Physical Sciences and Mathematics Commons^™

Deliquescence Behavior Of Organic/Ammonium Sulfate Aerosol, Sarah D. Brooks, Matthew E. Wise, Melinda Cushing, Margaret A. Tolbert

Matthew E. Wise

Recent studies have shown that tropospheric aerosols composed of internal mixtures of organics with sulfates are quite common with the organic composing up to 50% of the particle mass. The influences of the organics on the chemical and physical properties of the aerosol are not known. In this paper, we report the solubility of a series of dicarboxylic acids in saturated ammonium sulfate solution as a function of temperature. We also report the deliquescence relative humidity (DRH) of the pure dicarboxylic acids and of mixtures of dicarboxylic acids with ammonium sulfate. For the systems studied, we find that the presence …

Hygroscopic Behavior And Liquid-Layer Composition Of Aerosol Particles Generated From Natural And Artificial Seawater, Matthew E. Wise, Evelyn J. Freney, Corey A. Tyree, Jonathan O. Allen, Scot T. Martin, Lynn M. Russell, Peter R. Buseck

Matthew E. Wise

Sea-salt aerosol (SSA) particles affect the Earth's radiative balance and moderate heterogeneous chemistry in the marine boundary layer. Using conventional and environmental transmission electron microscopes (ETEM), we investigated the hygroscopic growth and liquid-layer compositions of particles generated from three types of aqueous salt solutions: sodium chloride, laboratory-synthesized seawater (S-SSA particles), and natural seawater (N-SSA particles). Three levels of morphological change were observed with the ETEM as the laboratory-generated particles were exposed to increasing relative humidity (RH). The first level, onset of observable morphological changes, occurred on average at 70, 48, and 35% RH for the NaCl, S-SSA, and N-SSA particles, …

Depositional Ice Nucleation Onto Hydrated Nacl Particles: A New Mechanism For Ice Formation In The Troposphere, M. E. Wise, K. J. Baustian, T. Koop, M. A. Freedman, E. J. Jensen, M. A. Tolbert

Matthew E. Wise

Sea-salt aerosol particles (SSA) are ubiquitous in the marine boundary layer and over coastal areas. Therefore SSA have ability to directly and indirectly affect the Earth’s radiation balance. The influence SSA have on climate is related to their water uptake and ice nucleation characteristics. In this study, optical microscopy coupled with Raman spectroscopy was used to detect the formation of an NaCl hydrate that could form under atmospheric conditions. NaCl(s) particles deliquesced at the well established value of 75.7±2.5% RH. NaCl(aq) particles effloresced to a mixture of hydrated and non-hydrated particles at temperatures between 236 and 252 K. The aqueous …

Depositional Ice Nucleation On Solid Ammonium Sulfate And Glutaric Acid Particles, K. J. Baustian, M. E. Wise, M. A. Tolbert

Matthew E. Wise

Heterogeneous ice nucleation on solid ammonium sulfate and glutaric acid particles was studied using optical microscopy and Raman spectroscopy. Optical microscopy was used to detect selective nucleation events as water vapor was slowly introduced into an environmental sample cell. Particles that nucleated ice were dried via sublimation and examined in detail using Raman spectroscopy. Depositional ice nucleation is highly selective and occurred preferentially on just a few ammonium sulfate and glutaric acid particles in each sample. For freezing temperatures between 214 K and 235 K an average ice saturation ratio of S = 1.10±0.07 for solid ammonium sulfate was observed. …

Depositional Ice Nucleation On Solid Ammonium Sulfate And Glutaric Acid Particles, K. J. Baustian, M. E. Wise, M. A. Tolbert

Matthew E. Wise

Heterogeneous ice nucleation on solid ammonium sulfate and solid amorphous glutaric acid particles was studied using optical microscopy and Raman spectroscopy. Optical microscopy was used to detect selective nucleation events as water vapor was slowly introduced into an environmental sample cell. Particles that nucleated ice were dried via sublimation and examined in detail using Raman spectroscopy. Depositional ice nucleation occurred preferentially on just a few ammonium sulfate and glutaric acid particles in each sample. For freezing temperatures between 214 K and 235K average ice saturation ratios of S=1.10±0.07 for solid ammonium sulfate and S=1.39±0.16 for solid amorphous glutaric acid particles …

Power-Series.Pdf, Iosif Pinelis

Iosif Pinelis

On Abstraction And Equivalence In Software Patent Doctrine: A Response To Bessen, Meurer And Klemens, Andrew Chin

Andrew Chin

No abstract provided.

