Physical Sciences and Mathematics Commons^™

Zinc Speculation And Ligand Fluxes In Chesapeake Bay And Elizabeth River Pore Waters, Duncan Glover Byers

Chemistry & Biochemistry Theses & Dissertations

Presented here are the first data on the vertical concentrations, complexation, speciation, and fluxes of total dissolved zinc and zinc complexing ligands, and zinc speciation in sediment pore waters in the Chesapeake Bay and Elizabeth River, Virginia.

Sediment pore waters were collected in mid and southern Chesapeake Bay in November 1997 and in the Elizabeth River (Pinner's Point) in March, April, and July 1998. Flux experiments were conducted in Elizabeth River sediment cores in April and July 1998. [TDZn] and zinc complexation were determined using differential pulse anodic stripping voltammetry at a hanging mercury drop electrode (DPASV-HMDE).

[TDZn] in the …

A Family Of Hierarchical Encoding Techniques For Image And Video Communications, Samah A. Senbel

Computer Science Theses & Dissertations

As the demand for image and video transmission and interactive multimedia applications continues to grow, scalable image and video compression that has robust behavior over unreliable channels are of increasing interest. These desktop applications require scalability as a main feature due to its heterogeneous nature, since participants in an interactive multimedia application have different needs and processing power. Also, the encoding and decoding algorithm complexity must be low due to the practical considerations of low-cost low-power receiver terminals. This requires image and video encoding techniques that jointly considers compression, scalability, robustness, and simplicity.

In this dissertation, we present a family …

Two Approaches To Critical Path Scheduling For A Heterogeneous Environment, Guangxia Liu

Computer Science Theses & Dissertations

Advances in computing and networking technologies are making large scale distributed heterogeneous computing a reality. Multi-Disciplinary Optimization (MDO) is a class of applications that is being addressed under this paradigm. It consists of multiple heterogeneous modules interacting with each other to solve an overall design problem. An efficient implementation of such an application requires scheduling heterogeneous modules (with different computing and disk 1/0 requirements) on a heterogeneous set of resources (with different CPU, memory, disk IO specifications).

Given a set of tasks and a set of resources, an optimal schedule of the tasks on the resources is very hard to …

Circulation, Vol. 6, No. 3, Center For Coastal Physical Oceanography, Old Dominion University

CCPO Circulation

Spring 1999 issue of CCPO Circulation featuring article "Studying Earth's Environment from Space"

Characterization And Identification Of A Sludge-Associated Bacterial Isolate, Abiodun O. Adibi, Derrell Mcpherson, Minna Laine

Virginia Journal of Science

During a metal speciation study, an unusually high retention of lead ·was observed when lead solution was percolated through a column packed with sludge compost obtained from Hampton Roads Sanitation department. A bacterium was isolated from the sludge compost and identified as Bacillus sphaericus using electron microscopy, whole cell fatty acid analysis (Midi System) and Biolog GP Microplate. The isolate grows in broth and agar media containing up to 800 µM lead. Lead accumulation study using atomic absorption spectrophotometer indicates that the isolate adsorbs lead. Lead adsorption is pH dependent. The isolate contains a plasmid of approximately 40 -50 kbp …

Synthesis And Crystal Structure Of Tetrachloro (1,10-Phenanthroline) Platinum (Iv), Robert M. Granger Ii, Jill N. Granger, Kelly Del Campo, Molly B. Becherer, Phillip E. Fanwick

Virginia Journal of Science

We report the crystal structure determination of tetrachloro( l,10-phenan­throline)platinum(IV). X-ray data indicate there is little steric repulsion between the cx.-hydrogens on the phenanthroline ligand and the chloride ligands in the equatorial plane.

