Physical Sciences and Mathematics Commons^™

Mechanism Of The Ninhydrin Reaction, Carey B. Bottom, Samir B. Hanna, Donald J. Siehr

Chemistry Faculty Research & Creative Works

No abstract provided.

On The Classical‐Spin Model Of Amorphous Ferromagnets, Harry A. Brown

Physics Faculty Research & Creative Works

No abstract provided.

The Bethe‐Peierls‐Weiss Approximation For Amorphous Magnets, Harry A. Brown

Physics Faculty Research & Creative Works

No abstract provided.

Time Resolved Fluorescence Of The A ²∑+ State Of Gef, R. (Richard) A. Anderson, L. Hanko, S. J. Davis

Physics Faculty Research & Creative Works

The radiative lifetime and quenching rates for the A 2∑ + state of GeF have been measured in the flame of GeH 4+F2 by pulsed laser induced fluorescence. In addition, the radiative lifetime of the ν′=0 level of the A 2∑ + state of SiF has been measured in the flame of SiH 4+F2. Quenching rates for He, N2, and SF 6 on GeF A 2∑ and He on SiF A 2∑ have also been determined. The average zero pressure lifetime of ν′=0, 1, and 2 levels of A 2∑ GeF is 990±100 nsec. The zero-pressure lifetime of the A …

A Xenon Ion Pumped Blue Dye Laser, D. W. Fahey, Laird D. Schearer

Physics Faculty Research & Creative Works

A pulsed xenon ion laser with an output power of 5 kW at 364.5 nm has been used as a pump source for several blue dyes. Broadband conversion efficiencies exceed 20 percent. The use of a birefringent filter provides tunable output in the blue region of the spectrum with a bandwidth of 0.08 nm and a pulse width of 120 ns. © 1978 IEEE

Emulsification And The Hlb-Temperature, Stig Friberg, Concepcion Solans

Chemistry Faculty Research & Creative Works

No abstract provided.

The Synthesis And Characterization Of Several Copper (Ii) Complexes Of Quinuclidinone-Containing Ligands. Possible Models For Type I Copper Blue Proteins., Victor Thomas Wilcox

Masters Theses

Several copper (II) complexes with bidentate quinuclidinone containing ligands have been synthesized and characterized. These complexes appear to be possible models for the type I copper (II) in the copper "blue" proteins. The spectral and magnetic properties indicate that the complexes have a pseudo tetrahedral microsymrnetry about the central metal ion. The complexes contain chromophores of the following forms: CuN₄, CuN₂O₂, and CuN₂x₂, where X is either Cl or Br. While the spectra of these complexes lack the intense 17,000 cm^-1 band typical of copper "blue" proteins, the optical …

Landsat Image Analysis Of Linears And Lineaments In The Tri-State District, Missouri-Oklahoma-Kansas, Solomon Hartley Toweh

Masters Theses

"Lineations within the Tri-State mining district are classified as megalineaments, lineaments and linears, based on length. One megalineament, 120 lineaments and 205 linears are identified on the LANDSAT imagery. In order of importance a dominant northeast set, northwest set, north-south set and east-west set are recognized. These range from 0.8 miles (1.3 km) to 68 miles (109.4 km) in length.

Major lineation trends spatially relate with trends of mined areas In the Picher field both northeast and northwest lineations generally parallel mined areas. In the Galena field ore and lineations trend northeast while in the Joplin and Duenweg-Webb City-Oronogo field …

The Paleontology And Biostratigraphy Of The Lower Ordovician Gasconade Formation Of Missouri, Bruce L. Stinchcomb

Doctoral Dissertations

"The biostratigraphy, paleoecology and paleontology of the Lower Ordovician Gasconade Formation in Missouri is reinvestigated in an attempt to solve problems that have arisen since the classic earlier studies by Ulrich, Bridge and others. Twelve faunal zones are established, many based on primitive mollusks which dominate the formation. The oldest of these, in the Van Buren Member, is the Hypseloaonus Zone. This is followed by a zone characterized by the primitive cephalopod Dakeoaeras then a zone dominated by the gastropod Sinuopea. These zones are succeeded by the Euomphalopsis, Matthevia and Ozarkina Zones which lie stratigraphically below the Cryptozoon Zone, …

