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Articles 6061 - 6090 of 10319
Full-Text Articles in Physical Sciences and Mathematics
Tectonosedimentary Evolution Of The Karacasu And Bozdoğan Basins In The Central Menderes Massif, W Anatolia, Faruk Ocakoğlu, Sanem Açikalin, Erman Özsayin, Ramazan Kadi̇r Di̇ri̇k
Tectonosedimentary Evolution Of The Karacasu And Bozdoğan Basins In The Central Menderes Massif, W Anatolia, Faruk Ocakoğlu, Sanem Açikalin, Erman Özsayin, Ramazan Kadi̇r Di̇ri̇k
Turkish Journal of Earth Sciences
The Karacasu and Bozdoğan basins, which trend obliquely to modern grabens in the Central Menderes Massif, are investigated in terms of morphology, basinfill architecture, and structure. Evaluation of the previous geophysical and new structural data indicates that the basins are symmetrical grabens mostly running in a N-S direction. Analysis of sedimentary facies of the basins infill supports the simple graben model by revealing lateral alluvial/colluvial fans in basin margins and axial fluvial/lacustrine environments in a central trough. The long-term changes between fluvial and lacustrine conditions in the basins are attributed to paleoclimatic origin. Paleostress analysis of slickensides substantiates that the …
New Fossils Of Gaindatherium (Rhinocerotidae, Mammalia) From The Middle Miocene Of Pakistan, Abdul Majid Khan, Esperanza Cerdeño, Muhammad Akhtar, Muhammad Akbar Khan, Ayesha Iqbal, Muhammad Mubashir
New Fossils Of Gaindatherium (Rhinocerotidae, Mammalia) From The Middle Miocene Of Pakistan, Abdul Majid Khan, Esperanza Cerdeño, Muhammad Akhtar, Muhammad Akbar Khan, Ayesha Iqbal, Muhammad Mubashir
Turkish Journal of Earth Sciences
New isolated teeth with maxillary and mandibular fragments from the Chinji Formation of the Lower Siwaliks are described and determined as Gaindatherium browni and Gaindatherium vidali. This material comes from the Middle Miocene of Lava and Dhok Bun Ameer Khatoon localities, northern Pakistan, and significantly increases the number of remains previously known for this rhinocerotid genus. Specimens from the Lava site determined as G. vidali present morphological differences with respect to those of G. browni, being similar to those of G. vidali from the Nagri Formation, showing a greater size. Previously, G. vidali was reported only from the Nagri Formation …
Probabilistic Earthquake Hazard Assessment For Ankara And Its Environs, Bülent Özmen, Berna Burçak Başbuğ Erkan
Probabilistic Earthquake Hazard Assessment For Ankara And Its Environs, Bülent Özmen, Berna Burçak Başbuğ Erkan
Turkish Journal of Earth Sciences
The capital and the second largest city of Turkey, Ankara, is generally considered to be safe in terms of seismic activities and earthquake hazard. However, recent studies and earthquakes experienced in the region showed that Ankara is not indeed seismically safe. As the number of studies on Ankaras seismic hazard increases, the number of scientists who claim that the earthquake hazard in Ankara is higher than expected also increases. However, to date no detailed analysis has been undertaken as to the earthquake hazard facing Ankara. This study has compiled data from the earthquake catalogues available in Turkey and employed the …
Reply To Comment By Erkül And Erkül On Al-In-Hornblende Thermobarometry And Sr-Nd-O-Pb Isotopic Compositions Of The Early Miocene Alaçam Granite In Nw Anatolia (Turkey), Altuğ Hasözbek, Burhan Erdoğan, Muharrem Satir, Wolfgang Siebel, Erhan Akay, Güllü Deni̇z Doğan, Heinrich Taubald
Reply To Comment By Erkül And Erkül On Al-In-Hornblende Thermobarometry And Sr-Nd-O-Pb Isotopic Compositions Of The Early Miocene Alaçam Granite In Nw Anatolia (Turkey), Altuğ Hasözbek, Burhan Erdoğan, Muharrem Satir, Wolfgang Siebel, Erhan Akay, Güllü Deni̇z Doğan, Heinrich Taubald
Turkish Journal of Earth Sciences
No abstract provided.
