Physical Sciences and Mathematics Commons^™

High Resolution Imaging Of Single Nanoparticles And Two-Dimensional Nano-Material By Scanning Electrochemical Microscopy, Tong Sun

Dissertations, Theses, and Capstone Projects

Electrochemistry at nanostructured interfaces is of significant current interest. Metal nanoparticles (NPs) and two-dimensional semiconductor nanomaterial are particularly important because of their applications in catalysis, energy conversion and storage, sensors, and medicine. Electrocatalytic processes at such nanostructured interfaces are essential for the generation of hydrogen and other types of fuels and photochemical energy conversion. Nanoscale electrochemical experiments require the fabrication and characterization of nanometer-size electrochemical probes. The main advantages of the nanoprobes include very fast mass-transfer rate, high signal-to-noise ratio and extremely fine spatial resolution of electrochemical imaging. During my Ph.D. research, nanoscale disk-type platinum electrochemical probes were developed for …

The Philosophical Foundations Of Plen: A Protocol-Theoretic Logic Of Epistemic Norms, Ralph E. Jenkins

Dissertations, Theses, and Capstone Projects

In this dissertation, I defend the protocol-theoretic account of epistemic norms. The protocol-theoretic account amounts to three theses: (i) There are norms of epistemic rationality that are procedural; epistemic rationality is at least partially defined by rules that restrict the possible ways in which epistemic actions and processes can be sequenced, combined, or chosen among under varying conditions. (ii) Epistemic rationality is ineliminably defined by procedural norms; procedural restrictions provide an irreducible unifying structure for even apparently non-procedural prescriptions and normative expressions, and they are practically indispensable in our cognitive lives. (iii) These procedural epistemic norms are best analyzed in …

Characterization And Quantification Of Covalent Modification Of Proteins Using Mass Spectrometry, Pratikkumar N. Rathod

Dissertations, Theses, and Capstone Projects

Identification and characterization of various post-translational modifications of protein is a key to understanding many unknown cellular processes. In the last few decades, mass spectrometry has evolved as an essential and effective analytical tool for qualitative and quantitative analysis of proteins. In this research, we have developed a novel MALDI-MS² based quantification method for Desmosine and Isodesmosine, which served as cross-linking amino acids of elastin, in order to measure the elastin degradation in the body. This is the first quantification method that not only illustrates the potential of MALDI-Ion Trap MS², but also improvement over the current …

Using Cogenerative Dialogue To Catalyse Change, Carol A. Woodburn-Mcdonald

Dissertations, Theses, and Capstone Projects

Cogenerative dialogue is an empowering pedagogical approach to advance research. In my study cogenerative dialogue and coteaching were employed in an algebra 1 class in an urban high school in New York City. Lessons were cotaught with students and were videotaped for further analysis. The findings suggest that cogens constitute an excellent avenue to catalyze change in an urban algebra class.

Nuclear Magnetic Resonance Studies Of Imidazolium-Based Ionic Liquids And Garnet-Type Li7la3zr2o12, Shen Lai

Dissertations, Theses, and Capstone Projects

Advancements in electrochemical energy storage materials are critical in the development and utilization of renewable energy technologies. These advancements involve obtaining a better understanding of electrochemical mechanisms and properties through scientific research towards an improved energy storage technology. Nuclear magnetic resonance (NMR), is a sensitive and selective method to probe particle dynamics (magnetic relaxation, diffusometry, etc.) and material structures (spectroscopy) down to the atomic level. In this work, several NMR techniques are employed to study imidazolium-based ionic liquids and garnet-type inorganic materials. These are being studied due to their potential use as safer alternatives to organic solvent-based electrolytes in lithium-ion …

Interdisciplinary Studies Of Complex Network And Machine Learning And Its Applications, Shaojun Luo

Dissertations, Theses, and Capstone Projects

In this dissertation, we introduce the concept of network-based statistical inference methods of two types: network structure inference and variable inference. For network structure inference, we introduce correlation matrix, graphical Lasso, network clustering and identify the influencer in the network. For variable inference, we also introduce from Bayesian network, to Random Markov Field and Ising Model, Boltzmann and Restricted Boltzmann machine and the algorithm of Belief Propagation. Last but not the least, we introduce the most widely used neural network family and its two main types: Convolutional Neural Network and Recurrent Neural Network.