Development And Testing Of An Ac Micro Hollow Cathode Simulator, Thomas E. Caldwell

Electrical & Computer Engineering Theses & Dissertations

The use of AC source plasma discharge devices in applications such as material processing and film deposition has increased in recent years due to improvements in discharge efficiency made possible by devices such as the micro hollow cathode. Designing hollow cathodes for specific applications requires an understanding of the processes that govern the discharge. Simulation is an inexpensive tool for understanding hollow cathode operation and optimizing the device for specific applications. This thesis describes the development of an AC micro hollow cathode simulator. It details the theoretical models used in the simulation and presents the results of test cases intended …

Fiber-Optic Coupled Lidar Receiver System To Measure Stratospheric Ozone, David Brent Harper

Electrical & Computer Engineering Theses & Dissertations

A fiber-optic coupled lidar receiver system was constructed to determine ozone concentrations in the stratosphere. The system was used to make ground-based measurements of lidar returns from a UV DIAL system. A fiber-optic cable was used to couple the light from the receiver telescope to the light detector. Photon counting was implemented as the light detection technique. This technique allowed detection of 301 and 311 nm lidar returns up to 27.5 and 32.5 km respectively. A software application was developed to control the photon counting system and perform real-time data analysis of measured lidar returns. DIAL measurements of stratospheric ozone …

Stratal Architecture In A Prograding Shoreface Deposit, Eastern Shore, Va: Relationship To Grain Size, Permeability, And Facies Distribution, Andrew C. Miller

OES Theses and Dissertations

A fundamental concern of the stratigrapher is to develop predictive models of stratigraphic organization. In sedimentology one of the most significant problems that has yet to be resolved is the fact that there is a lack of quantitative information regarding the relationship between geometry of beds, thickness of beds, grain size and sedimentary structures in sandy environments, especially shallow marine deposits. Scientists have also realized the need to correlate quantitative permeability to sedimentary structures and scales of stratigraphic organization. The purpose of the study is to investigate the scales of stratigraphic organization that control the variation of grain size and …

Benthic Community Analysis Of Hog Island Bay, Virginia, David James Lewis

Biological Sciences Theses & Dissertations

The benthic infaunal macroinvertebrate communities of Hog Island Bay of the Virginia Eastern Shore were quantitatively sampled at 30 locations on August 31 and September 1, 1995. The primary objectives of this study were: (1) to characterize the subtidal macroinfaunal benthic communities of Hog Island Bay, (2) to examine relationships between abiotic factors and the macroinfaunal communities and (3) to characterize the environmental condition of the system using the Benthic Index of Biotic Integrity (B-IBI) (Weisburg et al. 1997) and the EMAP Benthic Index for the Virginian Province (Strobel et al. 1995).

The ecological condition of Hog Island Bay appears …

Production Of Copper-Complexing Ligands In Response To Elevated Concentrations Of Copper In Marine Synechococcus Spp., Arunsri Chatkaeomorakot Brown

Theses and Dissertations in Biomedical Sciences

Synechococcus spp. (marine cyanobacteria) are extremely sensitive to copper toxicity and can produce high-affinity ligands of unknown structure which form complexes with free cupric ion. These ligands may contribute to the biological control of the levels of free cupric ions in surface seawater. Synechococcus spp. are known to produce metallothioneins (MT) in response to cadmium and zinc stress. In the present study the hypothesis that marine Synechococcus produce MT in response to copper was tested. Three marine Synechococcus spp. i.e., PCC 7001, PCC 73109, and PCC 7003, were exposed to different concentrations of CUSO 4 for various time periods. Size …

Effects Of Organic Matter And Iron-Rich Clay On Mobility Of Trace Metals From Flue Dust Contaminated Soil, Scott Ephraim Lewis

OES Theses and Dissertations

The enhanced leaching of trace metals through soil becomes a concern for human health if dissolved trace metals reach groundwater and migrate into a public water system. A serial batch extraction procedure was implemented to determine the effects of Vitagrow © organic matter and Fe-Rich TM clay on the mobility of trace metals (Zn, Pb, and Cd) from a flue dust treated (0, 600, 1200, and 2400 μgig Zn) Appling soil.

The addition of an organic matter (OM) amendment to the Appling soil enhanced Pb mobility and reduced soluble Zn and Cd. In general, average solution concentrations of trace metals …

Analysis Of Lunar Basalt Flows In Oceanus Procellarum Using Clementine Data, Noel William Jackson

OES Theses and Dissertations

Remote sensing analyses of data set taken by Clementine in 1994 permit new observations about mineral distribution on the lunar surface, basalt flow stratigraphy, and thus the geologic evolution of the Moon. The northern section of Oceanus Procellarum contains numerous impact craters which penetrated the basalt and thus can be used as natural probes to estimate the number and thicknesses of flows.