Ree Geochemical Characteristics Of Titanium-Rich Bauxites: The Permian Kanigorgeh Horizon, Nw Iran, Ali Abedini, Ali Asghar Calagari
Ree Geochemical Characteristics Of Titanium-Rich Bauxites: The Permian Kanigorgeh Horizon, Nw Iran, Ali Abedini, Ali Asghar Calagari
Turkish Journal of Earth Sciences
The Permian Kanigorgeh bauxite horizon is one of the typical titanium-rich bauxite deposits in the northeast of Bukan, West Azerbaijan Province, NW Iran. It is a part of the Irano-Himalayan karst bauxite belt and was developed as discontinuous stratified layers and lenses in Upper Permian carbonates. Mineralogically, diaspore and kaolinite are 2 major mineral phases accompanied by boehmite, smectite, illite, rutile, anatase, hematite, goethite, chlorite, quartz, and plagioclase as minor phases. Geochemical considerations for a selected profile indicate that the concentration values of rare earth elements (REEs) in the bauxite ores range from 8.9 to 200.4 ppm. Eu and Ce …
Geochemistry Of Sands Along The San Nicolás And San Carlos Beaches, Gulf Of California, Mexico: Implications For Provenance And Tectonic Setting, John Selvamony Armstrong Altrin, Ramasamy Nagarajan, Yong Il Lee, Juan José Kasper Zubillaga, Leslie Patricia Córdoba Saldaña
Geochemistry Of Sands Along The San Nicolás And San Carlos Beaches, Gulf Of California, Mexico: Implications For Provenance And Tectonic Setting, John Selvamony Armstrong Altrin, Ramasamy Nagarajan, Yong Il Lee, Juan José Kasper Zubillaga, Leslie Patricia Córdoba Saldaña
Turkish Journal of Earth Sciences
The weathering conditions, provenance, and tectonic setting of sands from the San Nicolás (SN) and San Carlos (SC) beaches along the Gulf of California, Mexico, have been studied using mineralogy, major element, and trace element data. The compositional similarity among 4 independent groups (each beach area consists of 2 grain-size groups, i.e. medium- and fine-grained sands) was tested statistically by the application of analysis of variance at the 99% confidence level to avoid misinterpretation. The X-ray diffraction and SEM-EDS data revealed that the fine-grained SN sands were abundant in rutile and zircon minerals. The higher SiO_2/Al_2O_3 ratio of the SN …
Bicoelia Corticifera, A New Inozoid Sponge From The Upper Triassic (Norian) Reef Boulders Of The Central Taurids (Southern Turkey), Baba Senowbari-Daryan, Michael Link
Bicoelia Corticifera, A New Inozoid Sponge From The Upper Triassic (Norian) Reef Boulders Of The Central Taurids (Southern Turkey), Baba Senowbari-Daryan, Michael Link
Turkish Journal of Earth Sciences
Upper Triassic Norian reef boulders, exposed in a locality in the Central Taurids, southern Turkey, yielded a high number of hypercalcified sponges, including Sphinctozoans, Inozoans, Spongiomorphids, and Chaetetids. The reef boulders are exposed near the fountain Tavuk Çeşme, located at the road leading from the town of Aksu to Yenişarbademli. Geologically this locality belongs to the Anamas Akseki Autochthon. In this paper a new inozoan sponge, Bicoelia corticifera nov. sp., is described from Tavuk Çeşme. It is a cylindrical and unbranched sponge, found in several thin sections. The sponge is characterized by 2 axial spongocoels, and the sponge wall is …
A Microscopic Approach To The Pedogenic Formation Of Palygorskite Associated With Quaternary Calcretes Of The Adana Area, Southern Turkey, Meryem Yeşi̇lot Kaplan, Muhsi̇n Eren, Selahatti̇n Kadi̇r, Seli̇m Kapur, Jennifer Huggett
A Microscopic Approach To The Pedogenic Formation Of Palygorskite Associated With Quaternary Calcretes Of The Adana Area, Southern Turkey, Meryem Yeşi̇lot Kaplan, Muhsi̇n Eren, Selahatti̇n Kadi̇r, Seli̇m Kapur, Jennifer Huggett
Turkish Journal of Earth Sciences
