Physical Sciences and Mathematics Commons^™

Characterization Of Iron Oxides And Atmospheric Corrosion Of Steel, Sei Jin Oh

Physics Theses & Dissertations

The study of corrosion behavior was performed using three different analytical techniques, which provided information on the formation, development and layering of iron oxides on the corrosion products as a function of atmospheric conditions, exposure time and type of steel. In particular, the protective layer formed on weathering steel was investigated as a function of different amounts of alloying elements in the steel, atmospheric conditions and exposure times. Combined together, the results provided a better understanding of the atmospheric corrosion behavior of steel, and formed a part of database of the atmospheric corrosion characteristics.

Accurate characterization of the iron oxides …

Analysis Of Repeated Measures Data Under Circular Covariance, Andrew Montgomery Hartley

Mathematics & Statistics Theses & Dissertations

Circular covariance is important in modelling phenomena in epidemiological, communications and numerous physical contexts. We introduce and develop a variety of methods which make it a more versatile tool. First, we present two classes of estimators for use in the presence of missing observations. Using simulations, we show that the mean squared errors of the estimators of one of these classes are smaller than those of the Maximum Likelihood (ML) estimators under certain conditions. Next, we propose and discuss a parsimonious, autoregressive type of circular covariance structure which involves only two parameters. We specify ML and other types of estimators …

Note: On The Degree Of Lp Approximation With Positive Linear Operators, J. J. Swetits, B. Wood

Mathematics & Statistics Faculty Publications

The degree of approximation in L_p-spaces by positive linear operators is estimated in terms of the integral modulus of smoothness. It is shown that the conjectured optimal degree of approximation is not attained in the class of functions having a second derivative belonging to L_p.

Modeling Nutrient And Plankton Processes In The California Coastal Transition Zone: 1. A Time- And Depth-Dependent Model, J. R. Moisan, Eileen E. Hofmann

CCPO Publications

A time- and depth-dependent, physical-bio-optical model was developed for the California coastal transition zone (CTZ) with the overall objective of understanding and quantifying the processes that contribute to the vertical and temporal development of nutrient and plankton distributions in the CTZ. The model food web components included silicate, nitrate, ammonium, two phytoplankton size fractions, copepods, doliolids, euphausiids, and a detritus pool. The wavelength-dependent subsurface irradiance field was attenuated by sea water and phytoplankton pigments. The one-dimensional (1-D) model adequately simulated the development and maintenance of a subsurface chlorophyll maximum in different regions within the CTZ. An analysis of the individual …

Modeling Nutrient And Plankton Processes In The California Coastal Transition Zone: 2. A Three-Dimensional Physical-Bio-Optical Model, J. R. Moisan, Eileen E. Hofmann, D. B. Haidvogel

CCPO Publications

A three-dimensional (3-D) primitive equation model, developed to simulate the circulation features (filaments) observed in the California coastal transition zone (CTZ), was coupled to a nine-component food web model and a bio-optical model. The simulated flow fields from a 3-D primitive equation model are used to advect the constituents of the food web model, which include silicate, nitrate, ammonium, two phytoplankton size fractions, copepods, doliolids, euphausiids, and a detritus pool. The bio-optical model simulates the wavelength-dependent attenuation of the subsurface irradiance field. The overall objective of this modeling study was to understand and quantify the processes that contribute to the …

Circulation, Fall 1996, Center For Coastal Physical Oceanography, Old Dominion University

CCPO Circulation

Fall 1996 issue of CCPO Circulation featuring article "Antarctic Continental Shelves Are Strange And Unique"

Modeling Nutrient And Plankton Processes In The California Coastal Transition Zone: 3. Lagrangian Drifters, J. R. Moisan, Eileen E. Hofmann

