Physical Sciences and Mathematics Commons^™

Determination Of The Thermal Conductivity Of Sodium Chloride At Elevated Temperatures, Harold Robert Weisbrod

Masters Theses

"The purpose of this research is to investigate possible methods of determining the thermal conductivity of small poorly conducting samples at elevated temperatures, and, further, to assemble a suitable apparatus, followed by measurement of thermal conductivity of one or more cubic lattice samples.

Basic requirements of the apparatus are few. It is first required that the measurement of thermal conductivity be made over a considerable range temperature. It is also preferred that the basic apparatus be placed in a vacuum where undesirable heat flow by convection is eliminated and air corrodible samples are preserved.

The apparatus must use only the …

A Petrographic And Chemical Study Of The Bevier Coal Seam, Philip John Clarke

Masters Theses

"Samples of coal were taken at three inch intervals vertically down the Bevier seam at three localities in Macon and Randolph Counties. Channel samples were collected at the three localities. All samples were analyzed for ash content, total sulphur content, crucible swelling number, and volatile content. The channel samples were analyzed for "pyritic" sulphur, “sulphate" sulphur, and "organic" sulphur. Thin sections of the samples were used in an estimation of anthraxylon and attritus contents.

In all the samples studied, volatile content of the coal seemed to be related to the ash content and the sulphur content. Crucible swelling number also …

A Study Of Immiscibility In The Carbonates From The Metamorphic Rocks Of Southeastern Vermont, Ralph D. Cotter

Masters Theses

"This problem is an attempt to correlate grade of metamorphism (normally assumed to be temperature dependent) with the shape and dimensions of a solid miscibility gap. Such a correlation might permit mapping of a continuously variable function of metamorphism. The system, calcite and dolomite-ankerite, was chosen for study because of its relative simplicity. Samples of quartz-carbonate granulite were collected from the Waits River formation in southeastern Vermont through a range of metamorphic grades. Refractive index, "molecular" volume, manganese content, and density were determined for the carbonates of four of these samples. These values are plotted on a compositional diagram to …

A Linear Polymer X-Ray Scattering Model, Bernard Cohen

Masters Theses

"In the development of X-ray scattering intensity curves physical models are necessary for the theoretical mathematical development involved. The purpose of this paper is the development of a physical model suitable for X-ray diffraction analysis or a linear polymer.

X-ray intensity patterns may be used to give a greater insight as to the atomic structure, configuration or atoms, molecular weight, and therefore a greater knowledge of the structure of matter, both microscopic and macroscopic. The converse may sometimes be used. An atom or molecular model is constructed, from this model X-ray scattering curves may be derived. These curves may be …

The Fluorescence Of Uranium In Solid Solution, Robert Emmett Kelly

Masters Theses

"The fluorescence of uranium finds its greatest application in the so-called "bead test" which is a method of qualitative analysis. In the form of a bead, the uranium is in solid solution, and if the proper chemical solvent is used, the bead will fluoresce under ultraviolet radiation.

In the systematic separation of the metallic elements, uranium is associated with the aluminum group in that it is not precipitated by hydrogen sulfide in 0.3 N H ion but is precipitated by ammonium hydroxide and ammonium sulfide. In the analytical scheme, uranium acts like beryllium. This process of detection is sometimes tedious …

Geochemical Prospecting Applied To The Illinois-Kentucky Fluorspar Area, Matthew Peter Nackowski

Doctoral Dissertations

"This study was completed to determine whether geochemical methods of prospecting could be applied to the search for fluorspar deposits in the Illinois-Kentucky fluorspar district.

During the course of the study, aspects of the geochemical cycle of fluorine under the climatic environment encountered were noted in the zone of weathering.

The Illinois-Kentucky fluorspar district supplies a large portion of the fluorite consumed in the United States. The producing deposits are of two geologic types. The vein deposits occur as nearly vertical tabular lenses or pods which occupy fractures. These deposits may reach the bedrock surface, but in any case, the …

4-Benzoyl-4-Methyl-1, 2-Epoxypentane, An Attempted Synthesis, Robert L. Snell

Masters Theses

"The object of this research was to prepare first the simplest homologue of the epoxy-ketone considered by Russell to have been his product. If this homologue, 4-benzoyl-4-methyl-1,2-epoxypentane, could be prepared and caused to form a cyclic derivative of the type given by 1,4-diketones with 2,4-dinitrophenylhydrazone, the organic chemist would be given a new approach to substituted 1,2-diazines as well as a previously unreported reaction of the epoxide grouping. If this reaction could be made to occur, other epoxides of this series would be prepared and treated in the same manner.

