Physical Sciences and Mathematics Commons^™

Theoretical Studies Of 2,3 -Sigmatropic Rearrangements Of Allylic Selenoxides And Selenimides, Craig A. Bayse, Sonia Antony

Chemistry & Biochemistry Faculty Publications

Density-functional theory is used to model the endo and exo transition states for [2,3]-sigmatropic rearrangement of allylic aryl-selenoxides and -selenimides. The endo transition state is generally preferred for selenoxides if there is no substitution at the 2 position of the allyl group. Based upon the relative energies of the endo and exo transition states, enantioselectivity of rearrangements is expected to be greatest for molecules with substitutions at the 1- or (E)-3- position of the allyl group. Ortho substitution of a nitro group on the ancillary selenoxide phenyl ring reduces the activation barriers, increases the difference between the endo and exo …

Mermin Habitually Answers Opinions, Real And Abstract, Amin Dharamsi

Electrical & Computer Engineering Faculty Publications

(First paragraph) Because QFT is so neglected by the public (and by many physicists), I am writing a book that presents it without equations. A draft copy of the work, The Theory That Escaped Einstein, can be found through an internet search. Feedback is appreciated.

Effects Of Non-Equilibrium Plasma On Eukaryotic Cells (Final Report: Grant Fa9550-06-1-0004), Mounir Laroussi, Fred C. Dobbs, Old Dominion University

Electrical & Computer Engineering Faculty Publications

This document is our final report describing the research activities carried out under AFOSR Grant FA9550-06-1-0004. First, descriptions of our cold plasma generation systems are presented. Two systems, developed with past and present AFOSR support, are available in our laboratory. The first is a pulsed device capable of emitting a cold plasma plume in room air. The second is an air plasma generator the core of which is a dielectric barrier discharge excited by a high AC voltage. Following these brief descriptions we first present the effects of an atmospheric pressure air plasma on four different types of eukaryotic microalgae. …

Section Abstracts: Astronomy, Mathematics, And Physics & Materials Science

Virginia Journal of Science

Abstracts of the Astronomy, Mathematics and Physics & Materials Science Section for the 87th Annual Meeting of the Virginia Academy of Science, May 27-29, 2009, Virginia Commonwealth University, Richmond VA.

Section Abstracts: Computer Science

Virginia Journal of Science

Abstracts of the Computer Science for the 87th Annual Meeting of the Virginia Academy of Science, May 27-29, 2009, Virginia Commonwealth University, Richmond Virginia.

Section Abstracts: Environmental Science

Virginia Journal of Science

Abstracts of the Environmental Sciences Section for the 87th Annual Meeting of the Virginia Academy of Science, May 27-29, 2009, Virginia Commonwealth University, Richmond, Virginia.

Section Abstracts: Statistics

Virginia Journal of Science

Abstracts of the Statistics Section for the 87th Annual Meeting of the Virginia Academy of Science, May 27-29, 2009, Virginia Commonwealth University, Richmond, VA.

Reactivity And Chemical Characterization Of Dissolved Organic Matter In An Estuary, Hussain A. Abdulla

OES Theses and Dissertations

This dissertation used Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance spectroscopy (¹³C-NMR) data to quantify the changes of major chemical compound classes in high molecular weight (HMW, >1kDa) DOM isolated along a transect from Great Dismal Swamp through the Elizabeth River/Chesapeake Bay system to the coastal Atlantic Ocean off Virginia, USA. Results show that both carboxylic acids and aromatic compounds are lost along the transect, while amide, and carbohydrate moieties could have a mid-transect source.

Addressing the seasonal and spatial changes in the chemical composition of high molecular weight DOM using C/N ratio and δ^{13 …}

A Simulation Study Of Convergence Speed For Distributed Codeword Adaptation Algorithms In Cdma Wireless Systems, Sahana Maharjan

Electrical & Computer Engineering Theses & Dissertations

In this thesis we present a side-by-side comparison of interference avoidance (IA) algorithms for distributed codeword adaptation in Code Division Multiple Access (CDMA) systems. In CDMA systems, the interference is determined by the values of the cross-correlation of codewords assigned to users, and various algorithms can be used for codeword optimization. The IA algorithms for codeword adaptation considered are the eigen-algorithm, the Minimum Mean Square Error (MMSE) update, and the adaptive IA algorithm, for which we investigate convergence speed using the extensive simulations of several uplink CDMA system scenarios. The results of this thesis were presented at the Fourth IEEE …

Virtual Wired Transmission Scheme - A Novel Technique For Efficient Mobile Adhoc Networks, Manikya Vinay Rali