Quaternary calcretes in the Adana area (southern Turkey) are widespread and occur in a variety of forms such as nodular, columnar/tubular, fracture-infill, laminated hardpan, and conglomeratic crusts. Palygorskite associated with calcrete nodules, tubes, and fracture-infills in the columnar horizon and adjacent host-rock mudstones suggests a cogenetic formation. The Beta-fabric (biogenic) constituents and stable isotope values of calcretes support a pedogenic origin for calcretes and also palygorskite. Extensions of palygorskite fibre and fibre bundles from euhedral to subhedral calcite crystals in calcretes and from smectite flakes in adjacent host-rock mudstone suggest an authigenic origin related to calcretisation in which precipitation and …
Structural Analyses Of Şaphane Relay Ramps And Fault Linkage Evolution In Active Extensional Regime, Western Turkey, Şule Gürboğa
Structural Analyses Of Şaphane Relay Ramps And Fault Linkage Evolution In Active Extensional Regime, Western Turkey, Şule Gürboğa
Turkish Journal of Earth Sciences
The Şaphane relay ramps (SAR-I and SAR-II) are well-developed structures formed by extensional tectonic settings in western Turkey. Their formation is controlled by the configuration of 2 different breaching faults located in between and the overlapping area of 3 normal faults, which are the Şaphane, Gürlek, and Yumrutaş faults. The relay ramps form within a ~3 km-wide and ~12 km-long interaction zone between 045° and 060° trending faults on the northern boundary of the Erdoğmuş-Yenigediz graben. Some variations in structural styles and its products (for example, overlapping slip-lines (slickenlines), fractures, and antithetic-synthetic faults) are observed along the breaching faults in …
Carbonate Sealing And Its Controlling Factors: Cap Rock And Inner Barrier Layers Of Yingshan Formation On Tazhong Northern Slope, Tarim Basin, Xiaodong Lan, Xiuxiang Lu
Carbonate Sealing And Its Controlling Factors: Cap Rock And Inner Barrier Layers Of Yingshan Formation On Tazhong Northern Slope, Tarim Basin, Xiaodong Lan, Xiuxiang Lu
Turkish Journal of Earth Sciences
The Yingshan Formation, located on the Tazhong Northern Slope, contains oil- and gas-rich layers with the reserves of about 700 × 10^6 TOE. The high-resistivity inner layers isolate the hydrocarbon bearing zones and form the sequential sets of reservoir bed-seal assemblages in a vertical direction within the Yingshan Formation, which is directly bound above by a micritic carbonate cap rock that is overlain by the 3rd to 5th members of the Lianglitag Formation. The sealing capability of the cap rock and inner barrier layers was evaluated macroscopically and microscopically in terms of the core breakthrough pressure and thin-section identification. The …
Analysis Of Precursory Seismicity Patterns In Zagros (Iran) By Cn Algorithm, Majid Maybodian, Mehdi Zare, Hosseyn Hamzehloo, Antonella Peresan, Anooshiravan Ansari, Giuliano F. Panza
Analysis Of Precursory Seismicity Patterns In Zagros (Iran) By Cn Algorithm, Majid Maybodian, Mehdi Zare, Hosseyn Hamzehloo, Antonella Peresan, Anooshiravan Ansari, Giuliano F. Panza
Turkish Journal of Earth Sciences
This study illustrates the application of the CN algorithm for the analysis of precursory seismicity patterns in the Zagros region (Iran), an area characterized by a complex seismotectonic setting and by remarkable seismic activity. CN is a formally defined and widely tested algorithm for intermediate-term middle-range earthquake prediction, based on the analysis of routinely compiled earthquake catalogs. To allow its application, the global and regional catalogs available for the territory of Iran have been analyzed so as to compile a data set sufficiently complete and homogeneous over a time span of about 3 decades, as required for CN application. A …
Source Of The Mineralizing Fluids In Ultramafic Related Magnesite In The Eskişehir Area, Northwest Turkey, Along The İzmir–Ankara Suture: A Stable Isotope Study, Asuman Kahya, Mustafa Kuşcu