CCPO Publications

Two types of numerical Lagrangian drifter experiments were conducted, using a set of increasingly complex and sophisticated models, to investigate the processes associated with the plankton distributions in the California coastal transition zone (CTZ). The first experiment used a one-dimensional (1-D; vertical) time-dependent physical-bio-optical model, which contained a nine-component food web. Vertical velocities, along the track of simulated Lagrangian drifters, derived from a three-dimensional (3-D), primitive equation circulation model developed to simulate the flow observed within the CTZ; were used to parameterize the upwelling and downwelling processes. The second experiment used 880 simulated Lagrangian drifters from a 3-D primitive equation …

Monte Carlo Simulations Of Photoemission Characteristics From Gaas And Diamond, Abhishek Srivastava

Electrical & Computer Engineering Theses & Dissertations

Monte Carlo based numerical simulations were performed to study photoemission from GaAs and diamond. The central goal was to assess the potential for NEA photoemission from diamond, and to predict its characteristics. The GaAs material system was also included in the simulation study to provide: (i) calibration and validation of the numerical model developed by carefully matching the simulation results with available experimental data, and (ii) quantitative comparisons between the response characteristics of diamond and the better known GaAs system.

Predictions of the energy distribution, temporal response and angular distribution of emitted electrons were obtained. Effects of various parameters, such …

A Computational Paradigm On Network-Based Models Of Computation, Venkatavasu Bokka

Computer Science Theses & Dissertations

The maturation of computer science has strengthened the need to consolidate isolated algorithms and techniques into general computational paradigms. The main goal of this dissertation is to provide a unifying framework which captures the essence of a number of problems in seemingly unrelated contexts in database design, pattern recognition, image processing, VLSI design, computer vision, and robot navigation. The main contribution of this work is to provide a computational paradigm which involves the unifying framework, referred to as the multiple Query problem, along with a generic solution to the Multiple Query problem.

To demonstrate the applicability of the paradigm, a …

Resource/Dataflow Graph Operating System Development, Sriram J. Coimbatore

Electrical & Computer Engineering Theses & Dissertations

Implementation of a new dataflow schedule model is the objective of this thesis. The dataflow model algorithm called the resource/dataflow graph model is implemented on a peer-to-peer communication network comprising of six personal computers. This dataflow model is implemented making use of an earlier dataflow model called ATAMM (Algorithm to Architecture Mapping Model) developed by ODU and National Aeronautics and Space Administration (NASA). Development issues include modification of the RDFG testbed operating system and a scheme to transfer data buffers using the ethernet channel from one processor to another processor. This, in turn, equips each sub-module of an application with …

Depositional Environment And Sequence Stratigraphic Interpretation Of Miocene St. Marys Formation, Calvert County, Maryland, John J. Blandin

OES Theses and Dissertations

The Miocene St. Marys Formation at Calvert Cliffs, Maryland is divided into four depositional packages made up of marine fades representing shallow shelf through intertidal conditions. These depositional packages are separated by five laterally persistent surfaces and were defined based on detailed depositional fades analysis of 24 measured sections, averaging 17 meters thick. These four packages make up two marine sequences, stratigraphic units bound above and below by surfaces of sea level fall. The lower sequence is composed of a single depositional package, while the upper sequence is composed of three upward-shallowing depositional packages (i.e. para-sequences). A fifth depositional package …

Nutrients And Chlorophyll At The Shelf Break Off The Southeastern United States During The Genesis Of Atlantic Lows Experiment: Winter 1986, L. P. Atkinson, J. L. Miller, T. N. Lee, W. M. Dunstan

CCPO Publications

The outer shelf and upper slope off Charleston, South Carolina, were the site of oceanographic and meteorological measurements during the winter of 1986. The purpose of the study was to test ideas about front formation, heat transport, and stratification during cold air outbreaks. An ancillary part of the study was the observation of nutrients and chlorophyll concentrations. The observations extended across the shelf and sometimes crossed the Gulf Stream front. The results show slightly elevated nitrate concentrations in outer shelf waters (1 - 2 μM NO₃) with chlorophyll concentrations in the 1 - 1.8 μg L^-1 range. …