Electrical & Computer Engineering Theses & Dissertations

This thesis proposes a method called virtual wired transmission scheme for ad hoc networks. The scheme is an efficient method to improve network performance parameters such as energy efficiency, capacity, interference, network throughput, etc. Performance parameters improvement can be done at different layers of the network architecture for mobile ad hoc networks. However most of the research efforts are concentrated on Physical, MAC and Network layers. In this thesis, a MAC protocol with a major MAC layer modification is proposed in combination with the usage of directional antennas, developing a novel method called virtual wired transmission scheme. In virtual wired …

Changing Fecundity And Reproductive Output In Females Of A Chesapeake Bay Population Of Blue Crab, Callinectes Sapidus, Shannon L. Wells

OES Theses and Dissertations

The Chesapeake Bay blue crab, Callinectes sapidus, is an important species both ecologically and as a fishery. Fishery dependent and independent data indicate that the population declined abruptly in the mid-1990s and has remained low. Previous work prior to the decline in population abundance found a significant relationship between size and fecundity for mature females. As with many heavily fished populations, this population has experienced a reduction in the size at maturity. The objectives of this study were to reassess the fecundity of the population, determine the lipid and protein energy allocated for reproduction, and to examine the concentrations …

The Use Of Fourier Transform (Ft) Surface-Enhanced Raman Scattering For Biochemical Analysis, Robert Butler Jeffers

Chemistry & Biochemistry Theses & Dissertations

Surface-enhanced Raman scattering (SERS) is a powerful spectroscopic technique that has created exciting opportunities in the field of bioanalytical chemistry, where it combines ultrasensitive detection of biologically relevant molecules with vibrational spectroscopy. Due to the difficulties in preparing reproducible SERS active substrates, SERS has been mainly used as a qualitative tool. In order for SERS to be utilized as a viable tool for quantitative analysis, simple, facile SERS substrates which generate clean, highly reproducible signals must be developed. This dissertation deals with the evaluation of three different methods of SERS that led to the development of a novel substrate for …

An Adaptive Method For Calculating Blow-Up Solutions, Charles F. Touron

Mathematics & Statistics Theses & Dissertations

Reactive-diffusive systems modeling physical phenomena in certain situations develop a singularity at a finite value of the independent variable referred to as "blow-up." The attempt to find the blow-up time analytically is most often impossible, thus requiring a numerical determination of the value. The numerical methods often use a priori knowledge of the blow-up solution such as monotonicity or self-similarity. For equations where such a priori knowledge is unavailable, ad hoc methods were constructed. The object of this research is to develop a simple and consistent approach to find numerically the blow-up solution without having a priori knowledge or resorting …

High-Energy Amplitudes In Gauge Theories In The Next-To-Leading-Order, Giovanni Antonio Chirilli

Physics Theses & Dissertations

Scattering processes play a central role in physics, and high-energies experiments give us an insight into the fine structure of matter. The high-energy behavior of amplitudes in gauge theories can be reformulated in terms of the evolution of Wilson-line operators. In the leading order this evolution is governed by the non-linear Balitsky-Kovchegov (BK) equation. In order to see if this equation is relevant for existing or future deep inelastic scattering (DIS) accelerators (like Electron Ion Collider (EIC) or Large Hadron electron Collider (LHeC)) one needs to know how large are the next-to-leading order (NLO) corrections. In addition, the NLO corrections …

Compensation Of Loss And Stimulated Emission Of Surface Plasmon Polaritons, Guohua Zhu

Electrical & Computer Engineering Theses & Dissertations

Surface plasmon polaritons (SPPs) have become in recent years an important research topic because of their interesting, physics and exciting potential applications, ranging from sensing and biomedicine to nanoscopic imaging and information technology. However, many applications of surface plasmon polaritons are hindered by one common cause—absorption loss in metal.

Over the years, numerous proposals have been made on how to conquer the plasmon loss. In this dissertation, (1) the known solutions to the loss problem by adding optical gain have been reviewed; (2) the properties of surface plasmon polaritons are studied theoretically, and the solution of the controversy regarding the …

Section Abstracts: Chemistry

Virginia Journal of Science

Abstracts of the Chemistry Section for the 87th Annual Meeting of the Virginia Academy of Science, May 27-29, 2009, Virginia Commonwealth University, Richmond Virginia.

