Physical Sciences and Mathematics Commons^™

Techno-Economic And Environmental Assessments Of Produced Water Treatment Technologies For Beneficial Reuse, Elora Afrin

Water Resources Science and Technology Theses and Graduate Research Reports

Produced water (PW) is a bulk portion of byproduct generated during oil and gas extraction operations and can be potentially reused for various purposes. However, the treatment costs and associated environmental issues call for a multitude of factors for proper management. This research aims to evaluate the viability of technologies for treating PW in terms of their technical performance, cost-effectiveness, and environmental considerations. Technologies evaluated include well-established processes such as electrodialysis (ED), electrodialysis reversal (EDR), ion exchange, chemical oxidation, electrocoagulation (EC), chemical coagulation (CC), nanofiltration (NF) etc. Associated case studies have been studied. However, except EC and CC, other technologies …

Rock Wall Fracturing As A Potential Control On River Valley Width In The Buffalo National River, Arkansas, Kindle Hon

Graduate Theses and Dissertations

Quantifying bedrock properties that control the persistence of fallen rock material (talus) along bedrock walls bounding river valleys may be a key factor in understanding what controls the rate at which these river valleys widen. My work is a component of a collaborative research project focused on the overarching hypothesis that the persistence vs. erodibility of talus that buffers river valley walls can be a first-order control on valley widening rates. I hypothesize that the primary control for creating erodible or persistent talus is the fracture spacing of bedrock valley walls as it sets the maximum block size of collapsed …

Struvite Effects On Greenhouse Gas Emissions From Flood- And Furrow-Irrigated Rice In The Greenhouse, Chandler Arel

Graduate Theses and Dissertations

Over time, as the influences of climate-change and declining, mineable, global phosphorus (P) reserves begin to impact agricultural production systems, alternative fertilizer sources and management practices, such as struvite (MgNH4PO4 · 6H2O) and furrow-irrigation, will be necessary to accommodate nutrient and water demands. The precipitation and use of struvite as a fertilizer-P source could reduce environmental damages caused by nutrient-rich wastewater streams, supplement domestic P supply, and improve the sustainability of flood-, and furrow-irrigated rice production by reducing greenhouse gas emissions. The study of struvite from both chemical and electrochemical precipitation processes is well documented, but currently there is a …

Quantum Modeling & Experimental Studies Of Radical Chemistry, Justin Michael Barrett

Graduate Theses and Dissertations

This work describes two projects centered around radical chemical mechanisms. The first investigation generalized the utility of a C-N bond homolysis followed by a [1,3] – rearrangement synthetic strategy found possible in N-alkylated thiazole & benzothiazole species onto analogous systems. Computational investigation guided the inquiry on structurally analogous systems that would favor a radical, [1,3] – rearrangement. Herein, we describe the implementation of that mechanism to transform Breslow Intermediate-like substrates into tertiary alcohol and amide products under facile conditions. We confer on the proficiency of this strategy with 2-pyridinemethanol and the problematic implementation with 2-(aminomethyl)pyridine. The second investigation solved a …

Controls On The Development Of Hummocky Topography On Debris-Covered Glaciers, Ryan M. Strickland

Graduate Theses and Dissertations

Rock debris covers many glaciers in Earth’s highest mountains and the debris impacts glacier response to changes in climate. Interactions between debris, drainage, glacier dynamics, and climate produce contrasts in melt rates that cause debris-covered glaciers to develop complex, hummocky topography. Contrasts in melt rate produce thousands of hills–hummocks–and depressions. Ponds and ice cliffs often form in the depressions. Although ponds and ice cliffs occupy only a small fraction of the surface, they account for nearly half of glacier melt. Understanding the processes that control the development of hummocky topography is key to predicting the evolution of debris-covered glaciers. In …

Investigation Of Optically Pumped Gesn Quantum Well Lasers, Grey Steven Abernathy

Graduate Theses and Dissertations

Silicon photonic integrated circuits enable the capability of producing on-chip processing of photonic signals, including both emission and detection. Emission materials, however, have been limited for monolithic integration due to high processing temperatures, indirect bandgap materials, and material integration complications. The (Si)GeSn material system has recently attracted attention due to the bandgap transition from the Si and Ge, naturally indirect bandgap, to direct bandgap with sufficient Sn incorporation. Additionally, the low growth temperature (CMOS compatible; <400 >°C) of (Si)GeSn materials can enable the monolithic integration of the highly desired mid-infrared light emission on the Si Photonic platform. This dissertation first discusses …

