Physical Sciences and Mathematics Commons^™

Impact Of Sludge Layer Geometry On The Hydraulic Performance Of A Waste Stabilization Pond, Faissal Romaric Ouedraogo

USF Tampa Graduate Theses and Dissertations

Improving the hydraulic performance of waste stabilization ponds (WSPs) is an important management strategy to not only ensure protection of public health and the environment, but also to maximize the potential reuse of valuable resources found in the treated effluent. To reuse effluent from WSPs, a better understanding of the factors that impact the hydraulic performance of the system is needed. One major factor determining the hydraulic performance of a WSP is sludge accumulation, which alters the volume of the pond.

In this study, computational fluid dynamics (CFD) analysis was applied to investigate the impact of sludge layer geometry on …

On Spectral Properties Of Single Layer Potentials, Seyed Zoalroshd

USF Tampa Graduate Theses and Dissertations

We show that the singular numbers of single layer potentials on smooth curves asymptotically behave like O(1/n). For the curves with singularities, as long as they contain a smooth sub-arc, the resulting single layer potentials are never trace-class. We provide upper bounds for the operator and the Hilbert-Schmidt norms of single layer potentials on smooth and chord-arc curves. Regarding the injectivity of single layer potentials on planar curves, we prove that among single layer potentials on dilations of a given curve, only one yields a non-injective single layer potential. A criterion for injectivity of single layer potentials on …

Preparation And Characterization Of Van Der Waals Heterostructures, Horacio Coy Diaz

USF Tampa Graduate Theses and Dissertations

In this dissertation different van der Waals heterostructures such as graphene-MoS₂ and MoTe₂-MoS₂ were prepared and characterized. In the first heterostructure, polycrystalline graphene was synthesized by chemical vapor deposition and transferred on top of MoS₂ single crystal. In the second heterostructure, MoTe₂ monolayers were deposited on MoS₂ by molecular beam epitaxy.

Characterization of graphene-MoS₂ heterostructures was conducted by spin and angle resolve spectroscopy which showed that the electronic structure of the bulk MoS₂ and graphene in this van der Waals heterostructures is modified. For MoS₂ underneath the graphene, a band …

Secure Communication Scheme In Smart Home Environment, Hari Krishna Jonnalagadda

USF Tampa Graduate Theses and Dissertations

Internet of Things, has started to mark its existence from past few years. Right from its inception with a coke machine at Carnegie Mellon University, it has come a long way, connecting billions of devices to internet. This journey is well supported by the advancements in networking, hardware miniaturization and sensing capabilities. Diverse nature of applications of Internet of Things, has cut the communication barriers between the varieties of fields ranging from manufacturing industry to health-care industry. Smart Home is one such application of Internet of Things. Connectivity of home appliances, to achieve automation in living, defines Smart Home. Out …

Microcavity Enhanced Raman Scattering, Benjamin James Petrak

USF Tampa Graduate Theses and Dissertations

Raman scattering can accurately identify molecules by their intrinsic vibrational frequencies, but its notoriously weak scattering efficiency for gases presents a major obstacle to its practical application in gas sensing and analysis. This work explores the use of high finesse (50 000) Fabry-Pérot microcavities as a means to enhance Raman scattering from gases. A recently demonstrated laser ablation method, which carves out a micromirror template on fused silica--either on a fiber tip or bulk substrates-- was implemented, characterized, and optimized to fabricate concave micromirror templates ~10 µm diameter and radius of curvature. The fabricated templates were coated with a high-reflectivity …

Video Data Collection For Continuous Identity Assurance, Janani Venkatesan

USF Tampa Graduate Theses and Dissertations

Frequently monitoring the identity of a person connected to a secure system is an important component in a cyber-security system. Identity Assurance (IA) mechanisms which continuously confirm and verify users’ identity after the initial authentication process ensure integrity and security. Such systems prevent unauthorized access and eliminate the need of an authorized user to present credentials repeatedly for verification. Very few cyber-security systems deploy such IA modules. These IA modules are typically based on computer vision and machine learning algorithms. These algorithms work effectively when trained with representative datasets. This thesis describes our effort at collecting a small dataset of …

Blind And Visually Impaired Users Adaptation To Web Environments: A Qualitative Study, Raneem Saqr

