Physical Sciences and Mathematics Commons^™

Laboratory Resistivity Measurements For Soil Characterization, Behdad Mofarraj Kouchaki

Graduate Theses and Dissertations

Field based electrical resistivity measurements, such as electrical resistivity tomography (ERT) and capacitively coupled resistivity (CCR), are geophysical methods that offer a non-destructive and rapid means to collect continuous data. As such, ERT and CCR are becoming increasingly popular tools for geotechnical engineers; however, it is challenging to derive geotechnical information such as soil type, density, and water content from the data. A laboratory geophysical investigation was carried out to gain a better understanding of the parameters that affect the electrical resistivity of soils and devise a relationship between resistivity and soil type or classification. In this study, a soil …

Growth And Survivability Of Microorganisms At Martian Temperatures And Pressures, Rebecca Lynne Mickol

Graduate Theses and Dissertations

The discovery of methane in the martian atmosphere via numerous ground- and space-based sources has prompted the study of methanogens as models for life on Mars. Methanogens are microorganisms within the domain Archaea, many of which utilize carbon dioxide (CO2) and hydrogen to produce methane. The non-photosynthetic nature of methanogens indicates that they could exist in sub-surface environments, protected from harmful UV and ionizing radiation on the surface of Mars. These organisms also do not require organics, which are sparse on the planet.

Additionally, the wide variety of environments we find life in on Earth, as well as evidence for …

Characterization Of Nanoparticles Using Solid State Nanopores, Santoshi Nandivada

Graduate Theses and Dissertations

Solid state nanopores are widely used in detection of highly charged biomolecules like DNA and proteins. In this study, we use a solid state nanopore based device to characterize spherical nanoparticles to estimate their size and electrical charge using the principle of resistive pulse technique. The principle of resistive pulse technique is the method of counting and sizing particles suspended in a fluid medium, which are electrophoretically driven through a channel and produce current blockage signals due to giving rise to a change in its initial current. This change in current is denoted as a current blockage or as a …

Instrumental Aspects Of Oxygen Sensing: Quantitation And Recalibration Of A Biofouled Oxygen Sensor, Marlena Patrick

Graduate Theses and Dissertations

In vivo oxygen sensing is a critical area of research for medical applications, such as ischemic stroke, but this important topic is not fully understood or resolved. In addition, the best method for calibration of in vivo sensors is as yet undetermined. For all implantable devices, biofouling, the adsorption of biological material to the device surface, is another significant problem with no clear or well-defined solution. One method employed is to apply a protective polymer membrane to the sensor surface in order to minimize the adsorption of biological material. The work described here investigates two polymers applied to a gold …

Dental Microwear Textures Of Paranthropus Robustus From Kromdraai, Drimolen, And An Enlarged Sample From Swartkrans: Ecological And Intraspecific Variation, Alexandria Sachiko Peterson

Graduate Theses and Dissertations

The original microwear texture baseline for South African hominins was done by Scott et al. (2005) and concluded that Paranthropus robustus exhibited higher complexity values (Asfc) that are seen in occasional hard object feeders. Australopithecus africanus has higher anisotropy values (epLsar) consistent with consuming tough objects. This study expands upon this baseline by increasing the sample size from n = 9 for P. robustus and n = 10 for Au. africanus to n = 66 and n = 44, respectively. Additionally, this study incorporates multiple different sites and deposits. The P. robustus sample includes Drimolen, Kromdraai, and an expanded sample …

Effects Of Northern Bobwhite Management On Raccoon Abundance, Habitat Selection, And Home Range In Southwest Missouri, Jacob Cody Mcclain

Graduate Theses and Dissertations

Habitat management has become vital for northern bobwhite (Colinus virginianus) conservation. In Missouri, efforts to conserve remaining populations on public lands have included the use of two management models. The Intensive Management Model (IMM) promotes hard edges, by creating a juxtaposition of different habitat types, while the Extensive Management Model (EMM) maintains a grassland-dominated landscape through the processes of fire and grazing. Preliminary results suggest that bobwhite success is significantly higher on EMM sites than IMM sites. Management efforts through IMM may be hindered by unintentionally managing for nest predators like raccoons (Procyon lotor). Nest predators may forage more often …

