Physical Sciences and Mathematics Commons^™

Peroxynitrite-Mediated Oxidations: Nitration And Nitrosation, Rachel Bolzan

LSU Doctoral Dissertations

Using a direct ultraviolet second-derivative spectroscopy method, three peroxynitrite preparative methods were investigated for the nitrite and nitrate present either as impurities or produced during peroxynitrite decomposition: (I) ozonation of azide, reaction of hydrogen peroxide with (II) isoamyl nitrite and (III) nitrous acid. The oxidation of morpholine by peroxynitrite in the presence and absence of added carbonate gives N-nitromorpholine and N-nitrosomorpholine. Nitration and nitrosation of morpholine are catalyzed by low levels of CO₂; however, excess CO₂ dramatically reduces the yields of nitrosation but not nitration, and the combined yields of the products are about the same under …

Implementation Of An Integrated Quality Assurance Program For Ct-Tps Process, Junqing Wu

LSU Master's Theses

Systematic constancy and accuracy of a treatment planning system (TPS) are crucial for the entire radiation treatment planning process (TPP). The Quality Assurance (QA) of individual components does not necessarily lead to satisfying performance of the whole process due to the possible errors introduced by the data transfer process between components and other fluctuations. However, most of current QA for TPS is confined to the treatment planning computers. In this study, a time efficient and integrated CT-TPS QA procedure is presented, which starts at the beginning of the TPS input --- Computer Tomograhpy (CT). The whole QA procedure is based …

Overpressuring, Diagenesis, And Fluid Flow At The Matagorda Island 519 Field, Offshore Texas, Gulf Of Mexico, Kera Gautreau Spears

LSU Master's Theses

The relations between overpressuring, diagenesis, and fluid flow in sedimentary basins are complex and multifaceted. The Matagorda Island 519 field (MI 519), offshore Texas, provides an excellent area for investigating some of these relations. The top of overpressure at MI 519 occurs at a depth of 3.5 to 3.8 km in a Lower Miocene deltaic sequence. On the basis of log-derived lithostratigraphy, the pressure seal does not appear to be lithologic in origin. Geochemical, mineralogical, and cuttings information indicate instead that the precipitation of diagenetic calcite and possibly quartz cements has been the major factor in seal development. Stratigraphic variation …

Distributary Mouth Bar Formation And Channel Bifurcation In The Wax Lake Delta, Atchafalaya Bay, Louisiana, Anton J. Dumars

LSU Master's Theses

The Mississippi River has undergone at least seven cyclic avulsions during the Holocene epoch. The latest avulsion, down the Atchafalaya River into the Gulf of Mexico, has produced two bayhead deltas prograding into Atchafalaya Bay. The Wax Lake Delta, typical of other Mississippi sub-deltas, has a natural anastomosing channel pattern. In contrast, the Atchafalaya Delta, situated in the eastern side of the Bay, has experienced sporadic and limited growth due to the dredging of a navigation channel below natural depth. Channel bifurcation, and sediment transport processes and responses, were investigated in the Wax Lake Delta, using channel flow velocities, suspended …

Complexity And Heuristics In Ruled-Based Algorithmic Music Composition, Nigel Gwee

LSU Doctoral Dissertations

Successful algorithmic music composition requires the efficient creation of works that reflect human preferences. In examining this key issue, we make two main contributions in this dissertation: analysis of the computational complexity of algorithmic music composition, and methods to produce music that approximates a commendable human effort. We use species counterpoint as our compositional model, wherein a set of stylistic and grammatical rules governs the search for suitable countermelodies to match a given melody. Our analysis of the complexity of rule-based music composition considers four different types of computational problems: decision, enumeration, number, and optimization. For restricted versions of the …

Fast Scalable Visualization Techniques For Interactive Billion-Particle Walkthrough, Xinlian Liu