I constructed a mosaic taken in three frequencies ( 415 nm, 750 nm, 950 nm), and a Ratio Image (750/415 = red, 750/950 = green, 415/750 = blue). On such an image, red indicates the iron-poor mature highland …

Virtual Compton Scattering Processes In Quantum Chromodynamics, Igor V. Musatov

Physics Theses & Dissertations

Applications of perturbative QCD to deeply virtual Compton scattering and hard exclusive meson electroproduction processes require a generalization of usual Parton distributions for the case when long-distance information is accumulated in nonforward matrix elements [special characters omitted] of quark and gluon light-cone operators. We consider different aspects of the investigation of the virtual Compton amplitude in the QCD on two examples: the spin dependent observables in the forward virtual Compton process (measured in the experiments on deep inelastic scattering) and the γγ* transition form factor. Then we discuss in detail evolution equations for non-forward parton distributions [special characters omitted] The …

A Numerical Solution Of Low-Energy Neutron Boltzmann Equation, Martha Sue Clowdsley

Mathematics & Statistics Theses & Dissertations

A multigroup method using a straight ahead approximation is created to calculate low energy neutron fluence due to the elastic scattering of evaporation neutrons produced in interactions of high energy particles with target nuclei. This multigroup method is added to NASA Langley Research Center's HZETRN particle transport code. This new code is used to calculate the energy spectra of the neutron fluence in several different materials. The multigroup method is found to be an efficient way of calculating low energy neutron fluence in multiple atom materials as well as single atom materials. Comparisons to results produced by Monte Carlo methods …

An Iron-Based Ecosystem Model Of The Central Equatorial Pacific, Carrie L. Leonard, Charles R. Mcclain, Ragu Murtugudde, Eileen E. Hofmann, Lawrence W. Harding Jr.

CCPO Publications

The central and eastern equatorial Pacific region is characterized by lower than expected phytoplankton biomass and primary production given the relatively high ambient nitrate concentrations. These unusual conditions have spawned several field programs and laboratory experiments to determine why this high nitrate-low chlorophyll pattern persists in this region. To synthesize the results from these field programs, as well as providing additional evidence in support of the iron hypothesis, we developed a one-dimensional, nine-component ecosystem model of 0 degrees N 140 degrees W. The model components include two phytoplankton size fractions, two zooplankton size fractions, two detrital size fractions, dissolved iron, …

Decadal Variabilities Of The Upper Layers Of The Subtropical North Atlantic: An Ocean Model Study, Tal Ezer

CCPO Publications

Numerical simulations of the Atlantic Ocean during the period 1950 to 1989, using a sigma coordinate, free surface numerical model, show long-term variabilities in the upper ocean subtropical gyre similar to those obtained from observations. The simulations show how westward propagating planetary waves, originated in the eastern North Atlantic, affect interdecadal variabilities of ocean properties such as the Bermuda sea level, the Gulf Stream position and strength, and subsurface temperature anomalies in the western North Atlantic. Special attention is given to the dramatic sea level drop at Bermuda in the early 1970s, which is accompanied by cooling of subsurface layers …

Circulation, Vol. 6, No. 2, Center For Coastal Physical Oceanography, Old Dominion University

CCPO Circulation

Winter 1999 issue of CCPO Circulation featuring article "Identifying Different Flow Constituents in Estuaries"

Factorization And High-Energy Effective Action, Ian Balitsky

Physics Faculty Publications

I demonstrate that the amplitude for high-energy scattering can be factorized as a convolution of the contributions due to fast and slow fields. The fast and slow fields interact by means of Wilson-line operators—infinite gauge factors ordered along the straight line. The resulting factorization formula gives a starting point for a new approach to the effective action for high-energy scattering in QCD.

Role Of Spontaneous Emission In Ultracold Two-Color Optical Collisions, C. I. Sukenik, T. Walker

Physics Faculty Publications

We have observed violet photon emission resulting from energy-pooling collisions between ultracold Rb atoms illuminated by two colors of near-resonant infrared laser light. We have used this emission as a probe of doubly excited state ultracold collision dynamics. By varying the detuning of the lasers, we have clearly identified the effect of spontaneous emission on the collision process.

