Physical Sciences and Mathematics Commons^™

Technical Note: Swift - A Fast Semi-Empirical Model For Polar Stratospheric Ozone Loss, M. Rex, S. Kremser, P. Huck, G. Bodeker, I. Wohltmann, M. L. Santee, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

An extremely fast model to estimate the degree of stratospheric ozone depletion during polar winters is described. It is based on a set of coupled differential equations that simulate the seasonal evolution of vortex-averaged hydrogen chloride (HCl), nitric acid (HNO3), chlorine nitrate (ClONO₂), active forms of chlorine (ClO_x = Cl+ClO+2ClOOCl) and ozone (O₃) on isentropic levels within the polar vortices. Terms in these equations account for the chemical and physical processes driving the time rate of change of these species. Eight empirical fit coefficients associated with these terms are derived by iteratively fitting the equations …

Molecular Opacities For Exoplanets, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

Spectroscopic observations of exoplanets are now possible by transit methods and direct emission. Spectroscopic requirements for exoplanets are reviewed based on existing measurements and model predictions for hot Jupiters and super-Earths. Molecular opacities needed to simulate astronomical observations can be obtained from laboratory measurements, ab initio calculations or a combination of the two approaches. This discussion article focuses mainly on laboratory measurements of hot molecules as needed for exoplanet spectroscopy.

Global Stratospheric Fluorine Inventory For 2004-2009 From Atmospheric Chemistry Experiment Fourier Transform Spectrometer (Ace-Fts) Measurements And Slimcat Model Simulations, A. T. Brown, M. P. Chipperfield, N. A. D. Richards, C. Boone, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

Fluorine-containing species can be extremely effective atmospheric greenhouse gases. We present fluorine budgets using organic and inorganic species retrieved by the ACE-FTS satellite instrument supplemented with output from the SLIMCAT 3-D chemical transport model. The budgets are calculated between 2004 and 2009 for a number of latitude bands: 70-30 °N, 30-00 °N, 00 °N-30 °S, and 30-70°S. At lower altitudes total fluorine profiles are dominated by the contribution from CFC-12, up to an altitude of 20 km in the extra-tropics and 29 km in the tropics; above these altitudes the profiles are dominated by hydrogen fluoride (HF). Our data show …

Exomol Molecular Line Lists V: The Ro-Vibrational Spectra Of Nacl And Kcl, Emma J. Barton, Christopher Chiu, Shirin Golpayegani, Sergei N. Yurchenko, Jonathan Tennyson, Daniel J. Frohman, Peter F. Bernath

Chemistry & Biochemistry Faculty Publications

Accurate rotation-vibration line lists for two molecules, NaCl and KCl, in their ground electronic states are presented. These line lists are suitable for temperatures relevant to exoplanetary atmospheres and cool stars (up to 3000 K). Isotopologues ²³Na³⁵Cl, ²³Na³⁷Cl, ³⁹K³⁵Cl, ³⁹K³⁷Cl, ⁴¹K³⁵Cl and ⁴¹K³⁷Cl are considered. Laboratory data were used to refine ab initio potential energy curves in order to compute accurate ro-vibrational energy levels. Einstein A coefficients are generated using newly determined ab initio dipole moment curves calculated using the CCSD(T) method. …

So, You Want To Use Next Generation Sequencing In Marine Systems? Insight From The Pan Pacific Advanced Studies Institute, D. A. Willette, F. W. Allendorf, P. H. Barber, D. J. Barshis, K. E. Carpenter, E. D. Crandall, W. A. Cresko, I. Fernandez-Silva, M. V. Matz, E. Meyer, M. D. Santos, L. W. Seeb, J. E. Seeb

