Physical Sciences and Mathematics Commons^™

Electrochemistry Of Trinuclear Metal Clusters Of Molybdenum And Tungsten In 1-Ethyl-3- Methylimidazolium Tetrafluoroborate, Tracey Lynn Harris

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The imidazolium based ionic liquid: 1-ethyl-3-methylimidizoliumtetrafluoroborate, (EMIBF4) was synthesized to be used as a solvent for the electrochemical investigation of molybdenum and tungsten. The electrochemical window is about 4.2V after removing traces of impurities such as Cl^- and H₂O. Electronic spectra of metal clusters [Mo₃O₂(O₂CCH₃)₆(H₂O)₃]⁺² ; [W₃O₂(O₂CCH₃)₆(H₂O)₃]⁺² ; [MoW₂O₂(O₂CCH₃)₆(H₂O)₃]⁺² and [Mo_{2 …}

Estimation Of Evapotranspiration Of Cottonwood Trees In The Cibola National Wildlife Refuge, Cibola, Arizona, Amity J. Jetton

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This study used sap flow measurements and satellite imagery to estimatewater use by cottonwood (Populus fremontii S. Wats. ssp) trees in an irrigated restoration plot at Cibola National Wildlife Refuge on the Lower Colorado River. Several thousand hectares of irrigated plots of this type are planned to improve riparian habitat on the river, hence it is important to know how much water the trees require. In this study, the ET rates for 20 Freemont cottonwood trees, from an 8 ha plot, were monitored over a 30-day period. ET rates were estimated by measuring sap flow through branches of the trees. …

The Impact Of Nutrient Availability And Algal Community On Carbon Isotope Fractionaion In Crystal Lake, Clark County, Ohio, April R. Wisebaker

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Crystal Lakes are a group of four interconnected lakes, located in southwestern Clark County, Ohio. Several studies have looked at separate geochemical and isotopic information at this location. However, no one has thoroughly studied the relationship between the algal community, geochemistry, and carbon isotope fractionation within Crystal Lake. The fractionation of carbon isotopes of dissolved inorganic carbonate is greatly affected by the process of photosynthesis; the amount of photosynthesis is affected by the amount of algae in the aquatic community; the amount of algae is affected by the available nutrients in system. Therefore, there should be a correlation between the …

1-Alkyl-3-Methylimidazolium Bis(Pentafluoroethylsulfonyl)Imide Based Ionic Liquids: A Study Of Their Physical And Electrochemical Properties, Jennifer N. Decerbo

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Ionic liquids are an attractive possibility for battery electrolytes. Five ionic liquids were synthesized using a 1-alkyl-3-methylimidazolium (XMI+) cation, where the alkyl group was ethyl, propyl, butyl, pentyl, or hexyl, and a bis(pentafluoroethyl-sulfonyl)imide (Beti-) anion. The absorption and desorption of water, conductivities, densities, viscosities, decomposition temperatures, and electrochemical properties were studied. These ionic liquids were found to absorb less water than previously studied ionic liquids with tetrafluoroborate (BF4-) and hexafluorophosphate (PF6-) anions. Their conductivities decreased with longer alkyl chains on the imidazolium cation and were lower than ionic liquids with BF4- as the anion. The densities of the ionic liquids …

Paleoenvironment And Lateral Extent Of An Exposed Carbonate Build-Up: Horry County, South Carolina, Lisa A. Raterink

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A carbonate build-up exposed in the Intracoastal Waterway in Horry County, South Carolina is estimated to be Pleistocene to Pliocene in age. The carbonate build-up discontinuously spans approximately 12 kilometers of the waterway. Prominent formations in the area consist of the Waccamaw and the Canepatch Formation. A distinct sand layer is present laterally between the build-up and the excavated waterway bank, which consists primarily of well preserved fossil molluscs and echinoderms.

Field observations show that the carbonate build-up is bluish-gray in color and composed of shell fragments, predominantly mollusc, in a mud matrix. Thin sections analyzed, using a petrographic microscope, …

Evanescent Microwave Microscopy Of Porcine Skin Tissue, Richard A. Kleismit

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This thesis describes the application of a custom designed λ/4 resonant coaxial probe to measurements of the complex permittivity of in vitro freshly excised porcine skin tissue. The dielectric properties of the organic material within the near field of the tip of the probe frustrates the electric field and measurably changes the resonant frequency and quality factor Q of the coaxial sensor, where the change in resonant frequency and quality factor of a tuned resonance is measured as a function of tip-sample separation. The design of the probe enables better spatial resolution than previously developed probes. The following studies were …

