Physical Sciences and Mathematics Commons^™

Evaluation Of Search And Rescue Planning Tools On The West Florida Shelf, Benjamin O'Loughlin

USF Tampa Graduate Theses and Dissertations

The Coast Guard conducts over 20,000 search and rescue cases a year with approximately 5% of them occurring within the coastal waters of the West Florida Shelf (WFS). Each search effort is planned using the Coast Guard’s Search and Rescue Optimal Planning System (SAROPS) which uses model inputs to create composite probability distributions based on the results of Monte Carlo projections of thousands of particle trajectories. However, SAROPS is limited by the quality of model inputs and their associated errors. This study utilizes observations from three surface drifter deployments on the WFS to evaluate the effectiveness of available surface current …

Synthesis And Characterization Of Novel Polyurethanes And Polyimides, Kenneth Kull

USF Tampa Graduate Theses and Dissertations

Four novel high performance soft thermoplastic polyurethane elastomers utilizing methylene bis(4-cyclohexylisocyanate) as a hard segment, 1,4 butanediol as a chain extender and modified low crystallinity carbonate copolymer as a soft segment were synthesized. The samples were characterized by infrared spectroscopy (FTIR), tensile, elongation, hardness, abrasion resistance and atomic force microscopy (AFM). SAXS data shows evidence of an interdomain "center-to-center" distance of 45Å. DSC traces show evidence of one glass transition temperature and a weak melting region. DMA analysis reveals a low temperature secondary relaxation and the glass to rubber transition followed by a rubbery plateau. All samples demonstrated the ability …

Baiting Sustainability: Collaborative Coastal Management, Heritage Tourism, And Alternative Fisheries In Placencia, Belize, Eric Koenig

USF Tampa Graduate Theses and Dissertations

Local coastal fishers in Belize are adapting novel strategies to manage, exploit, and market marine and coastal resources in an effort to promote fishing livelihoods and coastal environmental sustainability. These resilience strategies respond to diminished fishing stocks, fisheries and environmental policies and regulations, climate change, shifting seafood markets, and expanding tourism development. With growing foreign investment and nationally-directed infrastructure improvement projects on the Placencia Peninsula in recent years, tourism development is shifting toward mass tourism, and local residents are seeking avenues to sustain their livelihoods. In Placencia, the need for effective monitoring and management of Marine Protected Areas, fisheries, and …

Pepper Mild Mottle Virus As A Surrogate For Enteric Viruses: Implications For Assessing Water Quality, Erin Michelle Symonds

USF Tampa Graduate Theses and Dissertations

Less than 10% of the world’s domestic wastewater is disinfected prior to discharge into surface waters; therefore, human exposure to diverse wastewater-related pathogens results in millions of cases of illness each year. Among the enteric pathogens, viruses represent an important group of emerging pathogens and are frequently the cause of food- and water-borne outbreaks of illness. Although the World Health Organization and many government agencies mandate the use of bacterial indicators to identify poor microbial water quality, it is well known that these indicators poorly correlate with fecal pollution contamination events and risk of disease. The field of public health-related …

Whiting Events Off Southwest Florida: Remote Sensing And Field Observations, Jacqueline Long

USF Tampa Graduate Theses and Dissertations

“Whiting” is a term used to describe a sharply defined patch of water that contains high levels of suspended, fine-grained calcium carbonate (CaCO₃). These features are named for their bright (at times white) appearance when compared to surrounding waters, and have been found to occur globally, persisting for multiple consecutive days. Although whitings have been widely studied using chemical, biological, geological, and physical techniques, there has been little effort to document their spatio-temporal distributions in a systematic way, not to mention the lack of consensus on what generates whitings and allows them to persist for days to weeks …

Towards An Understanding Of The Propensity For Crystalline Hydrate Formation By Molecular Compounds, Alankriti Bajpai, Hayley S Scott, Tony Pham, Kai-Jie Chen, Brian Space, Matteo Lusi, Miranda L Perry, Michael J Zaworotko

Chemistry Faculty Publications

Hydrates are technologically important and ubiquitous yet they remain a poorly understood and understudied class of molecular crystals. In this work, we attempt to rationalize propensity towards hydrate formation through crystallization studies of molecules that lack strong hydrogen-bond donor groups. A Cambridge Structural Database (CSD) survey indicates that the statistical occurrence of hydrates in 124 molecules that contain five- and six-membered N-heterocyclic aromatic moieties is 18.5%. However, hydrate screening experiments on a library of 11 N-heterocyclic aromatic compounds with at least two acceptor moieties and no competing hydrogen-bond donors or acceptors reveals that over 70% of this group …