Biological Sciences Faculty Publications

The emerging field of next-generation sequencing (NGS) is rapidly expanding capabilities for cutting edge genomic research, with applications that can help meet marine conservation challenges of food security, biodiversity loss, and climate change. Navigating the use of these tools, however, is complex at best. Furthermore, applications of marine genomic questions are limited in developing nations where both marine biodiversity and threats to marine biodiversity are most concentrated. This is particularly true in Southeast Asia. The first Pan-Pacific Advanced Studies Institute (PacASI) entitled "Genomic Applications to Marine Science and Resource Management in Southeast Asia" was held in July 2012 in Dumaguete, …

Evolution Of The Freshwater Sardinella, Sardinella Tawilis (Clupeiformes: Clupeidae), In Taal Lake, Philippines And Identification Of Iits Marine Sister-Species, Sardinella Hualiensis, Demian Willette, Kent E. Carpenter, Mudjekeewis Santos

Biological Sciences Faculty Publications

We identify the sister species of the world's only freshwater sardinella, Sardinella tawilis (Herre, 1927) of Taal Lake, Philippines as the morphologically-similar marine Taiwanese sardinella Sardinella hualiensis (Chu and Tsai, 1958). Evidence of incomplete lineage sorting and a species tree derived from three mitochondrial genes and one nuclear gene indicate that S. tawilis diverged from S. hualiensis in the late Pleistocene. Neutrality tests, mismatch distribution analysis, sequence diversity indices, and species tree analysis indicate populations of both species have long been stable and that the divergence between these two lineages occurred prior to the putative 18th century formation of Taal …

The Impact Of Multiple Nursery Areas On The Population Structure Of Atlantic Menhaden, Brevooria Tyrannus, Kristen A. Anstead

OES Theses and Dissertations

Understanding the population structure and patterns of connectivity in marine fishes is essential when making predictions about a species' resiliency and persistence in an increasingly changing environment. The Atlantic Menhaden Brevoortia tyrannus is a clupeid that plays a critical role in the marine food web and supports one of the largest fisheries on the US East Coast. In addition to a decrease in overall numbers and spawning stock biomass, recruitment levels have remained low since the 1990s. Menhaden use numerous estuaries along the Atlantic coast for juvenile development before recruiting to the adult population and the contribution of each of …

Enhancing Understanding Of Discrete Event Simulation Models Through Analysis, Kara Ann Olson

Computer Science Theses & Dissertations

Simulation is used increasingly throughout research, development, and planning for many purposes. While model output is often the primary interest, insights gained through the simulation process can also be valuable. Insights can come from building and validating the model as well as analyzing its behaviors and output; however, much that could be informative may not be easily discernible through these existing traditional approaches, particularly as models continue to increase in complexity.

This research extends current work in model analysis and program understanding to assist modelers in obtaining more insight into their models and the systems they represent. A primary technique …

Molecular Characterization And Photochemical Transformation Of Dissolved Organic Matter From Land To Ocean, Hongmei Chen

Chemistry & Biochemistry Theses & Dissertations

Molecular characterization and photochemical transformation of dissolved organic matter (DOM) in both rivers and the ocean is the main research focus of this dissertation. Chemical characterization of DOM is hampered by the limited application of advanced techniques to desalt, concentrate, isolate and then molecularly characterize DOM. An affordable, commercially available mini-electrodialysis (mini-ED) system has been evaluated and recommended for the efficient desalting of small volume samples of seawater prior to analysis by electrospray Fourier transform ion cyclotron resonance mass spectrometry (ESI FTICR-MS).

A high-recovery technique of DOM isolation – reverse osmosis coupled with electrodialysis (RO/ED) – was used to isolate …

Spectroscopic Characterization Of Dissolved Organic Matter: Insights Into The Linkage Between Sources And Chemical Composition, Xiaoyan Cao

Chemistry & Biochemistry Theses & Dissertations

This dissertation investigated the chemical structure of DOM by advanced solid-state nuclear magnetic resonance (NMR) spectroscopy and Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) techniques, as well as isotopic measurements and UV-visible spectroscopy, to shed light on the linkages between DOM sources and DOM composition. Unique and extensive sets of DOM samples studied here were isolated from various aquatic systems, covering end-member environments in which DOM is considered either microbially derived or terrestrially derived, and areas in which DOM has characteristics intermediate between the two end members. Important insights into specific site-related questions were also gained such as …