Availability And Toxicity Of Nickel To Lotic Periphyton And Macroinvertebrates, Stephanie Marie Bessom

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There is a lack of information regarding the bioaccumulation and toxicity of nickel (Ni) to lotic ecosystems. The objective of this study was to investigate the source, uptake, and toxicity of Ni by periphyton and macroinvertebrates (Hyalella azteca and Daphnia magna) in simulated stream ecosystems that included sediment and water. Periphyton were exposed to two types of sediment, a low-organic sandy mixture and a high organic silt, treated with varying levels of Ni. After 96 h, Ni levels in overlying water and periphyton were related to those in sediments, although differences existed between sediment types. Tests with 64Ni added to …

A Framework To Support Spatial, Temporal And Thematic Analytics Over Semantic Web Data, Matthew Steven Perry

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Spatial and temporal data are critical components in many applications. This is especially true in analytical applications ranging from scientific discovery to national security and criminal investigation. The analytical process often requires uncovering and analyzing complex thematic relationships between disparate people, places and events. Fundamentally new query operators based on the graph structure of Semantic Web data models, such as semantic associations, are proving useful for this purpose. However, these analysis mechanisms are primarily intended for thematic relationships. This dissertation proposes a framework built around the RDF data model for analysis of thematic, spatial and temporal relationships between named entities. …

Investigating Nickel Flux And Toxicity In Clay Sediments With Batch And Stream Recirculating Flume Experiments, Christina Elizabeth Cloran

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Using batch and stream recirculating flume experiments to compare and contrast one clayey sediment (Warden Ditch) and two analytical grade clay minerals (montmorillonite and kaolinite), the dynamic interactions between two aquatic stressors (suspended solids and nickel) were explored. Aldrich humic acid was incorporated to demonstrate the mitigating effects of dissolved organic carbon (DOC) on Ni toxicity. The flux of Ni between compartments (dissolved and sorbed) was quantified as a partition/distribution coefficient. The USEPA test organism Daphnia magna (neonates, < 24 h) was utilized to evaluate toxicity in dynamic non-renewal, short-term bioassays. Generally, toxicity showed a linear relationship with turbidity level. Conversely, sorption coefficients were experiment specific, making them difficult to predict and assess. Clay functioned as an adsorbent, scavenging Ni. Results support the hypotheses that solids and metals act as stressors in streams, DOC attenuates the toxicity of Ni, and Ni fluxes quickly between system compartments.

Evolutionary Methodology For Optimization Of Image Transforms Subject To Quantization Noise, Michael Ray Peterson

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Lossy image compression algorithms sacrifice perfect imagereconstruction in favor of decreased storage requirements. Modelossy compression schemes, such as JPEG2000, rely upon the discrete wavelet transform (DWT) to achieve high levels of compression while minimizing the loss of information for image reconstruction. Some compression applications require higher levels of compression than those achieved through application of the DWT and entropy coding. In such lossy systems, quantization provides high compression rates at the cost of increased distortion. Unfortunately, as the amount of quantization increases, the performance of the DWT for accurate image reconstruction deteriorates. Previous research demonstrates that a genetic algorithm can …

An Assessment Of The Allelopathic Potential Of Alliaria Petiolata, Eulondia Kathryn Barto

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Garlic mustard (GM), Alliaria petiolata, a European biennial herb invasive in North America, produces secondary metabolites that may contribute to its invasive success by allelopathically inhibiting growth of native plants. I tested this hypothesis by determining the levels, and stability, of these compounds in field soils. I also explored differences in the phytochemical profiles of GM and closely related North American species, and biogeographic differences in allelopathic effects on North American and European arbuscular mycorrhizal fungi (AMF). Furthermore, I exposed a North American annual herb, pale jewelweed (Impatiens pallida), and its AMF, to GM extracts in order …

Exploration Of Synthetic Routes To The Sulfoxide And Sulfone Derivatives Of Benzotrithiophenes, Tiffany M. Hall

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The synthesis of new organic materials that have the potential to be utilized in a thermoelectric application are in demand because they are able to convert thermal energy directly into electrical energy. The "end-on" sulfoxide and sulfone derivatives of Benzo[1,2-c:3,4-c':5,6-c'']trithiophene 1 were synthesized for this reason. The "end-on" mode sulfoxide derivative 13 of Benzo[1,2-c:3,4-c':5,6-c'']trithiophene 1 was prepared by utilizing 3-Carboxypyridinium Chlorochromate (CPCC) 16 and AlCl₃, as an oxidizing system. The ¹H NMR (DMSO-d₆) spectrum displayed a singlet peak at 5.03 ppm, and the IR spectrum displayed an absorption at 1059.33cm^-1, which confirmed its …