LSU Doctoral Dissertations

This research develops a comprehensive framework for interactive walkthrough involving one billion particles in an immersive virtual environment to enable interrogative visualization of large atomistic simulation data. As a mixture of scientific and engineering approaches, the framework is based on four key techniques: adaptive data compression based on space-filling curves, octree-based visibility and occlusion culling, predictive caching based on machine learning, and scalable data reduction based on parallel and distributed processing. In terms of parallel rendering, this system combines functional parallelism, data parallelism, and temporal parallelism to improve interactivity. The visualization framework will be applicable not only to material simulation, …

The Effects Of Fall Coldfront Passages On The Nekton Community In A Tidal Creek In Port Fourchon, La, As Monitored By Hydroacoustics, David J. Harmon

LSU Master's Theses

Split-beam hydroacoustic sampling with two, 420 KHz, 2x6 degree elliptical transducers was evaluated as a tool to quantify nekton movements in a Louisiana estuary. I measured the effects of atmospheric cold front passages on nekton in a tidal creek in Port Fourchon, LA during the fall of 2000. Six “fronts” were sampled between October 6 and December 18, 2000. Nekton density ranged from 0 to 24.4 fish/m³ with an overall mean of 2.44 fish/m³. Net samples were taken to supplement the acoustic data with species composition data. Species composition changed from October to December. A higher number …

Techniques To Explore Time-Related Correlation In Large Datasets, Sumeet Dua

LSU Doctoral Dissertations

The next generation of database management and computing systems will be significantly complex with data distributed both in functionality and operation. The complexity arises, at least in part, due to data types involved and types of information request rendered by the database user. Time sequence databases are generated in many practical applications. Detecting similar sequences and subsequences within these databases is an important research area and has generated lot of interest recently. Previous studies in this area have concentrated on calculating similitude between (sub)sequences of equal sizes. The question of unequal sized (sub)sequence comparison to report similitude has been an …

Precursors For Copper Chemical Vapor Deposition, Muna Bufaroosha

LSU Doctoral Dissertations

The main objective of this study was to synthesize precursors that are capable of producing copper films of high quality by chemical vapor deposition (CVD). We investigated some copper(I) and copper(II) complexes as precursors for chemical or photochemical vapor deposition. In chapter 2, we synthesized a series of Cu(hfac)₂(amine) adducts, where hfac^- is hexafluoroacetylacetonate and the amines are: dimethylamine, isopropylamine, allylamine, pyrrolidine, and piperidine. The efficiency of these adducts compared to Cu(hfac)₂(H₂O) as Cu-CVD precursors was examined under hydrogen. We found that among these amine adducts, Cu(hfac)₂(allylamine)₂ gave the best …

The Combined Effects Of Salinity And Sulfide On The Growth And Physiology Of The Freshwater Marsh Plant Pancium Hemitomon J.A. Schultes, James Wesley Pahl

LSU Doctoral Dissertations

Vegetative response to saltwater intrusion into coastal freshwater wetlands is governed by the combined effects of increased salinity and porewater sulfide concentrations. I conducted a series of experiments to address the primary hypothesis that growth of Panicum hemitomon is adversely affected by an interaction between salinity and sulfide stresses associated with saltwater intrusion, and the mechanisms for decreased growth are alterations in the metabolic and morphological adaptations needed for a plant to survive in a flooded environment. I exposed marsh sods to a factorial treatment arrangement of three salinities (0, 2, and 4 ppt) and three porewater sulfide concentrations (0, …

Efficient Parallel Computation On Multiprocessors With Optical Interconnection Networks, Min He

LSU Doctoral Dissertations

This dissertation studies optical interconnection networks, their architecture, address schemes, and computation and communication capabilities. We focus on a simple but powerful optical interconnection network model - the Linear Array with Reconfigurable pipelined Bus System (LARPBS). We extend the LARPBS model to a simplified higher dimensional LAPRBS and provide a set of basic computation operations. We then study the following two groups of parallel computation problems on both one dimensional LARPBS's as well as multi-dimensional LARPBS's: parallel comparison problems, including sorting, merging, and selection; Boolean matrix multiplication, transitive closure and their applications to connected component problems. We implement an optimal …

