Physical Sciences and Mathematics Commons^™

An Application Of Cathodic Sputtering To The Etching Of Metallographic Specimens, Robert Ruch

Masters Theses

"The U. S. Bureau of Mines at Rolla, Missouri has for some years been conducting research on manganese-copper alloys. The study of the physical metallurgy of these alloys -- dissimilar metal couples -- has always been complicated by the difficulty of satisfactorily etching this material. It was felt that by introducing a new etching technique, cathodic bombardment, satisfactory etching might be accomplished. On this basis the following research program was proposed:

1) To survey the present state of art of cathodic etching, etching by means of cathodic sputtering;

2) To design and construct suitable equipment for the experimental study of …

Permeability Study Of Algal Reef Beds Within The Bonneterre Formation, National Mine, St. Francois, Missouri, Bobbie L. Perry

Masters Theses

"The Missouri "Lead Belt" comprises approximately 50 square miles, centering around the town of Flat River, in St. Francois County. Missouri. This district has been producing lead for more than 200 years, the total production being at least 8,000,000 tons of lead, valued at more than $1,000,000,000. For many years, the annual production of the district has been at least one-fourth of the total production in the United States.

An excellent description of the geology of this area was published recently by Ohle and Brown in 1954.

The ore consists principally of galena which is disseminated within the Bonneterre formation …

A Geological Study Of The Irvine Ranch Area, Johnson And Campbell Counties, Wyoming, Gale E. Butterfield

Masters Theses

"The discovery of uranium in the Powder River Basin, Wyoming, by the U. S. Geological Survey in 1952 has lead to an extensive exploration program throughout the region by both private and governmental agencies. This report is a geological study of an area in the southwestern part of the basin.

Geological and radiometric mapping carried out as a part of this report indicated several areas of uranium occurrence. Some of these occurrences warrant tests by drilling.

Mineralogical and petrographic study has shown the principal uranium minerals to be carnotite and metatyuyamunite. The mineralization occurs in arkosic sandstones. Assays of the …

Transference Numbers Of Concentrated Manganous Chloride Solutions, Marshall L. Severson

Masters Theses

"Electrolytic conduction differs from metallic conduction only in the nature of the carrier of the current. In the case of metallic conduction the carrier is electrons. The passage of an electric current through an electrolyte occurs only by the movement of ions of opposite charge moving in opposite directions under an applied potential. The current carried by a particular ionic species is a direct function of the concentration, the charge on the ion, and the ionic mobility. A transference number is the fraction of the total current a given ion carries in a particular electrolyte undergoing electrolysis. The sum of …

Detection Of Low Energy Positive Ions By Scintillation Methods, Graydon J. Hanson

Masters Theses

"This thesis deals with the feasibility of efficiently detecting low energy positive ions, those with energies of less than several hundred electron volts, using phosphors.

The scintillation technique, first used visually and greatly improved in the last ten years by the use of a photomultiplier tube, has greatly advanced detection in high energy fields. The photomultiplier is capable of delivering milliampere pulses of current of short duration and these can be registered directly by the many electronic devices currently in use.

Extensive work has been done with phosphors which scintillate under which energy bombardment, due in part to their wide …

Some Thermodynamic And Structural Properties Of A Linear Chain Of Atoms, And Extension Of The Model To Two- And Three-Dimensional Cases, Hari Gopal Mukerjee

Masters Theses

"An attempt has been made in the present work to derive some thermodynamic and structural properties of a linear chain of atoms (under somewhat idealized conditions) moving in the fields of nearest neighbours and assuming a parabolic well in the interaction of pairs within the range of relative movements. The equation of state and other formulas derived are applicable only to the linear model which could be considered as a simplified form of one-dimensional crystals in the form of chain-like molecules of rubber-like substances. An attempt has also been made to extend the model to two- and three-dimensional cases"--Introduction, page …

Internal Friction In Manganese Copper Alloys, William Paul Dixon

Masters Theses

"The study of the physical properties of the manganese-copper alloys is an intriguing one. These alloys show promise of usefulness in instances in which high internal friction is needed to reduce the noise and vibrational stresses at resonant frequencies of a part of a machine. The purpose of this study has been to learn more about the internal friction of manganese-copper alloys as a function of temperature, stress amplitude, frequency, time, and past history of the specimen. From this information the mechanism for absorption of vibrational energy is proposed, or at least some progress has been made toward its determination. …

A Probe For Measuring Ultrasonic Pressures, Robert F. Rohrer

Masters Theses

"In the study of acoustics, the term ultrasonics is defined as those wave motions that have frequencies greater than about 20,000 cycles per second. The characteristics of a sound wave at any point in a medium can be regarded as completely defined when the amplitude, frequency, and phase of its Fourier components are known.

