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Articles 1111 - 1140 of 3417

Full-Text Articles in Physical Sciences and Mathematics

The Role Of Upper Ocean Heat Content And Sea Surface Temperature On Northeast Pacific Hurricane Evolution During Average And Active Years, Victoria Lauren Ford Jan 2016

The Role Of Upper Ocean Heat Content And Sea Surface Temperature On Northeast Pacific Hurricane Evolution During Average And Active Years, Victoria Lauren Ford

LSU Master's Theses

Upon comparison to typical neutral-ENSO conditions in the Northeast Pacific Ocean, the 2014 hurricane season has been identified as highly anomalous in both tropical cyclone frequency and intensity. This thesis seeks to investigate the influence of sea surface temperatures (SSTs) and upper ocean heat content (UOHC), defined as the excess of heat present above 26°C, upon the upper ocean thermal structure, mesoscale features, and anomalies that led to an active hurricane season in the Northeast Pacific. The 2012 Northeast Pacific hurricane season was selected as a ‘normal’ season to fully quantify the anomalous 2014 hurricane season. Data sets utilized in …

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Investigating Species And Population Level Foraging Variation And Individual Specialization In Pygoscelis Penguins Using Stable Isotope Analysis, Rachael W. Herman Jan 2016

Investigating Species And Population Level Foraging Variation And Individual Specialization In Pygoscelis Penguins Using Stable Isotope Analysis, Rachael W. Herman

LSU Master's Theses

Gentoo Penguins (Pygoscelis papua) are known to be generalist foragers, while Adélie (P. adeliae) and Chinstrap (P. Antarctica) tend to specialize on krill within the Western Antarctic Peninsula and South Shetland Islands, particularly during the breeding season. However, little is known on temporal consistency in diet and foraging habitat of these species, particularly at the individual level. We used stable isotope analysis (SIA) of blood and feathers to evaluate seasonal and individual foraging consistency within Adélie, Chinstrap and Gentoo Penguins breeding in the South Shetland Islands, as well as among three Gentoo Penguins’ populations in the Western Antarctic Peninsula and …

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The Photodegradation Of 2,6-Dichloro-4-Nitroaniline (Dcna) In Freshwater And Saltwater, Emily Noelle Vebrosky Jan 2016

The Photodegradation Of 2,6-Dichloro-4-Nitroaniline (Dcna) In Freshwater And Saltwater, Emily Noelle Vebrosky

LSU Master's Theses

The fungicide 2,6-dichloro-4-nitroaniline (DCNA) is applied to crops grown in areas near both freshwater and saltwater bodies and it can enter the surface waters where it is susceptible to photolysis; limited information is published on the photodegradation of DCNA. It has been shown that the salinity of seawater can influence both the overall rate of degradation of chemicals and impact the distribution and types of photoproducts generated during the photodegradation processes of a pesticide. The photodegradation of DCNA was measured in distilled water, artificial seawater, estuarine water, and phosphate buffer to determine the degree of differences in the degradation rate …

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Study Of Resistivity And Shear Wave Velocity As A Predictive Tool Of Sediment Type In Levee Foundation Soils, Louisiana Gulf Coast Levee System, Derek Stephen Goff Jan 2016

Study Of Resistivity And Shear Wave Velocity As A Predictive Tool Of Sediment Type In Levee Foundation Soils, Louisiana Gulf Coast Levee System, Derek Stephen Goff

LSU Master's Theses

Geotechnical sediment type of levee foundation soils may be estimated by using cross-plots of shear-wave velocity and electrical resistivity for Louisiana levees. Best-fit polynomial models for estimating soil type in Japanese levees have been created using cross-plots of shear-wave velocity and electrical resistivity. A similar study or model for flood protection structures in the Mississippi River delta plain or other major river delta does not exist. We make the soil-type estimation model more relevant to the foundation soils in the Louisiana Coastal Zone by identifying silt in addition to sand and clay, and eliminating gravel as a dominant soil type. …