A New Method To Assess Long‐Term Sea‐Bottom Vertical Displacement In Shallow Water Using A Bottom Pressure Sensor: Application To Campi Flegrei, Southern Italy, Francesco Chierici, Giovanni Iannaccone, Luca Pignagnoli, Sergio Guardato, Marina Locritani, Davide Embriaco, Gian P. Donnarumma, Mel Rodgers, Rocco Malservisi, Laura Beranzoli

School of Geosciences Faculty and Staff Publications

We present a new methodology using bottom pressure recorder (BPR) measurements in conjunction with sea level, water column, and barometric data to assess the long‐term vertical seafloor deformation to a few centimeters accuracy in shallow water environments. The method helps to remove the apparent vertical displacement on the order of tens of centimeters caused by the BPR instrumental drift and by seawater density variations. We have applied the method to the data acquired in 2011 by a BPR deployed at 96 m depth in the marine sector of the Campi Flegrei Caldera, during a seafloor uplift episode of a few …

Automatic Pain Assessment From Infants’ Crying Sounds, Chih-Yun Pai

USF Tampa Graduate Theses and Dissertations

Crying is infants utilize to express their emotional state. It provides the parents and the nurses a criterion to understand infants’ physiology state. Many researchers have analyzed infants’ crying sounds to diagnose specific diseases or define the reasons for crying. This thesis presents an automatic crying level assessment system to classify infants’ crying sounds that have been recorded under realistic conditions in the Neonatal Intensive Care Unit (NICU) as whimpering or vigorous crying. To analyze the crying signal, Welch’s method and Linear Predictive Coding (LPC) are used to extract spectral features; the average and the standard deviation of the frequency …

Hidden Markov Chain Analysis: Impact Of Misclassification On Effect Of Covariates In Disease Progression And Regression, Haritha Polisetti

USF Tampa Graduate Theses and Dissertations

Most of the chronic diseases have a well-known natural staging system through which the disease progression is interpreted. It is well established that the transition rates from one stage of disease to other stage can be modeled by multi state Markov models. But, it is also well known that the screening systems used to diagnose disease states may subject to error some times. In this study, a simulation study is conducted to illustrate the importance of addressing for misclassification in multi-state Markov models by evaluating and comparing the estimates for the disease progression Markov model with misclassification opposed to disease …

Planetary-Scale Low-Level Circulation And The Unique Development Of Hurricane Wilma In 2005, Jinwoong Yoo, Robert V. Rohli, Jennifer Collins

School of Geosciences Faculty and Staff Publications

Large‐scale atmospheric and oceanic conditions in the western Atlantic basin were analyzed to understand the unique tropical cyclogenesis (TCG) and intensification mechanism of Hurricane Wilma in 2005, the most intense Atlantic basin tropical cyclone (TC) on record. An analysis of 850 hPa circulations depicted in the National Centers for Environmental Prediction/National Center for Atmospheric Research (NCEP/NCAR) reanalysis data suggests that anomalous development of the 850 hPa circulation pattern triggered by Hurricane Vince (October 8–11, 2005) contributed to the development of a large‐scale low‐level vortex that preceded Wilma's TCG in the eastern Caribbean. In particular, weakened easterly winds in the central …

Imparting Amphiphobicity On Single-Crystalline Porous Materials., Qi Sun, Hongming He, Wen-Yang Gao, Briana Aguila, Lukasz Wojtas, Zhifeng Dai, Jixue Li, Yu-Sheng Chen, Feng-Shou Xiao, Shengqian Ma

Chemistry Faculty Publications

The sophisticated control of surface wettability for target-specific applications has attracted widespread interest for use in a plethora of applications. Despite the recent advances in modification of non-porous materials, surface wettability control of porous materials, particularly single crystalline, remains undeveloped. Here we contribute a general method to impart amphiphobicity on single-crystalline porous materials as demonstrated by chemically coating the exterior of metal-organic framework (MOF) crystals with an amphiphobic surface. As amphiphobic porous materials, the resultant MOF crystals exhibit both superhydrophobicity and oleophobicity in addition to retaining high crystallinity and intact porosity. The chemical shielding effect resulting from the amphiphobicity of …

Analysis Of Managerial Decision-Making Within Florida’S Total Maximum Daily Load Program, Justin Barthle

USF Tampa Graduate Theses and Dissertations

Water quality has evolved legislatively from protection of navigation routes and quantity of sources to more emphasis on impairments on water quality for surface and groundwater sources. Nonpoint or diffuse sources of impairments represents a major challenge for management due to the complexity of its sources and difficulty in tracking.

