Physical Sciences and Mathematics Commons^™

A General Valence-Length Correlation For Determining Bond Orders: Application To Carbon-Carbon And Carbon-Hydrogen Chemical Bonds, F. D. Hardcastle

Journal of the Arkansas Academy of Science

A quantum-mechanical LCAO approach was used to derive Pauling’s popular empirical bond valencelength relationship s = exp((R₀-R)/b), where s is the bond order or bond valence associated with bond length R, and R₀ and b are fitting parameters. An expression for the b “empirical” fitting parameter is derived in terms of atomic orbital exponents. The b parameters calculated from the atomic orbital exponents are consistent with optimized b parameters. In general, atomic orbital exponents may be used to determine bond valence-length relationships for any chemical bond regardless of valence state, oxidation number, physical or chemical environment. In this study, almost …

Sequence Stratigraphy Of The St. Joe And Boone Formations, Lower Mississippian (Kinderhookian-Osagean), Southern Ozark Region, S. C. Kincade

Journal of the Arkansas Academy of Science

The Lower Mississippian (Kinderhookian-Osagean) St. Joe and succeeding Boone Formations are well exposed in northwestern Arkansas, southern Missouri, and northeastern Oklahoma, forming the Springfield Plateau of the southern Ozark region. This interval represents a single, third order, transgressive-regressive eustatic cycle deposited broadly across the North American craton. The initial transgression during the Kinderhookian covered the regional erosional surface developed on either the Devonian-Lower Mississippian Chattanooga Shale, or older units with crinoidal packstones deposited as platform successions or transported as down-ramp slurries. The Boone Formation is divided informally into lower and upper divisions that reflect differences in eustatic sea level. The …

Geochemical Processes And Controls Affecting Water Quality Of The Karst Area Of Big Creek Near Mt. Judea, Arkansas, V. Brahana, J. Nix, C. Kuyper, T. Turk, F. Usrey, S. Hodges, C. Bitting, K. Ficco, E. Pollock, R. Quick, B. Thompson, J. Murdoch

Journal of the Arkansas Academy of Science

Karst regions typically are considered to be vulnerable with respect to various land-use activities, owing to the intimate association of surface and groundwater and lack of contaminant attenuation provided by most karst aquifers. Inasmuch as the soluble rocks of the karst landscape can be dissolved to create large, rapid-flow zones that compete successfully with surface streams, groundwater and subsurface flow represent a much larger component of the hydrologic budget in karst regions than in areas where non-soluble rocks predominate. Karst areas typically are distinguished by being unique, but some general approaches can be applied to characterize the hydrology of the …

Characterizing Nanoparticle Size By Dynamic Light Scattering, M. Zaman, S. Ang, S. Singh

Journal of the Arkansas Academy of Science

The Dynamic Light Scattering (DLS) Technique was used to determine the size, shape and diffusion coefficient of rod-like nanoparticles. The intensity auto-correlation functions of light scattered by particles in a solution were measured and analyzed to obtain the relaxation rates for decay of intensity correlations. These decay rates are related to the diffusion coefficients pertaining to the motion of the particle. In the case of nanorods, there are two types of motion - translational and rotational. By disentangling the relaxation rates, corresponding to these two types of motion, the shape and size of nanoparticles were characterized. These experiments, though limited …

Age And Correlation Of The Moorefield Shale (Upper Mississippian) In Its Type Area, Northeastern Arkansas, O. Dalu, W. S. Coffey, W. L. Manger

Journal of the Arkansas Academy of Science

The name Moorefield was proposed by Adams and Ulrich (1904) for exposures of gray to brown, phosphatic shale with a basal limestone, overlying the Lower Mississippian Boone Formation, and underlying the Upper Mississippian Batesville Sandstone, in the vicinity of Moorefield, Independence County, northeastern Arkansas. Gordon (1944) 1) restricted the name Moorefield to the lower limestone-bearing interval, 2) applied a new name, Ruddell, to the succeeding shale section that comprises the bulk of the interval, with a type area near Moorefield, and 3) interpreted the interval contacts as unconformities. The name Ruddell was used for the revised Geological Map of Arkansas …

Biomass (Yard Waste) Suspensions As Alternative Daily Cover Material For Landfills, R. Sharma, K. Arnoult, K. Hart, G. Phillips, S. Knight, M. Grappe

