Physical Sciences and Mathematics Commons^™

Evaluation Of Conservation Practices Through Simulation Modeling And Tool Development, Gurdeep Singh

Graduate Theses and Dissertations

For the first objective, predicted impacts of selected Mississippi River Basin Initiative (MRBI) conservation practices (CPs) on sediment and nutrient loss were assessed. The study area was L’Anguille River Watershed (LRW), a priority focus watershed of the MRBI program and the simulated CPs were filter strip, critical area planting, grade stabilization structure, irrigation land leveling, irrigation pipeline, irrigation water management, and nutrient management. The Soil and Water Assessment Tool (SWAT) model was calibrated (1998 – 2005) and validated (2006 – 2012) for flow, sediment, total phosphorus (TP), and nitrate-nitrogen (NO3-N) at the Colt site (503 sq. km. drainage area) and …

Dark Matter Halo Concentration And The Evolution Of Spiral Structure In N-Body, Barred Spiral Galaxies, Jazmin Esmeralda Berlanga Medina

Graduate Theses and Dissertations

Motivated by the evidence of relationships between pitch angle (the tightness of spiral arm structure in the disk), P, and various indicators of central mass concentration, as well as the theoretical relationship between halo mass concentration and the density of visible matter in the central part of the galaxy, we look at a possible relationship between P and cvir (the virial concentration of the dark matter halo) in N-body simulations of barred, spiral galaxies. We also look at the evolution of pitch angle over time in higher temporal resolution than any data currently available in the literature. We find that …

Thermodynamic Modeling Of Aqueous Geochemistry Of Chlorine Salts: Application To Stability And Habitability Of Liquid Brines On Mars, Amira Elsenousy

Graduate Theses and Dissertations

The WCL (Wet Chemistry Lab) instrument on board the Mars’s Phoenix Lander has identified the soluble ionic composition of the soil at the landing site. Two important ions were detected at the landing site; perchlorates (ClO4-) with a concentration of ~ 2.4 wt% and chlorides (Cl-) with a concentration of 0.54 wt%. Between chloride and perchlorate ions three other oxidized ions exist and called chlorine ions: hypochlorite ClO - (ox. state +1), chlorite ClO2- (ox. state +3) and chlorate ClO3- (ox. state +5). These oxidized ions might be existed as intermediate species on the surface of Mars but remained undetected. …

Reservoir Characterization And Depositional System Of The Atokan Grant Sand, Fort Worth Basin, Texas, Victoria Wood

Graduate Theses and Dissertations

The Atokan Grant Sands are a tight gas sand play that would add new reserves to the Fort Worth Basin. The Fort Worth Basin is located in north-central Texas just west of Dallas, Texas. Within the basin, the study area consists of Denton, Wise, Tarrant, and Parker Counties in Texas. The basin is bounded to the north by the Red River Arch, to the west by the Bend Arch, to the south by the Llano uplift, to the east by the Ouachita structural front, and to the northeast by the Muenster Arch. The Grant Sands are approximately 1,500 ft stratigraphically …

Simulated Use Of 'First-Order' Ponds To Reduce Peakflow In An Eroding River System, J. Thad Scott, Brian E. Haggard

Technical Reports

No abstract provided.

Bacteria Monitoring In The Upper Illinois River Watershed, Erin E. Scott, Brina A. Smith, Mansoor Leh, Blake Arnold, Brian E. Haggard

Technical Reports

This project focuses on the Upper Illinois River Watershed (UIRW; HUC 11110103), which is within the Boston Mountains and Ozark Highlands ecoregions in northwest Arkansas. Headwaters of the Illinois River originate near Hogeye, Arkansas and flow north through Savoy, then west into Oklahoma near Watts. The UIRW drains an area of 1952 km2 , of which 50.3% is pasture and grassland, 35.9% is forest, 8.8% is urban and suburban, 4.3% is transitional and 0.3% is water (Arkansaswater.org, 2015). Land use throughout the watershed is also changing, with increases in residential, commercial and industrial development. The IRW has been designated a …

Monitoring Water Resources Of The Gulf Mountain Wildlife Management Area To Evaluate Possible Effects Of Natural Gas Development, Bradley J. Austin, Erin E. Scott, Sally Entrekin, Michelle A. Evans-White, Brian E. Haggard

Technical Reports

No abstract provided.