Longitudinal Success Of Calculus I Reform, Doug Bullock, Kathrine E. Johnson, Janet Callahan

Janet M. Callahan

This paper describes the second year of an ongoing project to transform calculus instruction at Boise State University. Over the past several years, Calculus I has undergone a complete overhaul that has involved a movement from a collection of independent, uncoordinated, personalized, lecture-based sections, into a single coherent multi-section course with an activelearning pedagogical approach. The overhaul also significantly impacted the course content and learning objectives. The project is now in its fifth semester and has reached a steady state where the reformed practices are normative within the subset of instructors who might be called upon to teach Calculus I. …

Metrics Dashboard Services: A Framework For Analyzing Free/Open Source Team Repositories, Shilpika Shilpika, George K. Thiruvathukal, Nicholas Hayward, Konstantin Läufer

George K. Thiruvathukal

No abstract provided.

A Mini-History Of Computing, George K. Thiruvathukal

George K. Thiruvathukal

This book was produced by George K. Thiruvathukal for the American Institute of Physics to promote interest in the interdisciplinary publication, Computing in Science and Engineering. It accompanied a limited edition set of playing cards that is no longer available (except in PDF). This book features a set of 54 significant computers by era/category, including ancient calculating instruments, pre-electronic mechanical calculators and computers, electronic era computers, and modern computing (minicomputers, maniframes, personal computers, devices, and gaming consoles).

Mechanical Properties Of Self-Assembled Nanoparticle Membranes: Stretching And Bending, Yifan Wang, Pongsakorn Kanjanaboos, Sean P. Mcbride, Edward Barry, Xiao-Min Lin, Heinrich M. Jaeger

Dr. Sean P. McBride

Monolayers composed of colloidal nanoparticles, with thickness less than ten nanometers, have remarkable mechanical strength and can suspend over micron-sized holes to form free-standing membranes. We discuss experiments probing the tensile strength and bending stiffness of these self-assembled nanoparticle sheets. The fracture behavior of monolayers and multilayers is investigated by attaching them to elastomer substrates which are then stretched. For different applied strain the fracture patterns are imaged down to the scale of single particles. The resulting detailed information about the crack width distribution allows us to relate the measured overall tensile strength to the distribution of local bond strengths …

Viscosity Dependent Liquid Slip At Molecularly Smooth Hydrophobic Surfaces, Sean P. Mcbride, Bruce M. Law

Dr. Sean P. McBride

Colloidal probe atomic force microscopy is used to study the slip behavior of 18 Newtonian liquids from two homologous series, the n-alkanes and n-alcohols, at molecularly smooth hydrophobic n-hexadecyltrichlorosilane coated surfaces. We find that the slip behavior is governed by the bulk viscosity η of the liquid, specifically, the slip length b∼ηx with x∼0.33. Additionally, the slip length was found to be shear rate independent, validating the use of Vinogradova slip theory in this work.

Improved In Situ Spring Constant Calibration For Colloidal Probe Atomic Force Microscopy, Sean P. Mcbride, Bruce M. Law

Dr. Sean P. McBride

In colloidal probe atomic force microscopy (AFM) surface forces cannot be measured without an accurate determination of the cantilever spring constant. The effective spring constant k depends upon the cantilever geometry and therefore should be measured in situ; additionally, k may be coupled to other measurement parameters. For example, colloidal probe AFM is frequently used to measure the slip length b at solid/liquid boundaries by comparing the measured hydrodynamic force with Vinogradova slip theory (V-theory). However, in this measurement k and b are coupled, hence, b cannot be accurately determined without knowing k to high precision. In this paper, a …

Forces At Individual Pseudopod-Filament Adhesive Contacts, Govind Paneru, Prem S. Thapa, Sean P. Mcbride, David Moore-Nichols, Bruce M. Law, Bret N. Flanders

Dr. Sean P. McBride

On-chip cellular force sensors are fabricated from cantilever poly(3,4-ethylene dioxythiophene) filaments that visibly deflect under forces exerted at individual pseudopod-filament adhesive contacts. The shape of the deflected filaments and their ∼3 nN/μm spring constants are predicted by cantilever rod theory. Pulling forces exerted by Dictyostelium discoideumcells at these contacts are observed to reach ∼20 nN without breaking the contact.