The most cited sections on public policy analysis focuses on the overall process agencies employ to understand the results the program yields. Often overlooked are finer details and mechanisms, such as decision-making and priority setting, which have a great impact on the overall process. To investigate these factors, we need …

Metal-Organic Frameworks As Potential Platforms For Carbon Dioxide Capture And Chemical Transformation, Wenyang Gao

USF Tampa Graduate Theses and Dissertations

The anthropogenic carbon dioxide (CO₂) emission into the atmosphere, mainly through the combustion of fossil fuels, has resulted in a balance disturbance of the carbon cycle. Overwhelming scientific evidence proves that the escalating level of atmospheric CO₂ is deemed as the main culprit for global warming and climate change. It is thus imperative to develop viable CO₂ capture and sequestration (CCS) technologies to reduce CO₂ emissions, which is also essential to avoid the potential devastating effects in future. The drawbacks of energy-cost, corrosion and inefficiency for amine-based wet-scrubbing systems which are currently used in industry, …

Why Consumers Disclose Their Tourism Experiences On Tourism Social Networking Sites: Multiple Theoretical Perspectives, Junshu Zhang

USF Tampa Graduate Theses and Dissertations

Tourism social networking sites (SNSs) are websites that provide users with templates for describing their travel experiences and an infrastructure to share such travel posts with a network of like-minded individuals. Tourism SNSs represent an important advertising channel for the tourism industry, as they may assist travelers in selecting destinations and planning vacations on the basis of other travelers’ experiences, which may further stimulate travel and generate income for the tourism industry (Yazdanifard & Yee, 2014). User-generated content (UGC) in the form of travel posts is the core offering and key success factor of tourism SNSs. Travel posts constitute a …

Voltage Droop Analysis And Mitigation In Sttram-Based Last Level Cache, Radha Krishna Aluru

USF Tampa Graduate Theses and Dissertations

Preferred especially for a Last Level Cache (LLC) due to its high retention and tolerance capabilities, Spin-Transfer Torque Random Access Memory (STTRAM) is an emerging and a promising Non-Volatile Memory (NVM) technology. To switch the magnetization of a Magnetic Tunnel Junction (MTJ), the amount of current needed is very high (~100μA per bit). For a full cache line (512-bit) write, this extremely high current results in a voltage droop in the conventional cache architecture. Due to this droop, the write operation fails especially when the farthest bank of the cache is accessed. In this thesis, we perform an analysis of …

Scalable Clustering Using The Dempster-Shafer Theory Of Evidence, Alireza Chakeri

USF Tampa Graduate Theses and Dissertations

Clustering large data sets has become very important as the amount of available unlabeled data increases. Single Pass Fuzzy C-Means (SPFCM) is useful when memory is too limited to load the whole data set. The main idea is to divide dataset into several chunks and to apply fuzzy c-means (FCM) to each chunk. SPFCM uses the weighted cluster centers of the previous chunk in the next data chunks. However, when the number of chunks is increased, the algorithm shows sensitivity to the order in which the data is processed. Hence, we improved SPFCM by recognizing boundary and noisy data in …

Asymmetric Transformations Catalyzed By Chiral Binol Alkaline Earth Metal Phosphate Complexes, Sri Krishna Nimmagadda

USF Tampa Graduate Theses and Dissertations

Small molecule hydrogen bond donors have emerged as versatile catalysts in asymmetric synthesis. Within this class, chiral BINOL phosphoric acid is regarded as one of the pioneer catalysts used in several asymmetric transformations. The ability of the catalyst to activate the substrates could be controlled in two different ways. (1) Dual activation/bifunctional activation of substrate by hydrogen bond interactions or ion pairing with phosphoric acid or (2) By forming chiral BINOL phosphate metal complex that could significantly alter the interactions in chiral space. In particular, chiral alkaline earth metal phosphate complexes have unique advantages as catalysts owing to the ubiquitous …

Pedestrian Detection In Low Quality Moving Camera Videos, Saurabh Hinduja

USF Tampa Graduate Theses and Dissertations

Pedestrian detection is one of the most researched areas in computer vision and is rapidly gaining importance with the emergence of autonomous vehicles and steering assistance technology. Much work has been done in this field, ranging from the collection of extensive datasets to benchmarking of new technologies, but all the research depends on high-quality hardware such as high-resolution cameras, Light Detection and Ranging (LIDAR) and radar.