Investigating The Applications Of Peps To The Measurement Of The Stabilities Of Staphylococcal Nuclease (Stw) And Human Acidic Fibroblast Growth Factor (Hfgf1), Motolani Omolade Matthew

Graduate Theses and Dissertations

This dissertation presents a detailed investigation into the applications of Protein Equilibrium Population Snapshot H/D Exchange Electrospray Ionization Mass Spectrometry (PEPS-H/D exchange or PEPS) method. This method is based on protein equilibrium unfolding, and its fundamental capability is to capture a "snapshot" of the protein's state, allowing us to monitor the ratio of the unfolded to folded populations at different chemical denaturant concentrations. First, to increase the accuracy of PEPS data analysis for assessing protein stability, the traditional linear extrapolation method (LEM) was replaced. Instead of using LEM, which calculates free energy change based on the peak ratio of unfolded …

Understanding And Control Of Frustration And Topological Defects In Ferroic Matter, Suyash Rijal

Graduate Theses and Dissertations

Ferroic matter are of great importance as they provide a platform to extend the understanding of many-body physics and also for their amazing functional properties relevant for technological advancements. The work in this dissertation is dedicated to two of such ferroic materials. First is CrGeTe3 (CGT), a two dimensional (2D) magnet discovered in 2017. The discovery of two-dimensional magnetism has invigorated the research community as their low dimensionality offers a unique avenue to understand and investigate the origin of magnetism in these atomically thin systems and harvest diverse application such as information processing, storage and transfer using their magnetic spins. …

Cover-Crop Effects On Near-Surface Soil Properties Over Time In The Lower Mississippi River Valley, Cooper Fanning

Graduate Theses and Dissertations

Human population growth and climate change are present stressors that continue to put pressure on current agricultural production systems, where typical row-crop agricultural practices can negatively impact soil health. Extensive use of cover crops (CC) to increase soil health remains widely unrealized. Soil health in Arkansas is a major concern for sustaining agricultural output, therefore research into CC implementation across Arkansas to maintain or improve soil health is needed. The objective of this study was to evaluate the effects of CC (i.e., with and without CC) across various physical, hydraulic, biological, and chemical soil indicators in the Lower Mississippi River …

The Gavel And The Camera: Environmental Law And Photojournalism's Relationship To Appalachian Identity, Emily S. Patton

Honors Theses

Both the federal government and photojournalism have played a substantial role in the “othering” of Appalachia while simultaneously attempting to save it. Examining both institutions demonstrates the exploitative processes that alter the perception of rural communities and their surrounding environment. Stacey Kranitz’s archival exhibit, As It Was Give(n) To Me, internalizes this precarious role of the camera in a region heavily journalized. By inhabiting the area for years, establishing close relationships, and researching the documented history of Appalachia, Kranitz’s work becomes her livelihood in the dissolution of profession vs. personal. She is critical of past projects whose objective portrayal of …

Querymate: A Custom Llm Powered By Llamacpp, Pegah Khosravi

Open Educational Resources

No abstract provided.

Metal Assisted O2-Dependent Carbon-Carbon Bond Cleavage Of Β-Diketones And Flavonols, Stephen N. Anderson

All Graduate Theses and Dissertations, Fall 2023 to Present

Almost everything we interact with on a daily basis has been synthesized by chemists ranging from plastics, food preservatives, and medications. The diversity of synthetic molecules are achieved by the formation of new bonds between existing molecules and/or through the cleaving of bonds found in a molecule. There are uncountable amount of conditions reported to facilitate chemical reactions which all depend on the nature of molecules being used and the environment it is used in.