Fundamental Studies Of Magnetoconvective Forces And Density Gradients In A Microfluidic Environment, Adam James Kreidermacher

Graduate Theses and Dissertations

Magnetoconvection is a promising phenomenon for developing new electrochemical-based microfluidic flow devices with unique capabilities, such as easily switching flow direction and adjusting flow speeds and flow patterns as well as avoiding bubble formation. In order to develop these devices it is necessary to study the underlying forces. Four contributions toward fluid flow were considered. The first and foremost is the magnetohydrodynamic force, which is the magnetic component of the Lorentz force and governed by the right hand rule. It generates the majority of the convention, and is the most well-known. The second is the gravitational force, which causes convection …

Novel Azole-Based Rearrangements, Kolawole Folayele Ayinuola

Graduate Theses and Dissertations

This work describes efforts targeted at the development of novel reactivity modes for the Breslow intermediate, which was proposed by Breslow to explain the mechanism of action of thiamine-dependent enzymes. By employing this intermediate as a hydroxy-substituted N,S-ketene acetal, we successfully captured it via Claisen rearrangement towards the preparation of diaryl tertiary alcohol products that are isomers of the hitherto elusive intermediate. This strategy also constitutes an unusual disconnection for a Claisen rearrangement precursor.

We have also uncovered an unprecedented radical C-N bond scission of a Breslow intermediate when a fluorenyl group is installed on the azolium nitrogen atom. This …

Engineering The Ground State Of Complex Oxides, Derek Joseph Meyers

Graduate Theses and Dissertations

Transition metal oxides featuring strong electron-electron interactions have been at the forefront of condensed matter physics research in the past few decades due to the myriad of novel and exciting phases derived from their competing interactions. Beyond their numerous intriguing properties displayed in the bulk they have also shown to be quite susceptible to externally applied perturbation in various forms. The dominant theme of this work is the exploration of three emerging methods for engineering the ground states of these materials to access both their applicability and their deficiencies.

The first of the three methods involves a relatively new set …

An Empirical Water Quality And Best Management Practice Prioritization Model For Select Arkansas Watersheds, James Mccarty

Graduate Theses and Dissertations

The purpose of this study was to prioritize subwatersheds using water quality data and watershed characteristics. Water quality data was provided through studies by the Arkansas Natural Resources Commission, Beaver Water District, Arkansas Water Resources Center, and publicly available USGS gage data. A total of 114 sites across five HUC-8 watersheds were analyzed, including 12 USGS gages. Watershed characteristic data was retrieved from USGS and Arkansas GeoStore geodatabase repositories. A significant linear relationship between baseflow and stormflow nutrient concentrations was established allowing for the use of baseflow concentrations in the prioritization methodology. Pearson correlation, linear regression, classification and regression tree, …

A Cradle To Farm Gate Life Cycle Analysis Of Land Use In U.S. Pork Production, William Benjamin Putman

Graduate Theses and Dissertations

The goal of this study was to conduct a detailed Life Cycle Assessment (LCA) of the U.S. live swine production supply chain to quantify land use requirements and to assess the impact associated with various ration compositions. The functional unit was defined as one kilogram (2.2 pounds) of live swine at the farm gate, ready for transport to the abattoir. This assessment focused on the three highest producing USDA regions, which encompassed the Midwest (Regions 5 and 7) and the Southeast (Region 4), representing 86% of U.S. market hog production.

First, a literature review was conducted to summarize the most …

Life Cycle Assessment Of Alternative Swine Management Practices, Prathamesh Avadhut Bandekar

Graduate Theses and Dissertations

Life Cycle Assessments (LCAs) are quantitative analyses of complex systems for evaluation of impacts and risk associated with management decisions. LCAs can be effective tools for determining comparative advantages of management strategies across specific impact concern. In this study, life cycle assessments of pork production management alternatives was performed. The alternative management practices included in this study were production of entire males (boars), use of pens for gestation housing, immunocastration, production without growth promoting antimicrobials, production without growth promoting and preventive antimicrobials, and production without ractopamine. These LCAs evaluated the impact of each management strategy on greenhouse gas emission (GHG), …