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Synthetic Approach Towards P3eht-B-Pss Conjugated And Ionic Block Copolymer, Zhaoyuan Liu Jan 2016

Synthetic Approach Towards P3eht-B-Pss Conjugated And Ionic Block Copolymer, Zhaoyuan Liu

LSU Master's Theses

This work is focused on the design, synthesis and characterization of block copolymers (BCPs) containing both conjugated and polyelectrolyte blocks. This type of rod-coil BCP is considered to have microphase separation which is different compared to coil-coil BCPs. The conjugated block used for studies is regioregular poly(3-alkylthiophene) (P3AT), which can be synthesized by Grignard metathesis (GRIM) polymerization. The polyelectrolyte block used is polystyrene sulfonate with well-defined structure, which can be synthesized by atom transfer radical polymerization (ATRP). Chapter II is focused on evaluation of synthetic routes for P3EHT-b-PSS, including using bifunctional initiator to synthesize both blocks, and separately synthesizing end-functionalized …

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Thin Films Of Semiconducting Polymers And Block Copolymers By Surface-Initiated Polymerization, Sang Gil Youm Jan 2016

Thin Films Of Semiconducting Polymers And Block Copolymers By Surface-Initiated Polymerization, Sang Gil Youm

LSU Doctoral Dissertations

The ability to control nanoscale morphology and molecular organization in organic semiconducting polymer thin films is an important prerequisite for enhancing the efficiency of organic thin-film devices, including organic light-emitting and photovoltaic devices. The current “top-down” paradigm for making such devices is based on utilizing solution-based processing (e.g. spin-casting) of soluble semiconducting polymers. This approach typically provides only modest control over nanoscale molecular organization and polymer chain alignment. A promising alternative to using solutions of pre-synthesized semiconducting polymers pursues instead a “bottom-up” approach to prepare surface-grafted semiconducting polymer thin films by surface-initiated polymerization of small-molecule monomers. This dissertation mainly focuses …

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The Effect Of Artificial Light On The Community Structure And Distribution Of Reef-Associated Fishes At Oil And Gas Platforms In The Northern Gulf Of Mexico, Victoria Anne Barker Jan 2016

The Effect Of Artificial Light On The Community Structure And Distribution Of Reef-Associated Fishes At Oil And Gas Platforms In The Northern Gulf Of Mexico, Victoria Anne Barker

LSU Master's Theses

The northern Gulf of Mexico (GOM) contains approximately 2,500 oil and gas platforms, resulting in one of the largest de facto artificial reef systems in the world. As of 2013, 1,227 additional structures had ceased to produce oil and gas and have been decommissioned and removed. While active platforms are lit by high-pressure mercury vapor lights, inactive platforms are only minimally lit for navigation. The positively phototaxic behavior of many fish species causes lit oil platforms to act as fish attraction devices, especially at night. Though a variety of fish species have been reported near these structures, changes in fish …

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Time-Lapse Polymerizations Triggered By Ph Clock Reactions, Elizabeth Jee Jan 2016

Time-Lapse Polymerizations Triggered By Ph Clock Reactions, Elizabeth Jee

LSU Doctoral Dissertations

The theme of this work is time-lapse polymerizations triggered by pH clock reactions. The first chapter is the introduction and gives a long overview of the different chemistries studied here. The second chapter focuses on the bromate-sulfite clock reaction. Based on some simplified and accepted reaction equations for the bromate-sulfite clock. We presumed it may be possible to increase the pH of the solution via ammonia addition and hinder or significantly reduce the reactivity of the clock reagents, thus creating a storage stable reaction. Adding a polymer system that would not crosslink until the solution became acidic would have created …

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Relative Resistance To Breaking Of Pinus Taeda L. And Pinus Palustris, Cory Glenn Garms Jan 2016

Relative Resistance To Breaking Of Pinus Taeda L. And Pinus Palustris, Cory Glenn Garms

