Physical Sciences and Mathematics Commons^™

Geophysical Model Of The Cu-Mo Porphyry Ore Deposit At Copper Flat Mine, Hillsboro, Sierra County, New Mexico, Adrian Emmanuel Gutierrez

Open Access Theses & Dissertations

A 3D gravity model of the Copper Flat Mine was performed as part of the exploration of new resources in at the mine. The project is located in the Las Animas Mining District in Sierra County, New Mexico. The mine has been producing ore since 1877 and is currently owned by the New Mexico Copper Corporation, which plans o bringing the closed copper mine back into production with innovation and a sustainable approach to mining development. The Project is located on the Eastern side of the Arizona-Sonora-New Mexico porphyry copper Belt of Cretaceous age. Copper Flat is predominantly a Cretaceous …

Furthering Our Understanding And Assessing The Effectiveness Of Scaling Patterns And Controls Of Land-Atmosphere Carbon Exchange In A Shrubland Of The Chihuahuan Desert With Novel Cyberinfrastructure, Aline Jaimes

Open Access Theses & Dissertations

Over the last century, arid and semiarid regions have undergone intense desertification and in many regions, vegetation has shifted from grassland to shrubland dominated ecosystems. This land cover change has important implications for how desert ecosystems function - especially with regards to land-atmosphere exchange of carbon, water, and energy. Although the extent of desertified landscapes is expected to expand over the next 30 to 40 years, there is a relatively poor understanding of how this state transition will impact ecosystem function and feedbacks to other components of the earth system. Key to addressing this challenge is an improved understanding of …

Structural Investigation Of The Molecular Chaperonin Tf55 From Thermophilic Archaeon Sulfolobus Solfataricus, Sanjay Kumar Molugu

Open Access Theses & Dissertations

Chaperonins are ubiquitous multi-subunit macromolecules that mediate the folding and assembly of certain proteins that cannot fold properly in vivo. The Archaea bacterium Sulfolobus solfataricus encodes for three chaperonin complexes formed from three different, but closely related subunits named alpha,betaand Gamma. These subunits form a homo-18mer composed of all beta subunits at temperatures ranging between 80oC-85oC, a hetero-16mer composed of alpha and beta subunits at temperatures ranging between 70oC-75oC and a hetero 18mer composed of alpha, beta and gamma subunits at temperatures of 60oC. Structures exist for the chaperonin TF55 all-beta complex and for the TF55 alpha-beta complex but not …

Design And Evaluation Of A High Temperature/Pressure Supercritical Carbon Dioxide Direct Tubular Receiver For Concentrating Solar Power Applications, Jesus Daniel Ortega

Open Access Theses & Dissertations

This work focuses on the development of a solar power thermal receiver for a supercritical-carbon dioxide (sCO2), Brayton power-cycle to produce ~1 MWe. Closed-loop sCO2 Brayton cycles are being evaluated in combination with concentrating solar power to provide higher thermal-to-electric conversion efficiencies relative to conventional steam Rankine cycles. High temperatures (923 - 973 K) and pressures (20 - 25 MPa) are required in the solar receiver to achieve thermal efficiencies of ~50%, making concentrating solar power (CSP) technologies a competitive alternative to current power generation methods. In this study, the CSP receiver is required to achieve an outlet temperature of …

Residential Electricity Demand In Arkansas, Ileana M. Resendez

Open Access Theses & Dissertations

This study analyzes residential electricity demand in Arkansas. Explanatory variables utilized include real per capita income, residential electricity price, heating degree days, cooling degree days, and residential natural gas price. The results indicate that the income effect dominates the substitution effect given a real personal income increase and a decline in real electricity rates in the state of Arkansas during the period under study.

Water Recovery From Silica Saturated Ro Concentrate By The Concentrate Enhanced Reverse Osmosis Process, Gautam Patwardhan

Open Access Theses & Dissertations

Membrane fouling due to silica precipitation during reverse osmosis (RO) continues to be documented as the most common challenge in attaining stable continuous operation of RO systems across water treatment plants (1). Silica scale precipitation is time dependent and involves multiple steps leading to aqueous polymerization, condensation of polymers to form colloids, and deposition onto a solid surface (2). Exceeding the solubility of silica, widely considered to be in the range of 100-140 ppm, under a pH of 8 at 25 °C by various researchers, results in the precipitation of silica on the membranes, thereby limiting water recovery. Once the …

