Physical Sciences and Mathematics Commons^™

Bond Length And Bond Valence Relationships For Chromium Oxides, Chromium Sulfides, Molybdenum Oxides, And Molybdenum Sulfides, J. Labrecque, F. D. Hardcastle

Journal of the Arkansas Academy of Science

Pauling determined an empirical logarithmic dependence of bond order (bond valence), s, to bond length, R, s = exp(R₀ – R/ b), where R₀ is unit bond length and b is a fitting parameter. Recently, an expression was derived for relating the b fitting parameter to theoretically derived atomic orbital exponents. With a method to calculate b, both R₀ and atomic orbital exponents can be experimentally determined through optimized fitting for Cr-O, Cr-S, Mo-O, and Mo-S. In the present study, bond length – valence relationships are found for Cr-O, Cr-S, Mo-O, and Mo-S chemical …

Simulating Foodborne Pathogens In Poultry Production And Processing To Defend Against Intentional Contamination, S. Lankford, D. R. Thompson, S. C. Ricke

Journal of the Arkansas Academy of Science

There is a lack of data in recent history of food terrorism attacks, and as such, it is difficult to predict its impact. The food supply industry is one of the most vulnerable industries for terrorist threats while the poultry industry is one of the largest food industries in the United States. A small food terrorism attack against a single poultry processing center has the potential to affect a much larger human population than its immediate consumers. In this work, the spread of foodborne pathogens is simulated in a poultry production and processing system to defend against intentional contamination. An …

How Do Designers Of The Built Environment Attempt To Make Ecological Sustainability Sensory Legible?, Carly L. Bartow

Architecture Undergraduate Honors Theses

This paper attempts to provide a theoretical framework for making ecosystem function and ecologically sustainable design more perceptible or sensible to people through architecture and the built environment. Design features of the Bertschi School Science Wing and the Bullitt Center in Seattle, Washington are incorporated to illustrate the sensory legibility of ecological sustainability criteria.The criteria are available to designers to help educate a building's occupants on environmentally sustainable design and motivate more sustainable behavior.

Growth Of Methanogens In The Presence Of Perchlorate Salts: A Study For Possible Life On Mars, John Cale

Biological Sciences Undergraduate Honors Theses

The Phoenix Lander collected soil samples from Mars, and it detected perchlorate salts in its analysis [1]. As oxidizing agents, perchlorates pose a threat to the hypothesis that there may be microbial life on Mars. Since Mars is very dry, perchlorate may continue to accumulate in the soil. If anaerobic methanogens inhabit Mars, then they must be able to grow in the presence of perchlorate salts. There were four species of methanogens tested in this project. The methanogens were first exposed to small concentrations of calcium perchlorate, and then they were gradually tested at higher concentrations. Growth was measured by …

Cryogenic Viscous Liquids On Icy Moons, Danielle Neighbour

Civil Engineering Undergraduate Honors Theses

The study of cryogenically viscous liquids such as methane and ethane offers critical insight into the behavior of fluids on icy moons such as Saturn’s moon Titan. Shrouded by a hazy hydrocarbon shield, Titan’s significant nitrogen atmosphere of 1.5 bar, methane-driven hydrological cycle, and lakes and rivers are vaguely similar to our Earthly home. The European-created Huygens probe, carried by the Cassini spacecraft, arrived on Titan’s surface in January 2005 [1]. Upon landing, Huygens photographed its landing site, as seen in Figure 1. The photo depicts rock like objects, thought to be comprised of water ice sitting in a dry …

Surface Water Infiltration In Loess Soils Of The Lower Mississippi River Valley: An Emphasis On Land Use, Matthew Thompson

Crop, Soil and Environmental Sciences Undergraduate Honors Theses

The Alluvial Aquifer is the shallowest and most heavily used groundwater aquifer in the Lower Mississippi River Valley, particularly in the Delta region of eastern Arkansas. However, the Alluvial Aquifer is being depleted faster than the rate of recharge, primarily due to excessive withdrawals for irrigated crop production. Since extensive irrigation in the highly agriculturally productive Delta region of eastern Arkansas has been a main culprit in the groundwater depletion issues the region faces, a better understanding of how ecological factors and/or agricultural best management practices could possibly increase infiltration, to consequently increase recharge, are needed in order to either …

Artificial Quantum Many-Body States In Complex Oxide Heterostructures At Two-Dimensional Limit, Xiaoran Liu