Advances In Understanding The Molecular Composition Of Dissolved Organic Matter And Its Reactivity In The Environment, Rajaa Mesfioui

Chemistry & Biochemistry Theses & Dissertations

Dissolved organic matter (DOM) is the ultimate product of Earth's systems dynamics. DOM chemical signature is strongly shaped by the interaction among Earth's spheres, such as the atmosphere, the geosphere, the biosphere, and the hydrosphere, but also life and human activity. DOM source, composition, photochemical alteration and availability affect freshwater ecosystems, their carbon and nitrogen fluxes and, thus, the global carbon and nitrogen cycles. The aim of this thesis was to gain an understanding of the molecular composition of DOM and its photochemical and biological reactivity in an environment impacted by anthropogenic disturbance. The York and James River systems within …

Synthesis And Characterization Of Sugar Based Low Molecular Weight Gelators And The Preparation Of Chiral Sulfinamides, Hari Prasad Reddy Mangunuru

Chemistry & Biochemistry Theses & Dissertations

Low molecular weight gelators (LMWGs) have received considerable attention in the field of chemistry from last few decades. These compounds form self-assembled fibrous networks like micelles, cylindrical, sheets, fibers, layers and so on. The fibrous network entraps the solvent and forms gel, because of the self-assembly phenomenon and their demonstrated potential uses in a variety of areas, ranging from environmental to medicinal applications.

Sugars are good starting materials to synthesize the new class of LMWG's, because these are different from some expensive materials, these are natural products. We have synthesized and characterized the LMGS's based on D-glucose and D …

Photoproduction Of Π0 On Hydrogen With Clas From 1.1 Gev - 5.45 Gev Using E+E –Γ Decay, Michael C. Kunkel

Physics Theses & Dissertations

Photoproduction of the π⁰ meson was studied using the CLAS detector at the Thomas Jefferson National Accelerator Facility using tagged incident photon energies spanning the range E_γ = 1.1 GeV - 5.45 GeV. The measurement is performed on a liquid hydrogen target in the reaction γp → pe ⁺e^–(γ). The final state of the reaction is the sum of two subprocesses for π⁰ decay, the Dalitz decay mode of π⁰ → e ⁺e^–γ and conversion mode where one photon from π⁰ → γγ decay is converted into a …

Simultaneous Optimization Of The Cavity Heat Load And Trip Rates In Linacs Using A Genetic Algorithm, Balša Terzić, Alicia S. Hofler, Cody J. Reeves, Sabbir A. Khan, Geoffrey A. Krafft, Jay Benesch, Arne Freyberger, Desh Ranjan

Physics Faculty Publications

In this paper, a genetic algorithm-based optimization is used to simultaneously minimize two competing objectives guiding the operation of the Jefferson Lab's Continuous Electron Beam Accelerator Facility linacs: cavity heat load and radio frequency cavity trip rates. The results represent a significant improvement to the standard linac energy management tool and thereby could lead to a more efficient Continuous Electron Beam Accelerator Facility configuration. This study also serves as a proof of principle of how a genetic algorithm can be used for optimizing other linac-based machines.

Plasma Processing Of Large Curved Surfaces For Superconducting Rf Cavity Modification, J. Upadhyay, Do Im, S. Popovic, A. M. Valente-Feliciano, L. Phillips, L. Vušković

Physics Faculty Publications

Plasma-based surface modification of niobium is a promising alternative to wet etching of superconducting radio frequency (SRF) cavities. We have demonstrated surface layer removal in an asymmetric nonplanar geometry, using a simple cylindrical cavity. The etching rate is highly correlated with the shape of the inner electrode, radio-frequency (rf) circuit elements, gas pressure, rf power, chlorine concentration in the Cl₂/Ar gas mixtures, residence time of reactive species, and temperature of the cavity. Using variable radius cylindrical electrodes, large-surface ring-shaped samples, and dc bias in the external circuit, we have measured substantial average etching rates and outlined the possibility …

