Physical Sciences and Mathematics Commons^™

Examining Denitrification In Agricultural Ditch Sediments Vegetated With Rice Cutgrass (Leersia Oryzoides): Modeling Seasonal Variation Across Increasing Levels Of Nitrate Loading And Model Application To Pre-Existing Datasets, Shannon Lee Speir

Graduate Theses and Dissertations

Nitrogen (N) derived from fertilizer application in agricultural systems may contribute to significant environmental impacts, including eutrophication of fresh and coastal waters. Rice cutgrass (Leersia oryzoides) can significantly enhance denitrification potential in agricultural ditch sediments, but relationships with known drivers are not well understood. To address this, I examined effects of nitrate (NO3-) availability on dinitrogen gas (N2) and NO3- fluxes seasonally in Chapter 2. Denitrification rates were measured as N2 flux from intact vegetated sediment cores using Membrane Inlet Mass Spectrometry (MIMS). Michaelis-Menten models were developed from observations to mathematically describe N2 fluxes across the spring, summer, and fall …

Automatic Assessment Of Environmental Hazards For Fall Prevention Using Smart-Cameras, Jeffrey Kutchka

Graduate Theses and Dissertations

As technology advances in the field of Computer Vision, new applications will emerge. One device that has emerged is the smart-camera, a camera attached to an embedded system that can perform routines a regular camera could not, such as object or event detection. In this thesis we describe a smart-camera system we designed, implemented, and evaluated for fall prevention monitoring of at-risk people while in bed, whether it be for a hospital patient, nursing home resident, or at home elderly resident. The camera will give a nurse or caregiver environmental awareness of the at-risk person and notify them when that …

Interactions In The Cpsrp Dependent Targeting Of Light Harvesting Chlorophyll Binding Protein To The Thylakoid Membrane, Rory Henderson

Graduate Theses and Dissertations

Targeting of proteins is a critical component of cellular function. A universally conserved targeting system of the cytosol utilizes a signal recognition particle (SRP) to target many proteins contranslationally to the endoplasmic reticulum in eukaryotes or the inner membrane in prokaryotes. A homologous SRP system exists in the chloroplast that delivers light harvesting chlorophyll binding proteins (LHCP) to they thylakoid membrane. The chloroplast SRP (cpSRP) is a heterodimer composed of a novel 43 kDa subunit and a 54 kDa subunit homologous to a component of the SRP system, SRP54. Many details regarding the interactions between the proteins of the cpSRP …

Soil Moduli Obtained From A Back Pressure Constant Rate Of Strain Bender Element Consolidation Apparatus, Yi Zhao

Graduate Theses and Dissertations

A back-pressure saturated, constant-rate-of-strain consolidation device was modified to incorporate bender elements (BP-CRS-BE) and thus allowed for shear wave measurements during consolidation tests. This newly fabricated system has many advantages over other previous or current devices: 1) it can be utilized not only for laboratory prepared soil samples but also for field sampled soils such as Shelby tube samples, and 2) continuous compression curves, and continuous values of vertical hydraulic conductivity and coefficient of consolidation can be acquired with a significant reduction in testing time. Soil modulus values such as shear modulus and constrained modulus are also able to be …

Sedimentary Petrology Of The Hartshorne Formation, Southeastern Arkoma Basin, Arkansas, Ruizhe Yin

Graduate Theses and Dissertations

The Pennsylvanian Hartshorne Sandstone crops out in an east trending belt across central Arkansas immediately north of the Ouachita orogenic belt and south of the Boston Mountains. The unit, composed of massive to cross bedded sandstone ranging to 150m in thickness, was deposited by a west-flowing river system that extended from central Arkansas to southeastern Oklahoma. The source of the sediment has been extensively discussed but not completely established. The object of this thesis is to constrain the source area and terrain based on thin section mineralogy and texture. Thin sections were prepared from outcrops in the Arkoma Basin and …

How To Collect Your Water Sample And Interpret The Results For The Fish Pond Analytical Package, Bradley J. Austin, Amit Sinha, Nathan Stone, W. Reed Green, Mike Daniels, Brian E. Haggard