In recent years, more attention has been paid to identify chemical reactions that can use more environmentally favorable conditions and reduce the use of limited …

Hydrogen Stable Isotope Constraints On Hydration Of Colorado Plateau Lower Crust From Oligocene-Miocene Navajo Volcanic Field Xenoliths, Shelby Dianne Litton

All Graduate Theses and Dissertations, Fall 2023 to Present

Understanding flat-slab subduction is crucial as it involves the horizontal movement of an oceanic plate beneath a continental margin over a long distance. This tectonic process is widespread yet not fully understood, particularly regarding how it influences the chemical makeup of the continental plate and recycling in the hydrosphere. By analyzing isotopes, which are variations of certain elements found in minerals and water, we can gain insights into the sources of chemicals and geological processes at play. Our study area included six locations within the Navajo volcanic field (NVF), a region in the Colorado Plateau. We analyzed 23 lower crustal …

Functional Electrolytes Designing And Studying For Lithium Metal And Non-Aqueous Zinc Metal Batteries, Liping Zhang

All Graduate Theses and Dissertations, Fall 2023 to Present

Our current energy policy relies heavily on burning fossil fuels, raising serious concerns due to CO₂-related global warming. Consequently, significant progress is being made in pursuing renewable and green energy sources, such as solar, wind, and geothermal energy. These renewable energies require rechargeable batteries as energy storage systems to compensate for their intermittent nature.

Over the decades, lithium-ion batteries (LIBs) have become the dominant power sources for portable electronic devices. Current LIBs rely on graphite anodes with a limited theoretical capacity (372 mAh g^-1), which restricts their advanced applications. Li metal (Li⁰) anodes, with …

Effective Wordle Heuristics, Ronald I. Greenberg

Computer Science: Faculty Publications and Other Works

While previous researchers have performed an exhaustive search to determine an optimal Wordle strategy, that computation is very time consuming and produced a strategy using words that are unfamiliar to most people. With Wordle solutions being gradually eliminated (with a new puzzle each day and no reuse), an improved strategy could be generated each day, but the computation time makes a daily exhaustive search impractical. This paper shows that simple heuristics allow for fast generation of effective strategies and that little is lost by guessing only words that are possible solution words rather than more obscure words.

Enabling Iov Communication Through Secure Decentralized Clustering Using Federated Deep Reinforcement Learning, Chandler Scott

Electronic Theses and Dissertations

The Internet of Vehicles (IoV) holds immense potential for revolutionizing transporta- tion systems by facilitating seamless vehicle-to-vehicle and vehicle-to-infrastructure communication. However, challenges such as congestion, pollution, and security per- sist, particularly in rural areas with limited infrastructure. Existing centralized solu- tions are impractical in such environments due to latency and privacy concerns. To address these challenges, we propose a decentralized clustering algorithm enhanced with Federated Deep Reinforcement Learning (FDRL). Our approach enables low- latency communication, competitive packet delivery ratios, and cluster stability while preserving data privacy. Additionally, we introduce a trust-based security framework for IoV environments, integrating a central authority …

Convex Ancient Solutions To Anisotropic Curve Shortening Flow, Benjamin Richards

Doctoral Dissertations

We construct ancient solutions to Anisotropic Curve Shortening Flow, including a
noncompact translator and compact solution that lives in a slab. We then show that
these are the unique ancient solutions that exist in a slab of a given width.

Probabilistic And Data-Driven Methods For Numerical Pdes, Johannes Krotz

Doctoral Dissertations

This dissertation consists of three integral self-contained parts. The first part develops a novel Monte Carlo algorithm, called the near-Maximal Algorithm for Poisson-disk Sampling (nMAPS), to efficiently generate the nodes of a high-quality mesh for the calculation of flow and the associated transport of chemical species in low-permeability fractured rock, such as shale and granite. A good mesh balances accuracy requirements with a reasonable computational cost, i.e., it is generated efficiently, dense where necessary for accuracy, and contains no cells that cause instabilities or blown-up errors. Quality bounds for meshes generated through nMAPS are proven, and its efficiency is demonstrated …

Sensitivity Of Present And Future Seasonal Precipitation Over Central United States To The Representation Of Rocky Mountain Topography, Ranasinghe Disanayakalage Sherly Shelton Ranathunga

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

Precipitation change across the Central United States (USA) is of great interest to the research community. Studies using global climate simulations suggest that the “100^th-Meridian”, which separates the “dry west” from the “moist east” will shift to the east as the climate responds to future emissions pathways. However, these simulations are run at relatively coarse resolutions, which do not accurately represent topography. Here, we perform regional simulations using the Weather Research and Forecasting (WRF) model to explore the sensitivity of present and future precipitation patterns across the central USA to the representation of the Rocky Mountains (RM). We …