Sound measurements at their best are difficult. In the last few years sensitive linear microphones and electronic amplifiers have become available. Still, there are two difficulties of prime importance with their use in a sound field. First, there is the precise, absolute calibration of the equipment …

The Phosphoria Formation Of The Northeastern Big Horn Basin, Wyoming, William A. Beatty

Masters Theses

"Purpose and Scope. — The Phosphoria formation of the northern Rocky Mountains of the United States has received considerable attention from geologists because of its important reserves of phosphate and petroleum. In the Big Horn Basin of Wyoming, however, still more work is needed to compile the information necessary for a complete understanding of the facies changes exhibited by this formation.

The purpose of this paper is two-fold: first to present a description of the lithology and the paleontology of the Phosphoria formation in the northeast part of the Big Horn Basin, and secondly to show the stratigraphic relationship of …

Pre-Cambrian Geology Of Washington County Area, Missouri, Gordon Blair French

Masters Theses

"The Problem.

Washington County, Missouri contains a limited number of outcrops of pre-Cambrian igneous rocks, the majority of which are in the extreme southern part of the county. The known association of lead ore with buried or partially buried pre-Cambrian igneous knobs and ridges in this part of Missouri has led the St. Joseph Lead Company to prospect in areas known to contain these features. In its exploration program, the St. Joseph Lead Company has drilled a number of prospect holes which have encountered other occurrences of pre-Cambrian igneous rocks within the limits of Washington County. This drilling, correlated with …

Geology Of The Northwest Quarter Of The Washington Quadrangle, Missouri, James Anthony Martin

Masters Theses

"This report presents the results of detailed mapping of the geology of the northwest quarter of the Washington Quadrangle, Missouri. Extensive mapping and stratigraphic work have been done in St. Louis and St. Charles Counties to the east and in Callaway and Boone Counties to the west. These two well studied areas are separated by approximately 45 miles. This study adds geologic information to the area immediately between the above locations. In this area a gentle regional dip to the north permits a study of sediments ranging in age from lower Ordovician in the south to late Paleozoic and Pleistocene …

The Thermal Conductivity Of Potassium Chloride At Elevated Temperatures, Wendell D. Miller

Masters Theses

"The transport of heat in solids is attributed to the combined effect of the quantized vibrations of lattice points, or phonons, and the flow of valence electrons. In dielectric solids, the thermal conductivity is due almost entirely to phonons, while in metals the latter method preponderates. Scattering processes in dielectric solids, giving rise to thermal resistance, also serve to limit the thermal conductivity. Scattering results from vacancies, dislocations, interstitial atoms and phonon interaction. Crystal boundaries also function as scattering points and in crystals of small dimensions, this process is the most pronounced conductivity-limiting factor. At low temperatures the thermal resistance …

The Effect Of Ph On Phase Reversals Of Protein-Stabilized Emulsions, Samuel Arthur Bradford

Masters Theses

"The phase reversal of an emulsion from a system in which oil droplets are dispersed in a water medium to a system in which water droplets are dispersed in oil is dependent upon the interfacial characteristics of the liquids and the emulsifying agent being used, as well as the volume ratio of the two liquid phases. A preliminary investigation at this institution has indicated a possible relationship between phase reversal and the isoelectric point of gelatin used as the emulsifying agent. Since the properties of proteins vary so greatly with the hydrogen ion concentration, particularly near their isoelectric points, research …

Geothermometry At The Balmat No. 2 Mine, New York By The Fes-Zns System, Bruce R. Doe

Masters Theses

"Definition Of The Study. The study consists of an investigation of the variation in the temperature of formation of sphalerite on the 500 and 1500 ft levels of the Balmat zinc deposit at Balmat, New York. A subsidiary investigation was performed on the use of x-ray fluorescence as a means of chemical quantitative analysis. Twelve samples of sphalerite from the 500 ft level and 13 samples from the 1500 ft level were analyzed for atomic percent iron content by measuring Zn/Fe x-ray fluorescent ratios. The x-ray fluorescent ratios were standardized by ''wet" quantitative analysis. The results of the analyses are …

An Investigation Of The Internal Friction Of Manganese-Copper Alloys, Ed. (Edward) Sickafus

Masters Theses

"Internal friction is defined as the ability of a vibrating solid to convert its mechanical energy of vibration into heat, even when completely isolated from its surroundings. (1) The most familiar manifestation of internal friction is the damping of a freely vibrating body, such as a torsional pendulum. Another example would be the increased width of the resonance peak observed when a nonelastic body is forced to vibrate over a spectrum of frequencies.(2) Internal friction manifests itself in numerous ways, and we will here be concerned with the first example cited and the potency of data gained in studying the …