Time Valuation Of Risk A Delayed-Bang Approach, Abhishek Pathak

Engineering Management & Systems Engineering Theses & Dissertations

The subject of this thesis is the combined use of engineering economics and survival analysis in estimating time-value of risk-related resources. The discussion includes (1) the need for sustainable risk management, (2) the importance of time-valuation of risk related resources in the allocation or selection among competing risk mitigation alternatives, (3) the convergence of deterministic engineering economics, survivability analysis, and probabilistic analysis, and (4) results and examples of application in the context of prevention of risk event or mitigation of its consequences.

The significance of this thesis is in how three topics: engineering economics, survivability analysis, and probability theory can …

Analysis Of Partial Discharge Pulse Height Distribution Parameters, Vinay N. Nimbole

Electrical & Computer Engineering Theses & Dissertations

Partial Discharges (PD) have been traditionally used to assess the state of any insulation system and its remnant life. In earlier work, Perspex (PMMA) samples with a needle plane gap have been aged with AC voltage. Their tree growth was monitored simultaneously by collecting PD at regular intervals of time and taking microphotographs in real time without interrupting the aging voltage. The obtained partial discharge pulse amplitude records were clustered together into groups of class intervals. The sequence of PD pulse height records was quantified as a time series of shape (η), and scale (σ) parameters of a Weibull distribution. …

Brain Tumor Progression Assessment Using Multiple Mri Volumes, Yufei Shen

Electrical & Computer Engineering Theses & Dissertations

Predicting and assessing tumor progression is important in brain tumor treatment. We attempt to use machine learning techniques to achieve consistency in assessing brain tumor progression. This thesis presents a prediction method of brain tumor progression by exploring a large MR database, which contains two patients ' complete records covering all their visits in the past two years. All ten MRI series, namely, apparent diffusion coefficient (ADC) , diffusion tensor imaging (DTI) , fractional anisotropy (FA), fluid attenuated inversion recovery (FLAIR), max eigenvalue (MAX), mid eigenvalue (MID), min eigenvalue (MIN) , post-contrast T₁-weighted, T₁- weighted, and …

A Study Of Decision Analysis Methods In Aerospace Technology Assessments, Sharon Monica Jones

Engineering Management & Systems Engineering Theses & Dissertations

Managers of aerospace technology programs and projects are faced with the challenge of making technology portfolio decisions under conditions of limited data, rapidly changing macro level factors and organizational uncertainties. To help make these technology investment decisions, some aerospace managers and analysts have used techniques from the field of decision analysis. In addition, there have been a limited number of research studies of real decision problems.

This dissertation presents the results of a non-experimental examination of the use of decision analysis methods for the assessment of aerospace technology portfolios. A web-based survey instrument was developed based on the results of …

Synchronicity: Just-In-Time Discovery Of Lost Web Pages, Martin Klein, Michael L. Nelson

Computer Science Presentations

PDF of a powerpoint presentation from the National Digital Information Infrastructure and Preservation Program (NDIIPP) Partners Meeting, Washington D.C., June 24-25, 2009. Also available on Slideshare.

Using Timed-Release Cryptography To Mitigate The Preservation Risk Of Embargo Periods, Rabia Haq, Michael L. Nelson

Computer Science Presentations

PDF of a powerpoint presentation from the 2009 ACM/IEEE Joint Conference on Digital Libraries, Austin, Texas, June 15-19, 2009. Also available on Slideshare.

Improving Oceanic Overflow Representation In Climate Models: The Gravity Current Entrainment Climate Process Team, Sonya Legg, Bruce Briegleb, Yeon Chang, Eric P. Chassignet, Gokhan Danabasoglu, Tal Ezer, Arnold L. Gordon, Stephen Griffies, Robert Hallberg, Laura Jackson, William Large, Tamay M. Ozgokmen, Hartmut Peters, Jim Price, Ulrike Riemenschneider, Wanli Wu, Xiaobiao Xu, Jiayan Yang

CCPO Publications

Oceanic overflows are bottom-trapped density currents originating in semienclosed basins, such as the Nordic seas, or on continental shelves, such as the Antarctic shelf. Overflows are the source of most of the abyssal waters, and therefore play an important role in the large-scale ocean circulation, forming a component of the sinking branch of the thermohaline circulation. As they descend the continental slope, overflows mix vigorously with the surrounding oceanic waters, changing their density and transport significantly. These mixing processes occur on spatial scales well below the resolution of ocean climate models, with the result that deep waters and deep western …

Adding Escience Assets To The Data Web, Herbert H. Van De Sompel, Carl Lagoze, Michael L. Nelson, Simeon Warner, Robert Sanderson, Pete Johnston