Graduate Theses and Dissertations

As the representative family of complex oxides, transition metal oxides, where the lattice,

charge, orbital and spin degrees of freedom are tightly coupled, have been at the forefront

of condensed matter physics for decades. With the advancement of state-of-the-art heteroepitaxial deposition techniques, it has been recognized that combining these oxides on the atomic scale, the interfacial region offers great opportunities to discover emergent phenomena and tune materials' functionality. However, there still lacks general guiding principles for experimentalists, following which one can design and fabricate artificial systems on demand. The main theme of this dissertation is to devise and propose some …

Gastrointestinal Health As A Stimulus For Native American Attraction To Medicinal Asteraceae And Further Implications For Human Evolution, Christopher David Stiegler

Graduate Theses and Dissertations

The Asteraceae, or the daisy family, is the largest family of flowering plants in the world, and its ethnobotanical, medical, and economic value is readily apparent cross-culturally. The aim of this thesis is to examine why constituent genera of the Aster family have remained such an integral part of human medicinal plant knowledge, and thereby to reveal any potential physiological, biological, or evolutionary mechanisms underlining human patterns of use regarding the Asteraceae. The present study focuses specifically on Native American plant knowledge made available by the expansive database in the works Daniel Moerman (Moerman 2003). Frequencies of plant use and …

Effects Of Mars Regolith Analogs, Uvc Radiation, Temperature, Pressure, And Ph On The Growth And Survivability Of Methanogenic Archaea And Stable Carbon Isotope Fractionation: Implications For Surface And Subsurface Life On Mars, Navita Sinha

Graduate Theses and Dissertations

Mars is one of the suitable bodies in our solar system that can accommodate extraterrestrial life. The detection of plumes of methane in the Martian atmosphere, geochemical evidence, indication of flow of intermittent liquid water on the Martian surface, and geomorphologies of Mars have bolstered the plausibility of finding extant or evidence of extinct life on its surface and/or subsurface. However, contemporary Mars has been considered as an inhospitable planet for several reasons, such as low atmospheric surface pressure, low surface temperature, and intense DNA damaging radiation. Despite the hostile conditions of Mars, a few strains of methanogenic archaea have …

Stratigraphy And Depositional Environment Of The Middle Atoka Formation, Central Arkoma Basin, Western Arkansas, Yueyang Wang

Graduate Theses and Dissertations

Wire line logs are widely used in analysis of the subsurface stratigraphy of the middle Atoka Formation, Central Arkoma Basin, Western Arkansas. SP log, Gamma ray log, resistivity log and conductivity log provide valuable information to construct cross sections.

The middle Atoka formation is composed of a succession of shale and sandstone alternations with thickness reaching approximately 3000 feet in the study area. It contains several sandstone units which include Morris, Tackett, Areci, Bynum, Casey and Dunn”A” separated by shale intervals. The purpose of this study is to identify these units and predict sequence stratigraphy and depositional environment by constructing …

Soil And Plant Property Differences Among High-Yield Soybean Areas In Arkansas, Taylor Cass Adams

Graduate Theses and Dissertations

Continued achievement of soybean [Glycine max (L.) Merr.] yields greater than 6719 kg ha-1 (100 bu ac-1) will depend on decreasing the yield gap, which is contingent on gathering more information regarding the soil physical, chemical, and microbiological environment and the main plant factors contributing to high-yield soybean. Therefore, understanding the main factor differences between high- and average-yield areas may provide insight for making management decisions to increase yields. The objectives of this study were i) to evaluate the effects of region and soil depth on soil property differences between high- and average-soybean-yielding areas, ii) to determine which soil properties …

Temporal Co2 Variations And The Influence Of Bat Colonies In Speleogenesis: Continuous Co2 Monitoring In War Eagle Cavern, Arkansas, Ginny Sue Holcomb

Graduate Theses and Dissertations

Dissolved concentrations of CO2 in a karst aquifer are a major control on calcite dissolutional processes, as CO2 combines chemically with water to form carbonic acid. As increasing amounts of CO2 are added to the system, greater resultant water aggressivity generates greater rates of dissolution. Spatial and temporal variations in carbon flux through the system may occur over a range of time scales, and high-resolution data collection is needed to truly understand and characterize such variability. Continuous CO2 monitoring in War Eagle Cavern, Arkansas, will suggest a number of influential parameters with varying degrees of importance throughout an annual cycle. …