Thermal Conductivity Of Sodium Chloride Within The Temperature Range 375°K To 637°K, Paul E. Ohlsen

Masters Theses

"The transport of heat in dielectric solids is attributed entirely to lattice waves whereas in metals there is in addition a transfer by the flow of valence electrons. The thermal conductivity of a non-electrical-conductor is limited by a number of scattering processes giving rise to thermal resistances. Scattering results from impurity atoms and from vacancies and dislocations within the crystal structure and from the interaction of the lattice vibrations amongst themselves. Scattering also occurs at the boundaries of the crystal. The thermal resistance of an ideal crystal at low temperatures is due almost entirely to boundary scattering and at high …

Direct Correlation Functions For Liquid Argon, Arthur Reetz Jr.

Masters Theses

"The purpose of this research is to obtain the direct interaction functions from the liquid argon x-ray scattering structure factors of Eisenstein at various temperatures and over a wide range of interatomic separations"--Introduction, page 1.

The Effect Of Metallic Naphthenates On The Oxidation Of Linoleic Acid, David Elliott Troutner

Masters Theses

"It has been known for many years that certain metallic soaps catalyse the drying of oils. A great deal of information is available concerning the use of these soaps, but there is little knowledge of the actual manner in which the soaps catalyse drying. As the drying is known to be an autoxidation reaction, it is generally believed that the soaps must affect the oxidation of the oil in some way. The work described in this thesis was undertaken to gain some knowledge of the mechanism of the catalysis, and to correlate the effect of the soaps on the drying …

Separation Of Germanium, Lead, Zinc, And Cadmium By Anion Exchange, Franklin Maynard Hill

Masters Theses

"The object of this study was to investigate the ion exchange behavior of germanium and apply the anion exchange technique for the separation of germanium, cadmium, lead, and zinc.

A new interest in germanium has developed because of its recent industrial application as a semi-conductor. Analytical methods for the separation and analysis of germanium in low concentrations have not been perfected. Krause and Johnson, in a recent review, discussed and evaluated a number of methods.

Most of the methods for the analysis of germanium require a preliminary separation. The analytical methods for germanium reported in the literature are troublesome and …

Correlation Functions For Use In Small Angle X-Ray Scattering, James Edwin Thomas Jr.

Masters Theses

"Thus, the determination of the structure of the material, and obtaining a distribution function which will enable the theoretical scattering to be predicted is the major problem.

In this work the diffraction material shall be considered to contain scattering regions of identical geometrical forms at such a distance from one another that they will essentially scatter the incident beam independently of their closest neighbor. An effort will be made to determine a correlation function characteristic of these forms, which may be interpreted as a distribution function, that might allow the low angle scattering pattern to be predicted. This correlation function …

Morphology And Systematic Position Of Some Anomalinid Foraminifera, Billy G. Deaver

Masters Theses

"Morphological studies of the following species are the basis for a partial revision of the Family Anomalinadae: Anomalina acuta Plummer, A. midwayensis (Plummer), A. pseudopapillosa Carsey, A. vulgaris (Plummer), Anomalinoides pinguis (Jennings), Cibicides alleni (Plummer), C. beaumontianus (d’Orbigny), c. harperi (Sandidge), Cibicidina danvillensis (Howe and Wallace), Planulina correcta (Carsey), and P. dumblei (Applin); a description of Stensioina americana Cushman and Dorsey, discorbid foraminifer, is included for comparison. The classificatory position and incomplete content of the family are: Superfamily Discorbidea; Family Anomalinidae; Subfamily Anomalininae (revised) -- with ventral supplementary apertures: Anomalina , Planulina ; Subfamily Cibicidinae -- with dorsal supplementary apertures: …

Addition Of Ketene To Ethylene Oxide, John Philip Friedrich

Masters Theses

"The object of this work was to study the reaction between ethylene oxide and ketene, and if possible, to isolate and identify the postulated γ-butyrolactone. Although the results could hardly be described as completely gratifying, they were at least in a sense positive. Many possibilities remain with regard to further modifications of the experimental work on this problem, however it is the author's sincere wish that this investigation will serve some useful purpose in the future"--Introduction, page 4.