Computer Science Faculty Publications

Aggregations of Web resources are increasingly important in scholarship as it adopts new methods that are data-centric, collaborative, and networked-based. The same notion of aggregations of resources is common to the mashed-up, socially networked information environment of Web 2.0. We present a mechanism to identify and describe aggregations of Web resources that has resulted from the Open Archives Initiative - Object Reuse and Exchange (OAI-ORE) project. The OAI-ORE specifications are based on the principles of the Architecture of the World Wide Web, the Semantic Web, and the Linked Data effort. Therefore, their incorporation into the cyberinfrastructure that supports eScholarship will …

Effects Of Hze Irradiation On Chemical Neurotransmission In Rodent Hippocampus, Mayumi Machida

Theses and Dissertations in Biomedical Sciences

Space radiation represents a significant risk to the CNS (central nervous system) during space missions. Most harmful are the HZE (high mass, highly charged (Z), high energy) particles, e.g. ⁵⁶Fe, which possess high ionizing ability, dense energy deposition pattern, and high penetrance.

Accumulating evidence suggests that radiation has significant impact on cognitive functions. In ground-base experiments, HZE radiation induces pronounced deficits in hippocampus dependent learning and memory in rodents. However, the mechanisms underlying these impairments are mostly unknown.

Exposure to HZE radiation elevates the level of oxidation, resulting in cell loss, tissue damage and functional deficits through direct ionization …

Characterization Of Antibiotic Resistance In Vibrio Cholerae Isolated From Ships' Ballast And Other Environmental Sources, Frank Kornegay Thomson Iii

OES Theses and Dissertations

Ships' ballast has been implicated as a vector in the dispersal of invasive species into new environments. Numerous cases have been documented for the introduction of macroorganisms via ballasting operations, but what is less known is the role of ballast water and residuals in the spread of potentially harmful microbes, especially with reference to novel genotypes. Of particular interest are the genes encoding for various forms of antibiotic resistance, many of which are carried on mobile genetic elements. A four-year sampling effort has yielded over 300 putative isolates of Vibrio cholerae from ships' ballast tanks and various environmental sources, of …

Algorithms For Vertex-Weighted Matching In Graphs, Mahantesh Halappanavar

Computer Science Theses & Dissertations

A matching M in a graph is a subset of edges such that no two edges in M are incident on the same vertex. Matching is a fundamental combinatorial problem that has applications in many contexts: high-performance computing, bioinformatics, network switch design, web technologies, etc. Examples in the first context include sparse linear systems of equations, where matchings are used to place large matrix elements on or close to the diagonal, to compute the block triangular decomposition of sparse matrices, to construct sparse bases for the null space or column space of under-determined matrices, and to coarsen graphs in multi-level …

A Bio-Optical Model For Syringodium Filiforme Canopies, Margaret A. Stoughton

OES Theses and Dissertations

Seagrasses are significant ecological and biogeochemical agents in shallow water ecosystems throughout the world. In many regions, seagrass meadows occupy a sufficient fraction of the coastal zone, and generate optical signatures that can be observed from space. Bio-optical models of light absorption and scattering by submerged plant canopies for certain species such as Thalassia testudinum and Zostera marina have successfully modeled the plane irradiance distribution and photosynthesis within the submerged canopies. Syringodium filiforme differs &om T. testudinttm and Z marina, in leaf morphology and canopy architecture. The objective of this study was to develop a radiative transfer model that …

A Hidden Markov Model Based Approach To Detect Rogue Access Points, Gayathri Shivaraj

Electrical & Computer Engineering Theses & Dissertations

One of the most challenging security concerns for network administrators is the presence of Rogue access points. The challenge is to detect and disable a Rogue access point before it can cause hazardous damage to the network. This thesis proposes a statistically based approach to detect Rogue access points using a Hidden Markov Model, which is applied to passively measure packet-header data collected at a gateway router or any monitoring point. This approach utilizes variations in packet inter-arrival time to differentiate between authorized access points and Rouge access points. This approach used the inter-arrival time of a packet as a …

Characterization Of Microwave Cavity Discharges In A Supersonic Flow, Dareth Janette Drake

Physics Theses & Dissertations

A partially ionized gas is referred to as either a plasma or a discharge depending on the degree of ionization. The term discharge is usually applied to a weakly ionized gas, i.e. mostly neutrals, where as a plasma usually has a larger degree of ionization. To characterize a discharge the plasma parameters, such as the rotational temperature, vibrational temperature, and electron density, must be determined. Detailed characterization of supersonic flowing discharges is important to many applications in aerospace and aerodynamics. One application is the use of plasma-assisted hydrogen combustion devices to aid in supersonic combustion. In conditions close to the …