USF Tampa Graduate Theses and Dissertations

Although much research exists on human behavior in online environments, research on users with disabilities is still rare. To draw more attention to this population, this dissertation explored browsing patterns and adaptive behaviors of people with visual disability across different online environments common in daily activities: social network, e-commerce, online information, and search engines’ websites. The main objective of this study is to propose a conceptual framework of how blind and visually impaired users browse and adapt to different web environments. We achieve this objective using a qualitative approach through three studies. In the first study, the researchers collect data …

Spatially Directional Resorcin[4]Arene Cavitand Glycoconjugates For Organic Catalysis In Aqueous Media, Ali Husain Husain

USF Tampa Graduate Theses and Dissertations

Resorcin[4]arenes and their rigid structures “cavitands” offer a unique molecular structure scaffolds suitable for attaching and orienting multi-ligands on their upper rims. Their remarkable structure properties, the relative ease of chemical modification on their either rims or through the multiple phenolic hydroxyl (-OH) groups, manipulating their cavity size and the role of spatial directionality provided by their cores, led synthetic chemist to explore their utilities in the synthesis of valuable resorcin[4]arene/cavitand assemblies with wide range of applications in many research areas such as supramolecular chemistry, host-guest chemistry, glycoconjugates, polymer chemistry, host-guest chemistry, micro-reactors in chemical catalysis and others. In particular, …

Some Results Concerning Permutation Polynomials Over Finite Fields, Stephen Lappano

USF Tampa Graduate Theses and Dissertations

Let p be a prime, p a power of p and 𝔽_q the finite field with q elements. Any function φ: 𝔽_q → 𝔽_q can be unqiuely represented by a polynomial, 𝔽_φ of degree < q. If the map x ↦ F_φ(x) induces a permutation on the underlying field we say F_φ is a permutation polynomial. Permutation polynomials have applications in many diverse fields of mathematics. In this dissertation we are generally concerned with the following question: Given a polynomial f, when does the map x ↦ F( …

Inquiry Of Lipid Membranes Interacting With Functional Peptides And Polyphenol Drug Molecules, Chian Sing Ho

USF Tampa Graduate Theses and Dissertations

Cellular membranes are important targets for many membrane-active peptides and drug compounds. Here we are interested in deciphering how lipid membranes are perturbed by several membrane-active molecules, including the transmembrane domain of the influenza M2 protein (M2TM), aggregates formed by a synthetic polyglutamine peptide, and three polyphenol compounds (i.e., tamoxifen, genistein, and verapamil). We employ phase-separated ternary lipid model membranes in the form of giant unilamellar vesicles (GUVs) to simulate raft-like structures that have been proposed to govern many important processes in plasma membranes (e.g., intracellular singling and trafficking). Specifically, we use fluorescent microscopy to interrogate how those membrane additives …

Msspark: Implementation Of Molecular Simulation Queries Using Apache Spark, Parneet Kaur

USF Tampa Graduate Theses and Dissertations

Huge amount of data is being generated in almost every field and it cannot be avoided, rather is essential for the advancement of the field. Analysis of this data requires intensive computing power. Molecular Simulation is a powerful tool for understanding the behavior of natural systems. The simulation generates large amount data while observing the spatial and temporal relationships. The challenge is to handle the analytical queries that are often compute intensive.

Although various tools exist to tackle this problem, but in this paper we have tried an alternate approach that uses Apache Spark- a modern big data platform – …

Sustainability At U.S. Urban Water Utilities: A Framework To Assess Key Attributes, Matthew Paul Ries

USF Tampa Graduate Theses and Dissertations

Urban water utilities in the United States face challenges due to a combination of external drivers. These include urbanization and population growth, which are stressing a system of aging infrastructure. Compliance with increasing regulations is also a challenge in a fiscally-constrained economic environment. A changing climate threatens infrastructure and past assumptions for water supply and quality. Urban utilities provide clean water and sanitation services to over 80% of the country’s population and its industrial centers. Therefore, the sustainability of these water utilities are crucial to the country’s and the public’s well-being.