Finite Density Qed At Strong Magnetic Field, Paul Lee Springsteen

Open Access Theses & Dissertations

In this Thesis we study the effect of a dense medium on the quantum properties of a relativistic electron-positron plasma under a magnetic field. From the calculation of the photon polarization operator depending on temperature, chemical potential, and the magnetic field; we study how the electric susceptibility of the strongly magnetized plasma is charged with temperature and density. In the same manner we study the dependence of the Debye mass with density. Then we investigated the phenomenon of magnetic catalysis of chiral symmetry breaking for a dense medium. We found that there exist a critical value of the chemical potential …

Variable Selection For Cox Proportional Hazards Models Via Subtle Uprooting, Chalani S. Wijayasinghe

Open Access Theses & Dissertations

Cox proportional hazards model (Cox PH model) is heavily used in survival analysis to assess the importance of various covariates on the survival times of individuals or objects through the hazard function. This study suggests a new variables selection method for Cox PH models, under the title 'Subtle uprooting', that does variable selection and model estimation for Cox proportional hazards (PH) models simultaneously.

There are subset selection methods and shrinkage selection methods suggested in the context of Cox PH model. However the subset selection methods become infeasible in higher dimensions and the available shrinkage methods need tuning of parameters making …

Natural Selectivity Of Nickel And Vanadium In Crude Oil, Olienka P. De La O Fernandez

Open Access Theses & Dissertations

Nickel and Vanadium have always been found in crude oil all around the world. The metal content is found mainly in porphyrin structures in the asphaltene fraction of the petroleum. In order to determine the reason for this natural preference, a set of experiments testing thermodynamics, kinetics, and other factors were performed. Candidate metalloporphyrins containing Vanadyl, Chromium, Iron, Nickel, Copper and Zinc were analyzed through chemical reactions characterized using Silica Column Chromatography, HPLC, MS and UV-Visible. Theoretical analysis of the stability of metalloporphyrins was conducted using DFT/NRLMOL for computational calculation. The analysis of all factors leads us to conclude that …

Isomerase Activity Of Candida Rugosa Lipase In Conversion Of Racemic Ibuprofen To (S)-Ibuprofen, Saideh Sadat Mortazavi

Open Access Theses & Dissertations

The Candida rugosa lipase-catalyzed Dynamic Kinetic Resolution of racemic ibuprofen methyl ester was optimal at pH 7.6 to produce (S)-ibuprofen in 72 hours. The concentration of various buffers for these reactions ranged from 0.2 to 0.5 M. The commercial lipase was found to be acidic altering the final pH of the reaction mixtures. Dimethylformamide co-solvent maintained the reaction pH better than dimethylsulfoxide, with evidence of the latter functioning as an oxidizing agent. Lower concentrations of ibuprofen methyl ester and higher stirring rates led to faster conversions. The minimal amount of lipase needed was 20 mg/mL buffer. Reaction of (R)-ibuprofen methyl …

Design And Synthesis Of Porous Organic Frameworks For H2 And Ch4 Storage And For Selective Co2 Adsorption, Venkata Neti

Open Access Theses & Dissertations

Three new boronate-ester based covalent organic frameworks (CoPc-PorDBA, CoPc-BPDA and HHTP-PorDBA), an imine-linked porphyrin porous polymer (CuPor-BPDC) and imine and benzothiazole based porous polymers (IBTP), and a triazole based phthalocyanine "click" polymer (Pc-POP) were synthesized. The CoPc-PorDBA and CoPc-BPDA COFs exhibited high BET surface areas (1087, 1315 m2 g-1, respectively) whereas HHTP-PorDBA showed a low BET surface area of 205 m2 g-1. The H2 storage capacities of CoPc-BPDA and CoPc-PorDBA range between 0.8-1.2wt% at 77K, 1bar and the CH4 storage capacities range between 0.4-0.8wt% at 298K, 1bar. These materials also had good thermal stabilities up to 350° C. The BET …

Determination Of The Uptake And Effects Of Tio2 Nanoparticles In Cucumber (Cucumis Sativus), Alia D. Servin

Open Access Theses & Dissertations

The profuse use of nanoparticles (NPs) in consumer products has raised concerns about their impacts in environmental and human health and possible transfer into the food chain through plants. Cucumber (Cucumis sativus L.) is a widely cultivated garden vegetable that could be in contact with NPs through biosolids. In this Dissertation research, the impact of TiO2 NPs was evaluated in cucumber plants grown in hydroponics and sandy loam soil. Hydroponically grown plants were treated for 15 days with 0-4000 mg/L of TiO2 NPs, and their vegetative tissues were studied using synchrotron micro X-Ray Fluorescence (micro-XRF) and Micro X-ray Absorption Near …