The Cause And Consequence Of Ontogenetic Changes In Social Aggregation In New Zealand Spiny Lobsters, Mark J. Butler Iv, Alistair B. Macdiarmid, John D. Booth

Biological Sciences Faculty Publications

Ontogenetic changes in the behavior, spatial distribution, or habitat use of a species are presumably adaptations to ecological forces that differ in their effect on various life stages. The New Zealand rock lobster Jasus edwardsii is one of several species of spiny lobster that exhibits dramatic ontogenetic shifts in sociality and spatial distribution, and we tested whether such changes are adaptive. We first surveyed several natural populations of J. edwardsii to document size-specific differences in aggregation. To determine if chemical cues discharged by conspecifics promote aggregation of certain ontogenetic stages, we tested the responsiveness of lobsters of 3 ontogenetic stages …

Warm Water Formation And Escape In The Upper Tropical Atlantic Ocean - 2. A Numerical Model Study, Sang-Ki Lee, G. T. Csanady

CCPO Publications

We seek the simplest mass and heat balance scenario within the upper tropical Atlantic Ocean using a 2.5-layer numerical model, with the help of a newly suggested entrainment formula. The model ocean is driven by the seasonal wind and heat flux associated with the movement of the Intertropical Convergence Zone (ITCZ). The entrainment rate is scaled by the product of wind stress and shear at the bottom of the mixed layer. On an annual average, the northward transport of the tropical warm water is about 11 Sv, with roughly 10 Sv associated with entrainment of upper thermocline water. Out of …

Frontogenesis In The North Pacific Oceanic Frontal Zones--A Numerical Simulation, Michael S. Dinniman, Michele M. Rienecker

CCPO Publications

A primitive equation model [Geophysical Fluid Dynamics Laboratory's (GFDL's) MOM 2] with one degree horizontal resolution is used to simulate the seasonal cycle of frontogenesis in the subarctic frontal zone (SAFZ) and the subtropical frontal zone (STFZ) of the North Pacific Ocean. The SAFZ in the model contains deep (greater than 500 m in some places) regions with seasonally varying high gradients in temperature and salinity. The gradients generally weaken toward the east. The STFZ consists of a relatively shallow (less than 200 m in most places) region of high gradient in temperature that disappears in the summer/fall. The high …

Continental Runoff And Effects On The North Atlantic Ocean Subtropical Mode Water, Larry P. Atkinson, Chester E. Grosch

CCPO Publications

Interannual salinity variations in North Atlantic Subtropical Mode Water (STMW) are well known although the cause is less well understood. Attempts to model local salinity variation with local evaporation and precipitation have not been successful and some authors invoke advection of low salinity water as the cause. Examination of the STMW and North American river runoff data suggests that runoff may partly explain the salinity variations. It is known that low salinity water resulting from Mississippi River outflow is transported well past Cape Hatteras. Spearman Rank Correlation analysis and spectra and cross-spectra Fourier correlation analysis both show that river flow …

Modification Of No, Po, And No/Po During Flow Across The Bering And Chukchi Shelves: Implications For Use As Arctic Water Mass Tracers, Lee W. Cooper, Glenn F. Cota, Lawrence R. Pomeroy, Jacqueline M. Grebmeier, Terry E. Whitledge

CCPO Publications

The NO and PO tracers (9[NO₃-] + 02 and 135[PO₄-] + 02, respectively,) and their derivative NO/PO have found increasing use in Arctic water mass analyses for identifying the specific basin or shelf areas from which surface waters originate, based upon assumed differences in Pacific- and Atlantic-derived content and basin-to-basin differences within the Arctic. Following shipboard sampling in June-September 1993 and May-June 1994, both north and south of Bering Strait, we have found evidence that Pacific-derived waters flowing north to Bering Strait do not necessarily have any unique NO, PO, or NO/PO identity that would permit …

Modeling The Effects Of Doliolids On The Plankton Community Structure Of The Southeastern Us Continental Shelf, A. G. Edward Haskell, Eileen E. Hofmann, Gustav-Adolf Paffenhofer, Peter G. Verity