Fact Sheets

The Arkansas Water Resources Center (AWRC) in cooperation with the Cooperative Extension Service offers several analytical packages to assess the quality of your water resources. This document is intended to provide guidance to aquaculture producers and pond owners on the “Fish Pond Report” provided by the AWRC’s water quality laboratory. The information contained within this fact sheet should be used as general guidance, and the reader is encouraged to seek advice from Extension specialists regarding the interpretation of individual reports and water testing results that may be of concern. The Aquaculture Center for Excellence is at the University of Arkansas …

How To Collect Your Water Sample And Interpret The Results For The Livestock Analytical Package, Bradley J. Austin, Dirk Philipp, Mike Daniels, Brian E. Haggard

Fact Sheets

A plentiful supply of clean water is crucial for livestock health and productivity. To determine the quality of your livestock’s water resources, periodic sampling and analysis is needed. The Arkansas Water Resources Center (AWRC) in cooperation with the UA Cooperative Extension Service offers several analytical packages to assess the quality of your water resources. This document is intended to provide guidance to livestock owners on collecting water samples for analysis and understanding the results on your report provided by the AWRC’s Water Quality Laboratory (Lab). The information contained within this fact sheet should be used as general guidance, and the …

Water Quality Reporting Limits, Method Detection Limits, And Censored Values: What Does It All Mean?, Bradley J. Austin, J. Thad Scott, Mike Daniels, Brian E. Haggard

Fact Sheets

The Arkansas Water Resources Center (AWRC) maintains a fee-based water-quality lab that is certified by the Arkansas Department of Environmental Quality (ADEQ). The AWRC Water Quality Lab analyzes water samples for a variety of constituents, using standard methods for the analysis of water samples (APHA 2012). The lab generates a report on the analysis, which is provided to clientele, and reports the concentrations or values as measured. Often times the concentrations or values might be very small, even zero as reported by the lab – what does this mean? How should we use this information? This document is intended to …

Beaver Lake Numeric Chlorophyll-A And Secchi Transparency Standards, Phases Ii And Iii: Uncertainty And Trend Analysis, J. Thad Scott, Brian E. Haggard, Zachary Simpson, Matthew Rich

Technical Reports

The objective of Phases II and III of this study were to 1) assess the variation in chl‐a and ST across multiple spatial and temporal scales in Beaver Lake in order to validate the assessment method, and 2) quantify trends in chl‐a, ST, and nutrient (total phosphorus and total nitrogen) concentrations in Beaver Lake and the major inflowing rivers to verify any potential water quality impairment.

Database Analysis To Support Nutrient Criteria Development (Phase I), B. E. Haggard, J.T. Scott, M.A. Evans-White

Technical Reports

The intent of this publication of the Arkansas Water Resources Center is to provide a location whereby a final report on water research to a funding agency can be archived. The Texas Commission on Environmental Quality (TCEQ) contracted with University of Arkansas researchers for a multiple year project titled “Database Analysis to Support Nutrient Criteria Development”. This publication covers the first of three phases of that project and has maintained the original format of the report as submitted to TCEQ. This report can be cited either as an AWRC publication (see below) or directly as the final report to TCEQ.

Database Analysis To Support Nutrient Criteria Development (Phase Iii), J. T. Scott, E.M. Grantz

Technical Reports

The intent of this publication of the Arkansas Water Resources Center is to provide a location whereby a final report on water research to a funding agency can be archived. The Texas Commission on Environmental Quality (TCEQ) contracted with University of Arkansas researchers for a multiple year project titled “Database Analysis to Support Nutrient Criteria Development”. This publication covers the third of three phases of that project and has maintained the original format of the report as submitted to TCEQ. This report can be cited either as an AWRC publication (see below) or directly as the final report to TCEQ.

Database Analysis To Support Nutrient Criteria Development (Phase Ii), B. E. Haggard, M.A. Evans-White, L.B. Massey, E.M. Grantz

Technical Reports

The intent of this publication of the Arkansas Water Resources Center is to provide a location whereby a final report on water research to a funding agency can be archived. The Texas Commission on Environmental Quality (TCEQ) contracted with University of Arkansas researchers for a multiple year project titled “Database Analysis to Support Nutrient Criteria Development”. This publication covers the second of three phases of that project and has maintained the original format of the report as submitted to TCEQ. This report can be cited either as an AWRC publication (see below) or directly as the final report to TCEQ.