New operating models are emerging for a “utility of …

Optimizing Methods For Extraction Of Organic Compounds From Molluscan Shells, Kaydee Jo West

USF Tampa Graduate Theses and Dissertations

Mollusk shells contain proteins within and between the crystals of calcium carbonate. These organic molecules play an important role in biomineralization and shell function, and their stable isotope ratios of carbon and nitrogen are also thought to record important ecological information about the animal's diet and nutrient sources. These proteins can be preserved for millions of years, offering potential insight into pre-anthropogenic ecological conditions. However, shell organics in older shells are typically recovered in reduced abundances due to leaching and remaining organics are often converted from insoluble proteins to soluble, free amino acids, making them difficult to detect and recover. …

The Effects Of Age And Gender On Pedestrian Traffic Injuries: A Random Parameters And Latent Class Analysis, Tatok Raharjo Raharjo

USF Tampa Graduate Theses and Dissertations

Pedestrians are vulnerable road users because they do not have any protection while they walk. They are unlike cyclists and motorcyclists who often have at least helmet protection and sometimes additional body protection (in the case of motorcyclists with body-armored jackets and pants). In the US, pedestrian fatalities are increasing and becoming an ever larger proportion of overall roadway fatalities (NHTSA, 2016), thus underscoring the need to study factors that influence pedestrian-injury severity and potentially develop appropriate countermeasures. One of the critical elements in the study of pedestrian-injury severities is to understand how injuries vary across age and gender ‒ …

Hamiltonian Formulations And Symmetry Constraints Of Soliton Hierarchies Of (1+1)-Dimensional Nonlinear Evolution Equations, Solomon Manukure

USF Tampa Graduate Theses and Dissertations

We derive two hierarchies of 1+1 dimensional soliton-type integrable systems from two spectral problems associated with the Lie algebra of the special orthogonal Lie group SO(3,R). By using the trace identity, we formulate Hamiltonian structures for the resulting equations. Further, we show that each of these equations can be written in Hamiltonian form in two distinct ways, leading to the integrability of the equations in the sense of Liouville. We also present finite-dimensional Hamiltonian systems by means of symmetry constraints and discuss their integrability based on the existence of sufficiently many integrals of motion.

Development And Validation Of A Remote Sensing Model To Identify Anthropogenic Boreholes That Provide Dry Season, Refuge Habitat For Anopheles Vector Mosquitoes In Sub-Saharan Africa, James Pkemoi Kukat

USF Tampa Graduate Theses and Dissertations

A lack of surveillance systems is an impediment to public health intervention for perennial vector-borne disease transmission in northern tropical savanna region of Kenya. The population in this area are mostly poor nomadic pastoralists with little acquired functional immunity to Plasmodium falciparum, due to infrequent challenges with the parasite. A common characteristic in tropical savanna climatic zone is the availability of riverbeds that have anthropogenic boreholes that provide malaria vector mosquitoes, such as Anopheles gambiae s.l and Anopheles funestus, with aquatic refuge habitats for proliferation and endemic transmission to proximity human households during the dry-season. Unfortunately, currently there …

Putnam's Inequality And Analytic Content In The Bergman Space, Matthew Fleeman

USF Tampa Graduate Theses and Dissertations

In this dissertation we are interested in studying two extremal problems in the Bergman space. The topics are divided into three chapters.

In Chapter 2, we study Putnam’s inequality in the Bergman space setting. In [32], the authors showed that Putnam’s inequality for the norm of self-commutators can be improved by a factor of 1 for Toeplitz operators with analytic symbol φ acting on the Bergman space A2(Ω). This improved upper bound is sharp when φ(Ω) is a disk. We show that disks are the only domains for which the upper bound is attained.

In Chapter 3, we consider the …

Identification Of Ecdysone Hormone Receptor Agonists As A Therapeutic Approach For Treating Filarial Infections, Amruta S Mhashilkar, Sai L Vankayala, Canhui Liu, Fiona Kearns, Priyanka Mehrotra, George Tzertzinis, Subba R Palli, H. Lee Woodcock Iii, Thomas R Unnasch

Chemistry Faculty Publications

BACKGROUND: A homologue of the ecdysone receptor has previously been identified in human filarial parasites. As the ecdysone receptor is not found in vertebrates, it and the regulatory pathways it controls represent attractive potential chemotherapeutic targets.