Geophysical Assessment Of Kinion Lake Dam, Tim Allen Moody

Graduate Theses and Dissertations

Geophysical methods including Capacitively-Coupled Resistivity (CCR), Electrical Resistivity Tomography/Imaging (ERT/ERI), Multichannel Analysis of Surface Waves (MASW) with Love and Rayleigh waves and a Full-Waveform Inversion (FWI) were performed on Kinion Lake Dam, an earth-filled embankment dam that has historically experienced significant seepage and internal erosion issues. Surveys were completed along the crest and downstream toe of the dam. Results from the surveys indicate that each method is capable of resolving the bedrock depth within 1-2 m of locations shown on previous drilling logs, though some discrepancies between the methods exist. A weathered bedrock layer is believed to have led to …

A Comparative Analysis Of Feed And Environmental Factors On Broiler Growth In The United States, Alexandra Gulli

Graduate Theses and Dissertations

Broiler production in the United States has become an important industry within the last half century. As the demand for poultry continues to increase and the concern of climate change also increases, it will become an important part of the industry to become more sustainable. This study uses a feed optimization model, a broiler growth model, and a life cycle assessment (LCA) to determine how feed ingredients and the barn environment can affect the broiler’s growth and production emissions. A multi-criteria ration optimization model is used to produce feeds based on carbon footprint and cost. A growth model is used …

Genomic And Physiological Approaches To Improve Drought Tolerance In Soybean, Avjinder Kaler

Graduate Theses and Dissertations

Drought stress is a major global constraint for crop production, and improving crop tolerance to drought is of critical importance. Direct selection of drought tolerance among genotypes for yield is limited because of low heritability, polygenic control, epistasis effects, and genotype by environment interactions. Crop physiology can play a major role for improving drought tolerance through the identification of traits associated with drought tolerance that can be used as indirect selection criteria in a breeding program. Carbon isotope ratio (δ13C, associated with water use efficiency), oxygen isotope ratio (δ18O, associated with transpiration), canopy temperature (CT), canopy wilting, and canopy coverage …

An Upper Limit On The Tightening Of Galactic Spiral Arm Pitch Angle In Cosmic Time, Douglas William Shields

Graduate Theses and Dissertations

We present Spirality, a novel method of measuring pitch angle by fitting galaxy images to spiral templates of known pitch. Using this algorithm in concert with 2-dimensional Fast Fourier Transform (2DFFT), we determined that the pitch angle of the redshift 2.011 galaxy GZ5001 (J2000 RA 189.14811 degrees, Dec 62.24002 degrees) is approximately (16.2 +/- 2.6) degrees. The redshift 2.3219 galaxy GS21 (J2000 RA 53.14863 degrees, Dec -27.95469 degrees), which is believed to be the most distant galaxy with visible spiral structure yet measured, has a pitch of approximately (-10.6 +/- 1.6) degrees. Using a large sample of galaxies from the …

Using Stable Isotope Geochemistry To Determine Changing Paleohydrology And Diagenetic Alteration In The Late Cretaceous Kaiparowits Formation, Ut Usa, Daigo Yamamura

Graduate Theses and Dissertations

The Western Interior Basin of the North America preserves one of the best sedimentary and paleontological records of the Cretaceous in the world. The Upper Cretaceous Kaiparowits Formation is a rapidly deposited fluvial sequence and preserves one of the most complete terrestrial fossil record of the North America. Such a unique deposit provides an opportunity to investigate the interaction between the physical environment and ecology. In an effort to decipher such interaction, stable isotope composition of cements in sedimentary rocks, concretions and vertebrate fossils were analyzed.

Despite the difference in facies and sedimentary architecture, the isotope composition does not change …

A Linear-Linear Growth Model With Individual Change Point And Its Application To Ecls-K Data, Ping Zhang

Graduate Theses and Dissertations

The latent growth curve model with piecewise functions is a useful analytics tool to investigate the growth trajectory consisted of distinct phases of development in observed variables. An interesting feature of the growth trajectory is the time point that the trajectory changes from one phase to another one. In this thesis, we propose a simple computational pipeline to locate the change point under the linear-linear piecewise model and apply it to the longitudinal study of reading and math ability in early childhood (from kindergarten to eighth grade). In the first step, we conduct the hypothesis testing to filter out the …

Sustainability Assessment Of U.S. Beef Production Systems, Greg Thoma, Ben Putman, Marty Matlock, Jennie Popp, Leah English