It was decided that the shortest route to 4-benzoyl-4-methyl-1,2-epoxypentane would …

Halogenated Epoxide-Phenol Reactions A Mechanism Study, Richard L. Rowton

Masters Theses

"The object of this investigation was to study the reactions of two other halogenated epoxides--namely, 3-bromo-1,2-epoxybutane and l-bromo-2,3-epoxybutane--with the phenolate ion, with the hope that the results obtained would shed additional light upon the mechanisms of such reactions. At the present time, no direct practical applications of the results can be forseen. However, the information gained will be a worthwhile addition to the vast existing store of knowledge already at our disposal, and might be of some help to future investigators"--Introduction, page 2.

The Partition Function Of Silver, Ralph H. Lilienkamp

Masters Theses

"The study of the thermodynamic properties of solids at low temperatures has shown that most theories either break down or become too cumbersome.

A theory based upon a crystal lattice of atoms gives the best physical picture of a solid. Fisher has developed partition functions from this theory for the simple cubic, body-centered cubic, and the face-centered cubic lattices. In his paper Fisher gave three partition functions of increasing complexity and accuracy for each of the three lattices. In this paper the three partition functions for a face-centered cubic lattice shall be applied to silver and compared.

The Helmholtz free …

A Study Of The Effect Of Jointing On The Blasting Of Granite, Graniteville, Missouri, Avery Ala Drake

Masters Theses

"Purpose of investigation: The purpose of this investigation is to attempt to determine the influence that joints exert upon the blasting of granite and if joints are induced by blasting. The problem grew out of an explosive evaluation project that was conducted by the Mining Department, Missouri School of Mines. In late May 1950, the project was moved into the granite area near Graniteville, Missouri. It became apparent upon study of this area that the jointing would have certain effects upon the results obtained. Dr. J. D. Forrester, Chairman, Department of Mining Engineering, Missouri School of Mines, Rolla, Missouri, suggested …

Radioactive Carbon Labeled Molecules: A Method Of Synthesis, Glen E. Benedict

Masters Theses

"Use of isotopic carbon in determining organic reaction mechanisms is becoming more popular daily. The reasons for this trend are, the increasing availability of intermediate compounds, the increase in isotope handling knowledge, and mechanisms defined by well ordered tracer reactions are considered infallible.

The mechanism of reaction of halo-epoxides has been a point of conjecture for some time"--Introduction, page 1.

Geology Of The North Half Of The Meramec Spring Quadrangle, Missouri, Harold Edward Mueller

Masters Theses

"The Ozark region is visited by many persons each year, and one of its popular tourist attractions is Meramec Spring. In recent years, with the advent of better roads and swifter means of transportation, visitors are coming to this beautiful spring in increasing numbers. For those who are geologists, this work will serve as a handy guide; for those who are laymen, this work may give a better understanding of the geologic events which have made this part of the Ozarks a place of scenic beauty. Mapping of the Meramec Spring Quadrangle will complete a program of geologic mapping of …

A Lead Sulfide Near Infrared Detection System, William V. Cummings Jr.

Masters Theses

"The infrared region of the spectrum is conveniently divided into the near infrared, which extends from the red end of the visible to about 25 microns, and the far infrared, which continues to an ill-defined division point of approximately 1,000 microns. The near infrared region has been further subdivided on the basis of instrumental techniques so that the particular portion of the spectrum consisting of radiations of wave length up to 3 microns has become known as the photoelectric infrared.

Several types of detection instruments have been designed and perfected for work in the photoelectric region, but new methods and …

A Correlation Function For Liquid Argon, Walter Graham

Masters Theses

"X-ray scattering patterns have given considerable information concerning atomic distributions in matter, both crystalline and amorphous. Work on the diffraction of x-rays by crystals was begun in 1912 by Friedrich, Knipping, and Laue, and much valuable information concerning the arrangement of atoms in crystals has been supplied by this method. Diffraction of x-rays by gases was studied as early as 1911, and work in this field has given information concerning the arrangement of atoms in molecules and electron distribution in atoms. Work on the diffraction of x-rays by liquids was begun by Friedrich who obtained diffraction patterns of Canada Balsam, …