Occurrence, Inputs, And Ecological Significance Of Antibiotics And Pharmaceuticals In Western Nebraska Streams, Katelyn F. Glause

School of Natural Resources: Dissertations, Theses, and Student Research

Few emerging environmental contaminants are as concerning as antibiotics. Human and animal health benefits greatly from the prudent use of antibiotics, yet we give little thought to environmental release of these biologically active compounds. Environmental occurrence of these and other pharmaceutical compounds must be measured in different environmental compartments such as municipal wastewater and in the vicinity of large animal feeding operations to understand potential effects. This study reports the results of a monitoring study in western Nebraska, with a large population of livestock and smaller but more concentrated population of humans, comparing the relative environmental concentrations and loading from …

Applying Circuit Theory To Describe Changes In Structural Landscape Connectivity In Response To Wildfire, Christian Ross Nielsen

School of Natural Resources: Dissertations, Theses, and Student Research

Understanding and conserving ecological connectivity is critical to the preservation of vulnerable landscapes. Circuit theory, in which landscapes are imagined as circuit boards with varying resistances to the flow of current, is being increasingly used to model spatially explicit connectivity of landscapes and to inform land management and conservation decision-making. Utilizing continuous, quantitative estimates of percent cover by five land cover functional groups to create a conductance surface, this study expanded upon an established application of circuit theory that used the open-source software Circuitscape to model species-agnostic, omnidirectional connectivity. This model was automated using Python to create time-series connectivity maps …

Spatiotemporal Plasticity In Reproductive Readiness And Recruitment Of Ichthyoplankton Of Invasive Silver Carp Along A Western Invasion Front, Jessi L. Urichich

School of Natural Resources: Dissertations, Theses, and Student Research

Individuals of invasive species at the edge of their invasion distribution may exhibit enhanced reproductive capacity and phenotypic plasticity leading to accelerated range expansion. Environmental conditions in highly fluctuating environments at distribution edges may either promote or hinder such reproductive readiness and phenotypic plasticity. Dynamic habitat conditions and periodic disturbances experienced in prairie streams, such as drought (e.g., low-flow, high water temperatures), may potentially reduce suitable spawning environments and ichthyoplankton recruitment of invasive Silver Carp, potentially slowing range expansion or enabling management strategies that reduce abundance in the absence of a reproducing population. Female Silver Carp batch fecundity, Gonadosomatic Index …

Assessing, Restoring, And Centering Social-Ecological Relationships For Advancing Social-Ecological Resilience In The Northern Great Plains Grasslands, Katia Pilar Carranza Bernal

School of Natural Resources: Dissertations, Theses, and Student Research

The Northern Great Plains grasslands are social-ecological systems that were shaped by evolutionary and Indigenous social-ecological relationships. European colonization disrupted many of these interactions, including the coupling of fire and grazing, and degraded social-ecological resilience, shifting these grasslands to a new state. For those reasons, my research focused on assessing, restoring, and centering evolutionary and Indigenous social-ecological relationships for advancing social-ecological resilience in the Northern Great Plains grasslands. I first performed a study in the Nebraska Sandhillls assessing the potential of patch-burn grazing to support grassland resilience by comparing its effects to those of rotational grazing. Through vegetation and bird …

Analysis Of Drought-Flood Abrupt Alternation Events And Their Impacts In Kenya, Betty Makena

School of Natural Resources: Dissertations, Theses, and Student Research

Drought-Flood Abrupt Alternation (DFAA) is a compound disaster event that refers to the abrupt shift of extreme drought events to extreme floods resulting in exacerbated impacts on already vulnerable communities and hindering their coping abilities. This study aimed to analyze drought-flood abrupt alternation events and their impacts in Kenya. The first chapter aimed to understand historical drought events in the Greater Horn of Africa and their impacts, while drawing comparisons with the recent 2020-2022 drought period, referred to as the ‘triple dip La Niña’. Datasets used in this study include the Climate Hazards Group InfraRed Precipitation with Station (CHIRPS), Normalized …

Impacts Of Invasive Carp And Their Population Dynamics On Fish Communities In The Missouri River, Joshua F. Kocik