Food Systems

With increasing public concern and awareness of agricultural sustainability issues, comprehensive methodologies such as life cycle assessment are required to benchmark the beef industry and identify areas of opportunity for continuous improvement. To that end, the Beef Checkoff completed a retrospective sustainability assessment benchmark in 2013 by using Eco-efficiency analysis to compare the years 2005 and 2011. At the time of the analysis, the methodology used was the most up-to-date and comprehensive – indeed the analysis remains one of the only complete cradle-to-grave assessments of the U.S. beef industry. In 2015, a further refined version of the Eco-efficiency analysis was …

Simulating Foodborne Pathogens In Poultry Production And Processing To Defend Against Intentional Contamination, Silas B. Lankford

Computer Science and Computer Engineering Undergraduate Honors Theses

There is a lack of data in recent history of food terrorism attacks, and as such, it is difficult to predict its impact. The food supply industry is one of the most vulnerable industries for terrorist threats while the poultry industry is one of the largest food industries in the United States. A small food terrorism attack against just a single poultry processing center has the potential to affect a much larger population than its immediate consumers. In this work, the spread of foodborne pathogens is simulated in a poultry production and processing system to defend against intentional contamination. An …

Enzyme Kinetics Studies To Guide Mathematical Modeling Of Microdialysis Sampling To Predict In Situ Biochemistry, Justin M. Klucher

Chemistry & Biochemistry Undergraduate Honors Theses

Microdialysis is a diffusion-based sampling method that can be useful for monitoring various biological systems. Matrix metalloproteinases are a class of enzymes responsible for remodeling the extracellular matrix that, when dysregulated, are linked to various diseases. The delivery method of microdialysis is of particular interest as a sampling technique for enzymatic reactions. Microdialysis was performed in vitro using a model enzyme, porcine pancreatic elastase, because it is a useful substitute for matrix metalloproteinases. A colorimetric substrate for elastase, succinyl-ala-ala-ala-p-nitroanilide, and its product p-nitroaniline were measured using a UV-Vis spectrophotometer. Using an expanded Beer’s Law equation, both analytes’ concentrations were determined …

Plasmon-Mediated Energy Conversion In Metal Nanoparticle-Doped Hybrid Nanomaterials, Jeremy Dunklin

Graduate Theses and Dissertations

Climate change and population growth demand long-term solutions for clean water and energy. Plasmon-active nanomaterials offer a promising route towards improved energetics for efficient chemical separation and light harvesting schemes. Two material platforms featuring highly absorptive plasmonic gold nanoparticles (AuNPs) are advanced herein to maximize photon conversion into thermal or electronic energy. Optical extinction, attributable to diffraction-induced internal reflection, was enhanced up to 1.5-fold in three-dimensional polymer films containing AuNPs at interparticle separations approaching the resonant wavelength. Comprehensive methods developed to characterize heat dissipation following plasmonic absorption was extended beyond conventional optical and heat transfer descriptions, where good agreement was …

Depositional Dynamics Of The Upper Eagle Ford (Upper Cretaceous): Karnes And Gonzales Counties, South Texas, Josie Brunick

Graduate Theses and Dissertations

The mixed siliciclastic/carbonate late Cretaceous Eagle Ford Formation is commonly divided into the lower Eagle Ford and the upper Eagle Ford. The lower Eagle Ford is arguably the most obvious organic rich interval highlighted with wireline log data; however, the upper Eagle Ford may have just as much potential for hydrocarbon production success as the lower Eagle Ford has had. A better understanding of the upper Eagle Ford will allow a more thorough and educated assessment into its full potential as an unconventional reservoir, and allow its sweet spots for oil or gas to be found and exploited.

This study …

Tailings Dust Emissions, Emily Degner, Sam Horn, Zakary Galligan, Ryan Bernard, Julie Jameson, Josh Mueller, Natalie Tucker, Joe Griffin

Chemical Engineering Undergraduate Honors Theses

Fugitive dust emissions from the storage and handling of mine tailings presents environmental and safety concerns, which must be addressed to promote the land sustainability and the health and safety of individuals around a tailings storage facility (TSF). The investigated dust control methods were agglomeration, binder slurry injection, and topical spray.

