Physical Sciences and Mathematics Commons^™

The Lateral Extent And Spatial Variation Of Mercury Exposure In Birds And Their Prey Near A Polluted River, Mikaela Gioia Selene Howie

Dissertations, Theses, and Masters Projects

No abstract provided.

Multimodal Non-Rigid Registration For Image-Guided Head And Neck Surgery, Michael Lawrence Weissberger

Dissertations, Theses, and Masters Projects

No abstract provided.

"You Have No Boss Here To Work For": Women And Labor In Chesapeake Bay Fishing Communities, Elizabeth Marie O'Grady

Dissertations, Theses, and Masters Projects

No abstract provided.

Adaptive Learning And Cryptography, David Goldenberg

Dissertations, Theses, and Masters Projects

Significant links exist between cryptography and computational learning theory. Cryptographic functions are the usual method of demonstrating significant intractability results in computational learning theory as they can demonstrate that certain problems are hard in a representation independent sense. On the other hand, hard learning problems have been used to create efficient cryptographic protocols such as authentication schemes, pseudo-random permutations and functions, and even public key encryption schemes.;Learning theory / coding theory also impacts cryptography in that it enables cryptographic primitives to deal with the issues of noise or bias in their inputs. Several different constructions of "fuzzy" primitives exist, a …

Silver-Polyimide Nanocomposite Films: Single-Stage Synthesis And Analysis Of Metalized Partially-Fluorinated Polyimide Btda/4-Bdaf Prepared From Silver(I) Complexes, Joshua Erold Robert Abelard

Dissertations, Theses, and Masters Projects

No abstract provided.

Acoustics Of Anthropogenic Habitats: The Impact Of Noise Pollution On Eastern Bluebirds, Caitlin Rebecca Kight

Dissertations, Theses, and Masters Projects

An increasing number of habitats are affected by anthropogenic noise pollution, which is often louder, has a different frequency emphasis, and may occur over a different temporal scale, than natural noise. An increasing number of studies indicate that acoustically-communicating animals in such areas can modify their vocalizations in order to make themselves heard over the noise, but many questions still remain, including: How taxonomically widespread is vocal flexibility in response to anthropogenic noise, and do all vocally flexible species employ the same mechanisms to escape acoustic masking? Are there fitness repercussions for living, communicating, and breeding in noisy habitats? and, …

Virginia Game Fish Tagging Program Annual Report 2009, John A. Lucy, Lewis Gillingham

Reports

Through 2009, the Virginia Game Fish Tagging Program has maintained a 15-year database for tagged and recaptured fish. The program is a cooperative project of the Virginia Saltwater Fishing Tournament (under the Virginia Marine Resources Commission/VMRC) and the Virginia Institute of Marine Science (VIMS) of the College of William and Mary (under VIMS Sea Grant Marine Extension Program).

Fairfax County And The City Of Alexandria, Virginia Shoreline Inventory Report Methods And Guidelines, Marcia Berman, Harry Berquist, Sharon Killeen, Carl Hershner, Karinna Nunez, Karen Reay, Tamia Rudnicky

Reports

The data inventory developed for the Shoreline Inventory is based on a three‑tiered shoreline assessment approach. In most cases this assessment characterizes conditions that can be observed from a small boat navigating along the shoreline. The three tiered shoreline assessment approach divides the shorezone into three regions: 1) the immediate riparian zone, evaluated for land use; 2) the bank, evaluated for height, stability, cover and natural protection; and 3) the shoreline, describing the presence of shoreline structures for shore protection and recreational purposes. Hand-held GPS units are used to log features observed in the field.

Three GIS coverages are developed …

Copper(I) Complexes Of Heterocyclic Thiourea Ligands, Aakarsh Saxena, Emily C. Dugan, Jeffrey Liaw, Matthew D. Dembo, Robert D. Pike

Arts & Sciences Articles

The coordination of heterocyclic thiourea ligands (L = N-(2-pyridyl)-N′-phenylthiourea (1), N-(2-pyridyl)-N′-methylthiourea (2), N-(3-pyridyl)-N′-phenylthiourea (3), N-(3-pyridyl)-N′-methylthiourea (4), N-(4-pyridyl)-N′-phenylthiourea (5), N-(2-pyrimidyl)-N′-phenylthiourea (6), N-(2-pyrimidyl)-N′-methylthiourea (7), N-(2-thiazolyl)-N′-methylthiourea (8), N-(2-benzothiazolyl)-N′-methylthiourea (9), N,N′-bis(2-pyridyl)thiourea (10) and N,N′-bis(3-pyridyl)thiourea (11)) with CuX (X = Cl, Br, I, NO3) has been investigated. CuX:L product stoichiometries of 1:1–1:5 were found, with 1:1 being most common. X-ray structures of four 3-coordinate mononuclear CuXL2 complexes (CuCl(6)2, CuCl(7)2, CuBr(6)2, and CuBr(9)2) …