Suppression Of ϒ Production In D + Au And Au + Au Collisions At √Sɴɴ = 200 Gev, L. Adamczyk, J.K. Adkins, G. Agakishiev, M. M. Aggarwal, Z. Ahammed, I. Alekseev, J. Alford, C. D. Anson, A. Aparin, D. Arkhipkin, S. Bültmann, Donika Plyku

Physics Faculty Publications

We report measurements of ϒ meson production in p + p, d + Au, and Au + Au collisions using the STAR detector at RHIC. We compare the ϒ yield to the measured cross section in p + p collisions in order to quantify any modifications of the yield in cold nuclear matter using d + Au data and in hot nuclear matter using Au + Au data separated into three centrality classes. Our p + p measurement is based on three times the statistics of our previous result. We obtain a nuclear modification factor for ϒ (1S + 2S …

Virtuality Distributions In Application To Ɣɣ* → Π​0 Transition Form Factor At Handbag Level, Anatoly V. Radyushkin

Physics Faculty Publications

We outline basics of a new approach to transverse momentum dependence in hard processes. As an illustration, we consider hard exclusive transition process ɣ*ɣ -> π⁰ at the handbag level. Our starting point is coordinate representation for matrix elements of operators (in the simplest case, bilocal O(0, z)) describing a hadron with momentum p. Treated as functions of (pz) and z², they are parametrized through virtuality distribution amplitudes (VDA) Φ(x, σ), with x being Fourier-conjugate to (pz) and σ Laplace-conjugate to z². For intervals with z⁺ = 0, we introduce the transverse momentum distribution …

Nlo Hierarchy Of Wilson Lines Evolution, I. Balitsky

Physics Faculty Publications

The high-energy behavior of QCD amplitudes can be described in terms of the rapidity evolution of Wilson lines. I present the hierarchy of evolution equations for Wilson lines in the next-to-leading order.

Beam Energy Dependence Of Moments Of The Net-Charge Multiplicity Distributions In Au + Au Collisions At Rhic, L. Adamczyk, J. K. Adkins, G. Agakishiev, S. Bültmann, D. Plyku, Star Collaboration

Physics Faculty Publications

We report the first measurements of the moments-mean (M), variance (σ²), skewness (S), and kurtosis (κ)-of the net-charge multiplicity distributions at midrapidity in Au + Au collisions at seven energies, ranging from √ˢᶰᶰ = 7.7 to 200 GeV, as a part of the Beam Energy Scan program at RHIC. The moments are related to the thermodynamic susceptibilities of net charge, and are sensitive to the location of the QCD critical point. We compare the products of the moments, σ²/M, Sσ, and κσ², with the expectations from Poisson and negative binomial distributions (NBDs). The Sσ …

Data Analysis Techniques, Differential Cross Sections, And Spin Density Matrix Elements For The Reaction ᵞp → Φp, K.P. Adhikari, D. Adikaram, M.J. Amaryan, A. Klein, S. Koirala, Clas Collaboration

Physics Faculty Publications

High-statistics measurements of differential cross sections and spin density matrix elements for the reaction ᵞp → ϕp have been made using the CLAS detector at Jefferson Lab. We cover center-of-mass energies (√s) from 1.97 to 2.84 GeV, with an extensive coverage in the ϕ production angle. The high statistics of the data sample made it necessary to carefully account for the interplay between the ϕ natural lineshape and effects of the detector resolution, that are found to be comparable in magnitude. We study both the charged-(ϕ → K⁺ K^-) and neutral( ϕ → (K^O_SK …