Electronic And Structural Properties Of Rare Gas Cation Clusters, Jose Alejandro Gascon

LSU Doctoral Dissertations

We study structure and ground and excited state properties of rare gas cation clusters, Rg⁺_N, for N=3-60. The main goal is to understand how the positive charge is delocalized over the cluster and the relationship between cluster geometry and delocalization. He⁺_N, Ar⁺_N, and Xe⁺_N are selected as representatives of the rare gas elements. We perform Monte Carlo simulations to obtain finite temperature properties of the energy spectrum. The Hamiltonian of the system is based on a semi-empirical model whose parameters are obtained through the fitting of experimental and calculated …

Synthesis And Properties Of Novel Macrocycles And Related Chromophoric Benzenoid Compounds, Jorge O. Escobedo Cordova

LSU Doctoral Dissertations

The synthesis and properties of some macrocyclic compounds of interest are presented. Resorcinarenes with functionalized conjugated rigid rods made of oligo-p-phenylenes would lead to an entirely new class of functional, soluble, well-defined architectures impacting a variety of multidisciplinary research efforts. The general synthetic design described in this document could be readly extrapolated to include other electronic systems such as heteroaromatics and polyenes. An extensive collaborative study of chromophore formation in resorcinarene solutions is also described here. The study reveals that upon oxidation, the reversible conversion to acyclic precursors occur first, and then these precursors undergo oxidation to quinoid-type compounds (xanthenes). …

Scientific And Management Perspectives In Wetland Groundwater Hydrology, Lorna Veronica Inniss

LSU Doctoral Dissertations

Wetland groundwater hydrology was investigated at different spatial scales to assess the usefulness of the information to coastal managers. Specific objectives were to: (1) review studies related to coastal groundwater discharge, evaluating techniques and identifying controls; (2) understand regional trends in groundwater flow along the U.S. East and Gulf coasts; (3) evaluate the applicability of naturally occurring radioisotopes as indicators of groundwater in a shallow deltaic system; and (4) evaluate groundwater-surface water exchange within Barataria Basin, Louisiana. Results of the review confirmed discharge estimates vary over several orders of magnitude, due to differences in precipitation and tidal prisms. In addition, …

Synthesis, Characterization, And Applications Of Novel Pseudostationary Phases In Micellar Capillary Electrophoresis For Separation Of Chiral And Archiral Compounds H[Electronic Resource], Cevdet Akbay

LSU Doctoral Dissertations

The research presented in this dissertation involves the synthesis, characterization, and the use of novel surfactants, including both micelles and vesicles, as pseudostationary phases in micellar capillary electrophoresis (MCE) for the separation of achiral and chiral compounds. Separation of environmental pollutants such as 2 to 6-ring polycyclic aromatic hydrocarbons (PAHs) was achieved using poly(sodium undecylenic sulfate). A baseline separation of all 16 PAHs was possible for the first time in MCE by a single-surfactant system. In addition, a surfactant with a phosphated head group, i.e., di(2-ethylhexyl)phosphate (DEHP), was also introduced as a novel pseudostationary phase for separation of 21 weakly …

Sediment Transport In Wind-Exposed Shallow, Vegetated Aquatic Systems, Allen Michael Teeter

LSU Doctoral Dissertations

Ecosystems with submersed vegetation are relatively shallow, physically stable and of moderate hydrodynamic energy. Submersed vegetation affect hydrodynamic friction for currents and waves resulting in increased overall frictional loss. Seagrasses shelter the sediment bed and reduce wind-wave resuspension. Bed sheltering factors were estimated from previous flume data on Laguna Madre seagrass species. Data from Laguna Madre indicate that total suspended material levels for bare areas are about an order of magnitude higher than some areas with submersed vegetation. Waves in Laguna Madre at depths less than 2 m were found to be smaller than those expected for the same non-dimensional …

A Monotone Follower Control Problem With A Nonconvex Functional And Some Related Problems, Jamiiru Luttamaguzi