For detection in low-quality moving camera videos, we use image deblurring techniques to reconstruct image frames and use existing pedestrian detection algorithms and compare our results with the leading research done in this area.

Lava Flow Hazard Assessment For The Idaho National Laboratory, Idaho Falls, And Pocatello, Idaho, U.S.A., Elisabeth Gallant

USF Tampa Graduate Theses and Dissertations

This study presents a probabilistic lava flow hazard assessment for the Idaho National Laboratory (INL) and the cities of Idaho Falls and Pocatello, Idaho. The impetus of this work is to estimate the conditional probability that a lava flow on the eastern Snake River Plain (ESRP) will impact the areas of interest given the formation of a new volcanic vent in the region. A list of 288 eruptive events, derived from a previously published inventory of 506 surface and 32 buried vents, was created to reduce the biasing of spatial density maps towards eruptions with multiple dependent vents. Conditional probabilities …

Mapping Robinia Pseudoacacia Forest Health Conditions By Using Combined Spectral, Spatial And Textureal Information Extracted From Ikonos Imagery, H. Wang, Ruiliang Pu, Z. Zhang

School of Geosciences Faculty and Staff Publications

n this study grey-level co-occurrence matrix (GLCM) textures and a local statistical analysis Getis statistic (Gi), computed from IKONOS multispectral (MS) imagery acquired from the Yellow River Delta in China, along with a random forest (RF) classifier, were used to discriminate Robina pseudoacacia tree health levels. The different RF classification results of the three forest health conditions were created: (1) an overall accuracy (OA) of 79.5% produced using the four MS band reflectances only; (2) an OA of 97.1% created with the eight GLCM features calculated from IKONOS Band 4 with the optimal window size of 13 × 13 and …

Seasonal Temperature Variations Controlling Cave Ventilation Processes In Cueva Larga, Puerto Rico, Rolf Vieten, Amos Winter, Sophie Friederike Warken, Andrea Schrӧder-Ritzrau, Thomas E. Miller, Denis Scholz

International Journal of Speleology

Two years of cave monitoring investigate ventilation processes in Cueva Larga, a tropical cave in Puerto Rico. The cave is 1,440 m long with a large main passage (about 120,000 m³). Cave air pCO₂ in the main passage varies seasonally, between 600 ppm in winter and 1,800 ppm in summer. The seasonal variability in cave pCO₂ permits the estimation of a cave air exchange time of 36 ± 5 days and a winter ventilation rate of 3,300 ± 1,000 m³/day for the main cave passage. Calculations of virtual temperature and differences between cave and …

Design And Development Of Peptidomimetic Ligands For Targeting Radiopharmaceuticals, Imaging Probes, And Immunotherapeutics In Oncologic Disease, Michael Lawrence Doligalski

USF Tampa Graduate Theses and Dissertations

Cancer is a leading cause of morbidity and mortality in the developed world. While much has been learned about these diseases in the last few decades, one of the main barriers to widespread advancement is the heterogeneity of cancer biology. A growing body of evidence supports the idea that certain protein receptors are overexpressed on the surface of tumor cells as compared to normal tissues. These extracellular biomarkers provide a unique opportunity to selectively target the tumor with both imaging and therapeutic modalities. The research in this dissertation focuses on targeting proteins on the tumor cell surface with peptidomimetic ligands. …

The Role Of Partial Surface Charge Compensation In The Properties Of Ferroelectric And Antiferroelectric Thin Films, Elena Glazkova

USF Tampa Graduate Theses and Dissertations

Ferroelectric and antiferroelectric ultrathin films have attracted a lot of attention recently due to their remarkable properties and their potential to allow for device miniaturization in numerous applications. However, when the ferroelectric films are scaled down, it brings about an unavoidable depolarizing field. A partial surface charge compensation allows to control the residual depolarizing field and manipulate the properties of ultrathin ferroelectric films. In this dissertation we take advantage of atomistic first-principles-based simulations to expand our understanding of the role of the partial surface charge compensation in the properties of ferroelectric and antiferroelectric ultrathin films.