LSU Master's Theses

Patterns from hurricane damage give an indication that longleaf pine (Pinus palustris) is more windfirm than loblolly pine (Pinus taeda). Tree windfirmess has been attributed to many factors including species and material properties like wood strength and stiffness. Because longleaf pine wood is stronger and stiffer than loblolly pine wood, this study used static winching methodology to see if these properties account for differences in windfirmness by measuring bending force required to break stems (MMAX). Stress-strain diagrams were constructed for pulled trees to explore how they behave under increasing loads. Based on these diagrams, it appears that living trees can …

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Efficacy And Feasibility Of Alginate Bait For The Louisiana Commercial Blue Crab (Callinectes Sapidus) Fishery, Elizabeth Lorraine Clowes Jan 2016

Efficacy And Feasibility Of Alginate Bait For The Louisiana Commercial Blue Crab (Callinectes Sapidus) Fishery, Elizabeth Lorraine Clowes

LSU Master's Theses

Louisiana leads all U.S. states in blue crab (Callinectes sapidus) landings, but high fuel and bait costs have hindered commercial fishing productivity of Louisiana in recent years. The primary baitfish, Atlantic menhaden (Brevoortia tyrannus), has steadily increased in price and decreased in availability, while crab prices remain low. To reduce costs for fishermen, an alternative bait was developed that incorporates shrimp waste into a semi-rigid alginate matrix. Lab testing and preliminary field tests show that shrimp-alginate bait may be a suitable alternative to menhaden for Louisiana crab fishermen. I evaluated bait performance by conducting field sampling to compare catch rates …

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Immune Gene Variation And Susceptibility To Upper Respiratory Tract Disease In Gopher Tortoises, Jean Pierre Elbers Jan 2016

Immune Gene Variation And Susceptibility To Upper Respiratory Tract Disease In Gopher Tortoises, Jean Pierre Elbers

LSU Doctoral Dissertations

The immune system defends the host from bacteria, fungi, parasites, and viruses. The immune system is partially under genetic control through immune response genes, such as those of the major histocompatibility complex (MHC) whose nucleotide variation influences the host’s ability to recognize foreign pathogens and can influence disease susceptibility. Populations of threatened species generally possess low levels of genetic variation, and genetically depauperate hosts may be at greater risk of infectious disease contributing to extirpations because they also possess low immunogenetic variation. My dissertation examines the relationship between immunogenetic variation and disease susceptibility and the factors that influence innate immune …

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Interplay Effects In Highly Modulated Stereotactic Body Radiation Therapy Lung Cases Treated With Volumetric Modulated Arc Therapy, Desmond Joseph Fernandez Jan 2016

Interplay Effects In Highly Modulated Stereotactic Body Radiation Therapy Lung Cases Treated With Volumetric Modulated Arc Therapy, Desmond Joseph Fernandez

LSU Master's Theses

Purpose: To evaluate the influence of tumor motion on dose delivery in highly modulated stereotactic body radiotherapy (SBRT) of lung cancer using volumetric modulated arc therapy (VMAT). Methods: 4D-CT imaging data of the quasar respiratory phantom were acquired, using a GE Lightspeed 16-slice CT scanner, while the phantom reproduced patient specific respiratory traces. Flattening filter-free (FFF) dual-arc VMAT treatment plans were created on the acquired images in Pinnacle3 treatment planning system. Each plan was generated with varying levels of complexity characterized by the modulation complexity score. Static and dynamic measurements were delivered to GafChromic EBT3 film inside the respiratory phantom …

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Use Of X-Ray K-Edge Tomography And Interferometry Imaging Techniques For The Studies Of Brominated Flame Retardants, Mutairu Bolaji Olatinwo Jan 2016

Use Of X-Ray K-Edge Tomography And Interferometry Imaging Techniques For The Studies Of Brominated Flame Retardants, Mutairu Bolaji Olatinwo