METHODOLOGY/ PRINCIPAL FINDINGS: Administration of 20-hydroxyecdysone to gerbils infected with B. malayi infective larvae disrupted their development to adult stage parasites. A stable mammalian cell line was created incorporating the B. malayi ecdysone receptor ligand-binding domain, its heterodimer partner and a secreted luciferase reporter in HEK293 cells. This was employed to screen a series of ecdysone agonist, identifying seven agonists active at sub-micromolar concentrations. …

Developing A Sustainable Water Supply In The American West: The Case Of Rio Rancho, New Mexico, Hubert B. Stroud, Mary K. Kilmer

Suburban Sustainability

Suburban and urban communities in the American West are challenged by rapid population growth combined with limited natural resources. Supporting sustainable development is of great concern in this region and in similar regions throughout the world. This research examines the sustainability of the water supply within a rapidly growing suburban city in the American West. The city, Rio Rancho, New Mexico, began as an interstate land sales operation and rapidly became a “boom” town, in part because of its location near metropolitan Albuquerque.

Because of a very limited water supply and an increasing demand for water associated with population growth, …

Global Attractors And Random Attractors Of Reaction-Diffusion Systems, Junyi Tu

USF Tampa Graduate Theses and Dissertations

The dissertation studies about the existence of three different types of attractors of three multi-component reaction-diffusion systems. These reaction-diffusion systems play important role in both chemical kinetics and biological pattern formation in the fast-growing area of mathematical biology.

In Chapter 2, we prove the existence of a global attractor and an exponential attractor for the solution semiflow of a reaction-diffusion system called Boissonade equations in the L² phase space. We show that the global attractor is an (H, E) global attractor with the L^∞ and H² regularity and that the Hausdorff dimension and the …

A Communication Protocol For Nanogrids And Its Application In Off-Grid Rural Areas Of Developing Countries, Sowmya Srikanth

USF Tampa Graduate Theses and Dissertations

In a developing country such as India, 44% of the population does not have access to power and for many others, the power supply is unreliable. A nanogrid, defined as “a single domain for voltage, reliability and administration”, is a possible solution to distribute power to such off-grid areas. Built from the bottom up, nanogrids have the ability to function independently, using locally generated power (such as solar power) as the power source. Such grids enable residents to lead more productive lives, with improved access to power. This thesis designs a new communication protocol for nanogrids to enable matching demand …

Statistical Analysis And Modeling Health Data: A Longitudinal Study, Bhikhari Prasad Tharu

USF Tampa Graduate Theses and Dissertations

Lung cancer has been considered one of the leading causes of deaths while cancer re- mains the second most common cause of deaths in the USA. Understanding the behavior of a disease over time could yield important information to make decisions about the disease. Statistical models could provide crucial clues and help to make a decision about the dis- ease, budget allocation, evaluation, and implement prevention. Longitudinal trend analysis of the diseases helps to understand long term effects and nature. Cholesterol level is one of the most contributing risk factors for Coronary Heart Disease. Studying cholesterol statistically helps to know …

Pollutants And Foraminiferal Assemblages In Torrecillas Lagoon: An Environmental Micropaleontology Approach, Michael Martinez-Colon

USF Tampa Graduate Theses and Dissertations

Torrecillas Lagoon in the North Coast of Puerto Rico has experienced extensive anthropogenic influence over the past 400 years. Elevated concentrations of Potential Toxic Elements (PTEs) have been reported in surficial sediments. The main goal of this dissertation was to implement in Puerto Rico the use of benthic foraminifers as a bioindicators of PTEs and to compare the impact of Cu(II) on field samples with results of experimental work using cultures.

Analyses included geochemical assessment for bulk and carbonate- soluble bioavailable concentrations of PTEs in surface, core and pore-water samples, as well as analyses of grain-size, Percent Total Organic Carbon …

Alumni Narratives On Computational Geology (Spring 1997 – Fall 2013), Victor J. Ricchezza

USF Tampa Graduate Theses and Dissertations

Recent meetings and publications have discussed what geoscience undergraduates should learn for professional success, and among other items, have identified several quantitative skills and habits of mind as being necessary for geoscience students; many of these items are commonly associated with Quantitative Literacy (QL). The Computational Geology course in the geology department has been evolving at USF for 20 years. The course teaches QL in a geologic setting independent of specific core geology topics. This course has long preceded the national acknowledgment of the need for what it teaches within the field. As the first of a series of related …

Determining The Effectiveness Of Soil Treatment On Plant Stress Using Smart-Phone Cameras, Anurag Panwar