Square Wave Modulation, Richard Henry Duncan

Masters Theses

"Modulation of a radio frequency carrier can be defined as the variation of some wave parameter such as amplitude, frequency, or phase, in accordance with intelligence to be transmitted. An unmodulated carrier is simply a continuous sine wave and contains no information other than the fact that the transmitter has been turned on. The spectrum of an unmodulated signal consists of a single frequency. Any type of modulation is characterized by the appearance of additional frequencies, known as sidebands. One of the fundamental problems in radio engineering is to reduce the number of sidebands to a minimum and still adequately …

The Completion, Adjustment, And Operation Of A Grazing Incidence Vacuum Ultraviolet Spectrograph, William Clinton Johnson-Chamberlain

Masters Theses

"Most gases, and particularly oxygen and nitrogen, are nearly opaque to radiation in the region from about 1800 Å downward to about 2 Å and hence, for spectroscopic work in this region, the removal of these gases is mandatory. Popular usage generally refers to the range mentioned above as the vacuum ultraviolet. That there remains much experimental work to be done in the vacuum ultraviolet has been pointed out by Boyce in his exhaustive survey of vacuum ultraviolet spectroscopy. In order to fill in some of these gaps, Mr. L. H. Chapin, in the, spring of 1950, undertook the construction …

Torsional Modulus Of Rupture Of Thick-Walled Magnesium Alloy Fs-1 Tubing, Delbert R. Cox

Masters Theses

"Magnesium is taking a more prominent position in the structure of aircraft, and because of this, it is important that the mechanical properties of the material be understood more fully. In the high speeds of today, the tendency is toward the use of thick-walled tubing instead of the thin-walled tubing with stiffening structures. For this reason, it is of interest to note the characteristics of thick-walled tubing when subjected to torsion.

This thesis was first suggested by a circular letter on proposed thesis titles from the Commanding General, Air Materiel Command, Wright-Patterson Air Force Base, Dayton, Ohio. When interest was …

Geology And Mineralization Of The Jefferson Mine, Hardin County, Illinois, Robert Joe Cronk

Masters Theses

"Purpose of the Investigation: The geology of the Jefferson Mine was mapped to determine the relationship of the two fluorspar veins exposed on the 260-foot level to the single vein on the 200-foot level to study the mineralogy and paragenesis of the ore, and to gain any other information that would lead to a better understanding of the fluorspar deposits"--Introduction, page 1.

An Application Of The Atomic Distribution Function Of Liquid Mercury, Robert Lee Choate

Masters Theses

"The study of liquids and the knowledge of an adequate description of liquid structure have not advanced as rapidly as it has in the case of solids and gases. In a perfect crystal, the atoms or molecules are held in equilibrium positions by strong intermolecular forces. There are vibrations about these positions, but the translational energy is negligible. The molecules of an ideal gas move independently of each other and the intermolecular potential energy may be neglected. For each of these cases it is possible to derive a partition function from which the properties of the state can be readily …

Integrated Scattering Of Microwaves By Small Metal Spheres, A. L. Merts

Masters Theses

"When electromagnetic radiation falls upon a material body of any kind, the associated electric field induces periodic oscillations of the electrons of the material synchronous with the incident radiation. The material serves as a secondary source and emits energy in the form of scattered radiation with a frequency equal to that of the incident electromagnetic wave. The polarization and intensity of the scattered radiation are determined by the size, shape, electric constants, and interactions among the scattering elements.

The scattering of electromagnetic waves is an old problem in physics. Such names as Rayleigh, Debye, and Mie have become associated with …

A Light Source To Be Used With A Vacuum Spectrograph, Roy George Woodle Jr.

Masters Theses

"A grazing incidence vacuum grating spectrograph for use in the vacuum ultraviolet was designed and partially constructed by Mr. L. H. Chapin, as a research project for a Master’s Degree. This instrument is designed to photograph the region of the spectrum from 100 Å to 1000 Å. As Boyce pointed out in his exhaustive review, there is much important observational work to be done in this region.