LSU Doctoral Dissertations

The work presented in this dissertation is based on the studies of flame retardancy performance of various formulations consisting of brominated flame retardants (BFRs: Saytex 8010 and Green Armor) and their synergist, antimony trioxide (Sb2O3) in high impact polystyrene (HIPS). Chemical flame retardants are incorporated in polymers to improve their flame inhibition for optimal applications in electrical and electronic devices, furniture, printers and more. These flame retardant polymer blends are studied using the Underwriters Laboratory vertical burn test (UL 94) and X-ray imaging techniques such as X-ray K-edge absorption tomography and X-ray grating interferometry. The UL 94 burn test is …

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Source Mechanism Analysis Of Single-Well Microseismic Data Using Full-Wavefield Moment Tensor Inversion, Trudy Watkins Jan 2016

Source Mechanism Analysis Of Single-Well Microseismic Data Using Full-Wavefield Moment Tensor Inversion, Trudy Watkins

LSU Master's Theses

Receiver angular coverage of microseismic sources occurring during hydraulic fracturing treatments is an important factor to consider when interpreting moment tensor inversion results. A horizontal receiver array can provide greater angular coverage of vertical failure planes than a vertical receiver array. The source orientation can be accurately determined if the array samples both sides of the failure plane. However, the compensated-linear-vector-dipole (CLVD) mechanism can be overestimated by up to ~40% for double-couple (DC) sources and the isotropic mechanism can be overestimated by ~70% for CLVD sources. Source mechanism constraints on the moment tensor inversion are used to mitigate the lack …

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Feedback Control Theory In Stochastic Dynamical Systems, Ashkan Balouchi Jan 2016

Feedback Control Theory In Stochastic Dynamical Systems, Ashkan Balouchi

LSU Doctoral Dissertations

A stochastic dynamical system is a system composed of many interacting components which includes stochastic behavior. Feedback control theory is designed to use information from the current state of the system in order to temper the final state toward the desired outcome. In this dissertation, I perform studies on two choices of classic and quantum dynamical systems to cover vast variety of statistical tools and methods. For classical model, I perform a study on finite-size effects at the phase transition in the Nagel-Schreckenberg traffic model as an example of non-equilibrium many body stochastic dynamical system. For quantum mechanical model, I …

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Excluding A Weakly 4-Connected Minor, Kimberly Sevin D'Souza Jan 2016

Excluding A Weakly 4-Connected Minor, Kimberly Sevin D'Souza

LSU Doctoral Dissertations

A 3-connected graph $G$ is called weakly 4-connected if min $(|E(G_1)|, |E(G_2)|) \leq 4$ holds for all 3-separations $(G_1,G_2)$ of $G$. A 3-connected graph $G$ is called quasi 4-connected if min $(|V(G_1)|, |V(G_2)|) \leq 4$. We first discuss how to decompose a 3-connected graph into quasi 4-connected components. We will establish a chain theorem which will allow us to easily generate the set of all quasi 4-connected graphs. Finally, we will apply these results to characterizing all graphs which do not contain the Pyramid as a minor, where the Pyramid is the weakly 4-connected graph obtained by performing a $\Delta …

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Microscopic Study Of Structure, Chemical Composition And Local Conductivity Of La2/3sr1/3mno3 Films, Lina Chen Jan 2016

Microscopic Study Of Structure, Chemical Composition And Local Conductivity Of La2/3sr1/3mno3 Films, Lina Chen

LSU Doctoral Dissertations

The colossal magnetoresistance (CMR) manganites have attracted intensive study due to their richness of underlying physics and potential technological applications. Of particular interest is half-metallic La2/3Sr1/3MnO3 (LSMO) because it possesses the highest known Curie temperature of the group ~ 370 K), which makes it a promising candidate for room temperature spintronic applications. On the other hand, LSMO ultrathin films exhibit a metal-insulator transition (MIT) when reducing film thickness. The origin of such a thickness-dependent MIT remains highly controversial, though understanding and controlling this kind of behavior is necessary for any possible device applications. An essential first step then, and the …