Validation Of N-Star Nitrogen Rate Recommendations And Evaluation Of N-Star Soil Sampling Procedures For Clay Soils In Arkansas, Jarom Thane Davidson

Graduate Theses and Dissertations

The two methods for determining N-fertilizer recommendations for rice (Oryza sativa L.) in Arkansas are the standard N recommendation (SR) based on soil texture, previous crop, and rice cultivar, and the Nitrogen-Soil Test for Rice (N-STaR) which quantifies the potentially mineralizable-N of the soil and provides a site-specific N recommendation. The N-STaR program has recently been developed, and the validation of N-STaR for clay soils is an important step in ensuring that N-STaR predicts correct N-fertilizer rates for rice under a delayed-flood production system. Small-plot trials located across Arkansas compared the N-STaR 95 and 100% relative grain yield (RGY) N …

Stream Microbial Communities As Potential Indicators Of River And Landscape Disturbance In North-Central Arkansas, Wilson Howard Johnson

Graduate Theses and Dissertations

In the past decade, 29 shale basins have been actively developed across 20 states for extraction of natural gas (NG) via horizontal drilling/hydraulic fracturing (=fracking). This includes ~5000 wells within the Fayetteville shale of north-central Arkansas. Development often impacts both river- and landscapes, and management requires catchment-level evaluations over time, with organismal presence/absence as indicators. For this study next-generation sequencing was used to identify/characterize microbial communities within biofilm of eight Arkansas River tributaries, so as to gauge potential catchment influences. Streams spanned a gradient of landscape features and hydrological flows, with four serving as ‘potentially impacted catchment zones’ (PICZ) and …

Lidar-Assisted Extraction Of Old Growth Baldcypress Stands Along The Black River Of North Carolina, Weston Pierce Murch

Graduate Theses and Dissertations

The remnants of ancient baldcypress forests continue to grow across the Southeastern United States. These long lived trees are invaluable for biodiversity along riverine ecosystems, provide habitat to a myriad of animal species, and augment the proxy climate record for North America. While extensive logging of the areas along the Black River in North Carolina has mostly decimated ancient forests of many species including the baldcypress, conservation efforts from The Nature Conservancy and other partners are under way. In order to more efficiently find and study these enduring stands of baldcypress, some of which are estimated to be more than …

Optical Water Quality And Human Perceptions Of Rivers, Amie West

Graduate Theses and Dissertations

Understanding water quality dynamics in recreational rivers is integral in shaping management strategies that maintain ecosystem health, perceived value and appeal, and regional economic significance in a changing environment. Optical water quality describes the behavior of light in water as governed by its physical and chemical composition, and is among the strongest influences on human perceptions of water quality. Ethnohydrology is the study of culturally constructed knowledge and understanding of water. This work is the culmination of an interdisciplinary approach to water resources research—integrating optical water quality and ethnohydrology methods to recognize the intersection between measured water quality and visible …

Chlorine Demand Shows Thresholds And Hierarchy With Source Water Quality At Beaver Lake, Arkansas, Jaime M. Gile

Graduate Theses and Dissertations

This study investigated the effects of source water quality in Beaver Lake on the amount of chlorine (Cl) needed to develop decision support system to help guide chlorination practices in pre-treatment of source water. Chlorine demand assays were performed on water samples from Beaver Lake collected from the intake structure at Beaver Water District from March 2014 through August 2015, and using data from these assays, the two points of interest in this study were the Cl dose at which Cl residuals began to accumulate and the mean Cl demand occurring after that dose. Three methods of analysis were used …

Agro-Climatic Change, Crop Production And Mitigation Strategies-Case Studies In Arkansas, Usa And Kenya, John Westley Magugu

Graduate Theses and Dissertations

Although climate change impacts vary geographically and temporally, studies at local levels are not readily available for stakeholders to better understand how their local communities would be affected and what remedial measures could be more effective in their local contexts. This dissertation has examined climate change and its impacts in two different local contexts: eastern Arkansas in the USA and Nyando in Kenya. The first part of this dissertation develops agro-meteorological indicators and examines the relationship between agro-meteorological indicators and crop yields in eastern Arkansas between 1960 and 2014. Results reveal that temperature based indicators were more strongly correlated to …