Estimating Relative Abundance Of Young-Of-Year American Eel, Anguilla Rostrata, In The Virginia Tributaries Of Chesapeake Bay (Spring 2009), Troy D. Tuckey, Mary C. Fabrizio

Reports

The Atlantic States Marine Fisheries Commission (ASMFC) adopted the Interstate Fishery Management Plan (FMP) for the American eel in November 1999. The FMP focuses on increasing coastal states’ efforts to collect American eel data through both fishery-dependent and fishery-independent studies. Consequently, member jurisdictions agreed to implement an annual survey for young-of-year (YOY) American eels. The survey is intended to “…characterize trends in annual recruitment of the YOY eels over time [to produce a] qualitative appraisal of the annual recruitment of American eel to the U.S. Atlantic Coast” (ASMFC 2000). The development of these surveys began in 2000 with full implementation …

Status Of The Major Oyster Diseases In Virginia 2006-2008 A Summary Of The Annual Oyster Disease Monitoring Program, Ryan Carnegie, Eugene M. Burreson

Reports

Fall Survey sampling revealed P. marinus levels to be generally normal to high in Virginia tributaries. By 2007 P. marinus was present on every oyster reef sampled, and by the end of the 2006-2008 period the parasite was probably causing some mortality throughout Virginia waters. Data for H. nelsoni are still incomplete for 2006/7 because of funding limitations, but in 2008 H. nelsoni was observed at 17 of 31 sampled reefs, a marked expansion in distribution since 2003/4. A significant MSX disease outbreak occurred in the Great Wicomico River in 2008, as a mild winter and a long period of …

City Of Newport News, Virginia Shoreline Inventory Report Methods And Guidelines, Marcia Berman, Harry Berquist, Sharon Killeen, Carl Hershner, Karinna Nunez, Karen Reay, Tamia Rudnicky, Daniel Schatt, Dave Weiss

Reports

This shoreline inventory is developed as a tool for assessing conditions along the tidal shoreline in the City of Newport News. Field data were collected during July and September 2002, and data were updated using VBMP 2006/2007 imagery. Conditions are reported for three zones within the immediate riparian river area: riparian land use, bank and buffers, and the shoreline. A series of maps and tabular data are published to illustrate and quantify results of an extensive shoreline survey. Shorelines of the James River, Skiffes Creek, Warwick River and Deep Creek, including small tributaries, were surveyed. Some sections were coded using …

Sand Dunes And Beaches In Virginia: Science And Management, Pamela Mason

Reports

No abstract provided.

2009 York County, Virginia Shoreline Inventory Report Methods And Guidelines, Marcia Berman, Harry Berquist, Sharon Killeen, Carl Hershner, Karinna Nunez, Karen Reay, Tamia Rudnicky, Daniel E. Schatt, David Weiss

Reports

The data inventory developed for the Shoreline Inventory is based on a three tiered shoreline assessment approach. In most cases this assessment characterizes conditions that can be observed from a small boat navigating along the shoreline. The three tiered shoreline assessment approach divides the shorezone into three regions: 1) the immediate riparian zone, evaluated for land use; 2) the bank, evaluated for height, stability, cover and natural protection; and 3) the shoreline, describing the presence of shoreline structures for shore protection and recreational purposes.

The 2009 Inventory for York County was updated using on-screen, digitizing techniques in ArcMap v10.0 while …

Virginia Wetlands Report Vol. 24, No. 2, Virginia Institute Of Marine Science, Center For Coastal Resources Management

Virginia Wetlands Reports

Current Issues in Coastal Resources

Sand Dune And Beaches In Virginia: Science And Management, Center For Coastal Resources Management, Virginia Institute Of Marine Science

Reports

Rivers & Coast is a periodic publication of the Center for Coastal Resources Management, Virginia Institute of Marine Science. The goal of Rivers & Coast is to keep readers well informed of current scientific understanding behind key environmental issues related to watershed rivers and coastal ecosystems of the Chesapeake Bay.

Evolving Guidance For Tidal Wetlands Management, Center For Coastal Resources Management, Virginia Institute Of Marine Science

Reports

Rivers & Coast is a periodic publication of the Center for Coastal Resources Management, Virginia Institute of Marine Science. The goal of Rivers & Coast is to keep readers well informed of current scientific understanding behind key environmental issues related to watershed rivers and coastal ecosystems of the Chesapeake Bay.