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Spectral Properties Of Photonic Crystals: Bloch Waves And Band Gaps, Robert Paul Viator Jr Jan 2016

Spectral Properties Of Photonic Crystals: Bloch Waves And Band Gaps, Robert Paul Viator Jr

LSU Doctoral Dissertations

The author of this dissertation studies the spectral properties of high-contrast photonic crystals, i.e. periodic electromagnetic waveguides made of two materials (a connected phase and included phase) whose electromagnetic material properties are in large contrast. A spectral analysis of 2nd-order divergence-form partial differential operators (with a coupling constant k) is provided. A result of this analysis is a uniformly convergent power series representation of Bloch-wave eigenvalues in terms of the coupling constant k in the high-contrast limit k -> infinity. An explicit radius of convergence for this power series is obtained, and can be written explicitly in terms of the …

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Comparison Of Group Size, Abundance Estimates And Movement Patterns Of Common Bottlenose Dolphins (Tursiops Truncatus) In Mississippi Sound, Mississippi, Carrie Sinclair Jan 2016

Comparison Of Group Size, Abundance Estimates And Movement Patterns Of Common Bottlenose Dolphins (Tursiops Truncatus) In Mississippi Sound, Mississippi, Carrie Sinclair

LSU Master's Theses

Common bottlenose dolphins (Tursiops truncatus; dolphins) inhabiting Mississippi Sound (MSS) in the north-central Gulf of Mexico (GMx) are considered a part of a single stock of dolphins that includes Bay Boudreau and Lake Borgne by the National Marine Fisheries Service (NMFS). MSS is bounded by the mainland (north) and several barrier islands (south). Dolphins inhabiting coastal waters directly south of the barrier islands constitute part of the Northern Coastal Stock. Abundance in MSS has been reported to fluctuate seasonally, with higher abundances of dolphins estimated in summer versus winter. Analysis of covariance was used to compare previous abundance estimates. Results …

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Temporal Dynamics Of Benthic Responses To Habitat Disturbance In Coastal Plain Headwaters Of Southwestern Louisiana, Catherine Elizabeth Murphy Jan 2016

Temporal Dynamics Of Benthic Responses To Habitat Disturbance In Coastal Plain Headwaters Of Southwestern Louisiana, Catherine Elizabeth Murphy

LSU Doctoral Dissertations

Weak biotic responses to habitat gradients within Northern Gulf of Mexico streams have been attributed to spatial and temporal variability. Landscape and in-stream habitat descriptions are presented for watersheds within Pleistocene terraces of the Coastal Plains geomorphic province of Louisiana, USA. Geologic influences on stream habitat were inferred by comparing multivariate ordinations on physicochemical measurements between terraces. Seasonal variability was assessed during a drought year (2011) and a typical water year (2013). Within coastal plains of Louisiana, stream condition was more similar within terraces than within river basins. Permutational MANOVA models indicated significantly different stream habitat between Uplands and Prairie, …

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Data-Driven Rational Drug Design, Yun Ding Jan 2016

Data-Driven Rational Drug Design, Yun Ding

LSU Doctoral Dissertations

Vast amount of experimental data in structural biology has been generated, collected and accumulated in the last few decades. This rich dataset is an invaluable mine of knowledge, from which deep insights can be obtained and practical applications can be developed. To achieve that goal, we must be able to manage such "Big Data'' in science and investigate them expertly. Molecular docking is a field that can prominently make use of the large structural biology dataset. As an important component of rational drug design, molecular docking is used to perform large-scale screening of putative associations between small organic molecules and …

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Feeding Ecology Of Red Snapper And Greater Amberjack At Standing Platforms In The Northern Gulf Of Mexico: Disentangling The Effects Of Artificial Light, Kristin Leanne Foss Jan 2016