The Thermal Conductivity Of Sodium Chloride At Elevated Temperatures, Howard Martin Brown

Masters Theses

"The thermal conductivity of solids has been attributed to a combined effect of the quantized vibration of the lattice points, called phonons, and the flow of valence electrons. In nonconductors the thermal conductivity is due almost entirely to phonons, as was shown by Debye, whereas in metals the conductivity is due mostly to the flow of valence electrons. After Debye, Peierls calculated the lattice conductivity at elevated temperatures using quantum mechanics and demonstrated that it is proportional to 1/T. There are not enough data available to substantiate any theory but what data there are seem to indicate a mixed conductivity …

A Model For X-Ray Scattering From A Free-Volume Liquid, Charles A. Hewett

Masters Theses

"Investigation of the diffraction of x-rays by liquids was begun soon after the well-known work of Friedrich, Knipping, and Laue proved to be of value in supplying information as to the arrangement of atoms in crystalline matter. Friedrich in 1913 reported x-ray diffraction patterns of Canadian Balsam, paraffin, and amber; three years later Debye and Scherrer, in their work on benzene, (among other liquids investigated) showed that the diffraction phenomenon exhibited was one of interference. Still later, in 1922, Keesom and de Smedt reported similar investigations carried out on argon, nitrogen, and oxygen in the liquid state, the results of …

Coloration Of Glass By High Energy Radiation, Thomas L. Nickens

Masters Theses

"Purpose of Investigation: One of the objects of this investigation is to determine the amount of CeO₂ required to prevent the discoloration of glass when exposed to gamma radiation. By discoloration, it is meant that there has been a change in the absorption bands of visible light. Another objective is an attempt to prevent the coloration by the introduction of two oxides not previously used. Finally, a theory is presented which could explain why glass containing CeO₂ does not change color upon irradiation by gamma rays"--Introduction, page 1.

The Mineralogy Of The Grassy Creek And Saverton Formations, Dirk Pieter Van Duym

Masters Theses

"A study of the mineralogy of the Grassy Creek and Saverton formations of Northeast Missouri was undertaken to determine whether a division is justified, as proposed by some stratigraphers, of these argillaceous beds into two formations. The formations were sampled systematically at surface exposures on the northeast limb of the Lincoln Arch in the vicinity of Hannibal and Louisiana, Missouri. The samples were investigated mineralogically in the laboratory. Previous studies showed that the fossils of the Grassy Creek and Saverton beds were virtually identical. The present study demonstrates that the Grassy Creek and Saverton beds are too near alike in …

Foraminifera Of The Type Section Of The Archusa Marl Of Mississippi (Eocene, Claiborne Group, Wautubbee Formation), Nathan Eugene Crockett

Masters Theses

"The type locality of the Archusa marl member of the Wautubbee formation is situated south of Quitman, Clarke County, Mississippi. Stratigraphically, the unit falls within the middle Eocene Claiborne group, being roughly equivalent to the upper part of the Lisbon formation of Alabama and the lower part of the Cook Mountain. The marl falls within the Ostrea sellaefonnis zone and the zone of "Ceratobulimina eximia.” The type section consists of 48 feet of sandy marls, with a thin oyster bed near the middle.

The Archusa foraminifera fauna consists of 87 species and varieties, belonging to 49 genera and …

Geology Of The South Half Of The Meramec Spring Quadrangle, Missouri, Howard Joseph Yorston

Masters Theses

"This report is a continuation of the work initiated by Mueller in his mapping of the north half of the Meramec Spring Quadrangle. The completion of this work provides not only a geologic map of the whole quadrangle but also completes the mapping of the geology of a strip of quadrangles extending from Rolla to the Mississippi River. In addition to being a step closer to the goal of complete geologic coverage for the state, this work will be of value to those concerned with the prediction of depths of wells drilled in search for water, which in view of …

A Study Of The Emission And Absorption Spectra Of Nacl And Kcl Between 100 A And 1000 A, Paul Henry Blackmon

Masters Theses

"This investigation was begun with the idea of obtaining the emission and absorption spectra of NaCl and KCl in the region between 100 A and 1000 A. From these data, it is hoped that useful information concerning the energy levels of these two substances may be obtained.

The vacuum ultraviolet region is rather difficult to investigate because of the necessity of removing all air, lenses and other absorbing material from the light path. Many writers have enumerated the problems involved and some have indicated that much work still needs to be done in the vacuum ultraviolet.

In order to do …

The Velocity Of Ultrasonics In Liquids, Mack A. Breazeale

Masters Theses

"In acoustics the term ultrasonics is used to refer to those frequencies which are above the range of human hearing; that is, frequencies above approximately 20,000 cycles per second. Since the laws of sound which are valid for the audible range are also valid in the ultrasonic range and since the wave length of ultrasonics is much shorter than that of audible sound, ultrasonic has proved very valuable in the calculation of both the velocity and the absorption coefficient of sound in various media. This is especially notable in the case of liquids, where the velocity of sound is much …