An Investigation Of Software Reliability Models, Pamela Elaine Bowman

Computer Science Theses & Dissertations

Many software reliability models have been promoted in the literature in an attempt to provide a meaningful response to the growing need to know the reliability of software during and after the development process. However, there are well-founded concerns as to the accuracy of the individual model, as well as to the choice of which model to use for a particular program. A recent experiment based on the debugging history of a partially debugged program used a gold version to label a debugging graph from replicated data. This experiment concluded that presenting the replicated data to the models in a …

Exploring Knowledge Processes For Technology Assimilation, Rochelle K. Young

Engineering Management & Systems Engineering Theses & Dissertations

In the emerging knowledge society, the ability to make the experience and expertise of those involved in and affected by new technology unconditionally available to all members of an organization is becoming increasingly important. One of the problems in developing such knowledge processes for technology assimilation is that current social structures do not easily accommodate unconditional participation. Since the implementation of modern information technology is changing the workplace and the nature of work itself, alternative social structures are needed. This research takes as given that deep questions concerning knowledge processes and social transformation are in principle undecidable; and, only questions …

Visual Speech Recognition Using Multiple Deformable Lip Models, Devi Chandramohan

Electrical & Computer Engineering Theses & Dissertations

Motivated by the fact that human speech perception is a bimodal process (auditory and visual), several researchers have designed and implemented automatic speech recognition (ASR) systems consisting of both audio and visual subsystems, and shown improved performance relative to traditional purely auditory systems. Several visual speech reading approaches have used deformable templates to model the shape of a speaker's lips. Deformable templates are models of image objects, which can be deformed by adjusting a set of parameters to match the object in some optimal way, as defined by a cost function. Using a single deformable lip model has disadvantages such …

Two-Dimensional Drift-Diffusion Simulations Of Silicon Avalanche Shaper (Sas) Devices For High Power Applications, Hamid Jalali

Electrical & Computer Engineering Theses & Dissertations

Silicon Avalanche Shaper devices have been projected as being important components of an inexpensive, semiconductor-based technology for high power switching applications. The primary advantage of this technology is that it is based on Silicon material which is easy to fabricate and has a well established processing technology. Unlike other high power technologies, the SAS devices do not rely on external optical triggering which eliminates the need for lasers and related optical circuitry.

The SAS based high power switching technology has been pioneered and tested by a Russian group. Though preliminary results have been very encouraging, the device reliability and its …

Neural Generalized Predictive Control For Real-Time Control, Donald I. Soloway

Electrical & Computer Engineering Theses & Dissertations

In this thesis a computationally efficient Generalized Predictive Control (GPC) algorithm is presented and implemented. The algorithm is more efficient than others because the number of iterations needed for convergence is significantly lower with Newton-Raphson. The main additional cost with Newton-Raphson algorithm is the calculation of the Hessian. This overhead is not a problem because of the reduced number of iterations, making the algorithm suitable for real-time control. For nonlinear control applications, a neural network is used as a dynamical system predictor leading to a Neural Generalized Predictive Control (NGPC) algorithm which is presented in detail in this thesis. An …

Scalability In Real-Time Systems, Ramesh Yerraballi

Computer Science Theses & Dissertations

The number and complexity of applications that run in real-time environments have posed demanding requirements on the part of the real-time system designer. It has now become important to accommodate the application complexity at early stages of the design cycle. Further, the stringent demands to guarantee task deadlines (particularly in a hard real-time environment, which is the assumed environment in this thesis) have motivated both practioners and researchers to look at ways to analyze systems prior to run-time. This thesis reports a new perspective to analyzing real-time systems that in addition to ascertaining the ability of a system to meet …

Comparison Of Positive Screening And Confimatory Results From Federally Mandated Drug Testing Of Urine, Mary M. Stuck

Community & Environmental Health Theses & Dissertations

The purpose of this study was to analyze the accuracy of FDA approved immunoassays for the detection of drug positive urine samples.

Federal civilian employees are tested under the strict protocol of the Department of Health and Human Services mandatory guidelines for federal workplace drug testing programs. The guidelines provide for a two instrument testing protocol for the analysis of urine samples. The first is an FDA approved immunoassay. Samples which test positive on this screening immunoassay are then submitted for confirmatory testing with the "gold standard" gas chromatography/mass spectrometry.