Journal of the Arkansas Academy of Science

Biomass makes up approximately 16% of the landfills (this number can vary significantly depending upon the geographical location and time of the year). A majority of the biomass disposed in landfills is comprised of yard waste including grass and leaf clippings. This is becoming a problem as most landfills are running out of space and it is expensive to build new landfills. Twenty-four states have prohibited the disposal of yard waste in landfills with more states likely to follow suit. To conserve landfill space it is important to identify processes and methods for effective utilization and disposal of yard waste. …

Lithostratigraphic Succession And Depositional Dynamics Of The Lower Mississippian, Southern Ozarks, Northern Arkansas And Adjacent Areas, F. Mcfarlin

Journal of the Arkansas Academy of Science

The Lower Mississippian interval comprises a single, third-order, eustatic cycle subdivided lithostratigraphically into the St. Joe Limestone (Hopkins 1893) and overlying Boone Formation (Branner 1891, Simonds 1891) with type areas in northern Arkansas. Coeval, homotaxial limestones occur in adjacent southwestern Missouri and northeastern Oklahoma, but neither Arkansas name is applied. To eliminate this “state line fault,” Missouri formation names for the St. Joe interval are recognized in Arkansas as members (ascending order): Bachelor, Compton, Northview, Pierson. The Boone interval in Missouri is represented by the (ascending order): Reeds Spring, Elsey, Burlington-Keokuk undifferentiated, but utilization of those names in Arkansas is …

A Life Cycle Analysis Of Land Use In Us Pork Production, Greg Thoma, Marty Matlock, Ben Putman, Jasmina Burek

Food Systems

The goal of this study was to analyze land use in the production of US pork using Life Cycle Assessment (LCA). LCA is a comprehensive methodology for quantitatively analyzing potential environmental impacts associated with complex systems. Identification of processes contributing to high environmental impacts often highlights opportunities for gains in efficiency, which can increase the profitability and sustainability of US pork. The environmental impact category analyzed in this assessment was land use. After reviewing existing information regarding land use in agriculture and livestock production, analysis for US pork production was performed at two scales: cradle-to-grave and cradle-to-farm gate. The cradle-to-grave …

Disaggregating The Effect Of Drought And Heat Stress During Flowering On Spikelet Fertility In Rice, Lisa Straussberger

Graduate Theses and Dissertations

Due to rice’s wide geographic distribution, extending from 50°N to 35°S, rice is

forecasted to be the most vulnerable crop to warming global climates. Previous studies have

predicted lower rice yields and increasing rice yield variability due to higher frequencies of heat

stress events, and a higher variability in precipitation patterns due to global warming. As such,

understanding the effects of drought and heat stress intensity and frequency on rice yields is of

upmost importance to feeding the growing global population.

Given that drought and high-temperature stress often occur together, it is essential to

disaggregate the two individual stressors and …

Applications Of Cultural Theory And Empirical Analysis Of Sustainable Energy Policy Preferences In Arkansas, John Henry Kester Iii

Graduate Theses and Dissertations

The local policy arena is ripe for research on policy elite decisionmaking because where policy diffusion is concerned, previous studies focus on state-to-state and city-to-city dynamics. Therefore, there is a significant opportunity to expand understanding about the adoption of policies and policy diffusion at the local level. Identification of individual level determinants that signify policy adoption is a cornerstone to fostering this knowledge. This study examines such preference indicators found among policy elites in select Arkansas cities. For this research, the primary theoretical perspective for evaluating individual determinants is cultural theory, which has shown strong correlation to individual policy preference …

Synthesis Of Medicinally Relevant Thiazolyl Aryl Ketones Under Mild Conditions, Danielle M. Gardner

Health, Human Performance and Recreation Undergraduate Honors Theses

Purpose: The growing amount of clinical resistance observed in current antifungal drugs and in anti-HIV pharmaceuticals is a concern in the medical community. The purpose of this study is to develop a mild synthetic process for biomedically relevant thiazolyl aryl ketones that can be used to develop antifungal and anti-HIV drugs. We hypothesized that the proposed synthetic technique would be more efficient, produce fewer unwanted byproducts, and be more tolerant of functional groups than existing methods.