USF Tampa Graduate Theses and Dissertations

Plants are vital to the health of our biosphere, and effectively sustaining their growth is fundamental to the existence of life on this planet. A critical aspect, which decides the sustainability of plant growth is the quality of soil. All other things being fixed, the quality of soil greatly impacts the plant stress, which in turn impacts overall health. Although plant stress manifests in many ways, one of the clearest indicators are colors of the leaves. In this thesis, we conducted an experimental study in a greenhouse for detecting plant stress caused by nutrient deficienceies in soil using smartphone cameras, …

The Design And Testing Of A Novel Batch Photocatalytic Reactor And Photocatalyst, Shawn Sasser

USF Tampa Graduate Theses and Dissertations

With an ever-increasing human population, the importance in having sustainable energy resources is becoming increasingly evident, as the current energy habits have brought about massive atmospheric pollution in the form of CO₂ emissions, resulting in a rise in the average global temperature. To battle the effects of climate change, many alternative energy resources have been investigated. Among these, photocatalytic conversion of CO₂ to renewable hydrocarbon fuels such as methane and methanol is one of the most desirable, as it provides the opportunity to utilize the sun’s energy to convert CO₂ to renewable fuels. The work in this …

Statistical Modeling Of Carbon Dioxide And Cluster Analysis Of Time Dependent Information: Lag Target Time Series Clustering, Multi-Factor Time Series Clustering, And Multi-Level Time Series Clustering, Doo Young Kim

USF Tampa Graduate Theses and Dissertations

The current study consists of three major parts. Statistical modeling, the connection between statistical modeling and cluster analysis, and proposing new methods to cluster time dependent information.

First, we perform a statistical modeling of the Carbon Dioxide (CO₂) emission in South Korea in order to identify the attributable variables including interaction effects. One of the hot issues in the earth in 21st century is Global warming which is caused by the marriage between atmospheric temperature and CO₂ in the atmosphere. When we confront this global problem, we first need to verify what causes the problem then we …

Is Uplift Of Volcano Clusters In The Tohoku Volcanic Arc, Japan, Driven By Magma Accumulation In Hot Zones? A Geodynamic Modeling Study, Ophelia A. George, Rocco Malservisi, Rob Govers, Charles B. Connor, Laura J. Connor

School of Geosciences Faculty and Staff Publications

In many volcanic arcs, the rate of tectonic uplift cannot be explained by lithospheric plate motion alone but may be associated with dynamic uplift. Buoyant forces associated with underplated magma bodies lift the upper crust and leads to relatively high rates of topographic change. One such region is northern Honshu, Japan, where Quaternary volcano clusters are spatially associated with uplifted crust and isostatic gravity anomalies. Axisymmetric inversion of Bouguer gravity data for the Sengan volcano cluster shows that these gravity anomalies can be modeled by 30 km radius bodies emplaced at ∼15 km depth. Axisymmetric, finite element models, generated using …

Applications Of Satellite Geodesy In Environmental And Climate Change, Qian Yang

USF Tampa Graduate Theses and Dissertations

Satellite geodesy plays an important role in earth observation. This dissertation presents three applications of satellite geodesy in environmental and climate change. Three satellite geodesy techniques are used: high-precision Global Positioning System (GPS), the Gravity Recovery and Climate Experiment (GRACE) and Interferometric Synthetic Aperture Radar (InSAR). In the first study, I use coastal uplift observed by GPS to study the annual changes in mass loss of the Greenland ice sheet. The data show both spatial and temporal variations of coastal ice mass loss and suggest that a combination of warm atmospheric and oceanic condition drove these variations. In the second …

Nano-Photonic Waveguides For Chemical And Biomedical Sensing, Surya Venkatasekhar Cheemalapati

USF Tampa Graduate Theses and Dissertations

In this dissertation, advances in the fields of Photonics, and Plasmonics, and specifically, single cell analysis and waveguide sensing will be addressed. The first part of the dissertation is on Finite Difference Time Domain (FDTD) optimization and experimental demonstration of a nano-scale instrument that allows sensing at the cellular and subcellular levels. A new design of plasmonic coupler into a nanoscale waveguide is proposed and optimized using FDTD simulations. Following this, a subcellular nanoendoscope that can locally excite fluorescence in labelled cell organelles and collect the emitted fluorescent light for detailed spectrum analysis is fabricated and tested. The nanoendoscope has …