with nuclear properties well suited for alpha therapy of malignant tumors. The present global …

Ulva Spp. Bloom Dynamics In A Hyper-Eutrophic Estuary: Jamaica Bay, New York, Annesia Lamb

Dissertations, Theses, and Capstone Projects

In this dissertation, I present three studies that further our understanding of macroalgae identity, growth, and proliferation. Eutrophication is prevalent in shallow coastal ecosystems world-wide. One of the ecosystem consequences is the development of a bloom forming green marine macroalgae, Ulva spp. Ulva can have negative effects such as Zostera spp. degradation, fish, and shellfish declines. I performed assessments of (1) identity of the bloom-forming Ulva and other macroalgae assemblage, (2) physical, chemical, and biological drivers of Ulva bloom growth and proliferation, and (3) optimal irradiance and temperature requirements for early growth stages in Ulva linza.

The first study …

Digital Storytelling [Natural Sciences], Preethi Radhakrishnan

Open Educational Resources

A well-crafted and executed storytelling assignment can serve as an efficient and engaging learning activity which targets the three highest levels of Blooms’ taxonomy which are to Create, Evaluate and Analyze. This digital storytelling assignment is part of a signature assignment series (Stage 1) conducted in all courses of the First Year Seminar for Natural Sciences (NSF101). Students begin collecting pictures and videos for their assignment from the 3^rd week of the semester on a flash drive. During the fourth week of the semester, the instructor first describes the storytelling process and stages. This is followed by learning around …

Private-Key Fully Homomorphic Encryption For Private Classification Of Medical Data, Alexander N. Wood

Dissertations, Theses, and Capstone Projects

A wealth of medical data is inaccessible to researchers and clinicians due to privacy restrictions such as HIPAA. Clinicians would benefit from access to predictive models for diagnosis, such as classification of tumors as malignant or benign, without compromising patients’ privacy. In addition, the medical institutions and companies who own these medical information systems wish to keep their models private when used by outside parties.

Fully homomorphic encryption (FHE) enables practical polynomial computation over encrypted data. This dissertation begins with coverage of speed and security improvements to existing private-key fully homomorphic encryption methods. Next this dissertation presents a protocol for …

Iron Oxide Nanomagnets In Polymer Matrices – Synthesis And Characterization, Shenjie Qiu

Dissertations, Theses, and Capstone Projects

Magneto-responsive polymer-iron oxide materials have been fabricated by coating various polymers on iron oxide nanoparticles (NPs). The stability of magneto-responsive polymer-iron oxide materials relies on the selection of appropriate coating anchors, such as catechols and silanes. This dissertation describes two robust polymer coating systems on iron oxide NPs. One system focuses on thermo-responsive nitrated catechol-N-isopropylacrylamide polymers with binding enhancement factors (EnF) of ~40 and ~20 towards iron oxide NPs and a boronic acid compared to the polymers without the nitro group. The second system involves coating of poly(vinyl alcohol) (PVA) on iron oxide NPs via a silane anchor …

Personality Recognition For Deception Detection, Guozhen An

Dissertations, Theses, and Capstone Projects

Personality aims at capturing stable individual characteristics, typically measurable in quantitative terms, that explain and predict observable behavioral differences. Personality has been proved to be very useful in many life outcomes, and there has been huge interests on predicting personality automatically. Previously, there are tremendous amount of approaches successfully predicting personality. However, most previous research on personality detection has used personality scores assigned by annotators based solely on the text or audio clip, and found that predicting self-reported personality is a much more difficult task than predicting observer-report personality. In our study, we will demonstrate how to accurately detect self-reported …

A Network Theoretical Approach To Real-World Problems: Application Of The K-Core Algorithm To Various Systems, Kate Burleson-Lesser

Dissertations, Theses, and Capstone Projects

The study of complex networks is, at its core, an exploration of the mechanisms that control the world in which we live at every scale, from particles no bigger than a grain of sand and amino acids that comprise proteins, to social networks, ecosystems, and even countries. Indeed, we find that, regardless of the physical size of the network's components, we may apply principles of complex network theory, thermodynamics, and statistical mechanics to not only better understand these specific networks, but to formulate theories which may be applied to problems on a more general level. This thesis explores several networks …