School of Natural Resources: Dissertations, Theses, and Student Research

Invasive Carp species: Silver Carp Hypophthalmichthys molitrix, Bighead Carp Hypophthalmichthys nobilis, Grass Carp Ctenopharyngodon idella, and Black Carp Mylopharyngodon piceus have both potential and realized abilities to negatively impact native species. Specifically, Bighead Carp and Silver Carp as filter feeders have been theorized to be detrimental not only to adult filter-feeding species, but to many fish which rely on plankton and algae in their early-life stages. The impact of Invasive Carp on the overall fish community remains underexplored. The fish communities below Gavins Point Dam (Invasive Carp present) and Fort Randall Dam (Invasive Carp absent) afford the …

Tales In The Teeth: Using Isotopic Analysis To Understand The Paleoecology And Social Behavior Of Brontotheres Of The Intermountain Basins During The Middle Eocene, John Michael Michalski

All Graduate Reports and Creative Projects, Fall 2023 to Present

Isotopic analysis has been a common practice used in paleontology to study ancient ecosystems, and the lives of animals therein. Oxygen isotopic analysis is of particular importance not only because of its use in studying paleoecology, diet, and migration, but also its use in studying mountain elevation, and its impact on ancient ecosystems. I use stable oxygen isotopic analysis to study the habits and ecology of brontotheres from intermountain basins surrounding the Uinta Mountains of Utah and Wyoming, USA. I studied the oxygen isotopes from 16 fossil specimens of teeth, most of which belonged to brontotheres, including the genera Palaeosyops …

Land-Use Change As A Major Driver For Mid-20th-Century Flood Intensity Reduction In The Southeastern Us, Zhixiong Shen, Nicholas Conway, Shaowu Bao, Samuel Muñoz, Andreas Lang

Marine Science

Land-use changes affect hydrologic processes, but their impact on flooding remains obscure amid increasingly heavy precipitation. Instrumental records are short relative to land-use change history and inadequate for flood attribution studies. Here we integrate a high-resolution paleodischarge record spanning the past ∼200 years from the largest basin in the Southeastern United States with instrumental data and hydrological modeling. We find that the 100 yr flood magnitude for large regional rivers exhibits 50%–75% reductions in the mid-20th century. We attribute at least 50% of the reductions to a regional shift from widespread agricultural land to conservation and reforestation and the rest …

Simulation Study On Confidence Interval Estimation For Standard Deviation With Non-Normal Distributions, Theophilus Oppong Kyeremeh

Electronic Theses and Dissertations

This study explores innovative approaches to constructing confidence intervals for the population standard deviation, σ, in non-normal data scenarios. While the sample standard deviation, s, is widely used, its reliability is compromised when dealing with skewed or heavy-tailed distributions and exhibits sensitivity to outliers. Our research addresses these limitations by investigating alternative estimation methods that offer greater robustness and accuracy.

Numerically Efficient Coherent Mode Representations For Partially Coherent Beams With Separable Phases, Milo W. Hyde, Carolina Rickenstorff

Faculty Publications

We present a method to numerically compute the coherent mode representations (CMRs) for partially coherent beams with separable phases. This special class of random light field has the ability to self-focus and is resistant to turbulence-induced degradation, making it potentially useful in applications such as optical communications. We validate our method by generating (in simulation) two such sources from the literature using their computed CMRs. Lastly, we conclude with a summary of our approach and a discussion of potential applications.

Shaking Off The Rust: Unraveling The Depositional And Diagenetic History Of Enigmatic Ferroan Dolostones In The Cambrian Bright Angel Formation, Tonto Group, Grand Canyon, Joseph J. Clevenger

All Graduate Theses and Dissertations, Fall 2023 to Present

Within the siliciclastic-sediment-dominated Bright Angel Formation (BAF) of the iconic Cambrian sedimentary strata (Tonto Group) in Grand Canyon National Park, Arizona, workers have identified and named prominent reddish-brown cliffs breaking up the generally slope-forming unit near, but separated from, its upper contact with the limestone-dominated Muav Formation, the "Rusty Brown Dolostones" (RBDs). Previous hypotheses suggest that the RBDs are chemically and physically altered tongues of the Muav Formation intercalated with the BAF at increasingly higher stratigraphic positions from west to east within the Canyon. A genetic association between the Muav Formation and the RBDs, as well as between the RBDs …