In Chapter 3 we provide an example …

Direct Experimental Evidence Of Toroidal Symmetry In A Lanthanide-Based Molecular Magnet, Qing Zhang

Dissertations, Theses, and Capstone Projects

Molecular magnets (MM) are finite clusters of identical exchange-coupled magnetic systems arranged within a crystalline array such that interactions between neighboring MMs are negligible. Their small size has proven them amenable test beds for the investigation of a wide range of fundamental quantum phenomena such as spin frustration quantum tunneling (QT) of magnetization and Neel vector quantum coherence and Berry phase interference.

Cases where MMs have been found to exhibit quantum wave-functions that evolve coherently are particularly interesting due to their potential for use in quantum information processing. Toroidal magnetic moments, a kind of MM, have fascinating properties that could …

Investigation Of Biogeochemical Mechanisms Of Greenhouse Gas Production In The Urban Hudson River Estuary, Brian Alan Brigham

Dissertations, Theses, and Capstone Projects

Coastal megacities deposit significant amounts of carbon (C), nitrogen (N) and other pollutants into surrounding waters. These inputs, including wastewater and surface water runoff, may affect estuarine and adjacent wetland biogeochemical cycles, microbial production and ultimately greenhouse gas (GHG) efflux. In many megacities pollutant loading is typically greatest after periods of precipitation when the volume of wastewater and storm water runoff exceeds local sanitation capacity, resulting in the discharge of raw sewage into adjacent waters. These combined sewage overflow (CSO) events have received considerable attention primarily due to their potential impact on human health and eutrophication. However, whether these events …

Quantifying The Effects Of Wind Regimes And Temperature On Surface Melt Over The Antarctic Peninsula (1982–2017) Through Modeling, Remote Sensing And In-Situ Data, Rajashree Datta

Dissertations, Theses, and Capstone Projects

Surface melting over the Antarctic Peninsula (AP) plays a crucial role for the stability of ice shelves and dynamics of grounded ice, hence modulating the mass balance in a region of the world which is particularly sensitive to increasing surface temperatures. Understanding the processes that drive melting using surface energy and mass balance models is fundamental to improving estimates of current and future surface melting and associated sea level rise through ice-shelf collapse. This is even more important in view of the specific challenges presented by how circulation patterns over the topographically-complex Antarctic Peninsula, especially foehn winds, impact surface melt. …

Quantum And Classical Transport Of 2d Electrons In The Presence Of Long And Short Range Disorder, Jesse Kanter

Dissertations, Theses, and Capstone Projects

This work focuses on the study of electron transport of 2-D electron gas systems in relation to both fundamental properties of the systems such as disorder and scattering mechanisms, as well as unique magnetoresistance (MR) effects. A large portion of the discussion is built around the use of an in plane magnetic field to vary the ratio between the Zeeman energy between electrons of different spins and the Landau level spacing, creating a tool to control the quantization of the density of states (DOS).

This tool is first used to isolate Quantum Positive Magnetoresistance (QPMR), which grants insight to the …

The Development Of Novel Platforms For The Imaging Of Cancer By Positron Emission Tomography, Brendon E. Cook

Dissertations, Theses, and Capstone Projects

The role of antibody-based imaging of cancer by positron emission tomography (PET) has expanded significantly in recent years and is poised to radically alter the way that cancer is diagnosed and treated. However, one hurdle that remains is the potentially harmful radiation dose that comes from these imaging agents, as the long circulation time of antibodies (days to weeks) necessitates the use of radionuclides with comparable physical half-lives (i.e. ⁸⁹Zr, ¹²⁴I, etc.). One particularly promising solution is the use of the inverse electron demand Diels-Alder (IEDDA) reaction between a 1,2,4,5-tetrazine (Tz) and a trans-cyclooctene (TCO) for pretargeting. …

Enhancing 3d Visual Odometry With Single-Camera Stereo Omnidirectional Systems, Carlos A. Jaramillo

Dissertations, Theses, and Capstone Projects

We explore low-cost solutions for efficiently improving the 3D pose estimation problem of a single camera moving in an unfamiliar environment. The visual odometry (VO) task -- as it is called when using computer vision to estimate egomotion -- is of particular interest to mobile robots as well as humans with visual impairments. The payload capacity of small robots like micro-aerial vehicles (drones) requires the use of portable perception equipment, which is constrained by size, weight, energy consumption, and processing power. Using a single camera as the passive sensor for the VO task satisfies these requirements, and it motivates the …