Agency monthly drug testing summaries, required under the DHHS guidelines …

Reactions Of Aqueous Chlorine With Alanylphenylalanine In Model Solutions And In A Wastewater, Thomas C. Fox

Chemistry & Biochemistry Theses & Dissertations

Model solutions of the dipeptide alanylphenylalanine were chlorinated to four different chlorine-to-amino nitrogen (Cl₂/Ala-Phe) mole ratios and analyzed by high performance liquid chromatography. At mole ratios ≤ 1, N-chloroalanylphenylalanine was the only major product. As the Cl₂/Ala-Phe mole ratio was increased to ≥ 2, N,N-dichloroalanylphenylalanine was the only major product. In model solutions (pH 7.0) the dichlorinated dipeptide decomposed (t_1/2= 4.1 hr) to form a stable N-chloroketimine, which has a half-life of 125 hours. This N-chloroketimine then decomposed to form phenylalanine.

To follow these reactions in a wastewater, alanyl-p-[ …

Concentrations, Complexation And Speciation Of Total Dissolved Zinc In The Chesapeake Bay, Charles William Henry Iii

Chemistry & Biochemistry Theses & Dissertations

This is the first research to examine the horizontal, vertical, and temporal variability of total dissolved zinc, organic complexation of zinc, and zinc speciation in the Chesapeake Bay. Filtered (0.45μm) surface and bottom water samples were taken along the salinity gradient of the Chesapeake Bay in October 1993, March 1995, July 1995, and October 1995. Analysis by Differential Pulse Anodic Stripping Voltammetry (DP ASV) indicated that total dissolved zinc concentrations in the Bay ranged from 2.9 ± 0.7nM to 38.8 ± 2nM. Total zinc was highest at the northern end of the Bay (low salinity), approximately 10 times lower at …

Comprehensive Conjunctive-Use Management Of Connected Surface Water Groundwater Systems Using Stochastic Inputs And Uncertainties, Seshadri Suryanarayana

Civil & Environmental Engineering Theses & Dissertations

A comprehensive conjunctive-use management model is developed. The dynamics of flow and solute transport processes in connected surface water groundwater systems are integrated by a dual programming management model. The governing aquifer flow parameters and streamflows are treated as stochastic random processes. Multiple realizations of the random field are generated and are explicitly incorporated in a non-linear optimization model along with other system, environmental, and management constraints. To facilitate management of large aquifer systems, a linked simulation-optimization approach is used. The simulation program generates the response matrices for flow and transport processes. The management model then determines optimal well discharges …

Optimality And Construction Of Designs With Generalized Group Divisible Structure, Sudesh K. Srivastav

Mathematics & Statistics Theses & Dissertations

This thesis is an investigation of the optimality and construction problems attendant to the assignment of v treatments to experimental units in b blocks of size k, paying special attention to settings for which equal replication of the treatments is not possible. The model is that of one way elimination of heterogeneity, in which the expectation of an observation on treatment i in block j is T_i + βj (treatment effect + block effect), where T_i and βj are unknown constants, 1 ≤ i ≤ v and 1 ≤ j ≤ b. All observations are assumed to …

A Test Of An Alternate Calibration Matrix For Niosh Method 7300, Robert T. Vitek

Community & Environmental Health Theses & Dissertations

The purpose of this study was to determine if the analytical results (when determining cadmium, lead, and zinc concentrations) for air sample filters prepared and analyzed according to N:OSH Method 7300, differ significantly, from those obtained when the instrument is calibrated using EPA Method 200.7 acid matrix standards. The null hypothesis was that no statistically significant difference, measured at the 95% confidence level, would exist between results obtained from the two calibration standards. Careful standard and sample preparation, the use of an internal standard, and the application of working standard and working internal standard correction factors served to isolate the …

Ionization Of Rydberg Wave Packets By Subpicosecond, Half-Cycle Electromagnetic Pulses, C. Raman, C. W. S. Conover, C. I. Sukenik, P. H. Bucksbaum