Migration Ecology Of American Woodcock (Scolopax Minor), Joseph Daniel Moore

Graduate Theses and Dissertations

Improving the understanding of American woodcock (Scolopax minor) migration ecology has been identified as a priority information need for woodcock management. Developments in remote tracking technology and analytical techniques present an opportunity to gain insight into woodcock migratory connectivity and migration phenology and to evaluate the degree in which the current two-region (Eastern and Central) basis for woodcock management represents migratory movements. To analyze woodcock migration using band return records, I excluded observations that took place during the migratory period. Using this dataset, 17.9% of records showed crossover between management regions, higher than the < 5% crossover found in studies including non-migratory band returns. During autumn migration, woodcock from the Central Region largely migrated to destinations within the Central Region, whereas woodcock from the Eastern Region migrated to destinations across their wintering range, mixing with individuals from the Central Region. Between 2013 and 2016, I deployed 75 satellite transmitters on woodcock. I tracked the migration paths of 61 woodcock and documented 88 woodcock migrations. Average migration duration was longer during spring migration (53 days) than during autumn migration (31 days) because woodcock made a higher number of close-together migratory stopovers, not because woodcock stayed at individual stopovers longer during spring migration. Woodcock captured in the Central Management Region used 2 primary migrations routes: a Western Route and a Central Route. The Western Route ran north-south, connecting the breeding and wintering grounds of the Central Management Region. The hourglass-shaped Central Route connected an area on the wintering grounds reaching from Texas to Florida, to sites throughout northeastern North America. Woodcock following the Central Route funneled between the Appalachian Mountains and the Mississippi Alluvial Valley in western Tennessee during both autumn and spring migration. A higher than anticipated percentage (36%, n = 12) of marked woodcock captured in Texas and Louisiana and monitored during spring migration migrated to breeding-period sites in the Eastern Management Region, raising questions about the biological basis of managing woodcock as separate populations. The supplementary material includes woodcock capture information (Appendix I), information on individual stopovers (Appendix II), and migration maps for individual woodcock (Appendix III).

Monte Carlo Methods In Bayesian Inference: Theory, Methods And Applications, Huarui Zhang

Graduate Theses and Dissertations

Monte Carlo methods are becoming more and more popular in statistics due to the fast development of efficient computing technologies. One of the major beneficiaries of this advent is the field of Bayesian inference. The aim of this thesis is two-fold: (i) to explain the theory justifying the validity of the simulation-based schemes in a Bayesian setting (why they should work) and (ii) to apply them in several different types of data analysis that a statistician has to routinely encounter. In Chapter 1, I introduce key concepts in Bayesian statistics. Then we discuss Monte Carlo Simulation methods in detail. Our …

Role Of The Inner Shell Architecture On The Various Blinking States And Decay Dynamics Of Core-Shell And Core-Multishell Quantum Dots, Pooja Bajwa

Graduate Theses and Dissertations

Colloidal semiconductor nanocrystals (quantum dots, QDs) have received much attention in recent years due to their uniquely size-tunable properties leading to a number of promising applications. Some of their most popular applications include their use as fluorescent probes in biology, as electro-optical components and in photovoltaic devices. CdSe-based QDs are particularly important because of their ease of synthesis, high photoluminescence quantum yields (PL QYs) across the whole visible spectrum and their photostabilty. Shelling of core QDs is usually carried out to improve their optical properties, minimize outer environmental effects on their properties, and avoid toxic element exposure to the environment. …

Fabrication Of Infrared Photodetectors Utilizing Lead Selenide Nanocrystals, Justin Anthony Hill

Graduate Theses and Dissertations

Colloidal lead selenide and lead selenide / lead sulfide core/shell nanocrystals were grown using a wet chemical synthesis procedure. Absorbance and photoluminescence measurements were made to verify the quality of the produced nanocrystals. Absorbance spectra were measured at room temperature, while photoluminescence spectra were measured at 77 K. Organic ligands were exchanged for shorter ligands in order to increase the conductivity of the nanocrystals. Absorption and PL spectra for both core and core/shell nanocrystals were compared. Interdigital photodetector devices with varying channel widths were fabricated by depositing gold onto a glass substrate. Lead selenide nanocrystals were deposited onto these metallic …

Willingness To Pay For Irrigation Water Under Scarcity Conditions, Tyler Robert Knapp

Graduate Theses and Dissertations

Reliance of Arkansas agricultural producers on groundwater for irrigation has led to depletion of the Mississippi River Valley alluvial aquifer. Without intervention, consequences include insufficient groundwater to meet irrigation demand as well as drawdown of the deeper Sparta Aquifer, upon which communities in eastern Arkansas rely for non-agricultural use. Among proposed solutions to combat groundwater decline is the construction of off-farm surface water infrastructure to meet the irrigation needs of producers. Despite the importance of irrigated agriculture to Arkansas, there is little know about the economic value of irrigation water to producers. Thus, we implement a double-bounded dichotomous choice contingent …

Just In Time Assembly (Jita) - A Run Time Interpretation Approach For Achieving Productivity Of Creating Custom Accelerators In Fpgas, Sen Ma