Is Chir Pine Displacing Banj Oak In The Central Himalaya? Socioeconomic Implications For Local People And The Conservation Of Oak Forest Biodiversity, Ankush Nautiyal

Graduate Theses and Dissertations

Various studies have suggested that chir pine (Pinus roxburghii) is replacing banj oak (Quercus leucotrichophora) in the Central Himalaya. Five sites with three different types of forests (banj oak, chir pine and mixed oak-pine) were sampled to compare the diversity of their vegetation and to assess the impact of this ongoing conversion on biodiversity. Soil samples collected from oak and pine forests were analyzed and compared. In addition, dendrochronology was used to obtain age estimates of chir pine and to understand the growth response of this species to precipitation. Also, samples of ectomycorrhizal fungi were collected in the form of …

Alliaria Petiolata (M.Bieb.) Cavara & Grande [Brassicaceae], An Invasive Herb In The Southern Ozark Plateaus: A Comparison Of Species Composition And Richness, Soil Properties, And Earthworm Composition And Biomass In Invaded Versus Non-Invaded Sites, Jennifer D. Ogle

Graduate Theses and Dissertations

Invasive species are widely recognized as organisms that severely alter ecosystem processes in the habitats to which they are introduced. Alliaria petiolata is one of the most important invasive plants in forests of the northern United States. This study examined the geographic distribution of the plant in the southern Ozarks, as well as the effect that it may be having on natural processes within forests of the region by comparing plant species richness, plant cover, and soil properties in invaded and non-invaded plots. It was found that A. petiolata is not significantly altering species richness, cover, or soil properties in …

Long-Term Effects Of Alternative Residue Management Practices On Near-Surface Soil Properties And Soybean Production In A Wheat-Soybean, Double-Crop System In Eastern Arkansas, Christopher Ryan Norman

Graduate Theses and Dissertations

Adoption of management practices that maintain or increase soil organic matter (SOM), which contains 58% carbon (C) on average, may help to mitigate climate change by sequestering atmospheric C. Therefore, the main objective of this study was to determine the long-term trends in SOM, soil C and nitrogen (N), bulk density, various soil chemical properties (i.e., pH, electrical conductivity [EC], and Mehlich-3-extractable nutrients) in the top 10 cm, and soybean yield as affected by residue burning (burning and non-burning), tillage (conventional and no-tillage), irrigation (irrigated and non-irrigated), and N-fertilization/residue level (high and low) in a wheat (Triticum aestivum L.)-soybean [Glycine …

Lithologic Controls On Bedrock Channel Morphology In The Buffalo River Basin, Evan A. Thaler

Graduate Theses and Dissertations

The longevity of high relief terrains in passive margin systems remains an explained phenomenon in geomorphology. Current landscape evolution models assume an equilibrium state between rock uplift rates and erosion rates. However, analysis of chi gradients of bedrock channels across several lithologies in the Buffalo River Basin reveals disequilibrium in the basin controlled by the presence of a thick interval of Pennsylvanian sandstone that caps many of the plateaus in the basin. Headwater channels beneath the caprock tend to have higher chi gradient values in all lithologies than headwater channels in basins where the sandstone caprock is absent. High chi …

Metal Mobilization In Groundwater, Bauxite, Ar, Steven Alexander Hamlin

Graduate Theses and Dissertations

The Wilcox Aquifer of Bauxite, AR contains bauxite ore deposits that may contribute heavy metals to groundwater. Twenty-four wells were sampled for aluminum, iron, manganese, zinc, lead, barium, nitrate, sulfate, sodium, alkalinity, calcium, magnesium, chloride, pH, total organic carbon, and total dissolved solids. A Wilcoxon Rank-Sum compared the similarity of the three geographic areas covered in the study. All parameters for wells in Bauxite and Sardis failed to reject the null hypothesis, signifying that wells all occupy the Saline Formation. 2/3rds of the parameters from BFI261 and the Bauxite region did not agree, suggesting the two areas do not occupy …

Paleoclimate Implications From Stable Isotope Analysis Of Sedimentary Organic Carbon And Vertebrate Fossils From The Cedar Mountain Formation, Ut, U.S.A., Garrett Andrew Hatzell