Influence Of Line Tension On Spherical Colloidal Particles At Liquid-Vapor Interfaces, Sean P. Mcbride, Bruce M. Law

Dr. Sean P. McBride

Atomic force microscopy (AFM) imaging of isolated submicron dodecyltrichlorosilane coated silica spheres, immobilized at the liquid polystyrene- (PS-) air interface at the PS glass transition temperature, Tg , allows for determination of the contact angle θ versus particle radius R . At Tg , all θ versus R measurements are well described by the modified Young’s equation for a line tension τ=0.93  nN . The AFM measurements are also consistent with a minimum contact angle θmin and minimum radius Rmin , below which single isolated silica spheres cannot exist at the PS-air interface.

Hydrolysis Of P-Nitrophenyl Esters Promoted By Semi-Fluorinated Quaternary Ammonium Polymer Latexes And Films, Baljinder Kaur, Sean P. Mcbride, Warren T. Ford

Dr. Sean P. McBride

Semifluorinated polymer latexes were prepared by emulsion polymerization of 2.5-25% of a fluoroalkyl methacrylate, 25% chloromethylstyrene, 1% styrylmethyl(trimethyl)ammonium chloride, and the remainder 2-ethylhexyl methacrylate under surfactant-free conditions. The chloromethylstyrene units were converted to quaternary ammonium ions with trimethylamine. In aqueous dispersions at particle concentrations of less than 1 mg mL-1 the quaternary ammonium ion latexes promoted hydrolyses of p-nitrophenyl hexanoate (PNPH) in pH 9.4 borate buffer and of diethyl p-nitrophenyl phosphate (Paraoxon) in 0.1 M NaOH at 30 oC with half-lives of less than 10 minutes. Thin 0.7-2 μm films of the latexes on glass promoted fast hydrolysis of Paraoxon …

Electron Acceleration And Generation Of High-Brilliance X-Ray Radiation In Kilojoule, Subpicosecond Laser-Plasma Interactions, Serge Y. Kalmykov, X. Davoine

Serge Youri Kalmykov

Multi-Disciplinary Hands-On Desktop Learning Modules And Modern Pedagogies, Bernard J. Van Wie, David B. Thiessen, Marc Compere, Ximena Toro, Jennifer C. Adam, Et Al.

Marc Compere

Our team’s research focuses on fundamental problems in undergraduate education in terms of how to expand use of well researched, yet still “new”, teaching pedagogies of ‘sensing’ or ‘hands-on’, ‘active’ and ‘problem-based learning’ within engineering courses. It is now widely accepted that traditional lectures ARE NOT best for students – yet that is what the community almost universally does. To address this issue we are developing new Desktop Learning Modules (DLMs) that contain miniaturized processes with a uniquely expandable electronic system to contend with known sensor systems/removable cartridges, as well as, unknown expansions to the project. We have shown that …

Project Haiti 2012: Providing An Experiential Learning Experience Through The Design And Delivery Of A Water Purifier In Haiti, Yung Wong, Johnathon Camp, Shavin Pinto, Kyle Fennesy, Marc Compere, Yan Tang

Marc Compere

In this paper, we share our experiences and lessons learned from Project Haiti 2012, a project to design and install a water purification system serving 20,000 people per day in the largest tent city in Haiti. Project Haiti 2012 was the third and largest system we have built for Haitians and represents a huge success for all participants and stakeholders. This paper discusses the unique experiential learning opportunity involved in the design and delivery of the water purifier in a foreign developing country. Multiple positive educational, social, and economic outcomes were achieved including students applying knowledge gained from coursework towards …

High Tech High Touch: Lessons Learned From Project Haiti 2011, Yan Tang, Marc Compere, Yung Lun Wong, Jared Anthony Coleman, Matthew Charles Selkirk

Marc Compere

In this paper, we will share our experiences and lessons learned from a design project for providing clean water to a Haitian orphanage (Project Haiti 2011). Supported by funds from a renewable energy company and the university president’s office, five engineering students and two faculty members from Embry-Riddle Aeronautical University successfully designed and installed a solar powered water purification system for an orphanage located in Chambellan, Haiti. This paper discusses the unique educational experiences gained from unusual design constraints, such as ambiguity of existing facilities due to limited communication, logistics of international construction at a remote village location, and cross-cultural …