Spin Correlations In Actinide Materials: A Neutron Study Of Usb, G. H. Lander, S. K. Sinha, Don M. Sparlin, O. Vogt

Physics Faculty Research & Creative Works

Measurements have been made of the short-range spin correlations in USb, a metallic compound that orders antiferromagnetically. The system has no transverse fluctuations, and the longitudinal spin correlations are anisotropic, showing stronger interactions within the ferromagnetic sheets than between them. The results of this and other experiments can be understood with simple concepts involving the bonding of 5f electrons. © 1978 The American Physical Society.

Sedimentology Of The Hannibal Formation In Northeastern Missouri And Western Illinois, Michael Harry Deming

Masters Theses

"The Hannibal Formation (Kinderhookian) occurring in northeastern Missouri and western Illinois is a fine-grained, terrigenous, sedimentary unit which can be divided into an upper and a lower portion, based on lithology. The upper portion consists of alternating coarse and argillaceous, fine siltstone units, while the lower portion consists of a silty mudstone with an occasional thin siltstone unit. At the extreme western margin of the formation, near where the Hannibal almost pinches out, the formation consists entirely of a silty claystone. Extending southward along the study area, the coarse siltstone units of the upper Hannibal become thinner, and eventually pinch …

Inferences On The Shape Parameter Of The Gamma Distribution And Cramer-Rao Lower Bounds From Censored Data, James Wyckoff

Doctoral Dissertations

"This dissertation is presented in publication form and consists of two articles. The first article considers inferential procedures on the shape parameter of a gamma distribution from censored sampling. Moments for the statistic T = log(x̅_r/x͠_r) are found and used to derive a two-moment chi-square approximation for T. This approximation is then used for testing, estimating, and setting confidence bounds on the shape parameter of a gamma distribution. The second article concerns the Cramér-Rao lower bounds for the variances of estimators, where the estimators are based on censored data. Convenient techniques are derived to evaluate the …

Intense Flowing Hollow Cathode Lamp, F. H.K. Rambow, Laird D. Schearer

Physics Faculty Research & Creative Works

An inexpensive, simple, and versatile hollow cathode lamp has been developed which produces intense ion resonance radiation of about 1 mW into 4π/25 sr. The lamp employs flowing helium gas to sustain the discharge. The construction permits a variety of cathode seed materials to be easily interchanged. The same lamp has been used as a source of ion resonance radiation for Ca, Ba, Zn, Mg, Sr, Yb, and Eu.

4th Annual Umr-Dnr Conference On Energy -- Entire Proceedings, University Of Missouri--Rolla

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

No abstract provided.

The Water Monomer On The Basal Plane Of Ice Iₕ: An Effective Pair, Central Force Potential Model Of The Static Interaction, Jerry Kiefer, Barbara N. Hale

Physics Faculty Research & Creative Works

The H₂O-H₂O intermolecular central force potential of Lemberg and Stillinger is used to obtain optimal binding energy surfaces, vibrational frequencies, and bonding configurations of an adsorbed water monomer on a model basal plane of ice I_h. The monomer interacts (pairwise) with 50 molecules arranged in two layers of the unrelaxed bulk ice lattice. The results of calculations for three model surface sites of differing proton arrangement indicate the existence of diffusion barriers of the order of 2.5 kcal/mole and optimal monomer bonding sites at about 9 kcal/mole with nonepitaxial characteristics. Perspective computer-drawn plots of …

Erratum: Excitation Of The N=2 State Of Atomic Hydrogen By Electron Impact In The Distorted-Wave Approximation (Physical Review A (1977) 16, 2), Ralph V. Calhoun, Don H. Madison, W. Neil Shelton

Physics Faculty Research & Creative Works

No abstract provided.