Physics Faculty Publications

We have studied the ionization of Rydberg wave packets by subpicosecond, nearly unipolar electromagnetic field pulses, in the regime where the duration of the electric field is less than the classical Kepler orbit time 2n3 for the wave packet. In contrast to the subpicosecond optical pulses, subpicosecond field pulses can ionize wave packets when the probability density near the inner turning point of the Kepler orbit is low. The transfer of energy from the electromagnetic field to essentially free electrons demonstrates that the pulses are substantially shorter than one field cycle. Such half-cycle pulses can track the wave packet throughout …

Observation Of Shelfwater Overrunning The Southern Slope Sea, Ajoy Kumar

OES Theses and Dissertations

Analyses of two years (1992 and 1993) of high resolution (1.47 km²) sea surface temperature satellite images of the southern Mid-Atlantic Bight (MAB), showed that unusually extensive overhang of shelf water occurs episodically, and coherently over along shelf distances of several hundred kilometers. These episodes are dubbed overrunning of the Slope Sea by shelf water. The overrunning volume has a "face" and a "back" (southern and northern limit). It transports substantial quantities of shelf water southward, and does not retreat onto the shelf, but eventually joins the western edge of the Gulf Stream in the vicinity of Chesapeake …

Wavelength Modulation Spectroscopy With Diode Lasers, Ying Lu

Electrical & Computer Engineering Theses & Dissertations

Wavelength Modulation Spectroscopy is a non-intrusive technique which enables several parameters such as concentration, velocity, and temperature of a target specie to be measured. The method involves a modulation of a probe laser beam and detection at the fundamental, or any harmonic frequency, by a phase-sensitive apparatus. The theory of wavelength modulation is discussed. Effects of the finite value of the wavelength modulation index, together with the effects of any residual amplitude modulation that often occurs simultaneously in a diode laser, are included. It is shown that there are several advantages in using detection harmonics orders greater than the second. …

Scheduling Processors For Distributed, Critical, Real-Time Systems, Hari K. Narasimhamurthy

Electrical & Computer Engineering Theses & Dissertations

The development of a procedure to obtain cyclo-static schedules for distributed, critical real-time applications is presented in this thesis. The applications considered in this thesis are characterized by hard deadlines and periodic inputs. The applica­ tions are described by a data flow graph model which guarantees performance. Given the data flow graph representation, processors are scheduled to complete tasks as specified in the representation. The scheduling technique separates the scheduling of tasks in time and the assignment of processors to tasks. While different criteria exist for task scheduling, a schedule which minimizes latency and maximizes throughput is used in this …

Adaptive Integration Of Audio And Visual Information Using Discrete And Semi-Continuous Hidden Markov Models In Audiovisual Automatic Speech Recognition, Qin Su

Electrical & Computer Engineering Theses & Dissertations

An audiovisual semi-continuous hidden Markov model (HMM)-based Automatic Speech Recognition (ASR) system and an improved method of integrating audio and visual information in an audiovisual discrete HMM-based ASR system are investigated.

In the audiovisual discrete HMM, an adaptive integration formulation is employed, which incorporates the integration into the HMM at a pre-categorical stage. A visual weighting parameter is determined automatically, which allows the relative contribution of audio and visual information to be adjusted adaptively. Using an adaptive weight, the accuracy increased by 13% compared to the same model with no adaptive weight.

The semi-continuous HMM is a class of models …

Variable Step Size Lms Adaptive Filters With Delayed Coefficient Updating, Guixian Xu

Electrical & Computer Engineering Theses & Dissertations

A new approach to delayed LMS adaptive filtering is presented, which uses a variable step size for coefficient updating to increase convergence speed and improve tracking characteristics. The new algorithm, called delayed variable step size LMS (DVLMS), is explained, analyzed, and simulated to experimentally determine performance characteristics. Three different strategies for adjusting the step size are examined, and their performance is compared. Also, simulation results are presented to show that the proposed DVLMS systems provide faster convergence and lower mis-adjustment than previously proposed DLMS systems.