Feeding Ecology Of Red Snapper And Greater Amberjack At Standing Platforms In The Northern Gulf Of Mexico: Disentangling The Effects Of Artificial Light, Kristin Leanne Foss

LSU Master's Theses

Approximately 2,300 petroleum platforms are currently operating in the Gulf of Mexico (GOM), and are estimated to provide an additional 4 to 12 km2 of artificial reef habitat. The ecological role of platforms has often been overlooked and little is known about the effect of artificial light from the active platforms on surrounding fish communities. This is the first study to address the potential impacts of artificial light on the trophic ecology of fish communities surrounding offshore platforms through gut content (GCA) and stable isotope (SIA) analyses. Red snapper (Lutjanus campechanus) were collected quarterly from February 2014 to November 2015 …

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Study Of Condensed Matter Systems With Monte Carlo Simulation On Heterogeneous Computing Systems, Sheng Feng Jan 2016

Study Of Condensed Matter Systems With Monte Carlo Simulation On Heterogeneous Computing Systems, Sheng Feng

LSU Doctoral Dissertations

We study the Edwards-Anderson model on a simple cubic lattice with a finite constant external field. We employ an indicator composed of a ratio of susceptibilities at finite momenta, which was recently proposed to avoid the difficulties of a zero momentum quantity, for capturing the spin glass phase transition. Unfortunately, this new indicator is fairly noisy, so a large pool of samples at low temperature and small external field are needed to generate results with a sufficiently small statistical error for analysis. We thus implement the Monte Carlo method using graphics processing units to drastically speed up the simulation. We …

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Intracontinental Neotectonics: Case Studies From The Tian Shan Orogen And Kuqa Fold-Thrust Belt, Cindy M. Colón Jan 2016

Intracontinental Neotectonics: Case Studies From The Tian Shan Orogen And Kuqa Fold-Thrust Belt, Cindy M. Colón

LSU Doctoral Dissertations

This dissertation focuses on the kinematic properties of intracontinental deformation during short geologic time scales. Using three case studies this work characterizes active deformation at varying spatial scales within the continental interior of Eurasia. The far-field effect of the Cenozoic Indo-Asia collision is the driving force controlling deformation within the Eurasian continental interior. Active deformation across the intracontinental Tian Shan range challenges the plate tectonic model that proposes crustal deformation is concentrated along plate boundaries. This work further constrains the active kinematics of intracontinental motion that is necessary to understand the dynamics of the Eurasian intracontinental system. The two standing …

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Molecularly Imprinted Polymers For Enantiomer Separations And Biomolecular Sensors, Britney Lyn Hebert Jan 2016

Molecularly Imprinted Polymers For Enantiomer Separations And Biomolecular Sensors, Britney Lyn Hebert

LSU Doctoral Dissertations

Molecularly Imprinted Polymers (MIPs) encompass a wide range of applications by changing the different components, e.g. the template, crosslinker or functional monomers. Of interest among these different applications are separations and sensors. Separations by MIPs traditionally use a chiral pure template but in some cases that chiral pure template may not be available for imprinting. Using chiral (N-α-bismethacyloyl-L-alanine) and achiral (N,O-bisacrylamide ethanolamine) crosslinkers we investigated imprinting of scalemic and racemic template mixtures of Boc-tyrosine enantiomers. The achiral and chiral crosslinkers yielded similar results for the partial separation of enantiomers by scalemic imprinted polymers because separation and recognition are not dependent …

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Scanning Probe Investigations Of Multidentate Thiol And Spatially Confined Porphyrin Nanoassemblies Using Nanoscale Lithography, Xianglin Zhai Zhai Jan 2016

Scanning Probe Investigations Of Multidentate Thiol And Spatially Confined Porphyrin Nanoassemblies Using Nanoscale Lithography, Xianglin Zhai Zhai