The Capacity For Multistability In Small Gene Regulatory Networks, Dan Siegal-Gaskins, Erich Grotewold, Gregory D. Smith

Arts & Sciences Articles

Background

Recent years have seen a dramatic increase in the use of mathematical modeling to gain insight into gene regulatory network behavior across many different organisms. In particular, there has been considerable interest in using mathematical tools to understand how multistable regulatory networks may contribute to developmental processes such as cell fate determination. Indeed, such a network may subserve the formation of unicellular leaf hairs (trichomes) in the model plant Arabidopsis thaliana.

Results

In order to investigate the capacity of small gene regulatory networks to generate multiple equilibria, we present a chemical reaction network (CRN)-based modeling formalism and describe …

A Guide To Shoreline Management Planning For Virginia’S Coastal Localities, Donna A. Milligan, C. Scott Hardaway Jr.

Reports

Short pamphlet describing methods for managing and making recommendations for shorelines.

Water Quality Conditions And Restoration Of Submerged Aquatic Vegetation (Sav) In The Tidal Freshwater James River, 2008, Ken Moore, Betty Berry Neikirk, Erin C. Shields, David Parrish

Reports

In 2008, wild celery (Vallisneria americana), water stargrass (Heteranthera dubia) and hydrilla (Hydrilla verticilata) shoots were transplanted into shallow water sites in the Hopewell region of the tidal James River and sampled for survivorship and growth throughout the SA V growing season. Water quality sampling was conducted at bi-weekly intervals throughout the year for water column nutrients, chlorophyll a, suspended solids, water transparency and other chemical and physical constituents important for SA V growth. Continuous water quality sampling was also conducted along the James River from the mouth of the Chickahominy River to the upstream limits of tidal water at …

Evaluating Recruitment Of American Eel, Anguilla Rostrata, In The Potomac River (Spring 2009), Troy D. Tuckey, Mary C. Fabrizio

Reports

The Atlantic States Marine Fisheries Commission (ASMFC) adopted the Interstate Fishery Management Plan (FMP) for the American eel in November 1999. The FMP focuses on increasing coastal states’ efforts to collect American eel data through both fishery-dependent and fishery-independent studies. Consequently, member jurisdictions agreed to implement an annual survey for young of year (YOY) American eels. The survey is intended to “…characterize trends in annual recruitment of the YOY eels over time [to produce a] qualitative appraisal of the annual recruitment of American eel to the U.S. Atlantic Coast” (ASMFC 2000). The development of these surveys began in 2000 with …

Global Change And Eutrophication Of Coastal Waters, N. N. Rabalais, R.E. Turner, Robert J. Diaz, Dubravko Justic

VIMS Articles

The cumulative effects of global change, including climate change, increased population, and more intense industrialization and agribusiness, will likely continue and intensify the course of eutrophication in estuarine and coastal waters. As a result, the symptoms of eutrophication, such as noxious and harmful algal blooms, reduced water quality, loss of habitat and natural resources, and severity of hypoxia (oxygen depletion) and its extent in estuaries and coastal waters will increase. Global climate changes will likely result in higher water temperatures, stronger stratification, and increased inflows of freshwater and nutrients to coastal waters in many areas of the globe. Both past …

Salt Marsh Ecosystem Biogeochemical Responses To Nutrient Enrichment: A Paired N-15 Tracer Study, Dc Drake, Bj Peterson, Et Al, Le Lemay, Et Al

VIMS Articles

We compared processing and fate of dissolved NO3- in two New England salt marsh ecosystems, one receiving natural flood tide concentrations of similar to 1-4 mu mol NO3-/L and the other receiving experimentally fertilized flood tides containing similar to 70-100 mu mol NO3-/L. We conducted simultaneous (NO3-)-N-15 (isotope) tracer additions from 23 to 28 July 2005 in the reference (8.4 ha) and fertilized (12.4 ha) systems to compare N dynamics and fate. Two full tidal cycles were intensively studied during the paired tracer additions. Resulting mass balances showed that essentially 100% (0.48-0.61 mol NO3-N.ha(-1).h(-1)) of incoming NO3- was assimilated, dissimilated, …

Aqua {6,60-Dimethoxy-2,20-[Ethane-1,2- Diylbis(Nitrilomethylidyne)]Diphenolato}- (4-Hydroxybenzoato)Manganese(Iii), R. Reshma, V. Soumya, S. M. Simi, V. S. Thampidas, Robert D. Pike

Arts & Sciences Articles

The title compound, [Mn(C18H18N2O4)(C7H5O3)(H2O)], was synthesized by a template reaction of ethane-1,2-diamine and 3-methoxy­salicylaldehyde in presence of manganese(II) 4-hydroxy­benzoate. The Jahn-Teller-distorted manganese(III) centre has an octa­hedral geometry. Extensive O-HO hydrogen-bonding inter­actions generate a two-dimensional sheet structure parallel to (103).