Analysis And Transformation Of Post-Conditions, Abhinav Vasikarla

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Software engineers have been trying for years to develop a software synthesis system that can transform a formal specification model to a design model from which executable code can be generated. AFIT wide spectrum object modeling environment (AWESOME) is one result of their research. AWESOME presents a formal model as an abstract syntax tree. This model consists mainly of object class specifications. The methods in these classes are specified using pre and post-conditions. The intent of this thesis is to support the transformation of post-conditions to code statements. A post-condition is first categorized as dependent or independent relative to other …

Poly(Arylene Ether)S With Truly Pendant Benzene Sulfonic Acid Groups, Mohamed Moustafa Abdellatif

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A series of new sulfonated poly(arylene ether)s containing one sulfonic acid group, located on a pendant phenyl sulfonyl moiety, at every repeat unit was synthesized using 3-sulfonated-3', 5'-difluorophenyl Sulfone, 4, and a variety of bisphenols. A conventional nucleophilic aromatic substitution (NAS) was utilized for the homopolymerization and copolymerization reactions. Polymerization reactions of 4 in NMP at 180 °C provided the corresponding linear sulfonated poly(arylene ether)s, s-PAEs, with number average molecular weight, M_n, ranging from 10,000 to 38,000 Daltons. All of the polymers were characterized by ¹H and ¹³C NMR spectroscopy, thermogravimetric analysis (TGA), and differential scanning …

Analysis And Interpretation Of 2d Seismic Data Over The Ancona Gas Storage Facility, Illinois, Using Petrel Visualization Software, Nilanjan Roy

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Intriguing features of the North American mid-continent are the widespread and prominent subhorizontal seismic reflectors that are thought to be associated with thick sequences of layered rocks beneath the Phanerozoic cover of the Illinois Basin. The present investigation was an effort to identify and interpret new structural features of the pre-Paleozoic crust at the Ancona Gas Storage field in north-central Illinois. A grid of existing seismic data was reprocessed using the technique of extended correlation.

The reprocessed data was then analyzed using Schlumberger's Petrel visualization software for seismic interpretation and reconstruction of the 2D and 3D crustal geometry. The reprocessing …

Towards Tractable Local Closed World Reasoning For The Semantic Web, Matthias Knorr, Jose Julio Alferes, Pascal Hitzler

Computer Science and Engineering Faculty Publications

Recently, the logics of minimal knowledge and negation as failure MKNF [12] was used to introduce hybrid MKNF knowledge bases [14], a powerful formalism for combining open and closed world reasoning for the Semantic Web. We present an extension based on a new three-valued framework including an alternating fixpoint, the well-founded MKNF model. This approach, the well-founded MKNF semantics, derives its name from the very close relation to the corresponding semantics known from logic programming. We show that the well-founded MKNF model is the least model among all (three-valued) MKNF models, thus soundly approximating also the two-valued MKNF models from …

Video On The Semantic Sensor Web, Cory Andrew Henson, Amit P. Sheth, Prateek Jain, Josh Pschorr, Terry Rapoch

Kno.e.sis Publications

Millions of sensors around the globe currently collect avalanches of data about our world. The rapid development and deployment of sensor technology is intensifying the existing problem of too much data and not enough knowledge. With a view to alleviating this glut, we propose that sensor data, especially video sensor data, can be annotated with semantic metadata to provide contextual information about videos on the Web. In particular, we present an approach to annotating video sensor data with spatial, temporal, and thematic semantic metadata. This technique builds on current standardization efforts within the W3C and Open Geospatial Consortium (OGC) and …

Semantic Web For Health Care And Biomedical Informatics, Amit P. Sheth

Kno.e.sis Publications

No abstract provided.

A General Boosting Method And Its Application To Learning Ranking Functions For Web Search, Zhaohui Zheng, Hongyuan Zha, Tong Zhang, Olivier Chapelle, Keke Chen, Gordon Sun

Kno.e.sis Publications

We present a general boosting method extending functional gradient boosting to optimize complex loss functions that are encountered in many machine learning problems. Our approach is based on optimization of quadratic upper bounds of the loss functions which allows us to present a rigorous convergence analysis of the algorithm. More importantly, this general framework enables us to use a standard regression base learner such as decision trees for fitting any loss function. We illustrate an application of the proposed method in learning ranking functions for Web search by combining both preference data and labeled data for training. We present experimental …

Leveraging Semantic Web Techniques To Gain Situational Awareness, Amit P. Sheth

Kno.e.sis Publications

No abstract provided.