Source Of The Mineralizing Fluids In Ultramafic Related Magnesite In The Eskişehir Area, Northwest Turkey, Along The İzmir–Ankara Suture: A Stable Isotope Study, Asuman Kahya, Mustafa Kuşcu
Turkish Journal of Earth Sciences
The Eskişehir magnesite deposits (Süleymaniye, Margı, and Tutluca) are located in the western part of the İzmir-Ankara Suture Zone, northwestern Turkey. These vein and stockwork type magnesite deposits, which occur along major and minor fault systems, are hosted by Alpine-type ultramafic rocks. The purpose of this study was to understand the origin of the hydrothermal waters responsible and the source of carbon dioxide, and to compare these deposits with similar magnesite occurrences in Turkey and elsewhere. Petrographic and XRD analyses indicate that magnesite was the major carbonate mineral formed. Deposits are predominantly micritic and locally microsparitic, but some also contain …
The Utility Of Vulnerability Maps And Gis In Groundwater Management: A Case Study, Muhterem Demi̇roğlu, John Dowd
The Utility Of Vulnerability Maps And Gis In Groundwater Management: A Case Study, Muhterem Demi̇roğlu, John Dowd
Turkish Journal of Earth Sciences
Groundwater supplies are experiencing a critical shortage in arid and semiarid regions, as population growth, and hence demand, is not matched by the development of new water supplies. Groundwater is often the only water source in these areas, making the preservation of groundwater quality a critical issue. Powerful tools for groundwater protection are vulnerability maps, which can be used to identify protection zones. A number of factors influence aquifer vulnerability, including geology, geography, land use, and commercial and industrial development. These factors often display a complex spatial pattern easily addressed with GIS. Each factor is entered in the GIS as …
Santonian-Campanian Biostratigraphy Of The Kalaat Senan Area (West-Central Tunisia), Zaineb Elamri, Dalila Zaghbib-Turki
Santonian-Campanian Biostratigraphy Of The Kalaat Senan Area (West-Central Tunisia), Zaineb Elamri, Dalila Zaghbib-Turki
Turkish Journal of Earth Sciences
The Santonian-Campanian (S/C) transition in the Kalaat Senan area is well exposed in the Assila Wadi (OA) section and consists of marls with indurate glauconitic levels towards the base. Standard Mediterranean ammonite biozonations could not be applied to this section because the biomarkers are absent. However, planktonic foraminiferal biozonation is more reliable for indicating the S/C boundary, and here we propose to use the last appearance datum of Dicarinella asymetrica as the index marker of this boundary. A high-resolution quantitative analysis of the planktonic foraminifera of the OA section allows us to define the main bioevents across the S/C transition …
Development Of A Numerical 2-Dimensional Beach Evolution Model, Cüneyt Baykal
Development Of A Numerical 2-Dimensional Beach Evolution Model, Cüneyt Baykal
Turkish Journal of Earth Sciences
This paper presents the description of a 2-dimensional numerical model constructed for the simulation of beach evolution under the action of wind waves only over the arbitrary land and sea topographies around existing coastal structures and formations. The developed beach evolution numerical model is composed of 4 submodels: a nearshore spectral wave transformation model based on an energy balance equation including random wave breaking and diffraction terms to compute the nearshore wave characteristics, a nearshore wave-induced circulation model based on the nonlinear shallow water equations to compute the nearshore depth-averaged wave-induced current velocities and mean water level changes, a sediment …