Estimating Effects With Rare Outcomes And High Dimensional Covariates: Knowledge Is Power, Laura Balzer, J. Ahern, S. Galea, M. Van Der Laan

Laura B. Balzer

Enhancing Public Engagement On Offshore Wind Energy Using Genius Loci: A Case Study From A Lake Michigan Coastal Community, Erik Edward Nordman, Daniel O'Keefe, Erika Arndt

Erik Edward Nordman

Constraint Cnf: A Sat And Csp Language Under One Roof, Broes De Cat, Yuliya Lierler

Yuliya Lierler

Ammonium Hydrogen Bis­­[4-(2-Phenyl-2h-Tetra­Zol-5-Yl)Benzoate], Daron E. Janzen, Kayla A. Lange, James A. Wollack

Daron E Janzen, Ph.D.

No abstract provided.

Next Generation Sequencing Data Of A Defined Microbial Mock Community, Esther Singer, Bill Andreopoulos, Robert M. Bowers, Janey Lee, Shweta Deshpande, Jennifer Chiniquy, Doina Ciobanu, Hans-Peter Klenk, Matthew Zane, Christopher Daum, Alicia Clum, Jan-Fang Cheng, Alex Copeland, Tanja Woyke

William B. Andreopoulos

Biophysical And Hydrological Effects Of Future Climate Change Including Trends In Co2, In The St. Joseph River Watershed, Eastern Corn Belt, Ruoyu Wang

Ruoyu Wang

Non-Human Primates In Neuroscience Research: The Case Against Its Scientific Necessity, Jarrod Bailey, Katy Taylor

Jarrod Bailey, PhD

Public opposition to non-human primate (NHP) experiments is significant, yet those who defend them cite minimal harm to NHPs and substantial human benefit. Here we review these claims of benefit, specifically in neuroscience, and show that: a) there is a default assumption of their human relevance and benefit, rather than robust evidence; b) their human relevance and essential contribution and necessity are wholly overstated; c) the contribution and capacity of non-animal investigative methods are greatly understated; and d) confounding issues, such as species differences and the effects of stress and anaesthesia, are usually overlooked. This is the case in NHP …

An Assessment Of The Role Of Chimpanzees In Aids Vaccine Research, Jarrod Bailey

Jarrod Bailey, PhD

Prior to Simian Immunodeficiency Virus (SIV)-infected macaques becoming the ‘model of choice’ in the 1990s, chimpanzees were widely used in AIDS vaccine research and testing. Faced with the continued failure to develop an effective human vaccine, some scientists are calling for a return to their widespread use. To assess the past and potential future contribution of chimpanzees to AIDS vaccine development, databases and published literature were systematically searched to compare the results of AIDS vaccine trials in chimpanzees with those of human clinical trials, and to determine whether the chimpanzee trials were predictive of the human response. Protective and/or therapeutic …

The Other Side Of Silence: Rachel Carson’S Views Of Animals, Marc Bekoff, Jan Nystrom

Marc Bekoff, PhD

The publication of Rachel Carson’s Silent Spring in 1962 is widely regarded as one of the major events that launched the modern environmental movement. Silent Spring is a compelling blend of stories, natural history, human values, and biological facts. In this essay we consider Carson’s attitude toward animals in Silent Spring and in other texts. Despite the facts that she was raised to love Nature and animals, little direct attention has been given to Carson’s views about our moral responsibilities to, and the moral standing of animals. Carson favored responsible stewardship, was more of an animal welfarist and environmentalist/conservation biologist …

Compassion As A Practical And Evolved Ethic For Conservation, David Ramp, Marc Bekoff

Marc Bekoff, PhD

The ethical position underpinning decisionmaking is an important concern for conservation biologists when setting priorities for interventions. The recent debate on how best to protect nature has centered on contrasting intrinsic and aesthetic values against utilitarian and economic values, driven by an inevitable global rise in conservation conflicts. These discussions have primarily been targeted at species and ecosystems for success, without explicitly expressing concern for the intrinsic value and welfare of individual animals. In part, this is because animal welfare has historically been thought of as an impediment to conservation. However, practical implementations of conservation that provide good welfare outcomes …