Dielectron Azimuthal Anisotrophy At Mid-Rapidity In Au+Au Collisions At √ˢᶰᶰ = 200 Gev, L. Adamczyk, J. K. Adkins, G. Agakishiev, S. Bültmann, I Koralt, Star Collaboration

Physics Faculty Publications

We report on the first measurement of the azimuthal anisotropy v₂ of dielectrons (e⁺e^- pairs) at mid-rapidity from √ˢᶰᶰ = 200 GeV Au + Au collisions with the STAR detector at the Relativistic Heavy Ion Collider (RHIC), presented as a function of transverse momentum p_T for different invariant-mass regions. In the mass region M_ee < 1.1 GeV/c² the dielectron v₂measurements are found to be consistent with expectations from π⁰, η, ω, and Φ decay contributions. In the mass region 1.1 < M_ee < 2.9 GeV/c², the measured dielectron v₂is consistent, within experimental …

Exclusive Πᵒ Electroproduction At W > 2 Gev With Clas, I. Bedlinskiy, K. P. Adhikari, L. El Fassi, A. Klein, S. E. Kuhn, Clas Collaboration

Physics Faculty Publications

Exclusive neutral-pion electroproduction (ep → e'p'π⁰ was measured at Jefferson Lab with a 5.75-GeV electron beam and the CLAS detector. Differential cross sections d⁴σ/dtdQ²dx_BdΦ_π and structure functions σ_T+ ϵσ_L, σ_TT, and σ_LT as functions of t were obtained over a wide range of Q² and x_B. The data are compared with Regge and handbag theoretical calculations. Analyses in both frameworks find that a large dominance of transverse processes is necessary to explain the experimental results. For the Regge analysis it is found …

Event Plane Dependent Dihadron Correlations With Harmonic Vⁿ Subtraction In Au + Au Collisions At √ˢᴺᴺ = 200 Gev, H. Agakishiev, M. M. Aggarwal, Z. Ahammed, S. Bueltmann, D. Plyku, Star Collaboration

Physics Faculty Publications

STAR measurements of dihadron azimuthal correlations (ΔΦ) are reported in midcentral (20-60%) Au + Au collisions at √ˢᴺᴺ = 200 GeV as a function of the trigger particle's azimuthal angle relative to the event plane, Φ_s = | Φ_t- Ψ_EP|. The elliptic (v₂), triangular (v₃), and quadratic (v₄) flow harmonic backgrounds are subtracted using the zero yield at minimum (ZYAM) method. It is found that a finite near-side (|ΔΦ| < π/2) long-range pseudorapidity correlation (ridge) is present in the in-plane direction (Φ_s ~ 0). The away-side (|ΔΦ| > π/2) correlation shows a modification from d+ Au data, varying with Φ_s. …

Measurement Of Charge Multiplicity Asymmetry Correlations In High-Energy Nucleus-Nucleus Collisions At √ˢᶰᶰ = 200 Gev, L. Adamczyk, J. K. Adkins, G. Agakishiev, M. M. Aggarwal, S. Bültmann, Star Collaboration

Physics Faculty Publications

A study is reported of the same-and opposite-sign charge-dependent azimuthal correlations with respect to the event plane in Au+ Au collisions at √ˢᶰᶰ = 200 GeV. The charge multiplicity asymmetries between the up/down and left/right hemispheres relative to the event plane are utilized. The contributions from statistical fluctuations and detector effects were subtracted from the (co-) variance of the observed charge multiplicity asymmetries. In the mid-to most-central collisions, the same- (opposite-) sign pairs are preferentially emitted in back-to-back (aligned on the same-side) directions. The charge separation across the event plane, measured by the difference, Δ, between the like-and unlike-sign up/down-left/right …

Measurement Of Longitudinal Spin Asymmetries For Weak Boson Production In Polarized Proton-Proton Collisions At Rhic, L. Adamczyk, J. K. Adkins, G. Agakishiev, M. M. Aggarwal, S. Bültmann, Star Collaboration

Physics Faculty Publications

We report measurements of single- and double-spin asymmetries for W± and Z/ɣ* boson production in longitudinally polarized p + p collisions at √s = 510 GeV by the STAR experiment at RHIC. The asymmetries for W± were measured as a function of the decay lepton pseudorapidity, which provides a theoretically clean probe of the proton's polarized quark distributions at the scale of the W mass. The results are compared to theoretical predictions, constrained by polarized deep inelastic scattering measurements, and show a preference for a sizable, positive up antiquark polarization in the range 0.05 < x < 0.2.