Early Pleistocene Freshwater Communities And Rodents From The Pasinler Basin (Erzurum Province, North-Eastern Turkey), Davit Vasilyan, Simon Schneider, Memet Sali̇h Bayraktutan, Şevket Şen
Early Pleistocene Freshwater Communities And Rodents From The Pasinler Basin (Erzurum Province, North-Eastern Turkey), Davit Vasilyan, Simon Schneider, Memet Sali̇h Bayraktutan, Şevket Şen
Turkish Journal of Earth Sciences
An Early Pleistocene lacustrine faunal assemblage from Pasinler (Erzurum Province, north-eastern Turkey) is described, which encompasses 13 mollusc, 5 fish, 2 amphibian, 1 reptile, and 1 mammal species. The autochthonous freshwater mollusc fauna indicates shallow stagnant waters and a fine-sandy to muddy lake bottom, grown with submersed plants. The fish community (Leuciscus sp., Rutilus sp., Chondrostoma sp., Leuciscinae sp. 1 and 2, and Capoeta sp.) and autochthonous herpetofauna (Latonia sp. and Natrix sp.) provide evidence of a well-oxygenised palaeolake with rich periphyton and partially rocky to gravelly bottom. Moreover, the presence of the terrestrial snail Caspicyclotus cf. akramowsii, the peri- …
Miocene Palynoflora Of The Kocaçay And Cumaovası Basins: A Contribution To The Synthesis Of Miocene Palynology, Palaeoclimate, And Palaeovegetation In Western Turkey, Mi̇ne Sezgül Kayseri̇ Özer, Hasan Sözbi̇li̇r, Funda Akgün
Miocene Palynoflora Of The Kocaçay And Cumaovası Basins: A Contribution To The Synthesis Of Miocene Palynology, Palaeoclimate, And Palaeovegetation In Western Turkey, Mi̇ne Sezgül Kayseri̇ Özer, Hasan Sözbi̇li̇r, Funda Akgün
Turkish Journal of Earth Sciences
Palynofloras of the Kocaçay and Cumaovası basins in western Turkey that belong to a time-span from the late Early to late Middle Miocene (the late Burdigalian-Serravallian) are studied and compared with published palynofloras of Europe and Turkey. Palynological data and numerical climatic results obtained by the coexistence approach indicate palaeoclimate changed from warm subtropical to temperate during the late Burdigalian-Serravallian. Moreover, the palaeoclimates of the Kocaçay and Cumaovası basins are compared with continental palaeoclimatic records of coal-bearing sediments in western Turkey and current temperatures in the İzmir region. According to this comparison, palaeoclimatic results of these basins and other localities …
Antique Quarries Of Marmor Troadense (Nw Turkey): Insights From Field Mapping And Absolute Dating, Enver Vural Yavuz
Antique Quarries Of Marmor Troadense (Nw Turkey): Insights From Field Mapping And Absolute Dating, Enver Vural Yavuz
Turkish Journal of Earth Sciences
In this study, we present new field and chronological data from 2 antique quarries of marmor troadense (Kestanbol quartz-monzonite) in northwestern Turkey. Marmor troadense has been mined and the building stones have been exported all over the Mediterranean region since approximately 2500 years ago. Analysis of 11 samples from the quarried bedrock for cosmogenic ^{10}Be showed that the landscape is so old that the inheritance obscured the absolute dating of the operation periods. Nonetheless, ^{14}C analysis of 4 charcoal samples from the sediments covering the ruins of Alexandria Troas indicated that these quarries stopped operating no later than 395 AD. …
A 3d Model For The Formation Of Turtleback Surfaces: The Horzum Turtleback Of Western Turkey As A Case Study, Gürol Seyi̇toğlu, Veysel Işik, Korhan Esat
A 3d Model For The Formation Of Turtleback Surfaces: The Horzum Turtleback Of Western Turkey As A Case Study, Gürol Seyi̇toğlu, Veysel Işik, Korhan Esat
Turkish Journal of Earth Sciences