Can Semantic Web Techniques Empower Comprehension And Projection In Cyber Situational Awareness?, Amit P. Sheth

Kno.e.sis Publications

No abstract provided.

Supporting Complex Thematic, Spatial And Temporal Queries Over Semantic Web Data, Matthew Perry, Amit P. Sheth, Farshad Hakimpour, Prateek Jain

Kno.e.sis Publications

Spatial and temporal data are critical components in many applications. This is especially true in analytical domains such as national security and criminal investigation. Often, the analytical process requires uncovering and analyzing complex thematic relationships between disparate people, places and events. Fundamentally new query operators based on the graph structure of Semantic Web data models, such as semantic associations, are proving useful for this purpose. However, these analysis mechanisms are primarily intended for thematic relationships. In this paper, we describe a framework built around the RDF metadata model for analysis of thematic, spatial and temporal relationships between named entities. We …

Semantic Convergence Of Wikipedia Articles, Christopher J. Thomas, Amit P. Sheth

Kno.e.sis Publications

Social networking, distributed problem solving and human computation have gained high visibility. Wikipedia is a well established service that incorporates aspects of these three fields of research. For this reason it is a good object of study for determining quality of solutions in a social setting that is open, completely distributed, bottom up and not peer reviewed by certified experts. In particular, this paper aims at identifying semantic convergence of Wikipedia articles; the notion that the content of an article stays stable regardless of continuing edits. This could lead to an automatic recommendation of good article tags but also add …

Conjunctive Queries For A Tractable Fragment Of Owl 1.1, Markus Krotzsch, Sebastian Rudolph, Pascal Hitzler

Computer Science and Engineering Faculty Publications

Despite the success of the Web Ontology Language OWL, the development of expressive means for querying OWL knowledge bases is still an open issue. In this paper, we investigate how a very natural and desirable form of queries-namely conjunctive ones-can be used in conjunction with OWL such that one of the major design criteria of the latter-namely decidability-can be retained. More precisely, we show that querying the tractable fragment EL++ of OWL 1.1 is decidable. We also provide a complexity analysis and show that querying unrestricted EL++ is undecidable.

Visualizing Morphometric Data Of Vasculatures, Thomas Wischgoll

Computer Science and Engineering Faculty Publications

Volume visualization is a common, very well-established visualization technique for volumetric data sets. Numerous advancements have been proposed and sophisticated improvements have been implemented to produce elaborated renderings that are capable of enhancing details within the volume. However, volume visualization alone is often not sufficient for the application domain. Often times, researchers are interested in accurate measurements extracted from volumetric data to gain further insight of the specimen. These extracted measurements can then be used to generate and visualize a geometric reconstruction of the specimen. The visualization can incorporate additional tools that allow researchers to determine additional measurements of the …

Ceg 420/620: Computer Architecture, Jack Jean

Computer Science & Engineering Syllabi

No abstract provided.

Ceg 210: Pc Networking I, Karen Meyer

Computer Science & Engineering Syllabi

Introduction to PC networking hardware, concepts, and technologies. Focus is on LAN administration, hardware and software configuration.

Ceg 220: Introduction To C Programming For Engineers I, Robert Helt

Computer Science & Engineering Syllabi

This course provides a general introduction to computers as a problem-solving tool using the C programming language. Emphasis is on algorithms and techniques useful to engineers. Topics include data representation, debugging, and program verification. 4 credit hours. Prerequisite: MTH 229 (Calculus I) or EGR 101 (Engineering Mathematics).f

Ceg 233: Linux And Windows, Prabhaker Mateti

Computer Science & Engineering Syllabi

Introduction to Linux and Windows systems. GUI and Windowing Systems. Files and Directories. Ownership and Sharing. Programs and Processes. System calls, Libraries. Loading. Dynamic linking. Command Line Shells. Scripting languages. Regular expressions. Clients and Servers. Web browser clients and servers. Secure shell, sftp. SSL/TSL. HTTPS. System Administration.

Ceg 220: Introduction To C Programming For Engineers I, Jay Dejongh

Computer Science & Engineering Syllabi

This course provides a general introduction to computers as a problem-solving tool using the C programming language. Emphasis is on algorithms and techniques useful to engineers. Topics include data representation, debugging, and program verification. 4 credit hours. Prerequisite: MTH 229 (Calculus I) or EGR 101 (Engineering Mathematics).