Exploring The Hydrogeologic Controls On Brackish Water And Its Suitability For Use In Hydraulic Fracturing: The Dockum Aquifer, Midland Basin, Texas, Francisco Ruben Reyes

Open Access Theses & Dissertations

Water scarcity in arid regions can limit or impede certain hydrocarbon production activities, such as hydraulic fracturing and well drilling. The Midland Basin, a major oil-producing area in semi-arid far west Texas and the eastern sub-basin of the Permian Basin, is already impacted by limited freshwater availability. A typical tight oil well in the Midland Basin requires ~3.8–11.4 × 103 m3 of water per fracture treatment (Nicot et al., 2012). Despite draught conditions and limited resources, data for 2011 indicate freshwater comprises ~70% of the water used in hydraulic fracturing in the Midland basin. Thus, the Midland Basin represents an …

Hispanic Communities And Environmental Justice: A Comparative Study Of Mobility And Exposure To Air Toxics In Houston, Maricarmen Hernandez

Open Access Theses & Dissertations

Environmental justice research has focused too little attention on immigrant communities. This study extends from the premise that themes of immigration and mobility among racial/ethnic minority communities must be more carefully analyzed by environmental justice (EJ) scholars. By clarifying why Hispanic people live where they live, and what factors shape their exposures to cancer risks from hazardous air pollutants, this study aims to contribute to the existing EJ body of knowledge. The analysis employs qualitative methods, implemented as part of a larger National Science Foundation-funded study. In-depth semi-structured phone interviews were conducted with randomly selected Hispanic individuals, some of whom …

Alkali Promoted Molybdenum (Iv) Sulfide Based Catalysts, Development And Characterization For Alcohol Synthesis From Carbon Monoxide And Hydrogen, Belinda Delilah Molina

Open Access Theses & Dissertations

For more than a century transition metal sulfides (TMS) have been the anchor of hydro-processing fuels and upgrading bitumen and coal in refineries worldwide. As oil supplies dwindle and environmental laws become more stringent, there is a greater need for cleaner alternative fuels and/or synthetic fuels. The depletion of oil reserves and a rapidly increasing energy demand worldwide, together with the interest to reduce dependence on foreign oil makes alcohol production for fuels and chemicals via the Fischer Tropsch synthesis (FTS) very attractive. The original Fischer-Tropsch (FT) reaction is the heart of all gas-to-liquid technologies; it creates higher alcohols and …

Essays On The Digital Divide, Belal Abdelfattah

Open Access Theses & Dissertations

The digital divide is a phenomenon that is globally persistent, despite rapidly decreasing costs in technology. While much of the variance in the adoption and use of information communication technology (ICT) that defines the digital divide can be explained by socioeconomic and demographic variables, there is still significant unaccounted variance that needs to be explained if the world's population is expected to be brought more fully into the digital age. The present research addresses this need with three cross-country studies. Study 1 primarily investigates the time individuals spend with traditional media sources as a likely explanation for their frequency of …

Development Of A Transferable Student Engagement And Knowledge Retention Framework For The Earth Sciences, Sunay Palsole

Open Access Theses & Dissertations

The earth sciences play an important role in engaging students in science and in science, technology, engineering and mathematics (STEM) disciplines, because of the integrative nature of the disciplines. It then becomes important for us to provide an engaging experience for students taking earth science courses, because it serves a dual purpose of possibly increasing new majors in the discipline and helping to create a science literate population.

Given that a majority of students in the larger introductory courses are non-majors, it behooves us to explore alternative engagement techniques and measure their efficacy in student engagement, which in turn can …

A Block Precondtioner For A Mixed Finite Element Method For Biot;S Equations, Maranda Lee Bean

Open Access Theses & Dissertations

In this Thesis, we explore the solution methods for the linear system resulting from a mixed finite element method applied to the Biot's consolidation model. This model describes the coupled interactions between a porous solid and the fluid contained within it. Specifically, we use a method developed by Yi [Numer. Methods for PDEs, 29(5), pp. 1749-1777] that expands Biot's system to include fluid pressure, solid displacement, fluid flux and total stress as primary unknowns.