Graduate Theses and Dissertations

Oxygen and carbon isotopic compositions of fossilized vertebrate teeth and bone were analyzed to determine isotopic values of vertebrate faunal diet from the early Cretaceous Cedar Mountain Formation of Utah. Results for δ18O of PO4 (δ18Op) (Suarez et al., 2014) from the same data set have been compared to the δ18O of CO3 (δ18Oc) portion of teeth and turtle shell to determine if diagenetic alteration of the isotopes has occurred by plotting the line of best fit equation that models the relationship between unaltered δ18OP and δ18OC of modern mammals from Iacumin et al., 1996. Results indicate slight diagenesis of …

The Effects Of Strain And Vacancies On The Electric And Vibrational Properties Of Ferroelectric Batio3 From First-Principles, Aldo Serge Michael Raeliarijaona

Graduate Theses and Dissertations

The studies of ferroelectricity (FE) are of technological significance because of the multitude of applicable properties that ferroelectric materials exhibit. The mastery, and control of these properties necessitate the knowledge of the fundamental physics governing these insulating materials.

In this dissertation I present the results of first-principles investigations of the behavior of the fundamental ferroelectric properties under strain, and in the presence of vacancies. In the first part I introduce the important FE properties, their common behavior, and their numerous valuable applications. Following this background on FEs, a review of theoretical methods is presented with topics such as: Density Functional …

Surface Modification Of Noble Metal Nanostructures Toward Biomedical Applications, Samir V. Jenkins

Graduate Theses and Dissertations

Noble metal nanostructures have seen a steady increase in biomedical application over the last several decades; new diagnostic and therapeutic modalities are under intense investigation. Many of these applications are possible because of post-synthetic modifications to the particle surface. These modifications take a variety of forms and can significantly affect the pharmacokinetics of these particles. In this work, various surface modifications were investigated. Particle agglomeration, which occurs when particle surfaces remain in contact, can significantly affect the toxicity and efficacy of a nanomedicine. Darkfield microscopy and single-particle ICP-MS were developed as complementary methods to detect agglomeration in blood, with the …

Isometries Of Besov Type Spaces Among Composition Operators, Melissa Ann Shabazz

Graduate Theses and Dissertations

Let Bp,alpha for p >1 and alpha >1 be the Besov type space of holomorphic functions on the unit disk D. Given Phi, a holomorphic self map of D, we show the composition operator CPhi is an isometry on Bp,alpha if and only if the weighted composition operator WPhiPhi, is an isometry on the weighted Bergman space Ap,alpha. We then characterize isometries among composition operators in Bp,alpha in terms of their Nevanlinna type counting function. Finally, we find that the only isometries among composition operators on Bp,alpha, except on B 2,0, are induced by rotations. This extends known results by …

The Functional And Distributional Ecology Of Mycetozoans Under Changing Edaphic And Climatic Dynamics, Geoffrey Lloyd Zahn

Graduate Theses and Dissertations

Investigations into the distribution and ecosystem functions of fruiting amoebae revealed that local-scale environmental conditions can largely explain broad biogeographical patterns in species assemblage, the way in which amoeboid predators shape bacterial communities and how this top-down influence may affect global biogeochemical processes in a changing climate. The distribution and assemblage of protosteloid amoebae on the islands of New Zealand and Hawaii did not yield any expected patterns of island biogeography, and conformed to other global regions studied. The strongest predictor of species richness in a given region was sampling effort and these species do not appear to have any …

Static And Dynamical Properties Of Ferroelectrics And Related Material In Bulk And Nanostructure Forms, Zhigang Gui

Graduate Theses and Dissertations

Ferroelectrics (FE) and multiferroics (MFE) have attracted a lot of attentions due to their rich and novel properties. Studies towards FE and MFE are of both fundamental and technological importance. We use a first-principles-based effective Hamiltonian method, conventional ab-initio packages and linear-scale three-dimension fragment method to investigate several important issues about FE and MFE. Tuning the properties of FE and MFE films are essential for miniaturized device applications, which can be realized through epitaxial strain and growth direction. In this dissertation, we use the effective Hamiltonian method to study (i) BaTiO 3 films grown along the (110) pseudocubic direction on …

Good Stein Neighborhood Bases For Nonsmooth Pseudoconvex Domains, Chizuko Iwaki

Graduate Theses and Dissertations

In 1979, Dufresnoy showed that the existence of a good Stein neighborhood base for Ω ⊂ℂⁿ implies that one can solve the inhomogeneous Cauchy-Riemann equations in C^∞(Ω̄), even if the boundary of Ω is only Lipschitz. In my thesis, I will show sufficient conditions for the existence of a good Stein neighborhood base on a Lipschitz domain satisfying Property (P).