The application of our computational …

Abundance Of Archaias Angulatus On The West Florida Coast Indicates The Influence Of Carbonate Alkalinity Over Salinity, Sean Thomas Beckwith

USF Tampa Graduate Theses and Dissertations

Archaias angulatus, a large symbiont-bearing foraminifer (Order Miliolida) that produces a Mg-calcite shell, is common throughout the Caribbean and warm western Atlantic region. This species lives abundantly in seagrass beds along the Springs Coast of northwest Florida (up to 4 adults per gram of sediment) where spring-fed rivers emerge from a limestone aquifer, and in Florida Bay to the southeast (25 adults/g) where the sediment is primarily biogenic carbonate. In contrast, live specimens are seldom found in the seagrass beds along the central-west coast of Florida, where barrier islands are dominated by quartz sand. My working hypothesis is that substratum …

Parallelization Of Push-Based System For Molecular Simulation Data Analysis With Gpu, Iliiazbek Akhmedov

USF Tampa Graduate Theses and Dissertations

Modern simulation systems generate big amount of data, which consequently has to be analyzed in a timely fashion. Traditional database management systems follow principle of pulling the needed data, processing it, and then returning the results. This approach is then optimized by means of caching, storing in different structures, or doing some sacrifices on precision of the results to make it faster. When it comes to the point of doing various queries that require analysis of the whole data, this design has the following disadvantages: considerable overhead on traditional disk random I/O framework while reading from the simulation output files …

Processes Of Multibathyal Aragonite Undersaturation In The Arctic Ocean, Jonathan G. Wynn, Lisa Robbins, L. G. Anderson

School of Geosciences Faculty and Staff Publications

During 3 years of study (2010–2012), the western Arctic Ocean was found to have unique aragonite saturation profiles with up to three distinct aragonite undersaturation zones. This complexity is produced as inflow of Atlantic‐derived and Pacific‐derived water masses mix with Arctic‐derived waters, which are further modified by physiochemical and biological processes. The shallowest aragonite undersaturation zone, from the surface to ∼30 m depth is characterized by relatively low alkalinity and other dissolved ions. Besides local influence of biological processes on aragonite undersaturation of shallow coastal waters, the nature of this zone is consistent with dilution by sea‐ice melt and invasion …

A New Image Processing Procedure Integrating Pci-Rpc And Arcgis-Spline Tools To Improve The Orthorectification Accuracy Of High-Resolution Satellite Imagery, Hongying Zhang, Ruiliang Pu, Xiuguo Liu

School of Geosciences Faculty and Staff Publications

Given the low accuracy of the traditional remote sensing image processing software when orthorectifying satellite images that cover mountainous areas, and in order to make a full use of mutually compatible and complementary characteristics of the remote sensing image processing software PCI-RPC (Rational Polynomial Coefficients) and ArcGIS-Spline, this study puts forward a new operational and effective image processing procedure to improve the accuracy of image orthorectification. The new procedure first processes raw image data into an orthorectified image using PCI with RPC model (PCI-RPC), and then the orthorectified image is further processed using ArcGIS with the Spline tool (ArcGIS-Spline). We …

The Morphology And Development Of Kalahroud Cave, Iran, Shirin Bahadorinia, Sayed Hassan Hejazi, Alireza Nadimi, Derek C. Ford, Karine Wainer

International Journal of Speleology

Kalahroud Cave is located in central Iran, ~50 km north of Isfahan. The landscape is a typical mountain desert morphology of cuestas dissected by ravines and gorges created during rare surface run-off events; crest lines are ~2800 m asl and lowlands at ~2100 m asl. Kalahroud Cave (4500 m of mapped passages, ~60 m deep) is entered through breakdown in the eastern wall of a gorge. The host rock is a Cretaceous limestone and mudstone formation 60 m in thickness, underlain by sandstones and conglomerates and overlain by weakly permeable calcareous marl strata, all dipping 15-20^o. Below the …

Effect Of Void Fraction On Transverse Shear Modulus Of Advanced Unidirectional Composites, Jui-He Tai

USF Tampa Graduate Theses and Dissertations

In composite materials, transverse shear modulus is a critical moduli parameter for designing complex composite structures. For dependable mathematical modeling of mechanical behavior of composite materials, an accurate estimate of the moduli parameters is critically important as opposed to estimates of strength parameters where underestimation may lead to a non-optimal design but still would give one a safe one.

Although there are mechanical and empirical models available to find transverse shear modulus, they are based on many assumptions. In this work, the model is based on a three-dimensional elastic finite element analysis with multiple cells. To find the shear modulus, …

Poster Madness, Jennifer Collins

School of Geosciences Faculty and Staff Publications

No abstract provided.