Trend Analysis Of Water Quality In Northwest Arkansas Streams Reflects Changes In The Watershed, Zachary Paul Simpson

Graduate Theses and Dissertations

Watershed export of nutrients, sediments, and chemicals impacts receiving waters. Changes within the watershed (e.g., anthropogenic or climatic) can alter the transport of constituents in streams. Stream monitoring is crucial for understanding these effects. This study developed a potential improvement to flow-adjusting constituent concentrations in streams, an important step of analyzing monitoring data in lotic systems for trends. The method incorporates a K-fold cross-validation procedure to optimize a model explaining the relationship between the concentration and streamflow, thus providing a valuable tool to researchers in water quality. Additionally, two case studies were conducted on watersheds located in northwest Arkansas using …

Stratigraphy And Structure Of A South-Trending Structural High, Northern Arkoma Basin, Arkansas, Yirong Chen

Graduate Theses and Dissertations

The Arkoma Basin is a Carboniferous peripheral foreland basin in southeastern Oklahoma and west-central Arkansas. The formation of the Arkoma Basin is a result of a collision between the North American Plate and the Sabine Terrane. To the north of the basin, there is a structural high that extends southward from the Arkoma Shelf into the basin. This structure is in contrast with the prevailing east-trending strike of structures in the northern margin of the basin and is poorly defined. This paper examined the structure of the salient with stratigraphic and structural cross sections. Across the study area, two NS …

Eucalyptus In Kenya; Impacts On Environment And Society, Brandy M. Garrett Kluthe

Graduate Theses and Dissertations

Eucalyptus trees were introduced to Kenya a little over a century ago. European colonization along with the development of a railway system increased the demand for a fast growing wood source. The expansion of the tree across the fertile lands in Kenya raises concerns about the environmental impact on ecosystems where it has been introduced. These concerns include degraded soils, loss of water resources, co-introduction of ectomycorrhizal species, and allelopathy. Economic benefits to local landowners were also explored as well as the potential for large Eucalyptus woodlots to maximize the sequestration of CO₂ from the atmosphere. This was examined through …

Experimental Simulations Of Recurring Slope Lineae And Other Flow Formation Features On Mars, Julia Ann Heydenreich

Graduate Theses and Dissertations

Various flow formation features from gullies to recurring slope lineae (RSL) have been identified across the martian surface. The formation of these geologic features are still being determined. Recently, several aspects of these flow features indicate that salt water flows in the subsurface during the warmer months when the ice melts. This paper explores the formation of these processes using laboratory experimental simulations. Experiments were conducted in a wooden flume under varying martian conditions of temperature, slope angle, regolith simulant and a liquid subsurface flow. By adjusting the flume at specific heights, several slopes were obtained to mimic the slopes …

Two Studies: Stereoselective C-C Bond Formations Of N-Boc-Piperidines Using Selected Organolithiums And Visible-Light-Mediated Synthesis Of Fused Indolines Using Tethered Styrenes, Scott Alan Morris

Graduate Theses and Dissertations

Chemists worldwide have accepted the challenge of developing methods to access a variety of compounds as single enantiomers, including the use of enzymes, chiral auxiliaries, and resolutions. In particular, dynamic resolutions offer a unique way to access chiral compounds using a few controllable steps, including the variation of both time and temperature. Many groups have implemented this methodology to generate various polysubstituted pyrrolidines and piperidines, which are substructures ranking high on the list of nitrogen–containing pharmaceuticals.