As the resulting linear system is a large, sparse, saddle point system, we attempt to solve this system via a Schur complement preconditioned iterative method. Using …

Risk Assessment Of Waterborne Cryptosporidium, Victoria Norma Ochoa

Open Access Theses & Dissertations

In an effort to update the risk assessment of waterborne Cryptosporidium an additional and more complete human dose-response dataset of the parasite was used to calculate the risk of infection. The complete data studied contains larger human outcomes than the initial prior risk assessment evaluated by Haas et. al. in 1999. Quantitative analysis of the complete dose-response indicates that it no longer follows the Exponential Model used to estimate the risk for the initial data. The complete dataset appears to provide a better fit with the Beta-Poisson Model and even a dose independent constant risk model, which shows a considerable …

Super Resolution Pump-Probe Microscopy With Point Spread Function Engineering, Farzaneh Mohajerani

Open Access Theses & Dissertations

Since the last decade, new techniques have made optical microscopy break the diffraction barrier of resolution where all of them are based on molecular fluorescence. Among them, stimulated emission depletion microscopy (STED) has reached less than 25 nm resolution by engineering the point spread function. However, the existing obstacles associated with fluorescence tagging makes it desirable to achieve label-free imaging. Recently the pump-probe method has made it possible to obtain image contrast from molecular absorption and vibration signatures that do not depend on fluorescence. We introduce Super Resolution Pump-Probe Microscopy (SRPPM), in which we combine both PSF engineering method and …

Effects Of Cerium Oxide Nanoparticles In Cereals: Insights Into The Toxicity Mechanisms And Macromolecular Modifications, Cyren Mendoza Rico

Open Access Theses & Dissertations

Despite the inundation of studies on the interaction of engineered nanomaterials (ENMs) with plants, investigations involving complete life cycle (i.e from seedling establishment to full maturity) are still lacking. Assessments on the nutritional value of plants cultivated to full maturity in ENMs-treated soil are also missing. Cerium oxide nanoparticles (nCeO2) have significant interactions with plants; however, there are no life cycle studies yet on their implications in cereals like rice (Oryza sativa L.), wheat (Triticum aestivum L.), and barley (Hordeum vulgare L.). These cereals are globally important crops that support the economic activity, and nutritional and health needs of billions …

Three Essays On Social/Political Structures And Icts Use, Seungeui Ryu

Open Access Theses & Dissertations

My research identifies how social structures affect the use of the Internet and/or a mobile chat application and how the Internet impacts the political structure of a nation. In my first essay of the 3-essay Dissertation, I am designing three models based on social structure theory that are used to study the Internet and a popular mobile chat application's use by managers in South Korea, with the help of a survey instrument. In my first essay, the contribution is on i) testing a model of manager's personal behavior on Information and Communication Technology (ICT) use at the individual level involving …

Two-Photon Microscopy For Biomedical Studies, Yassel Acosta

Open Access Theses & Dissertations

Fluorescence optical microscopy is one of the most important tools to investigate biological samples and to observe structures in living cells. Based on the principle of the simultaneous absorption of two-photons and subsequent emission of fluorescent light we have developed a Two-Photon Laser Scanning Fluorescence Microscope that allow us to perform optical sectioning and three-dimensional reconstructions of structures in biological samples such as dopaminergic clusters of neurons and tracheal branches in Drosophila brain. The spatial confinement of the excitation light to the focal plane combined with the temporal compression of photons into short packets during femtosecond pulses make our system …

Solar Pv Power Generation Forecasting Using Hybrid Intelligent Algorithms And Uncertainty Quantification Based On Bootstrap Confidence Intervals, Donna Alhakeem

Open Access Theses & Dissertations

This Thesis focuses on short-term photovoltaic forecasting (STPVF) for the power generation of a solar PV system using probabilistic forecasts and deterministic forecasts. Uncertainty estimation, in the form of a probabilistic forecast, is emphasized in this Thesis to quantify the uncertainties of the deterministic forecasts. Two hybrid intelligent models are proposed in two separate chapters to perform the STPVF. In Chapter 4, the framework of the deterministic proposed hybrid intelligent model is presented, which is a combination of wavelet transform (WT) that is a data filtering technique and a soft computing model (SCM) that is generalized regression neural network (GRNN). …

Electronic Structure And Charge Transfer Excited States Of Endohedral Fullerene Containing Electron Donor-Acceptor Complexes Utilized In Organic Photovoltaics, Fatemeh Amerikheirabadi