LSU Doctoral Dissertations

A generalized one-dimensional monotone follower control problem with a nonconvex functional is considered. The controls are assumed to be nonnegative progressively measurable processes. The verification theorem for this problem is presented. A specific monotone follower control problem with a nonconvex functional is then considered in which the diffusion term is constant. The optimal control for this problem, which is explicitly given, can be viewed as tracking a standard Wiener process by a non anticipating process starting at 0. For some parameters values, the value function for this monotone follower control problem is shown to be C² and for other …

Of Manatees, Mangroves, And The Mississippi River: Is There An Estuarine Signature For The Gulf Of Mexico?, R. Eugene Turner

Faculty Publications

Important parameters of estuarine variability include morphology, flushing times, nutrient loading rates, and wetland: water ratios. This variability both reflects and disguises underlying relationships between the physics and biology of estuaries, which this comparative analysis seeks to reveal, using the Gulf of Mexico (GOM) estuaries as a starting point. A question used to focus this analysis is: are the GOM estuaries unique? The GOM receives the Mississippi River, a uniquely large, world-class river, which dominates the freshwater and nutrient inflows to the GOM continental shelf, whose margins include 35 major estuarine systems. These GOM estuaries have 28% and 41% of …

A Study On The Effect Of Storage Time On Specific Gravity And Eggshell Quality, Brock Kendall Laborde

Honors Theses

No abstract provided.

Constructing Regular Ramanujan Graphs Via Graph Extension, Sage Michelle Accardo

Honors Theses

No abstract provided.

Analysis Of Near-Infrared Dye-Labeled Sanger Sequencing Fragments With Gel Electrophoresis Using The Time-Resolved Flourescence Lifetime Indentification Methods, Suzanne Jeanel Lassiter

LSU Doctoral Dissertations

The research presented in this dissertation involves the identification of sequencing fragments with time-resolved methods. For this application, near-infrared heavy-atom tricarbocyanine dyes were developed in our laboratory, which can be excited with a single laser and emission collected using a single detection channel. The dyes have four spectroscopically unique, but relatively short lifetimes that can be altered by the intramolecular heavy-atom they contain. The work described here involves the optimization of dye-primer chemistry for preparing Sanger sequencing reactions for longer reads and the optimization of the separation matrix for capillary gel electrophoresis that produces favorable statistical analysis of the aforementioned …

Analysis Of Inorganic Materials Using Advanced Nmr And Nqr Techniques, Anthony Adrian Mrse

LSU Doctoral Dissertations

Several advanced solid-state nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) techniques have been applied to inorganic materials of commercial interest. The specific techniques applied to each system were chosen to solve specific obstacles which impeded the flow of industrial science.

First, the dispersion of brominated flame retardants in polymers is monitored using pulsed ⁸¹Br NQR (nuclear quadrupole resonance) techniques. The NQR spectrometer consists of a homemade NMR console and an automatically tuned loop-gap resonator probe. The two factors which affect the ⁸¹Br NQR transition frequencies of brominated aromatics are: electron-donating and withdrawing substituents on the ring …

The Synthesis Of Deuterated Arylamine Dna Adducts For Use In The Development Of An Isotope Dilution Lc/Ms/Ms Method, Philip Dmitri Olsen

LSU Doctoral Dissertations

Polycyclic aromatic amines (arylamines) are a class of chemical carcinogens that are prevalent in environmental and industrial settings. In order to study the mechanism of their toxicity a quantitative and qualitative detection method was developed to measure the C8-adenine adducts of benzidine and 2-aminofluorene in DNA samples. To do this a novel synthetic method using a palladium catalyst was developed to prepare authentic and deuterated arylamine adducts to serve as standards. These standards were then used to develop a high performance liquid chromatography, electrospray, tandem mass spectrometry, isotope dilution, detection method. To demonstrate the validity of this method two spike …

Numerical Simulations Of Dynamical Mass Transfer In Binaries, Patrick Michael Motl