Methods: Prior to each of the ketone reactions, the necessary salt was synthesized by mixing thiazole and 9-bromofluorene neat in a reaction tube heated …

Economic Feasibility Of Aquaponics In Arkansas, Leah Ashley English

Graduate Theses and Dissertations

Concerns regarding population growth and resource scarcity have led to a recent renaissance of food production research. Over the past few decades, scientists have discovered new and innovative methods for growing food that, cumulatively, may hold the key to efficiently and sustainably feeding an ever-increasing world population. One method, known as aquaponics, has shown promise as being a sustainable solution for producing food locally in all parts of the world. Although many studies have shown aquaponic food production to be technically feasible, there are relatively few studies concerning the economic feasibility of aquaponics in various regions. To determine whether aquaponics …

Photochemistry Of A Series Of Weakly Coupled Dinuclear Ruthenium(Ii) Complexes, Latisha Michelle Puckett

Graduate Theses and Dissertations

An improved synthetic method was developed for symmetric ruthenium(II) polypyridine complexes with the form L2Ru(diphen)RuL2. The scope of the reaction was investigated in regards to the ligands, bridging ligands, and starting materials. Several ligands were successful in the synthesis, including 2,2’-bipyridine (bpy), 4,4’-dimethyl-2,2’-dipyridyl (dmb), 1,10-phenanthroline (phen), 4,7-diphenyl-1,10-phenanthroline (dpphen), and 3,4,7,8-tetramethyl-1,10-phenanthroline (tmphen). Ligands that did not react to form symmetric dimeric complexes were 2,2’-bipyrazine, bpz, and 2,2’-bipyrimidine, bpm.

Dpp, 2,3-bis(2-pyridyl)-pyrazine, effectively replaced diphen as the bridging ligand to produce (phen)2Ru(dpp)Ru(phen)24+. However, replacing the [Ru(CO)2Cl2]n with Ru(DMSO)4Cl2 did not prove successful. The newly developed synthesis was also applied to the synthesis of …

Defining The Potassium Nutritional Requirements And Distribution Among Plant Parts Of Representative Soybean Cultivars From Different Maturity Groups, Md. Rasel Parvej

Graduate Theses and Dissertations

The potassium (K) requirement of soybean [Glycine max (L.) Merr.] was investigated to determine whether cultivar sensitivity to K deficiency was affected by growth habit (determinate or indeterminate) and how cultivars from each growth habit accumulate and distribute K among plant structures. We also diagnosed K deficiency across reproductive growth stages (R2-6) using trifoliolate leaf- and petiole-K concentrations and at harvest (R8) using seed-K concentration. Soybean responded similarly to K deficiency in terms of yield, selected yield components, and seed-K concentration, regardless of growth habit. The yield loss from K deficiency was greatest on the middle to upper nodes of …

Influence Of Shelling Temperature And Time On The Optical And Structural Properties Of Cuins2/Zns Quantum Dots, Colette Robinson

Graduate Theses and Dissertations

CIS/ZnS core/shell QDs are an important class of nanomaterials for optoelectronic, photovoltaic and photoluminescence applications. They consist of lower toxicity materials than the prototypical II-VI Cd-based QDs and show long fluorescence lifetimes, which generates prospective in biological imaging applications. It is vital to develop reproducible synthetic methods for this new class of nanomaterials in order to maintain small sizes with high QYs. CIS core QDs have been shelled with ZnS at various temperatures from 90-210°C for reaction times ranging from 20-140 minutes to examine the role of thermodynamics and kinetics on the shell growth. Using HR-TEM and ICP-MS, it was …

Calorimetry And Body Composition Research In Broilers And Broiler Breeders, Justina Victoria Caldas Cueva

Graduate Theses and Dissertations

Indirect calorimetry to study heat production (HP) and dual energy X-ray absorptiometry (DEXA) for body composition (BC) are powerful techniques to study the dynamics of energy and protein utilization in poultry. The first two chapters present the BC (dry matter, lean, protein, and fat, bone mineral, calcium and phosphorus) of modern broilers from 1 – 60 d of age analyzed by chemical analysis and DEXA. DEXA has been validated for precision, standardized for position, and equations and validations developed for chickens under two different feeding levels. These equations are unique to the machine and software in use. Research in broilers …

Swat Model Simulation Of Bioenergy Crop Impacts On Water Quality In Cache River Watershed, Eeshan Kumar

Graduate Theses and Dissertations

Energy security through increased biofuel production is one of the components of the Energy Independence and Security Act (EISA) 2007. As per EISA 2007 mandate, appropriate independent research institutes are required to assess concerns to natural biodiversity due to biofuel production and report it to the Congress through the Environment Protection Agency (EPA). Planners, researchers, and agencies concerned with environmental regulations, ideally, would like to have location-specific information about the impacts for developing appropriate management interventions. This study examines long-term impacts on water quality in response to targeted (i.e. marginal lands) production of biofuel crops by setting up two SWAT …

The Structural Analysis Of Enola And Greenbrier, Arkansas Earthquake Swarms: Cause And Effect?, Minella Majenu

Graduate Theses and Dissertations

Almost 20 years after the remarkable earthquake swarm of 1982, near the town of Enola, Arkansas, with more than 40,000 micro-earthquakes, another event revisited the same North-Central Arkansas region in 2001. Nine years later, in 2010, a huge swarm event shook the northern part of Faulkner County, around the city of Guy. The following year, this seismic swarm event apparently migrated southward towards the city of Greenbrier, with an increase in the number of yearly recorded events. A 13km previously unrecognized, NE trending Guy-Greenbrier basement fault was revealed as a result of these swarm events.