Graduate Theses and Dissertations

The reconfigurable computing community has yet to be successful in allowing programmers to access FPGAs through traditional software development flows. Existing barriers that prevent programmers from using FPGAs include: 1) knowledge of hardware programming models, 2) the need to work within the vendor specific CAD tools and hardware synthesis. This thesis presents a series of published papers that explore different aspects of a new approach being developed to remove the barriers and enable programmers to compile accelerators on next generation reconfigurable manycore architectures. The approach is entitled Just In Time Assembly (JITA) of hardware accelerators. The approach has been defined …

Development Of A Pluto Chamber For Surface Simulations, Zachary Michael Mcmahon

Graduate Theses and Dissertations

In light of the exciting new discoveries being made by the New Horizons team, more data on Pluto is available than ever before. However, with the increase in recovered data, there is now a need for laboratory data to interpret it. Laboratory simulation of these conditions and subsequent testing of materials and samples therein is now possible and necessary to understand what has been observed. To do these simulations, a vessel that can achieve low temperatures and high vacuum is required. The scope of this work presented here was to design, build, and test a chamber that could perform these …

Discord And Global Discord In Systems Of Coupled Quantum Dots In Driven Cavities With Dissipation, And A Method For The Calculation Of Global Discord, Willa Danielle Rawlinson

Graduate Theses and Dissertations

In the field of quantum information, which is subdivided into quantum computing and quantum cryptography, quantum correlations are essential for a performance or security boost not achievable with classical means. Various quantum correlation measures exist for evaluating a state’s potential to be a qubit (quantum bit). Entanglement, or nonseparability of quantum states, is the older, better known class of measures. However, for a mixed state, quantum entanglement is an incomplete measure of quantumness. Quantum discord, and its multibody extension global discord, encompass all quantum correlations. We study systems of coupled quantum dots using these measures.

We study the discord of …

Measuring Nonlinear Properties Of Graphene Thin Films Using Z-Scan Technique, Thekrayat Hassan Al Abdulaal

Graduate Theses and Dissertations

The nonlinear studies of two-dimensional (2D) nanomaterials, specifically graphene, are very significant since graphene is finding its usefulness in handling the enormous heat in nanoscale high-density power electronics. Graphene has emerged to be a promising nanomaterial as an excellent heat spreader due to its high thermal conductivity. However, the experimental nonlinear study of graphene materials and their application in developing future optoelectronic devices demands for more developed research.

The research objective is first to build a precise, and sensitive technique to investigate and understand the thermal nonlinear properties, including nonlinear refractive index (n2), nonlinear absorption coefficient (β), and thermo-optic coefficient …

A Study Of Short-Season Winter Cover Crops For Organic High Tunnel Production Systems, Luke Riley Freeman

Graduate Theses and Dissertations

This two-year study investigated short-season winter cover crops to improve soil quality and growth of subsequent vegetable crops in an organic high tunnel production system. Five winter cover crop treatments including a nontreated control, Austrian winter peas (Pisum arvense), bell beans (Vicia faba), mustard (Brassica juncea cv. Kodiak), and Daikon radish (Raphanus sativus var. longipinnatus) were grown in a high tunnel in a randomized complete block design from mid-November to mid-March, mowed and incorporated into the soil, and followed by a succession of vegetable crops including tomato (Lycopersicon lycopersicum, cv. ‘Plum Dandy’) and broccoli (Brassica oleracea var. italica, cv. ‘Bay …

Analysis Of Break-Points In Financial Time Series, Jean Remy Habimana

Graduate Theses and Dissertations

A time series is a set of random values collected at equal time intervals; this randomness makes these types of series not easy to predict because the structure of the series may change at any time. As discussed in previous research, the structure of time series may change at any time due to the change in mean and/or variance of the series. Consequently, based on this structure, it is wise not to assume that these series are stationary. This paper, discusses, a method of analyzing time series by considering the entire series non-stationary, assuming there is random change in unconditional …

A Gis Approach To Modeling Groundwater Levels In The Mississippi River Valley Alluvial Aquifer, Josef Orion Lilly

Graduate Theses and Dissertations

Groundwater depletion, a subject of growing concern for a significant portion of Arkansas, may lead to future economic challenges for the Arkansas Delta region. The Mississippi River Valley Alluvial Aquifer is the uppermost aquifer and features the largest groundwater capacity in the Mississippi Embayment Aquifer System. The Mississippi River Valley Alluvial Aquifer, commonly referred to as the “alluvial aquifer”, spans 53,000〖 km〗^2 underlying portions of Arkansas, Kentucky, Louisiana, Mississippi, Missouri, Illinois, and Tennessee. As the alluvial aquifer trends southward for approximately 250 miles alongside the Mississippi River, its geographical extent ranges from 50 to 125 miles wide. There is a …