Solutions For Fermi Questions, October 2014: Question 1: Accelerating The Flash; Question 2: Flashing Through The Air, Larry Weinstein

Physics Faculty Publications

The article provides answers to questions including the amount of force needed by The Flash as he accelerates and amount of force needed by The Flash to run at constant velocity near the Earth's surface.

Precision Measurement Of The Neutron Twist-3 Matrix Element D(2)(N): Probing Color Forces, M. Posik, D. Flay, D. S. Parrno, K. Allada, W. Armstrong, F. Benmokhtar, M. Canan, L. El Fassi, S. Golge, C. Hyde

Physics Faculty Publications

Double-spin asymmetries and absolute cross sections were measured at large Bjorken x (0.25 ≤ x ≤ 0.90), in both the deep-inelastic and resonance regions, by scattering longitudinally polarized electrons at beam energies of 4.7 and 5.9 GeV from a transversely and longitudinally polarized ³He target. In this dedicated experiment, the spin structure function g(2)(3He) was determined with precision at large x, and the neutron twist-3 matrix element d(2)(n) was measured at < Q²> of 3.21 and 4.32 GeV²/c², with an absolute precision of about 10^-5. Our results are found to be in agreement …

Separated Response Function Ratios In Exclusive, Forward Π± Electroproduction, G. M. Huber, H. P. Blok, C. Butuceanu, D. Gaskell, T. Horn, D. J. Mack, D. Abbott, A. Klein, L. M. Qin, K. Vansyoc

Physics Faculty Publications

The study of exclusive π^± electroproduction on the nucleon, including separation of the various structure functions, is of interest for a number of reasons. The ratio R-L=sigma(pi-)(L) / sigma(pi+)(L) is sensitive to isoscalar contamination to the dominant isovector pion exchange amplitude, which is the basis for the determination of the charged pion form factor from electroproduction data. A change in the value of R-T=sigma(pi-)(L) / sigma(pi+)(L) from unity at small -t, to 1/4 at large -t, would suggest a transition from coupling to a (virtual) pion to coupling to individual quarks. Furthermore, the mentioned ratios may show an earlier …

Higher Order Mode Damping In Superconducting Spoke Cavities, C. S. Hopper, J. R. Delayen

Physics Faculty Publications

Parasitic higher order modes (HOMs) can be severely detrimental to the performance of superconducting cavities. For this reason, the mode spectrum and beam coupling strength must be examined in detail to determine which modes must be damped. One advantage of the spoke cavity geometry is that couplers can be placed on the outer body of the cavity rather than in the beam line space. We present an overview of the HOM properties of spoke cavities and methods for suppressing the most harmful ones.

Cryogenic Test Of A 750 Mhz Superconducting Rf Dipole Crabbing Cavity, A. Castilla, Hyekyoung Park, J. R. Delayen

Physics Faculty Publications

A superconducting rf dipole cavity has been designed to address the challenges of a high repetition rate (750 MHz), high current for both electron/ion species (0.5/3 A per bunch), and large crossing angle (50 mrad) at the interaction points (IPs) crabbing system for the Medium Energy Electron-Ion Collider (MEIC) proposed by Jefferson Lab. The cavity prototype built at Niowave, Inc. has been tested at the Jefferson Lab facilities. In this work we present a detailed analysis of the prototype cavity performance at 4 K and 2 K, corroborating the absence of hard multipacting barriers that could limit the desired transverse …