The Gawley group revealed a catalytic dynamic resolution (CDR) of N–Boc–piperidine using a chiral ligand. Impressively, the chemistry was tolerant of a variety of …

[3+2] Annulation Of Cyclopropylanilines With Alkynes Under Photocatalysis, Theresa Ha Nguyen

Graduate Theses and Dissertations

Over the past decade, pharmaceutical industries have prioritized their focus on discovering new innovative drugs, yet the syntheses are often either inefficient or the approach of environmental sustainability presents a great deal of concern. Moreover, the methodology developments for amine syntheses have continued to flourish due to their important role and wide use in pharmaceutics. Yet their syntheses often lack sustainability and efficiency. Synthetic chemists have continued to explore potential innovative avenues for conducting chemical reactions more effectively and efficiently. One of the most abundant, renewable natural resources is solar energy and to harvest, use, and store it directly is …

Evaluating A Measure-Calculate Method For Determining Sediment Oxygen Demand In Lakes, Adrian Beirise

Graduate Theses and Dissertations

A steady-state mass diffusion model used with simple measurable and calculable inputs for determining sediment oxygen demand (SOD) is compared to an intact core incubation (ICI) SOD method using samples from three lakes. The mass diffusion model coupled with inputs is known as the measure-calculate method (M-C) and is a potential alternative to existing methods for measuring SOD which are more complex, time-consuming, and costly. The M-C method requires inputs for volumetric sediment oxygen uptake (Ṅsed), sediment density and porosity, and water properties. Ṅsed was determined by suspending sediment in oxygen-saturated water with a DO probe and determining the steady …

Electricity Generation, Electricity Consumption, And Energy Efficiency In The United States: A Dual Climatic-Behavioral Approach, Christopher A. Craig

Graduate Theses and Dissertations

Much of the United States (US) has seen an increase in warm days, decrease in cool days, and increase in extreme weather events. These trends are projected to continue across much of the US and in turn increase the demand for electricity and subsequent greenhouse gas emissions. Ambitious energy efficiency (EE) programs are used across the US by energy utility organizations to reduce electricity demand and emissions. This study examined the impact of climatic variability on electricity consumption, as well as how pro-conservation interventions such as EE programs and experiential learning can be utilized to mitigate residential electricity consumption and …

On Compactness And Closed-Rangeness Of Composition Operators, Arnab Dutta

Graduate Theses and Dissertations

Let $\phi$ be an analytic self-map of the unit disk $\mathbb{D}:=\{z:\lvert z\rvert

Study Of Plasmonic Properties Of The Gold Nanorods In The Visible To Near Infrared Light Regime, Pijush Kanti Ghosh

Graduate Theses and Dissertations

Nanostructures of noble metals show unique plasmonic behavior in the visible to near-infrared light range. Gold nanostructures exhibit a particularly strong plasmonic response for these wavelengths of light. In this study we have investigated optical enhancement and absorption of gold nanorods with different thickness using finite element method simulations. This study reports on the resonance wavelength of the sharp-corner and round-corner rectangles of constant length 100 nm and width 60 nm. The result shows that resonance wavelength depends on the polarization of the incident light; there also exists a strong dependence of the optical enhancement and absorption on the thickness …

Electrodeionization Versus Electrodialysis: A Clean-Up Of Produced Water In Hydraulic Fracturing, Brigitte Marie Rodgers

Graduate Theses and Dissertations

Electrodeionization (EDI) is a widely studied process ranging from applications in wastewater clean-up in the food and beverage industry to purifying organic compounds. To date, there are no apparent studies on applying this technology to produced wastewater recovered from hydraulic fracking sites. Water consumption within hydraulic fracturing sites can reach in the upwards of millions of gallons per site, so a need for a water recycling process becomes necessary within areas where water requirements are scarce. Implementation of an EDI module that is capable of handling high salt solutions from produced wastewater in subsequent fracturing practices will decrease overall water …

The Large-Scale Synthesis And Asymmetric Hydrosilylations Of Cuiphet, A C2-Symmetric N-Heterocyclic Carbene, Elizabeth Suzanne Spahn

Graduate Theses and Dissertations

CuIPhEt is a C2-symmetric N-heterocyclic carbene catalyst used in the asymmetric hydrosilylation of a variety of prochiral ketones with good yields and selectivities. The large-scale, five-step synthesis of this carbene has been devised. The second step of the synthetic plan includes a double asymmetric hydrogenation of a 1,1-diaryl alkene—a traditionally difficult transformation. The procedure for the use of CuIPhEt in asymmetric hydrosilylations has been optimized and used on both the originally published substrate scope and new compounds. This protocol for the hydrosilylation has been applied in a 10 g reduction to create an intermediate for use toward the total synthesis …