Flexible And Versatile Soft Templates For Mesoporous Silicas And Organosilicas Based On Pluronic Block Copolymer Surfactants And Their Mixtures, George Farid

Dissertations, Theses, and Capstone Projects

In this dissertation, the work will be discussed that was focused on the synthesis of consolidated periodic mesoporous materials such as 2-D hexgonal ordered mesoporous silicas (SBA-15) as well as single-micelle-templated silica and organosilica nanotubes and nanospheres using triblock copolymer surfactants and their mixtures in the presence of a swelling agent. The introductory section, Chapter 1, will address the current state of the tunability of single-micelle-templated silica and organosilica nanotubes and will compare it with the work presented in this dissertation on the use of a dual-surfactant templating systems. Chapter 2 of the dissertation discusses transmission electron microscopy characterization of …

Synthesis And Evaluation Of Densely-Functionalized Troponoids, Danielle R. Hirsch

Dissertations, Theses, and Capstone Projects

Herein, we document our efforts to expand the scope of troponoid synthetic methodology towards densely-substituted scaffolds. This body of work has focused primarily on an oxidopyrylium cycloaddition/ring-opening strategy for the synthesis and biochemical evaluation of troponoids for assistance in a variety of medicinal chemistry studies. In Chapter 1, we outline the use of this synthetic strategy in the profiling of a library of synthetic αHTs against an aminoglycoside antibiotic resistance enzyme known as aminoglycoside-2’’-O-nucleotidyltransferase [ANT(2’’)-Ia]. Enzymatic mechanistic insights have been gleaned from an assessment of troponoid/antibiotic synergistic potential. In particular, two synthetic constructs were identified as promising antibiotic adjuvant candidates, …

Baryons And Interactions In Magnetic Fields, Amol Deshmukh

Dissertations, Theses, and Capstone Projects

The QCD external field problem allows one to probe the rich behavior of strongly interacting systems under external conditions, including the modification of hadron structure and interactions due to external electromagnetic fields. These dynamics, moreover, are likely relevant to describe the physics in the interiors of magnetars and in non-central heavy-ion collisions, for which large magnetic fields upwards of $10^{19}$ Gauss are conceivable. Additionally motivated by lattice QCD calculations in external fields, we study the behavior of single- and two-baryon (specifically, two-nucleon) systems in large magnetic fields. The dependence of single-baryon energies on magnetic fields is explored using chiral dynamics. …

Master Integrals For Double Real Radiation Emission In Heavy-To-Light Quark Decay, Roberto Bonciani, Alessandro Broggio, Leandro Cieri, Andrea Ferroglia

Publications and Research

We evaluate analytically the master integrals for double real radiation emission in the b→uW∗" role="presentation" style="box-sizing: inherit; display: inline-block; line-height: normal; word-spacing: normal; overflow-wrap: normal; text-wrap: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; position: relative;">𝑏→𝑢𝑊∗ decay, where b and u are a massive and massless quark, respectively, while W∗" role="presentation" style="box-sizing: inherit; display: inline-block; line-height: normal; word-spacing: normal; overflow-wrap: normal; text-wrap: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; position: relative;">𝑊∗ is an off-shell charged …

Burning Man’S Mathematical Underbelly, Seth S. Cottrell

Publications and Research

A math degree can take you to a lot of places, both physically and figuratively, and if you play your cards right, you too can argue counterfactual definiteness with a shaman. First in 2008, and several times since, a fellow math PhD and I traveled to the Burning Man art festival to sit in the desert and talk with the locals about whatever they happened to be curious about.