Within the vicinity of the …

Validation Of Soil-Test-Based Phosphorus And Potassium Fertilizer Recommendations For Rice And Soybean, Matthew Scott Fryer

Graduate Theses and Dissertations

The science of soil-testing for nutrient management and fertilizer recommendations is widely accepted among scientists and agronomists. Although this science is unsurpassed in predicting soil nutrient availability, soil-test interpretations are seldom validated. Major research objectives for irrigated soybean [Glycine max (L.) Merr.] and direct-seeded, delayed-flood rice (Oryza sativa L.) were to: i) validate the accuracy of Mehlich-3 soil-test P (STP) and K (STK) interpretations and ii) published critical tissue-P and -K interpretations in predicting the yield response to fertilizer at different significance levels (p≤0.05 to 0.25), iii) examine how seed nutrient concentrations are influenced by fertilization and crop response to …

Neural Decomposition Of Time-Series Data For Effective Generalization, Luke Godfrey

Graduate Theses and Dissertations

We present a neural network technique for the analysis and extrapolation of time-series data called Neural Decomposition (ND). Units with a sinusoidal activation function are used to perform a Fourier-like decomposition of training samples into a sum of sinusoids, augmented by units with nonperiodic activation functions to capture linear trends and other nonperiodic components. We show how careful weight initialization can be combined with regularization to form a simple model that generalizes well. Our method generalizes effectively on the Mackey-Glass series, a dataset of unemployment rates as reported by the U.S. Department of Labor Statistics, a time-series of monthly international …

Hydrology-Biology Response Relationships In The Ozark Highlands, Dustin Thomas Lynch

Graduate Theses and Dissertations

I examined flow-ecology relationships among stream communities in the Ozark Highlands, USA. I sampled fish, crayfish, and benthic macroinvertebrates during two consecutive summers, including a drought year (2012) and a flood year (2013). Biological response variables related to community structure were assessed via two different statistical methods: an Information Theoretic approach relating response variables to a priori selected predictor variables incorporating hydrology, habitat, geomorphology, and water quality, and canonical ordination using forward selection to relate these same response variables to a large assortment of hydrologic metrics. In addition to assessing metrics related to predicted natural flow, flow alteration at gaged …

Evaluating The Intrinsic Similarity Between Neural Networks, Stephen Charles Ashmore

Graduate Theses and Dissertations

We present Forward Bipartite Alignment (FBA), a method that aligns the topological structures of two neural networks. Neural networks are considered to be a black box, because neural networks contain complex model surface determined by their weights that combine attributes non-linearly. Two networks that make similar predictions on training data may still generalize differently. FBA enables a diversity of applications, including visualization and canonicalization of neural networks, ensembles, and cross-over between unrelated neural networks in evolutionary optimization. We describe the FBA algorithm, and describe implementations for three applications: genetic algorithms, visualization, and ensembles. We demonstrate FBA's usefulness by comparing a …

Stratigraphic And Structural Analysis Of Middle Atoka Formation In Aetna Gas Field, Franklin, Johnson And Logan Counties, Arkansas, Ikramuddin Bahram

Graduate Theses and Dissertations

Arkoma basin is a prolific natural gas basin. The defining feature of this basin is the Atoka Formation that was deposited in the early-middle Pennsylvanian. The Atoka is held equivalent to the tectonic and structural evolution of the basin. This study focuses on one of the many gas fields in the Arkoma Basin in Arkansas to assess the stratigraphic and structural evolution that the strata in this particular field display.