Designing Fret Assays To Study Electrostatic Interactions Pertaining To The Binding Of Intrinsically Disordered Proteins, Ashley Ann Howard

Graduate Theses and Dissertations

Fibroblast growth factor receptor plays a major role in several biological processes. Without FGFR, a human cannot live. FGFR is involved in cell differentiation and wound healing. Of course, if FGFR signaling becomes unregulated, it causes severe distress in the body. Several cancers are contributed to high signaling levels, as well as developmental conditions like rickets and Kallmann’s syndrome. FGFR is thought to undergo an auto-inhibition (or self-regulatory) process in order to try to facilitate regulation. The exact method of this inhibition is currently unknown, but is proposed to involve the unstructured acid box region of FGFR. We developed a …

In Vitro Microdialysis Sampling Collection Of Volatile Organic Compounds (Voc's), Dodecafluoropentane (Ddfp) And Isoflurane, Valerie Shannon Mckinney

Graduate Theses and Dissertations

Death by stroke occurs every four minutes to human beings. Strokes cause necrosis within the tissue of the brain due to deprivation of oxygen. Perfluorocarbons have the ability to transport oxygen to tissue and in return decrease cell death. Dodecafluoropentane (DDFP) is a volatile fluorocarbon and collection in vivo can be a challenge since this compound evaporates at room temperature. There is currently not an efficient collection method in vivo for compounds that are volatile. Without a method to collect DDFP it is impossible to be approved for clinical use since exact concentrations of the drug within the body will …

Asymmetric Synthesis And Transition Metal-Catalyzed Cross-Coupling Arylations Of Selected Organolithiums, Barry Kyle Sharp

Graduate Theses and Dissertations

My former boss, Dr. Gawley, always loved to say, “The world is chiral” (à la Pasteur). From DNA and proteins to hands and feet, it is obviously true. Also, a wide variety of chemical products exist as single enantiomers. Advances in chemical technology have greatly accelerated asymmetric synthesis in the past quarter century, and namely, organolithiums, have been shown to provide a versatile route to chiral natural products and biologically active molecules. Versatility arises from the array of methods that produce a chiral organolithium. Dynamic thermodynamic resolution (DTR) is considered one of the most practical methods, but among the others …

Solubility And Detectability Of Hydrocarbons On The Surface Of Titan, Sandeep Singh

Graduate Theses and Dissertations

Titan’s thick atmosphere is enriched with organic compounds and its surface holds reservoirs of hydrocarbons. This makes Titan the only other candidate in our solar system (apart from Earth) to have stable liquid at the surface. The stability and characteristics of liquid and ices on the surface of Titan are of high importance in understanding its surface-atmosphere interactions. Titan’s hydrological cycle is similar to what we see on Earth, with the exception of methane (CH4) and ethane (C2H6) taking the place of water. The smoggy atmosphere veils the surface of Titan from the view of Cassini spacecraft, except at seven …

Synthesis Of Palladium And Palladium-Copper Nanostructures As Electrocatalysts, Haibin Wu

Graduate Theses and Dissertations

Pd and its alloys are alternatives of Pt as promising catalysts and electrocatalysts for many reactions. Size controlled synthesis of nanoparticles remains a major research subject, since smaller size particles show better catalytic performance. In this work, we developed a modified chemical wet method to prepare Pd and Pd-Cu nanostructures with uniform small size. Different sizes and shapes of Pd nanostructures were successfully synthesized by using the two reducing agents (i.e., L-ascorbyl-6-palmitate or phenylphosphinic acid). The reducing agents play a role to control the final morphologies and sizes of particles. The use of L-ascorbyl-6-palmitate favors to form irregular branch shapes …