Kinetic Effects In 2d And 3d Quantum Dots: Comparison Between High And Low Electron Correlation Regimes, Marlina Slamet, Viraht Sahni

Publications and Research

Kinetic related ground state properties of a two-electron 2D quantum dot in a magnetic field and a 3D quantum dot (Hooke's atom) are compared in the Wigner high (HEC) and low (LEC) electron correlation regimes. The HEC regime corresponds to low densities sufficient for the creation of a Wigner molecule. The LEC regime densities are similar to those of natural atoms and molecules. The results are determined employing exact closed-form analytical solutions of the Schrödinger-Pauli and Schrödinger equations, respectively. The properties studied are the local and nonlocal quantal sources of the density and the single particle density matrix; the kinetic …

Mathematical Inquiry With Loops, Jeanne Funk

Open Educational Resources

Mathematical Inquiry with Loops is a fun activity designed to introduce students in LMF101 (First Year Seminar for Liberal Arts: Math and Science) to mathematical exploration and hypothesis formation via hands-on exploration with paper loops. It should make students understand that the “facts” that make up mathematics, are not arbitrary, but arise from observation and experience. It should also encourage students to view mathematics as a science rooted in exploration and problem solving, rather than an esoteric exercise in symbol manipulation.

This activity is designed to be very low stakes (ungraded) and to take one hour of class time. There …

Academic Interests, Career Choices And Job Opportunities, Doyel Pal, Praveenkumar Khethavath

Open Educational Resources

This assignment is designed for students in First Year Seminar for Engineering and Computer Science. The main goal of the assignment is to introduce students to their major and stimulating their interests related to career choices and academics. This will give students a chance to develop integrative learning skills by making connections between their major and respective career opportunities. This assignment will use new features of ePortfolio to enhance student’s creativity by customizing everything from background, photos, fonts, text, portfolio content etc. Instead of a uniform profile, each students’ page will reflect the distinct visual representation of their personality, brand, …

Hydrocarbon Reaction Experiment [Chemistry], Kevin Mark

Open Educational Resources

The Foundations of Chemistry SCC 110 course is required for LaGuardia’s Health Sciences students interested in the Nursing, Dietetic Technician and Veterinary Technician programs. This course has been designated for the Inquiry and Problem Solving competency as well the Digital Communication ability. SCC 110 students will use SCC 110 lecture material and information in the SCC 110 lab manual to perform an electrophilic addition. Students will be able to correlate the organic theory concepts with the experiment by making physical observations (e.g., color changes) when carrying out the lab procedures. The student findings will be synthesized and expressed by making …

Zero Textbook Cost Syllabus For Cis 2200h (Introduction To Information Systems And Technologies), Curtis Izen

Open Educational Resources

This course introduces students to information systems in business. Due to the rapid developments in Information Technology (IT) and the dramatic changes brought by these new technologies in the way companies operate, compete and do business, familiarity with information systems has become indispensable for the leaders of today and tomorrow's organizations.

Building Test Anonymity Networks In A Cybersecurity Lab Environment, John Schriner

Student Theses

This paper explores current methods for creating test anonymity networks in a laboratory environment for the purpose of improving these networks while protecting user privacy. We first consider how each of these networks is research-driven and interested in helping researchers to conduct their research ethically. We then look to the software currently available for researchers to set up in their labs. Lastly we explore ways in which digital forensics and cybersecurity students could get involved with these projects and look at several class exercises that help students to understand particular attacks on these networks and ways they can help to …

New Insights Into The Design Of Conjugated Polymers For Intramolecular Singlet Fission, Jiahua Hu, Ke Xu, Lei Shen, Qin Wu, Guiying He, Jie-Yu Wang, Jian Pei, Jianlong Xia, Matthew Y. Sfeir

Publications and Research

Singlet fission (SF), a multiple exciton generation process that generates two triplet excitons after the absorption of one photon, can potentially enable more efficient solar cell designs by harvesting energy normally lost as heat. While low-bandgap conjugated polymers are highly promising candidates for efficient SF-based solar cells, few polymer materials capable of SF have been reported because the SF process in polymer chains is poorly understood. Using transient spectroscopy, we demonstrate a new, highly efficient (triplet yield of 160-200%) isoindigo-based donor–acceptor polymer and show that the triplet pairs are directly emissive and exhibit a time-dependent energy evolution. Importantly, aggregation in …

Climate-Informed Environmental Inflows To Revive A Drying Lake Facing Meteorological And Anthropogenic Droughts, Aneseh Alborzi, Ali Mirchi, Hamed Moftakhari, Iman Mallakpour, Sara Alian, Ali Nazemi, Elmira Hassanzadeh, Omid Mazdiyasni, Samaneh Ashraf, Kaveh Madani, Hamid Norouzi, Marzi Azarderakhsh, Ali Mehran, Mojtaba Sadegh, Andrea Castelletti, Amir Aghakouchak