LSU Doctoral Dissertations

We present results from investigations of mass transfer instability in close binary star systems. By unstable mass transfer we mean the exchange of material where the response of the binary to the initial Roche lobe overflow causes the donor to loose even more material. Our work is guided by approximate arguments that dictate the stability boundaries for binary star systems. To proceed further one must explicitly treat extended mass and velocity distributions that are both nitially, and through their subsequent evolution in time, self-consistent. In this dissertation, we present the first three-dimensional, fully self-consistent treatment of mass transfer in close …

Synthesis And Analysis Of Three-Dimensional Molecular Architectures, Patricia Beck

LSU Master's Theses

The use of resorcinarenes in the study of biologically significant phenomena has been the focus of much attention, due to the versatility of these macrocyclic compounds. In this thesis, two applications of resorcinarenes are explored. First, the search for the mechanism by which tetraarylboronic acid resorcinarenes lead to colorimetric detection and quantization of saccharide analyte concentration in solution is described. Second, the extension of the lower rim conjugation of the resorcinarene macrocycle by the fourfold addition of various length oligo(p-phenylene) rods is discussed. The synthesis of these tubular materials, with potential uses as artificial ion channels and for binding and …

Evaluation Of In Situ Bioremediation Approaches In Meeting International Standards For Organic And Residual Metals Toxicity In Soils, Jason Allan Mcdonald

LSU Master's Theses

Drilling fluids and muds are an essential component of the rotary drilling process used to drill for oil and gas on land and in offshore environments. However, the bioaccumulation of petroleum contaminated soils/drilling mud due to oil and natural gas exploration has posed a major environmental concern due to its prolonged environmental persistence and its leachability below the rhizosphere. The main objectives of this research were: (i) To assess initial toxicity of drilling mud and related contaminated soils from an agricultural setting in Galliano, Sicily (Phase one) and (ii) To develop a low intervention bioremediation approach using bioplug technology to …

Bounding The Wild Set (Counting The Minimum Number Of Wild Primes In Hilbert Symbol Equivalent Number Fields), Marius M. Somodi

LSU Doctoral Dissertations

This dissertation makes a contribution to the study of Witt rings of quadratic forms over number fields. To every pair of algebraic number fields with isomorphic Witt rings one can associate a number, called the minimum number of wild primes. The situation is particularly nice when this number is 0; often it is not 0. Earlier investigations have established lower bounds for this number. In this dissertation an analysis is presented that expresses the minimum number of wild primes in terms of the number of wild dyadic primes. This formula not only gives immediate upper bounds, but can be considered …

Artin-Schreier Families And 2-D Cycle Codes, Cem Guneri

LSU Doctoral Dissertations

We start with the study of certain Artin-Schreier families. Using coding theory techniques, we determine a necessary and sufficient condition for such families to have a nontrivial curve with the maximum possible number of rational points over the finite field in consideration. This result produces several nice corollaries, including the existence of certain maximal curves; i.e., curves meeting the Hasse-Weil bound.We then present a way to represent two-dimensional (2-D) cyclic codes as trace codes starting from a basic zero set of its dual code. This representation enables us to relate the weight of a codeword to the number of rational …

Iron Acquisition Systems And The Effect Of Iron On Virulence, Amy E. Noles

Honors Theses

No abstract provided.

Salinity History Of Coastal Marshes Reconstructed From Diatom Remains, Michael L. Parsons, Quay Dortch, R. Eugene Turner, Nancy N. Rabalais

Faculty Publications

Sediment cores were collected from three Louisiana coastal marsh ponds, dated with radioisotopes, and analyzed for diatom remains to determine if long-term salinity changes were evident in the sediment record. A diatom-based salinity index formulated from a statistical comparison of available salinity data and changing diatom assemblages demonstrated that diatom remains appear to preserve salinity signals in coastal brackish and salt marsh environments. The salinity index was applied to sediment cores spanning the late 1600s to the 1990s and provided a more complete record of salinity than field data, which were temporally and spatially incomplete. The salinity reconstructions indicated that …