High Spin-Low Spin Crossover And Antiferromagnetic Interactions In Tris(1-Pyrrolidinecarbodithioato)Iron(Iii) And The 4-Morpholine (Fem) And Dibutyl Analogs, Effect Of Recrystallization Solvent, And Crystal Structure Of Fem·Nitrobenzene, Edward J. Cukauskas, Bascom Sine Deaver, Ekkehard Sinn

Chemistry Faculty Research & Creative Works

High sensitivity magnetic susceptibility determinations, especially in the range 1.2-4.2 K on pure and dilute tris(pyrrolidinecarbodithioato)iron(III) (FeP) in its high spin form, show that a maximum at about 2 K is caused by antiferromagnetic interactions. The analogous chromium(III) complex does not exhibit significant antiferromagnetism compared to that of the iron complex, and it is likely that the upper e electrons possessed by the iron and not by the chromium are responsible for the bulk of the antiferromagnetism. As the iron atoms are about 9 Å apart in discrete molecules, the antiferromagnetic interactions presumably occur between unpaired spins delocalized on to …

X-Ray Investigation Of The Critical Exponent Η In Argon, Harold D. Bale, J. S. Lin, Duane A. Dolejsi, James L. Casteel, Oran Allan Pringle, Paul W. Schmidt

Physics Faculty Research & Creative Works

Measurements were made of the small-angle x-ray scattering intensity from argon near the critical point. After the scattering curves are corrected for all known effects except those resulting from irrelevant variables, a value of the critical exponent η=0.09±0.02 is obtained, while if a correction for the estimated effect of irrelevant variables is also made, η=0.03±0.03. The scattering data for argon therefore show that if irrelevant variables can be neglected, the critical exponent η for argon is in good agreement with the value obtained by Warkulwiz, Mozer, and Green from small-angle neutron scattering data for neon. These values of η, however, …

Metal-Ion Oxidative Decarboxylations. 9. Reaction Of Benzilic Acid With Cerium(Iv) In Acidic Perchlorate And Sulfate Media, Samir B. Hanna, Sezai A. Sarac

Chemistry Faculty Research & Creative Works

The kinetics of oxidation of benzylic acid (HLH) to benzophenone by cerium (IV) has been studied in several media using the stopped-flow technique. In HClO₄-Na₂SO₄-NaClO₄ media, which allow for the variation and control of the concentrations of the various Ce(IV) species at constant [H⁺] and ionic strength, the rate data suggest CeSO₄²⁺ as the kinetically relevant species. In HClO₄ the observed first-order rate constants, tetrad, first increase with increasing HLH concentration, then decrease slightly at higher substrate concentrations suggesting the intermediacy of two complexes: a reactive [Ce(IV)HL] and …

Micellar Solutions Versus Microemulsions, Derek G. Rance, Stig Friberg

Chemistry Faculty Research & Creative Works

No abstract provided.

Metal-Ion Oxidative Decarboxylations. 10. Substituent Effects In The Cerium(Iv)-Benzilic Acids Reaction, Samir B. Hanna, Sezai A. Sarac

Chemistry Faculty Research & Creative Works

The rates of oxidation by cerium (IV) of several substituted benzylic acids (unsubstituted, 2,2′-dichloro, 4,4′-dichloro, 4,4′-dimethyl, 4,4′-dimethoxy, and 4,4′-dinitro) to the corresponding benzophenones have been studied spectrophotometrically in aqueous H₂SO₄, aqueous HClO₄-HOAc, and acetonitrile. The rates are much slower in H₂SO₄ than in the other two media, probably because of heavy sulfato complexation of cerium(IV). The px as of the various acids were determined potentiometrically. The Hammett p values in acetonitrile and HClO₄-HOAc media, derived from correlations with several sets of σ constants and with the newly determined pK …

Differential Energy-Loss Cross Sections For Ionization Of Atomic Hydrogen By 25-200-Kev Protons, John T. Park, Judith E. Aldag, Jacob M. George, Jerry Peacher, Jim H. Mcguire