The author of this paper has undertaken to develop a satisfactory source for the region from 100 Å to 1000 Å. This is part of a project to photograph the emission and absorption …

Mineral Composition In Relation To Particle Size For A Missouri Plastic Fire Clay, John Edward May

Masters Theses

"From the rather modest beginning of the refractory industry in Missouri prior to the Civil War, the industry has grown to challenge those of other states as the third largest producer of refractory clays and products in the United States. As Roberts (1950) points out, the development of the metallurgical and glass industries increased the demand for high grade refractory materials. A prominent factor in the development of the fire clays of Missouri was the discovery that flint clay could be mixed with the plastic or semi-plastic refractory clays to yield an excellent product. Perhaps the most important reason many …

Radiolaria From The Porters Creek Formation (Paleocene, Midway Group) Of Stoddard County, Missouri, Eldridge Sellers Middour

Masters Theses

"Fossil Radiolaria are described and figured from the Porters Creek formation (Paleocene) of Ardeola, Stoddard County Missouri. This is the first detailed treatment of fossil radiolarians from the Gulf Coast area. Thirty-one species are described and figured, all believed to be new, belonging to twenty-four genera. Fifteen families are represented, ten referable to the Legion Spumellaria, five to the Legion Nassellaria. Stratigraphic descriptions or the section at Ardeola is presented, and a discussion of laboratory techniques is included"--Abstract, page 3.

A Stratigraphic Study Of Fusulinid Foraminifera In The Cherokee Group (Pennsylvanian) Of Western Missouri And Kansas, Ralph Orlansky

Masters Theses

"Limestones or shaly limestones, from four stratigraphic levels in the Cherokee group (Desmoinesian series) of Missouri and Kansas, contain eight species and two varieties of fusulinid foraminifera, of which four species and two varieties are new, and one ophthalmidiid foraminiferal species (Hemigordius cf. regularis Plummer). The next to highest limestone (cap rock of the Fleming coal) is correlated with the Seahorne limestone of western Illinois, the Stonefort limestone of southern Illinois, and the Munterville limestone of Iowa. Hemigordius regularis, a limestone facies foraminifer apparently marks a correlatable interval in the Ardmore limestone. Descriptions of the fusulinids and the …

The Polarographic Determination Of Germanium, Herbert L. Bowkley

Masters Theses

"The purpose of this investigation was to study the polarographic behavior of germanium in various aqueous solutions. In addition to the simple polarographic behavior of germanium some attention was given to the applications or polarography for the development of an anlytical [sic] procedure for its quantitative determination in zinc ore concentrates and spelter fume materials"--Introduction, page 1.

The Determination Of The Solubility Of Hafnium Oxide In Aqueous Solution By The Radioactive Tracer Technique, Hampden O. Banks

Masters Theses

"To date, there is no information in the open literature concerning the solubility of hafnium oxide in water other than the fact that it is very insoluble. This lack of experimental information is due, partly, to the fact that hafnium is a relatively new addition to the list of known elements"--Introduction, page 1.

The Energy Levels Of Potassium Chloride, Clifford L. Adams

Masters Theses

"An understanding of the electronic energy states of solids has long been considered of importance. And the energy levels of the alkali halides have been the subject of much study in recent years. The present work is an attempt to set up an energy-level diagram for potassium chloride"--Introduction, page 1.

The Theory Of The Specific Heat Of A Face-Centered Cubic Lattice, Charles Robert Bonnell

Masters Theses

"It is generally accepted that a normal crystalline solid can be pictured at absolute zero as an assembly of atoms at rest arranged at periodic lattice points. Since at higher temperatures each molecule becomes a harmonic oscillator about its lattice point, it is necessary to know the distribution of normal modes of vibration in order to calculate the thermodynamic properties of the lattice...Many approaches have been made to get a simple solution of the problem, but either accuracy is sacrificed for simplicity, or the solutions demand a very considerable amount of labor. The classical theories failed to explain the change …

Intermolecular Potential Functions For Liquid Argon And Liquid Mercury, Richard H. Kerr

Masters Theses

"The purpose of this research is to obtain such intermolecular potential functions for liquid argon and liquid mercury by use of the experimental radial density functions available for these two liquids over a wide range of temperatures. We shall introduce the notion of a correlation between the motions of atoms in neighboring cells in a cell theory of liquid structure, and derive a theoretical radial density function involving the intermolecular potential function for a pair of atoms in the liquid. This radial density function, or as it is frequently termed, the atomic distribution function, applied to the experimental data should …

The Theory Of The Specific Heat Of A Body Centered Cubic Lattice, Curtis Cleveland Webster

Masters Theses

"In normal crystalline solids the atoms are at rest in their lattice points at absolute zero of temperature. Increasing the temperature of the crystal increases the motion of the atoms about their lattice points. Approximately, each atom or ion may be treated as a harmonic oscillator. then from the equations of motion of the atoms, by the Born-von Karman theory of specific heats, the normal modes of vibration of the lattice can be expressed as the roots of a secular determinant. Application of this theory to determine the thermodynamic properties of crystals has resulted either in solutions that are inaccurate …