The Dust Busters determined that pelletizing was the most practical method of agglomeration. In order to produce durable pellets from the mine tailings, which consist primarily of silica, a binder must be added. A variety of binders were considered including magnesium and calcium chloride, bentonite, barite, cement, vinyl polymers, …

The Impact Of A Science Field Camp Experience On Students' Learning Of Environmental Concepts, Madison E. Brown

Crop, Soil and Environmental Sciences Undergraduate Honors Theses

Environmental education has garnered progressively more attention in recent years as global concerns of climate issues and conservation become increasingly prevalent. Educating young students is essential to developing a generation of stewards that are knowledgeable of their environmental impact and motivated to incite positive change in their surroundings. Using a mixed-methods study, a quantitative and qualitative analysis was conducted to evaluate the Creek Critters class as part of the residential program at the Ozark Natural Science Center. Students attending the program were given pre-and post-assessments that evaluated their knowledge of the concepts of water quality and benthic macroinvertebrates discussed at …

Music Feature Matching Using Computer Vision Algorithms, Mason Hollis

Computer Science and Computer Engineering Undergraduate Honors Theses

This paper seeks to establish the validity and potential benefits of using existing computer vision techniques on audio samples rather than traditional images in order to consistently and accurately identify a song of origin from a short audio clip of potentially noisy sound. To do this, the audio sample is first converted to a spectrogram image, which is used to generate SURF features. These features are compared against a database of features, which have been previously generated in a similar fashion, in order to find the best match. This algorithm has been implemented in a system that can run as …

A Manufacturer Design Kit For Multi-Chip Power Module Layout Synthesis, Jonathan Main

Electrical Engineering Undergraduate Honors Theses

The development of Multi-Chip Power Modules (MCPMs) has been a key factor in recent advancements in power electronics technologies. MCPMs achieve higher power density by combining multiple power semiconductor devices into one package. The work detailed in this thesis is part of an ongoing project to develop a computer-aided design software tool known as PowerSynth for MCPM layout synthesis and optimization. This thesis focuses on the definition and design of a Manufacturer Design Kit (MDK) for PowerSynth, which enables the designer to design an MCPM for a manufacturer’s fabrication process.

The MDK is comprised of a layer stack and technology …

Environmental And Climatic Constraints On Large-Scale Camelina Production In Eastern Arkansas, Benjamin Robert Tracy

Graduate Theses and Dissertations

Camelina sativa is a cold weather crop that is typically grown in semi-arid environments in the Western United States, usually as a spring crop, but sometimes during the winter. Research analyzing climate data and soil hydrology is important to better understand the environmental and terrain conditions necessary for Camelina farming wherever it is proposed for large-scale production. This study focused on various conditions and constraints pertaining to the potential for Camelina as a crop biofuel in Eastern Arkansas. Due to interest in the economic potential of crop biofuels in this area, and in particular the low input costs for Camelina, …

Influence Of Histidine Residues, Ph And Charge Interactions On Membrane-Spanning Peptides, Ashley N. Henderson

Graduate Theses and Dissertations

Designed transmembrane peptides were employed for investigations of histidine residues within the hydrophobic environment of the lipid bilayer by means of oriented solid-state deuterium NMR spectroscopy. Using the model peptide GWALP23 sequence (GGALW(LA)6LWLAGA) as a host framework, the effects of single and double histidine mutations were explored. Replacement of leucine residue 12 to polar neutral histidine had little influence on the peptide average orientation, however under strongly acidic pH conditions in DOPC bilayers, the histidine becomes positively charged (pKa 2.5) and the GWALP23-H12 peptide exits the membrane and adopts a surface-bound orientation. Conversely, mutation of leucine 14 to neutral histidine …

Development Of A Multiband Remote Sensing System For Determination Of Unsaturated Soil Properties, Cyrus D. Garner

Graduate Theses and Dissertations

A multiband system including active microwave sensing and visible-near infrared reflectance spectroscopy was developed to measure unsaturated soil properties in both field and laboratory environments. Remote measurements of soil volumetric water content (θv), soil water matric potential (ψ), and soil index properties (liquid limit [LL], plastic limit [PL], and clay fraction [CF]) were conducted. Field-based measurement of θv was conducted using a ground-based radar system and field measurements within 10 percentage points of measurements acquired with traditional sampling techniques were obtained. Laboratory-based, visible and near infrared spectroscopy was found to be capable of obtaining empirical, soil specific regression functions (partial …