Turtleback surfaces are common elements of highly extended terrains all over the world. This paper presents a 3D model explaining the formation of turtleback surfaces based on field observations made on the Horzum Turtleback of the Alaşehir graben, western Turkey. Three essential features have been determined as forming a turtleback surface. These are 1) the rolling hinge mechanism on a normal fault system, where the initial fault stays operational after forming second and third normal faults in its hanging wall; 2) relay ramps between initial fault segments; and 3) a synextensional intrusion on the shear zone of the initial normal …
Alteration Mineral Mapping With Aster Data By Integration Of Coded Spectral Ratio Imaging And Som Neural Network Model, Mohammad Hassan Tayebi, Majid Hashemi Tangestani, Robert Keller Vincent
Alteration Mineral Mapping With Aster Data By Integration Of Coded Spectral Ratio Imaging And Som Neural Network Model, Mohammad Hassan Tayebi, Majid Hashemi Tangestani, Robert Keller Vincent
Turkish Journal of Earth Sciences
This study applied coded spectral ratio imaging and a self-organizing map (SOM) neural network model for subpixel classification of Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data to map alteration minerals of the Masahim volcano, SE Iran. Spectra of samples were measured using a FieldSpec spectroradiometer, and were interpreted for finding key alteration minerals. Key minerals including sericite and kaolinite were selected. Thirty-six nonreciprocal spectral ratios of 9 ASTER reflective bands were created. Each spectral parameter (of 9 spectral bands and 36 spectral ratios) for the field and library mineral spectra was divided into deciles. Each decile of spectral …
Testing Of The Recently Developed Tectonomagmatic Discrimination Diagrams From Hydrothermally Altered Igneous Rocks Of 7 Geothermal Fields, Kailasa Pandarinath
Testing Of The Recently Developed Tectonomagmatic Discrimination Diagrams From Hydrothermally Altered Igneous Rocks Of 7 Geothermal Fields, Kailasa Pandarinath
Turkish Journal of Earth Sciences
Recently developed multidimensional tectonomagmatic discrimination diagrams based on log-ratio variables of chemical elements, discordant outlier-free databases, and probability-based boundaries have been shown to work better than the earlier diagrams. Hydrothermally altered drilled well rock cuttings obtained from different depths of geothermal fields were used to test these diagrams to compare the inferred tectonic setting with the expected one. In spite of the hydrothermal alteration effects, these diagrams provided the following expected tectonic settings: (1) an arc setting for Ahuachapán and Berlin geothermal fields, El Salvador; (2) a rift setting for Cerro Prieto geothermal field, Mexico, and Tendaho geothermal field, Afar …
Oscillation Of Second Order Differential Equations With Mixed Nonlinearities, Zhiting Xu, Aijun Cheng
Oscillation Of Second Order Differential Equations With Mixed Nonlinearities, Zhiting Xu, Aijun Cheng
Turkish Journal of Mathematics
By refining the standard integral averaging technique, in this paper, new oscillation criteria as well as interval oscillation criteria are established for the second order delay differential equation with mixed nonlinearities \begin{equation*} (r(t) x^{\prime}(t) ^{\alpha-1}x^{\prime}(t))^{\prime}+q_0(t) x(\tau_0(t)) ^{\alpha-1}x(\tau_0(t)) +\sum\limits_{i = 1}^nq_i(t) x(\tau_i(t)) ^{\alpha_i-1}x(\tau_i(t)) = 0, \end{equation*} where \alpha>0, \alpha_i>0, i = 1,2,\cdots,n. Our results generalize and improve the known results in the literature. Examples are also given to illustrate the importance of our results.
Azolylimidazoles: Synthetic Strategies And Medicinal Applications, Bakr Fathy Abdelwahab, Rizk Elsayed Khidre
Azolylimidazoles: Synthetic Strategies And Medicinal Applications, Bakr Fathy Abdelwahab, Rizk Elsayed Khidre
Turkish Journal of Chemistry
The current review summarizes the known routes to different azoles linked directly to imidazole. This review is divided into classes based on the type of azoles connected to an imidazole ring. Some medical applications are mentioned.