Open Access Theses & Dissertations

Organic Donor &ndash Acceptor complexes form the main component of the organic photovoltaic devices (OPVs). The open circuit voltage of OPVs is directly related to the charge transfer excited state energies of these complexes. Currently a large number of different molecular complexes are being tested for their efficiency in photovoltaic devices. In this work, density functional theory as implemented in the NRLMOL code is used to investigate the electronic structure and related properties of these donor &ndash acceptor complexes. The charge transfer excitation energies are calculated using the perturbative delta self &ndash consistent field method recently developed in our group …

Long-Term Deformation In The Southern Rí­O Grande Rift As Inferred From Topographic And Uplifted Terraces, Linda K. Armour

Open Access Theses & Dissertations

This study examines Basin and Range topography relating tectonic processes to topographic features. The observation that the terraces along either side of the Franklin Mountains were deformed and uplifted is a reflection of tectonic uplift. The uplift represents long-term deformation of the range. This led to the question of what shapes the deformation and does it represent differential subsidence into the Río Grande Rift or true uplift. A more regional study of the Sacramento, San Andres, and Guadalupe Mountains follows. Two papers form this Dissertation.

The Rí­o Grande Rift and the Franklin Mountains, in particular, are the subject of the …

The Study Of The Dielectric Properties Of The Endohedral Fullerenes, Shusil Bhusal

Open Access Theses & Dissertations

Dielectric response of the metal nitride fullerenes is studied using the density functional theory at the all-electron level using generalized gradient approximation. The dielectric response is studied by computing the static dipole polarizabilities using the finite field method, i.e. by numerically differentiating the dipole moments with respect to electric field. The endohedral fullerenes studied in this work are Sc3N@C68(6140), Sc3N@C68(6146), Sc3N@C70(7854), Sc3N@C70(7960), Sc3N@C76(17490), Sc3N@C78(22010), Sc3N@C80(31923), Sc3N@C80(31924), Sc3N@C82(39663), Sc3N@C90(43), Sc3N@C90(44), Sc3N@C92(85), Sc3N@C94(121), Sc3N@C96(186), Sc3N@C98(166). Using the Voronoi and Hirschfield approaches as implemented in our NRLMOL code, we determine the atomic contributions to the total polarizability. The site-specific contributions to the polarizability …

Impacting Earthquake Science And Geoscience Education: Educational Programming To Earthquake Relocation, Tina Louise Carrick

Open Access Theses & Dissertations

This Dissertation is comprised of four studies: three related to research on geoscience education and another seismological study of the South Island of New Zealand. The geoscience education research is grounded in 10 years of data collection and its implications for best practices for recruitment and retention of underrepresented minority students into higher education in the geosciences. The seismological component contains results from the relocation of earthquakes from the 2009 Dusky Sound Mw 7.8 event, South Island, New Zealand.

In recent years, many have cited a major concern that U.S. is not producing enough STEM graduates to fit the forecasted …

Geophysical Investigation Of Hot Springs In The Vicinity Of Shoshone, California, Felix Dziedzorm Ziwu

Open Access Theses & Dissertations

Magnetic and gravity surveys were conducted in the vicinity of Shoshone, California to test a hypothesis from investigating hotsprings within Tecopa and Saratoga which states that deep faults must intersect with a specific orientation relative to the regional stress field in order to create hot springs along the Amargosa River.

Three isolated basalt flows with different gravity and magnetic properties were identified near the Shoshone hot spring. Two of the flows have very low magnetic anomalies and the remaining one has a high magnetic anomaly. The high magnetic anomaly basalt flow also has a significantly higher Bouguer anomaly than the …

An Optimization Of Neighbor Discovery In Mobile Ad Hoc Networks, Felipe Jovel

Open Access Theses & Dissertations

This Thesis aims to improve the performance of Mobile Ad Hoc Networks (MANETs) that use soft-state signaling for neighbor discovery, specifically OLSR. In particular, it uses simulations and previous work based on experiments conducted on a physical test bed to study the behavior of the neighbor-discovery algorithm used by OLSR to identify and explore ways to optimize the neighbor-discovery process. Candidate optimizations include the actual and relative settings of the refresh and expiry timers used by the algorithm.

Previous studies focused on understanding how the settings of the algorithms Hello Interval (δ) and TC Interval refresh timers affect network performance …