Physics Faculty Research & Creative Works

Ionization continuum cross sections, differential in energy loss, have been determined from the energy-loss spectra of 25-, 50-, 75-, 145-, and 200-keV protons scattered from atomic hydrogen. The theoretical differential cross sections in the Glauber and Born approximations that are presented show that the theory and the experimental results for 200-keV proton impact agree very well, but below 200 keV there are differences. These differences, which are more pronounced at the lower projectile energies, may be explained in terms of charge transfer to the continuum, which is not treated in our Born and Glauber calculations of direct Coulomb ionization. The …

Convex Cones And Dentability, J. C. Hankins, R. (Roy) M. Rakestraw

Mathematics and Statistics Faculty Research & Creative Works

No abstract provided.

On The Mann Iteration Process In A Hilbert Space, Troy L. Hicks, John D. Kubicek

Mathematics and Statistics Faculty Research & Creative Works

No abstract provided.

A Class Of Singular Neutral-Differential Systems, W. J. Fitzpatrick, L. J. Grimm

Mathematics and Statistics Faculty Research & Creative Works

Noetherian operator theory is used to prove an existence theorem for a singular functional-differential system. An analogue of the standard existence and uniqueness results at an ordinary point follows as a corollary. © 1977 American Mathematical Society.

Regular Singular Differential Equations Whose Conjugate Equation Has Polynomial Solutions, Leon M. Hall

Mathematics and Statistics Faculty Research & Creative Works

Consider the n -dimensional singular differential system defined by the operator $L:(Ly)(z) = z^p y'(z) + A(z)y(z)$, where z is a complex variable and p is a positive integer. The solvability of the nonhomogeneous system $Ly = g$ depends on the solutions of the homogeneous conjugate system, $L^ * f = 0$, where $L^ * $ is the operator conjugate to L. We show that $L^ * f = 0$ has polynomial solutions if the constant matrix in the series expansion of $A(z)$ has at least one nonpositive integer eigenvalue. Also, we show that if $L^ * f = 0$ …

Results Of A Remedial Laboratory Program Based On A Piaget Model For Engineering And Science Freshmen, Robert Gerson

Physics Faculty Research & Creative Works

Engineering and science freshmen who enter our institution with algebra deficiencies have a very low probability of performing satisfactorily in the required college-level calculus course. Two years ago, a remedial one-semester program was conducted for 36 freshmen who were identified by an entrance examination as being weak in algebra. The course was based on the assumption that the students were "concrete" in the Piagetian sense. The main part of the course required a general physics laboratory that provided selected experiences to bridge the concrete-formal gap. After three semesters, 31% of the participants in the course were receiving grades of C …

Interaction Of Electric And Magnetic Charges, I. Adawi

Physics Faculty Research & Creative Works

It is shown classically that in a head-on collision between an electric and a magnetic charge a repulsive polarization force of the form r-5 results (where r is the distance between the charges), if one (both) charge(s) is (are) assigned a finite spherical size. This force leads to a minimum distance of approach and prevents one particle from going through the other, and thus guards against the violation of the conservation of angular momentum. This polarization force is a manifestation of the diamagnetism (diaelectricity) of extended electric (magnetic) charges. © 1977 The American Physical Society.

Light Emission From Atom Beam - Plasma Interactions, Kaare J. Nygaard

Physics Faculty Research & Creative Works

A beam of atoms penetrating a plasma can be considered a line source of contaminants. Atoms excited by the plasma electrons yield information about the spatially resolved electron density and temperature. The light intensity as a function of time and position along the beam can be conveniently observed with an optical multichannel analyzer Since the beam atoms are different from the plasma constituents, the method does not suffer from self-absorption. Copyright © 1977 by The Institute of Electrical and Electronics Engineers, Inc.

Note On The Van Der Waals Equation, Louis H. Lund

Physics Faculty Research & Creative Works

No abstract provided.