Hard Chromium Electrodeposition From A Trivalent Chromium Bath Containing Water-Soluble Polymer, Vyacheslav Protsenko, Viktor Gordiienko, Tatiana Butyrina, Elena Vasileva, Felix Danilov
Hard Chromium Electrodeposition From A Trivalent Chromium Bath Containing Water-Soluble Polymer, Vyacheslav Protsenko, Viktor Gordiienko, Tatiana Butyrina, Elena Vasileva, Felix Danilov
Turkish Journal of Chemistry
The effect of polyvinylpyrrolidones (PVPs) with different molecular weights as polymeric additives to a sulfate trivalent chromium bath was ascertained. Introduction of PVPs to the plating bath was stated to result in improvement in the surface appearance of chromium deposits and stabilization of current efficiency value in long-term electrolysis. The rate of metal deposition is practically independent of the deposition time. Thus, using PVP additive allows one to obtain high-quality Cr-coatings with a thickness of several tens of micrometers. It is found by means of turbidimetric analysis that the polymer additive has an accelerating effect on the aggregation of particles …
Synthesis, Spectral, And Thermoanalytical Studies On The New Heterobimetallic [Mg(Ii)-Ti(Iv)]-\Mu-Oxoisopropoxide And Its \Beta-Diketonates, Rajesh Kumar
Turkish Journal of Chemistry
The new heterobimetallic [Mg(II)-Ti(IV)]-\mu-oxoisopropoxide was synthesized on treatment of magnesium acetate with titanium(IV) isopropoxide in refluxing decalin in 1:2 molar ratio and characterized by liberated isopropanol, elemental, spectral (IR, ^1H and ^{13}C NMR, and mass), thermal analysis, and molecular weight data. The reactions of [Mg(II)-Ti(IV)]-\mu-oxoisopropoxide compound with \beta-diketones in different molar ratios (1:1--1:4) yielded mono to tetra derivatives [{MgO_2Ti_2(OPr^i)_{6-n}L_n}] (where n is 1--4 and L = acetylacetonate/benzoylacetonate anion)] of the \mu-oxo complex and were characterized by elemental, liberated isopropanol, and spectral analysis (IR and ^1H and ^{13}C NMR). These studies revealed interesting facets in support of plausible structures of the …
A New And Simple Dp Polarographic Method For The Determination Of Uric Acid In Serum After Elimination Of The Interference Of Ascorbic Acid And Dopamine, Ali̇ Cengi̇z Çalişkan, Güler Somer
A New And Simple Dp Polarographic Method For The Determination Of Uric Acid In Serum After Elimination Of The Interference Of Ascorbic Acid And Dopamine, Ali̇ Cengi̇z Çalişkan, Güler Somer
Turkish Journal of Chemistry
Determination of trace amounts of uric acid (UA) in serum is of great importance since its level in serum may show disorders in purine metabolism. With this method, trace amounts of UA in blood serum can be determined by a fast and simple procedure using differential pulse polarography (DPP). The limit of detection was estimated to be 2 \times 10^{-7} M (S/N = 3), lower than that given in previous studies. Among the many electrolytes studied, the best electrolyte condition was found to be 0.05 M phosphate buffer, pH 10--12, in 0.1 M KNO_3. The peak for UA appeared at …
Aryl Butenoic Acid Derivatives As A New Class Of Histone Deacetylase Inhibitors: Synthesis, In Vitro Evaluation, And Molecular Docking Studies, Peruze Ayhan Eşi̇yok, Özlem Seven, Gülüzar Eymur, Gamze Bora Tatar, Di̇dem Dayangaç Erden, Kemal Yelekçi̇, Hayat Yurter, Ayhan Sitki Demi̇r
Aryl Butenoic Acid Derivatives As A New Class Of Histone Deacetylase Inhibitors: Synthesis, In Vitro Evaluation, And Molecular Docking Studies, Peruze Ayhan Eşi̇yok, Özlem Seven, Gülüzar Eymur, Gamze Bora Tatar, Di̇dem Dayangaç Erden, Kemal Yelekçi̇, Hayat Yurter, Ayhan Sitki Demi̇r
Turkish Journal of Chemistry
New aryl butenoic acid derivatives have been synthesized by combining hydroxy- or methoxy-substituted phenyl rings as the capping group, with a double bond in the short linker as well as metal binding groups, enoic ester, and salts bearing either methyl or morpholine. These compounds have been shown to possess promising histone deacetylase inhibition activities via in vitro fluorometric assay and molecular docking studies.