Publications and Research

The rapid shrinkage of Lake Urmia, one of the world's largest saline lakes located in northwestern Iran, is a tragic wake-up call to revisit the principles of water resources management based on the socio-economic and environmental dimensions of sustainable development. The overarching goal of this paper is to set a framework for deriving dynamic, climate-informed environmental inflows for drying lakes considering both meteorological/climatic and anthropogenic conditions. We report on the compounding effects of meteorological drought and unsustainable water resource management that contributed to Lake Urmia's contemporary environmental catastrophe. Using rich datasets of hydrologic attributes, water demands and withdrawals, as well …

An Application Of Game Theory In Distributed Collaborative Decision Making, Angran Xiao

Publications and Research

In a distributed product realization environment, new paradigms and accompanying software systems are necessary to support the collaborative work of geographically dispersed engineering teams from different disciplines who have different knowledge, experience, tools and resources. To verify the concept of collaboration by separation, we propose a generic information communication medium to enable knowledge representation and exchange between engineering teams, a digital interface. Across digital interfaces, each engineering team maintains its own perspective towards the product realization problem, and each controls a subset of design variables and seeks to maximize its own payoff function subject to individual constraints. Hence, we postulate …

Nanostructured Fibers As A Versatile Photonic Platform: Radiative Cooling And Waveguiding Through Transverse Anderson Localization, Norman Nan Shi, Cheng-Chia Tsai, Michael J. Carter, Jyotirmoy Mandal, Adam C. Overvig, Matthew Y. Sfeir, Ming Lu, Catherine L. Craig, Gary D. Bernard, Yuan Yang, Nanfang Yu

Publications and Research

Broadband high reflectance in nature is often the result of randomly, three-dimensionally structured materials. This study explores unique optical properties associated with one-dimensional nanostructures discovered in silk cocoon fibers of the comet moth, Argema mittrei. The fibers are populated with a high density of air voids randomly distributed across the fiber cross-section but are invariant along the fiber. These filamentary air voids strongly scatter light in the solar spectrum. A single silk fiber measuring ~50 μm thick can reflect 66% of incoming solar radiation, and this, together with the fibers' high emissivity of 0.88 in the mid-infrared range, allows …

R Program For Estimation Of Group Efficiency And Finding Its Gradient. Stochastic Data Envelopment Analysis With A Perfect Object Approach, Alexander Vaninsky

Publications and Research

The data presented here are related to the research article “Energy-environmental efficiency and optimal restructuring of the global economy” (Vaninsky, 2018) [1]. This article describes how the world economy can be restructured to become more energy-environmental efficient, while still increasing its growth potential. It demonstrates how available energy-environmental and economic information may support policy-making decisions on the atmosphere preservation and climate change prevention. This Data article presents a computer program in R language together with examples of input and output files that serve as a means of implementation of the novel approach suggested in publication[1]. The computer program utilizes stochastic …

Career/Interview Project, Kevin Mark

Open Educational Resources

Two of the core competencies designated for The First Year Seminar Liberal Arts Math and Science (LMF 101) course are Integrative Learning and Global Learning along with oral communication. These abilities are exercised by students in the Career/Interview Presentation project. The main goal of the assignment is to promote student networking within the scientific community through interviews with an expert in the field. Also the FYS students will conduct background research about their career choices and use their findings to determine if they can be realized when interviewing a professional. The assignment is scaffolded whereby students will learn to use …

Introduction To Data Analysis Using Excel And Lab Report Writing Using Lagcc Institution Data, Kevin Mark

Open Educational Resources

Objectives

Part 1: An Introduction to Data Analysis Using Excel

1. To interpret, summarize and present numerical data using the digital tool Microsoft program Excel.
2. To plot numerical data as a graph and determine an equation of a line. In addition, using the appropriate formatting functions to label your graph and creating a best fit line.

Part 2: Lab Report Writing Using LaGCC Institutional Data

1. To communicate your interpretations of research data. This is done writing discussions and conclusions (using scientific language) and is often accompanied by data tables and graphs.
2. To use your Microsoft Excel graphing skills to interpret, inquire …