LSU Doctoral Dissertations

Approaches to prepare spatially selective surfaces were developed in this dissertation for constructing nanopatterns of organic thin film materials. Nanoscale surface patterns were prepared using immersion particle lithography and scanning probe lithography combined with organothiol chemistry. Organic thin films and nanomaterials can be patterned with tunable periodicities and designed shapes by selecting the diameter of mesospheres used as surface masks or scanning probe lithography, respectively. The surface platforms of well-defined nanopatterns are ideal for high resolution investigations using scanning probe microscopy (SPM). Local measurements of surface properties and conductive properties combined with nanolithography were accomplished at the molecular level. Sample …

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Minimizing Decoherence In Optical Fiber For Long Distance Quantum Communication, Manish Kumar Gupta Jan 2016

Minimizing Decoherence In Optical Fiber For Long Distance Quantum Communication, Manish Kumar Gupta

LSU Doctoral Dissertations

In this research work, I have derived analytical models for decoherence of quantum states of light and developed techniques based on Dynamical Decoupling (DD) to preserve the quantum state of polarization qubit and Orbital Angular Momentum (OAM) qudit in single-mode, multi-mode and specialized optical fibers. In subsequent work, I have derived the analytical model for decoherence of an entangled state in an optical fiber to show that such a decoherence causes loss of entanglement. I also showed that such states can be preserved with DD. In Chapter 1, I have introduced the subject of a quantum computer and its relation …

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Investigating The Structure Of The Papain-Inhibitor Complex Using Spr And Nmr, Margaret Sara Thomasson Jan 2016

Investigating The Structure Of The Papain-Inhibitor Complex Using Spr And Nmr, Margaret Sara Thomasson

LSU Doctoral Dissertations

Cysteine proteases (CPs) are enzymes with a nucleophilic thiol in their active sites. Inhibitors of cysteine proteases (ICPs) occur naturally in bacterial pathogens and some protozoa. In parasites, ICPs are often virulence factors, contributing to the formation and survival of amastigotes within host cells. These amastigotes have higher CP activity, therefore making both ICPs and CPs potential drug targets. Despite great genetic variability, ICPs contain highly conserved structural features, including a series of defined loops that play a significant role in binding CPs. Papain, a CP from Carica papaya, complexes with ICP from Leishmania mexicana. Although the individual 3-D structures …

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Methodologies Utilizing Protected Oxyallyl Cations For Molecular Design, Jacob Reuben Stepherson Jan 2016

Methodologies Utilizing Protected Oxyallyl Cations For Molecular Design, Jacob Reuben Stepherson

LSU Master's Theses

This master’s thesis discusses developments of novel organic methodologies utilizing oxyallyl cationic systems in the pursuit of highly functionalized molecular scaffolds. Chapter 1 focuses on the discovery of the oxyallyl cation intermediate, and examines reported transformations. Detailed optimization and substrate studies following exploitation of a protected 2-oxyallyl cation for nucleophilc capture comprises the information in both Chapter 2 and Chapter 3. Chapter 4 extends methodologies performed by my colleagues and establishes a tandem process using 2-silyloxypentadienyl cations to furnish complex structures. In this report, reaction design and optimization are chronicled, followed by exploration into the reactivity, mechanism, and scope of …

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Simulating Behavioral Microcystin Impairment In Fish, Nicholas Richard Keeney Jan 2016

Simulating Behavioral Microcystin Impairment In Fish, Nicholas Richard Keeney

LSU Master's Theses

Fish experiencing blooms of the cyanobacteria genera Microcystis and Anabaena acquire microcystin and saxitoxin through ingestion of contaminated food and absorption of dissolved toxin. Even low chronic doses induce sensory and motor impairment—the impact of which is unquantified in wild populations. Here, I introduce Lagrangian particle models for cyanobacteria and fish which test the hypotheses that impairment symptoms suppress movement and growth. This is implemented within the Finite-Volume Coastal Ocean Model (FVCOM). Cyanobacteria particles move vertically according to mixing and buoyancy (a function of cellular reservoirs). Fish navigate the horizontal domain, foraging in high growth areas, and fleeing when toxin …

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