Domain-Specific Knowledge Exploration With Ontology Hierarchical Re-Ranking And Adaptive Learning And Extension, Grace G. Zhao

Dissertations, Theses, and Capstone Projects

The goal of this research project is the realization of an artificial intelligence-driven lightweight domain knowledge search framework that returns a domain knowledge structure upon request with highly relevant web resources via a set of domain-centric re-ranking algorithms and adaptive ontology learning models. The re-ranking algorithm, a necessary mechanism to counter-play the heterogeneity and unstructured nature of web data, uses augmented queries and a hierarchical taxonomic structure to get further insight into the initial search results obtained from credited generic search engines. A semantic weight scale is applied to each node in the ontology graph and in turn generates a …

List, Sample, And Count, Ali Assarpour

Dissertations, Theses, and Capstone Projects

Counting plays a fundamental role in many scientific fields including chemistry, physics, mathematics, and computer science. There are two approaches for counting, the first relies on analytical tools to drive closed form expression, while the second takes advantage of the combinatorial nature of the problem to construct an algorithm whose output is the number of structures. There are many algorithmic techniques for counting, they cover the explicit approach of counting by listing to the approximate approach of counting by sampling.

This thesis looks at counting three sets of objects. First, we consider a subclass of boolean functions that are monotone. …

Charge State Dynamics And Quantum Sensing With Defects In Diamond, Jacob D. Henshaw

Dissertations, Theses, and Capstone Projects

In recent years, defect centers in wide band gap semiconductors such as diamond, have received significant attention. Defects offer great utility as single photon emitters, nanoscale sensors, and quantum memories and registers for quantum computation. Critical to the utility of these defects, is their charge state.

In this dissertation, experiments surrounding the charge state dynamics and the carrier dynamics are performed and analyzed. Extensive studies of the ionization and recombination processes of defects in diamond, specifically, the Nitrogen Vacancy (NV) center, have been performed. Diffusion of ionized charge carriers has been imaged indirectly through the recapture of said carriers by …

Impacts Of Climate Extremes On Terrestrial Productivity, Suhua Wei

Dissertations, Theses, and Capstone Projects

Terrestrial biosphere absorbs approximately 28% of anthropogenic CO₂ emissions. This terrestrial carbon sink might become saturated in a future climate regime. To explore the issues associated with this topic, an accurate estimate of gross primary production (GPP) of global terrestrial ecosystems is needed. A major uncertainty in modeling global terrestrial GPP is the parameter of light use efficiency (LUE). Most LUE estimates in global models are satellite-based and coarsely measured with emphasis on environmental variables. Others are from eddy covariance towers with much greater spatial and temporal data quality and emphasis on mechanistic processes, but in a limited number …

Studying The Space Of Almost Complex Structures On A Manifold Using De Rham Homotopy Theory, Bora Ferlengez

Dissertations, Theses, and Capstone Projects

In his seminal paper Infinitesimal Computations in Topology, Sullivan constructs algebraic models for spaces and then computes various invariants using them. In this thesis, we use those ideas to obtain a finiteness result for such an invariant (the de Rham homotopy type) for each connected component of the space of cross-sections of certain fibrations. We then apply this result to differential geometry and prove a finiteness theorem of the de Rham homotopy type for each connected component of the space of almost complex structures on a manifold. As a special case, we discuss the space of almost complex structures …

A Stereospecific Pd-Catalyzed Suzuki Cross-Coupling Reaction And A Statistical Study Of The Ligand's Role In Stereoselection, Shibin Zhao

Dissertations, Theses, and Capstone Projects

The development of palladium-catalyzed carbon-carbon cross-coupling reactions has profoundly influenced the manner through which we approach the synthesis of complex organic molecules. Among established cross-coupling reactions, which include Kumada, Negishi, and Stille reactions, the Suzuki cross-coupling reaction exhibits particularly wide functional group compatibility, while employing non-toxic, air-stable organoboron nucleophiles. Conventional studies of Pd-catalyzed Suzuki cross-coupling reactions have focused on C(sp²)-C(sp²) cross-coupling reactions, which result in the formation of planar products. Conceptually, the use of C(sp³) (secondary) nucleophiles would enable the reliable manipulation of organic molecules in three dimensions. However, this process has not been …