CCPO Publications

A model of the lower trophic levels that consists of a system of coupled ordinary differential equations was developed to investigate the time-dependent behavior of doliolid populations associated with upwelling features on the outer southeastern US continental shelf. Model equations describe the interactions of doliolids with two phytoplankton size fractions, five copepod developmental stages and a detrital pool. Additional equations describe nitrate and ammonia. Model dynamics are based primarily upon data obtained from field and laboratory experiments for southeastern US continental shelf plankton populations. Variations on a reference simulation, which represents average upwelling conditions without doliolids, were carried out to …

Limitation Of Algal Growth By Iron Deficiency In The Australian Subantarctic Region, Peter N. Sedwick, Giacomo R. Ditullio, David A. Hutchins, Philip W. Boyd, F. Brian Griffiths, A. Clive Crossley, Thomas W. Trull, Bernard Queguiner

OES Faculty Publications

In March 1998 we measured iron in the upper water column and conducted iron- and nutrient-enrichment bottle-incubation experiments in the open-ocean Subantarctic region southwest of Tasmania, Australia. In the Subtropical Convergence Zone (∼42°S, 142°E), silicic acid concentrations were low (< 1.5μM) in the upper water column, whereas pronounced vertical gradients in dissolved iron concentration (0.12-0.84 nM) were observed., presumably reflecting the interleaving of Subtropical and Subantarctic waters, and mineral aerosol input. Results of a bottle-incubation experiment performed at this location indicate that phytoplankton growth rates were limited by iron deficiency within the iron-poor layer of the euphotic zone. In the Subantarctic water mass (∼46.8°S, 142°E), low concentrations of dissolved iron (0.05-0.11nM) and silicic acid (< 1μM) were measured throughout the upper water column, and our experimental results indicate that algal growth was limited by iron deficiency. These observations suggest that availability of dissolved iron is a primary factor limiting phytoplankton growth over much of the Subantarctic Southern Ocean in the late summer and autumn.

Trans-Resveratrol Inhibits Calcium Influx In Thrombin-Stimulated Human Platelets, Yuliya Dobrydneva, Roy L. Williams, Peter F. Blackmore

Chemistry & Biochemistry Faculty Publications

1 The phytoestrogenic compound trans-resveratrol (trans-3,5,4'-trihydroxystilbene) is found in appreciable quantities in grape skins and wine. It has been shown that both products rich in trans-resveratrol and pure trans-resveratrol inhibit platelet aggregation both in vivo and in vitro. However the mechanism of this action still remains unknown.

2 An essential component of the aggregation process in platelets is an increase in intracellular free Ca²⁺ ([Ca²⁺]_i). Ca²⁺ must enter the cell from the external media through specific and tightly regulated Ca²⁺ channels in the plasma membrane. The objective …

Direct Current Glow Discharges In Atmospheric Air, Robert H. Stark, Karl H. Schoenbach

Bioelectrics Publications

Direct current glow discharges have been operated in atmospheric air by using 100 μm microhollow cathode discharges as plasma cathodes. The glow discharges were operated at currents of up to 22 mA, corresponding to current densities of 3.8 A/cm² and at average electric fields of 1.2 kV/cm. Electron densities in the glow are in the range from 10¹² to 10¹³  cm⁻³. Varying the current of the microhollow cathode discharge allows us to control the current in the atmospheric pressure glow discharge. Large volume atmospheric pressure air plasmas can be generated by operating microhollow cathode discharges …

Field Sampling And Necropsy Examination Of Fish, A. S. Kane, A. Baya, R. Reimschuessel, K. M. St. Pé, C. A. Poukish, C. P. Driscoll

Virginia Journal of Science

This paper presents an overview of observational and fish sampling tech­niques for investigating fish lesions, morbidity and mortality. These sam­pling techniques and investigations are much like detective work and require attention to detail, common sense, technical proficiency and experience. To solve the mystery of a fish kill, the investigator must use available evidence and clues to piece together a series of events that often have long since passed. The cause of these field events may be chemical, biological or physical; more often, it is some combination of these. An initial categorization approach may be used to reduce the great number …