Estimating Relative Abundance Of Young Of Year American Eel, Anguilla Rostrata, In The Virginia Tributaries Of Chesapeake Bay (Spring 2008), Troy D. Tuckey, Mary C. Fabrizio

Reports

The Atlantic States Marine Fisheries Commission (ASMFC) adopted the Interstate Fishery Management Plan (FMP) for the American eel in November 1999. The FMP focuses on increasing coastal states’ efforts to collect American eel data through both fishery-dependent and fishery-independent studies. Consequently, member jurisdictions agreed to implement an annual survey for young-of-year (YOY) American eels. The survey is intended to “…characterize trends in annual recruitment of the YOY eels over time [to produce a] qualitative appraisal of the annual recruitment of American eel to the U.S. Atlantic Coast” (ASMFC 2000). The development of these surveys began in 2000 with full implementation …

Preparation Of 5-Bromo-2-Naphthol: The Use Of A Sulfonic Acid As A Protecting And Activating Group, Christopher J. Abelt

Arts & Sciences Articles

The preparation of 5-bromo-2-naphthol (4) in three steps from 5-amino-2-naphthol (1) is described. A sulfonic acid group is introduced at the 1-position as an activating and protecting group for the Sandmeyer reaction. The sulfonate group allows for the use of only water and sulfuric acid as solvents. The sulfonic acid is introduced with three equivalents of sulfuric acid, and it is removed in 20% aq. sulfuric acid.

Tidal Sediment Yield Estimate Methodology In Virginia For The Chesapeake Bay Program Water Quality Model, C. Scott Hardaway Jr., Donna A. Milligan, Lyle M. Varnell, Julie Herman

Reports

Water quality in Chesapeake Bay has degraded over the past 50 years with respect to oxygen depletion and reduced light attenuation. While the causes are numerous, sediment resuspension from wave and tidal action cloud the water column and reduce light attenuation thereby negatively affecting submerged aquatic vegetation (SAV) beds. Sediments on the Bay bottom come from upland runoff and shoreline erosion, each of which has significant contributions to the loading of sediments into estuary. The purpose of this report is to assess the present methods used to calculate sediment loading from tidal shoreline erosion that is input to the Chesapeake …

Changes In Continental Freshwater Discharge From 1948 To 2004, Aiguo Dai, Taotao Qian, Kevin E. Trenberth, John D. Millliman

VIMS Articles

A new dataset of historical monthly streamflow at the farthest downstream stations for the world’s 925 largest ocean-reaching rivers has been created for community use. Available new gauge records are added to a network of gauges that covers ∼80 × 10⁶ km² or ∼80% of global ocean-draining land areas and accounts for about 73% of global total runoff. For most of the large rivers, the record for 1948–2004 is fairly complete. Data gaps in the records are filled through linear regression using streamflow simulated by a land surface model [Community Land Model, version 3 (CLM3)] forced with observed …

Mathews County, Virginia Shoreline Inventory Report Methods And Guidelines, Marcia Berman, Harry Berquist, Sharon Killeen, Carl Hershner, Tamia Rudnicky, Daniel E. Schatt, Karinna Nunez, Karen Reay, David Weiss

Reports

The data inventory developed for the Shoreline Situation Reports are based on a three-tiered shoreline assessment approach. This assessment characterizes conditions in the shorezone observed from a small boat moving along the shoreline. Handheld GPS units record data observations in the field. The three tiered shoreline assessment approach divides the shorezone into three regions:

1. the immediate riparian zone, evaluated for land use

2. the bank, evaluated for height, stability and natural protection

3. the shoreline, describing the presence of shoreline structures for shore protection and recreational purposes.

Three GIS coverages are generated from the collection technique. The Mathews_lubc coverage are features related …

Shore Status, Evolution, And Storm Vulnerability Assessments For George Washington Birthplace National Monument, C. Scott Hardaway Jr., Donna A. Milligan, Kevin P. O'Brien, Christine A. Wilcox

Reports

The shoreline at the George Washington Birthplace National Monument (GEWA) is eroding and vulnerable to storms. Recent storms, such as Hurricane Isabel and Tropical Storm Ernesto impacted the region in 2003 and 2006, respectively. Large losses of the bank prompted the National Park Service to determine the vulnerability of the shore and its associated cultural, natural and archeological resources. This project maps the existing shoreline along the Potomac River and at the Memorial House on Popes Creek, provides an assessment of shore and bank dynamics, determines the rate of shoreline change between 1937 and 2007, and presents an analysis of …