Aetna Gas Field extends from T. 8N. R. 27 W to T. 9 N, R. 27 W and T. 8 N, R. 26 W to 8N, R. 27. Geographically, Aetna …

The Mass-Pitch Angle Relation For Three High Redshift Active Galaxies Selected From The Goods Field, John Adam Hughes

Graduate Theses and Dissertations

As we continue to investigate and ponder the heavens, we have come to realize the presence of highly energetic gravitational wells at the center of all galaxies. These supermassive black holes at a galaxies nucleus formed in the company of the other features making up the galaxy, particularly spiral arms. With nearby galaxies showing a relationship between the spiral arm pitch angle and that central mass, here we push that relationship out to distances of redshift one. With three galaxies at this distance we find that they also hold to the same relationship of tighter spiral arms corresponding to more …

Modifying A Cow-Calf Biophysical Simulation Model For Analyses Of Alternative Enterprises, Jennifer L. Lutes

Graduate Theses and Dissertations

Cow-calf producers in the United States, tasked with providing beef calves for the beef industry, have had a multitude of difficulties to overcome in recent years. Producers in northwest Arkansas were negatively impacted by high hay prices coupled with low beef cattle market prices due to severe drought experienced in portions of 2010, 2011, and 2012. During this time they also faced high grain prices, due to a record low harvest, combined with portions of the corn harvest diverted from human and animal feed to ethanol production. Tight lending policies of this time, reminiscent of the housing market crash in …

Probabilistic Graphical Modeling On Big Data, Ming-Hua Chung

Graduate Theses and Dissertations

The rise of Big Data in recent years brings many challenges to modern statistical analysis and modeling. In toxicogenomics, the advancement of high-throughput screening technologies facilitates the generation of massive amount of biological data, a big data phenomena in biomedical science. Yet, researchers still heavily rely on key word search and/or literature review to navigate the databases and analyses are often done in rather small-scale. As a result, the rich information of a database has not been fully utilized, particularly for the information embedded in the interactive nature between data points that are largely ignored and buried. For the past …

Compounds Released From Biomass Deconstruction: Understanding Their Effect On Cellulose Enzyme Hydrolysis And Their Biological Activity, Angele Djioleu

Graduate Theses and Dissertations

The effect of compounds produced during biomass pretreatment on cellulolytic enzyme was investigated. Liquid prehydrolyzates were prepared by pretreating switchgrass using 24 combinations of temperature, time, and sulfuric acid concentration based on a full factorial design. Temperature was varied from 140°C to 180°C; time ranged from 10 to 40 min; and the sulfuric acid concentrations were 0.5% or 1% (v/v). Identified products in the prehydrolyzates included xylose, glucose, hydroxymethylfurfural (HMF), furfural, acetic acid, formic acid, and phenolic compounds at concentration ranging from 0 to 21.4 g/L. Pretreatment conditions significantly affected the concentrations of compounds detected in prehydrolyzates. When assayed in …

Available Nitrogen And Denitrification In Soil Altered By Ground Cover And Nutrient Source In An Organic Apple Orchard, Jade Nicole Ford

Graduate Theses and Dissertations

A shift in public demand towards more organic and locally produced fruit and vegetables has been occurring across the United States in recent years. A common practice in organic fruit production is the application of organic ground covers to supply nutrients while enhancing other soil properties. A need for research exists in the southern region of the U.S. examining the effects of regionally applicable ground cover and nutrient management on nitrogen availability and the microbial community to provide information to organic farmers in the region. Two studies were conducted to determine how 12 treatment combinations of four ground covers (compost, …

Paddling A Trail, Erin Jennings Gilleece

Graduate Theses and Dissertations

Paddling A Trail documents construction of the first water trail in Arkansas. The 15 minute film is narrated by Arkansas Canoe Club Conservation Chair Debbie Doss. It follows Doss, and other volunteers as they mark the Wattensaw Bayou Trail in Hazen, Arkansas. The film is co-narrated by Kristen Bartlow of the Arkansas Game and Fish Commission. The footage was shot over three days, in two different locations. These were the White River in Northwest Arkansas and Wattensaw Bayou in Hazen, AR. The film illustrates the positive role trails can have on the environment and local economies. More importantly, the film …

Modified Polysulfone Nanofiltration Membrane Synthesis For Hydraulic Fracturing Water Recycle, Blake Alexander Johnson

Graduate Theses and Dissertations

The use of hydraulic fracturing has resulted in significant increases in the yield of oil and natural gas, as water pumped into wells at high pressure cracks the formations and releases the hydrocarbons that are locked in the rocks. This process has created large volumes of brackish water that is very difficult to process and is often disposed of into injection wells. Suspended solids and some dissolved solids are more readily removed, but the multivalent ions found in certain salts can precipitate in a well and complicate the reuse of flowback in future hydraulic fracturing operations.

Nanofiltration, a membrane separation …