Pw_{12}-Aptes@Mcf: Effective Nanosized Mesoporous Composites For The Oxidation Of Benzyl Alcohols, Razieh Fazaeli, Hamid Aliyan, Somaieh Parishani Foroushani, Zahra Mohagheghian
Pw_{12}-Aptes@Mcf: Effective Nanosized Mesoporous Composites For The Oxidation Of Benzyl Alcohols, Razieh Fazaeli, Hamid Aliyan, Somaieh Parishani Foroushani, Zahra Mohagheghian
Turkish Journal of Chemistry
The surface of mesocellular silica foam (MCF) was modified by grafting 3-aminopropyl-triethoxysilane (APTES) to have a positive charge, and thus to provide sites for the immobilization of H_3PW_{12}O_{40} (PW_{12}). This modified nanosized mesoporous silica (PW_{12}-APTES@MCF) was characterized by FTIR, XRD, BET, and TEM. XRD and adsorption--desorption analysis shows that the mesostructure of silica remains intact after various modifications, while the spectral technique shows the successful grafting of the neat PW_{12} inside the porous silica support. The oxidation of alcohols occurs effectively and selectively with H_2O_2 as the oxidant. PW_{12}-APTES@MCF was used as the catalyst. The catalyst can be reused several …
The Chemistry Concerned With The Sonochemical-Assisted Synthesis Of Ceo_2/Poly(Amic Acid) Nanocomposites, Shiva Yazdani, Mehdi Hatami, Seyed Mohammad Vahdat
The Chemistry Concerned With The Sonochemical-Assisted Synthesis Of Ceo_2/Poly(Amic Acid) Nanocomposites, Shiva Yazdani, Mehdi Hatami, Seyed Mohammad Vahdat
Turkish Journal of Chemistry
A series of new poly(amic acid) (PAA) surface-modified cerium oxide (CeO_2) nanocomposites were prepared by sonochemical-assisted method. In the first step, treatment of the surface of CeO_2 nanoparticles with hexadecyltrimethoxysilane as a surface modifier was achieved. In the second step, the partially surface-treated nanoparticles were incorporated into PAA by different weight from 4% to 12%. PAA was synthesized by polycondensation reaction of benzophenone tetracarboxylic dianhydride and 3,5-diamino-N-(4-hydroxyphenyl) benzamide in N-methyl-2-pyrrolidone. The chemical structure of PAA was confirmed by ^1H NMR and FTIR spectroscopy. The polymer had an inherent viscosity of 0.38 dL/g. Three PAA/CeO_2 nanocomposite formulations were prepared from the …
Deposition And Characterization Of Cu_9s_5 Nanocrystals From Unsymmetrical [(Hex)(Me)Nc(S)Nc(O)C_6h_3(No_2)_2-3,5]_2cu(Ii) And [(Et)(Bu)Nc(S)Nc(O)C_6h_4-4-No_2]_2cu(Ii) Complexes By Colloidal Thermolysis Method, Sohail Saeed, Rizwan Hussain
Deposition And Characterization Of Cu_9s_5 Nanocrystals From Unsymmetrical [(Hex)(Me)Nc(S)Nc(O)C_6h_3(No_2)_2-3,5]_2cu(Ii) And [(Et)(Bu)Nc(S)Nc(O)C_6h_4-4-No_2]_2cu(Ii) Complexes By Colloidal Thermolysis Method, Sohail Saeed, Rizwan Hussain
Turkish Journal of Chemistry
Cu_9S_5 nanocrystals were synthesized from unsymmetrical [(Hex)(Me)NC(S)NC(O)C_6H_3(NO_2)_2-3,5]_2Cu(II) and [(Et)(Bu)NC(S)NC(O)C_6H_4-4-NO_2]_2 Cu(II) complexes by colloidal thermolysis in the presence of surfactant oleylamine. The unsymmetrical copper complexes were synthesized by the reaction of copper(II) acetate with N-[hexyl(methyl)carbamothioyl]-3,5-dinitrobenzamide and N-[ethyl(butyl)carbamothioyl]-4-nitrobenzamide. The complexes were used as single-source precursors for the preparation of Cu_9S_5 nanocrsytals. The Cu_9S_5 nanocrystals were characterized by X-ray powder diffraction and transmission electron microscopy.