Influence Of Stream Permanence, Predation, And Invasive Species On Crayfish In The Ozark Highlands With An Emphasis On Species Of Greatest Conservation Need (Orconectes Marchandi, Orconectes Eupunctus And Cambarus Hubbsi), Allyson Noelle Yarra

Graduate Theses and Dissertations

Due to the ecological importance of crayfish and the increasing vulnerability of freshwater systems due to habitat loss, invasive species, and hydrologic alteration, understanding crayfish-environment relationships is crucial in the context of aquatic species conservation. I sought to examine the influence of hydrologic variation among intermittent and permanent streams on crayfish occupancy, abundance, predation risk, and potential vulnerability to invasive species effects. I conducted crayfish and environmental data sampling during two consecutive summers across 20 Ozark streams of differing permanence levels (10 intermittent, 10 permanent). In these same streams, I conducted fish and scat surveys over the course of four …

Rock Art Management And Landscape Change: Mixed Field Assessment Techniques For Cultural Stone Decay, Kaelin M. Groom

Graduate Theses and Dissertations

As tourism continues to grow as one of the world’s most ubiquitous markets, the development and promotion of non-invasive techniques for cultural stone decay analysis and landscape change are vital to establishing conditional base-lines to best aid cultural heritage management (CRM) efficacy. Using rock art as a medium, this dissertation presents three independent case studies employing the Rock Art Stability Index (RASI) and repeat photography to explore the merits of mixed rapid field assessment techniques in relation to CRM and heritage tourism. While rock art is only one example of irreplaceable world heritage resources, examining how they decay and what …

Exploiting Semantic Distance In Linked Open Data For Recommendation, Sultan Dawood Alfarhood

Graduate Theses and Dissertations

The use of Linked Open Data (LOD) has been explored in recommender systems in different ways, primarily through its graphical representation. The graph structure of LOD is utilized to measure inter-resource relatedness via their semantic distance in the graph. The intuition behind this approach is that the more connected resources are to each other, the more related they are. One drawback of this approach is that it treats all inter-resource connections identically rather than prioritizing links that may be more important in semantic relatedness calculations. Another drawback of current approaches is that they only consider resources that are connected directly …

Comparison Of Flow Dynamics And Bifurcation Angles In Tributary And Distributary Channel Networks, Thomas Coffey

Graduate Theses and Dissertations

The dynamics of channel mouth bifurcations on river deltas can be understood using theory developed in tributary channel networks. Bifurcations in groundwater-fed tributary networks have been shown to evolve dependent on diffusive ground water flow patterns

directly adjacent to the channel network, producing a critical angle of 72°. We test the hypothesis that bifurcation angles in distributary channel networks are likewise dictated by a diffusive external flow field, in this case the shallow surface water surrounding the subaqueous portion of distributary channels in a deltaic setting. We measured 25 unique distributary bifurcations in an experimental delta and 197 bifurcations in …

Infrared Energy Conversion In Plasmonic Fields At Two-Dimensional Semiconductors, Gregory Thomas Forcherio

Graduate Theses and Dissertations

Conversion of infrared energy within plasmonic fields at two-dimensional, semiconductive transition metal dichalcogenides (TMD) through plasmonic hot electron transport and nonlinear frequency mixing has important implications in next-generation optoelectronics. Drude-Lorentz theory and approximate discrete dipole (DDA) solutions to Maxwell’s equations guided metal nanoantenna design towards strong infrared localized surface plasmon resonance (LSPR). Excitation and damping dynamics of LSPR in heterostructures of noble metal nanoantennas and molybdenum- or tungsten-disulfide (MoS2; WS2) monolayers were examined by parallel synthesis of (i) DDA electrodynamic simulations and (ii) near-field electron energy loss (EELS) and far-field optical transmission UV-vis spectroscopic measurements. Susceptibility to second-order nonlinear frequency …

3-Manifold Perspective On Surface Homeomorphisms For Surfaces With Very Negative Euler Characteristic, Michael Harris

Graduate Theses and Dissertations

The goal of this paper is to show for a compact triangulated 3-manifold M with boundary which fibers over the circle that whenever F is a fiber with sufficiently negative Euler characteristic the monodromymaps an essential simple closed curve or an essential simple arc in F to be disjoint from its image (possibly after isotopy). This is shown by applying the theorem of Ichihara, Kobayashi, and Rieck in [10] to the double of M to get a pair of pants. We then find an equivariant pair of pants and use it to find an essential simple closed curve or an …