Bioorthogonal Reactions: Synthesis And Evaluation Of Different Ligands In Copper Catalyzed Azide-Alkyne1,3-Dipolar Cycloaddition (Cuaac), Zainab Abdullah Almansaf

Graduate Theses and Dissertations

The Copper CatalyzedAzide-Alkyne1,3-Dipolar Cycloaddition (CuAAC) reaction has unique features that qualify it to be one of the best click reactions. Its applications have been shown in different aspects and for multiple purposes. The oxidative degradation of biological systems (labile proteins and live cells) is, however, generally recognized as the major problem when using this reaction in living systems. Reactive oxidation species can be easily produced in the presence of copper(II), ascorbate and air, and this is the main cause of toxicity. However, the uses of ligands have shown a major impact on reducing copper toxicity, protecting Cu(I) from the redox …

Liming Characteristics Of A High-Calcium, Dry Flue Gas Desulfurization By-Product And Its Effects On Runoff Water Quality, Jason Richard Burgess-Conforti

Graduate Theses and Dissertations

In 2013, only 37% of the 32 million Mg of flue gas desulfurization (FGD) by-products generated in the United States were reused beneficially. If FGD by-products could be used as a beneficial soil amendment, millions of megagrams may be diverted away from surface impoundments and landfills. The purpose of this research was to identify the liming characteristics of a high-Ca dry FGD (DFGD) by-product in comparison to a Class-C fly ash (FA) and reagent-grade CaCO3, and to evaluate the effects of land application to a managed grassland on runoff, plant, and soil quality. Liming characteristics were determined by measuring the …

Direct Attachment Of 4-Hydroxybenzoic Acid Polymers And Capture Agents To Flat Sheet And Microdialysis Membranes For Improved Mass Transport, Sarah Jane Phillips

Graduate Theses and Dissertations

Microdialysis (MD) sampling is a diffusion-based separation method which has the ability to sample any analyte that can diffuse across the semi-permeable membrane. However one challenge for MD is that for soluble proteins greater than 10 kDa, the relative recovery (RR) using a 100 kDa MD probe is between 1-5%.1 There are two major barriers that lead to these low recovery values - nonspecific adsorption (NSA) and poor solute mass transport. To overcome these two barriers, the modification of PES-based MD membranes has been initiated by laccase. Previous researchers have used laccase to modify PES flat sheet and hollow fiber …

Synthesis, Characterization, And Fabrication Of All Inorganic Quantum Dot Leds, Haider Baqer Salman

Graduate Theses and Dissertations

Quantum Dot LEDs with all inorganic materials are investigated in this thesis. The research was motivated by the potential disruptive technology of core shell quantum dots in lighting and display applications. These devices consisted of three main layers: hole transport layer (HTL), electron transport layer (ETL), and emissive layer where the emission of photons occurs. The latter part was formed of CdSe / ZnS core-shell quantum dots, which were synthesized following hot injection method. The ETL and the HTL were formed of zinc oxide nanocrystals and nickel oxide, respectively. Motivated by the low cost synthesis and deposition, NiO and ZnO …

Interactive Physics And Characteristics Of Photons And Photoelectrons In Hyperbranched Zinc Oxide Nanostructures, Garrett Edward Torix

Graduate Theses and Dissertations

As is commonly known, the world is full of technological wonders, where a multitude of electronic devices and instruments continuously help push the boundaries of scientific knowledge and discovery. These new devices and instruments of science must be utilized at peak efficiency in order to benefit humanity with the most advanced scientific knowledge. In order to attain this level of efficiency, the materials which make up these electronics, or possibly more important, the fundamental characteristics of these materials, must be fully understood. The following research attempted to uncover the properties and characteristics of a selected family of materials. Herein, zinc …

Cover Crop Establishment And Potential Benefits To Arkansas Farmers, Ashley Elizabeth Humphreys

Graduate Theses and Dissertations

Soybean farmers in Arkansas need best management practices (BMPs) that maximize the benefits of using cover crops including planting date and fertilization recommendations. An evaluation of cover crop species, planting dates, seeding rates, fertilizer rates, and N accumulation aids in providing these BMPs. The first objective of this research is to assess the effect of planting date on biomass production, as well as looking at the interaction of seeding rate or fertilizer rate for legumes or non-legumes, respectively, using Austrian winter pea (Pisum sativum), cereal rye (Secale cereale), black oats (Avena strigosa), wheat (Triticum aestivum), and tillage radish (Raphanus sativus). …