Physical Sciences and Mathematics Commons^™

Random And Block Copolymers Of Poly(Dodecamethyleneterephthalamide), Theodore Frank Novitsky Jr.

Dissertations

The following dissertation focuses on the synthesis and characterization of poly(dodecamethylene terephthalamide) (PA-12,T) and novel copolymers. Chapter I details the synthesis of PA-12,T homopolymer by melt condensation polymerization. A series of homopolymers with different molecular weights were obtained by adjusting the stoichiometry of the polymerization using 1,12-diaminododecane, terephthalic acid and benzoic acid. End group 13C NMR spectroscopy resonances were obtained by correlating peak intensities with intrinsic viscosity values. From the NMR data, total end group concentrations and molecular weights were determined for each sample. The data exhibited a linear trend when plotting log (IV) versus log (Mn), and previously unknown …

Preparation And Characterization Of Thiol Based Polymeric Materials, Junghwan Shin

Dissertations

The thiol click-type reaction is one of the most efficient chemical processes that can undergo at room temperature in the benign organic solvent providing excellent opportunity in the fabrication of new materials as well as development of new manufacturing processes. Moreover, the versatility of thiol click-type reactions with many different functional groups such as ene, yne, epoxy, isocyanate, and alkyl halide is the important aspect that should be differentiated from the classic azide-alkyne click chemistry. Although, there are tremendous studies on many areas using thiol click-type reactions, the efficiency and utilities for the material applications have been barely explored. Especially, …

Transcript Analysis Of The Cso Operon And Characterization Of Two Sets Of Conserved Bacterial Microcompartment Genes In The Model Organism Halothiobacillus Neapolitanus, Fei Cai

Dissertations

This study was designed to achieve better understanding of (1) how carboxysome genes are regulated and expressed to yield with precise relative ratios and (2) the in vivo roles of two sets of conserved bacterial microcompartment genes, namely the three csoSl and two csoS4 genes of H. neapolitanus, in the biogenesis and function of the carboxysome. For the first goal, a detailed transcriptional profile of carboxysomal genes in H. neapolitanus was established using absolute quantification real-time RT-PCR and transcript ends analysis. This transcriptional profile revealed that a single promoter, denoted cso promoter, was located upstream from the clustered carboxysomal genes. …

Anomaly Detection Techniques For Ad Hoc Networks, Chaoli Cai

Dissertations

Anomaly detection is an important and indispensable aspect of any computer security mechanism. Ad hoc and mobile networks consist of a number of peer mobile nodes that are capable of communicating with each other absent a fixed infrastructure. Arbitrary node movements and lack of centralized control make them vulnerable to a wide variety of unknown and known attacks from inside as well as from outside. In this dissertation we propose two efficient statistical techniques for anomaly detection for these networks.

In order to take into account incomplete testing samples and the interaction among multiple features, we present BANBAD •- a …

A Two-Sample Adaptive Procedure Based On The Log-Rank And Peto And Peto's Wilcoxon Tests, Annie A. Tordilla

Dissertations

It has been shown that under a location-scale model y = μ + βz + σε at where y is right censored, the Log-Rank test is asymptotically efficient for the Extreme minimum value error distribution while Peto and Peto's Wilcoxon test is asymptotically efficient for the Logistic error distribution. We propose a two-sample adaptive test, which first selects between Extreme minimum value and Logistic error distribution as to which is a better fit to the data, then performs the asymptotically efficient test (Log-Rank or Peto and Peto's Wilcoxon test) for the selected distribution. The performance of the adaptive test is …

The Program Evaluation Standards Applied For Metaevaluation Purposes: Investigating Interrater Reliabiity And Implications For Use, Lori A. Wingate

Dissertations

Metaevaluation is the evaluation of evaluation. Metaevaluation may focus particular evaluation cases, evaluation systems, or the discipline overall. Leading scholars within the discipline consider metaevaluation to be a professional imperative, demonstrating that evaluation is a reflexive enterprise. Various criteria have been set forth for what constitutes excellence in evaluation. In the context of educational program evaluation, the dominant criteria are the Program Evaluation Standards, developed by the developed by the Joint Committee on Standards for Educational Evaluation.

There has been widespread acceptance and application of the Program Evaluation Standards, and their use is advocated by major organizations and several of …

Application Of Molecular Modeling In The Noncovalent Dispersion Of Carbon Nanomaterials, Praveen Kumar Madasu

Dissertations

Molecular modeling is a powerful tool to better understand the intermolecular interactions of carbon nanostructures. It provides structures and energies not easily obtainable from experiments and predicts properties that can be tested experimentally. Intermolecular interactions play an important role in the aggregation of various carbon nanomaterials. Three molecular modeling studies of carbon nanomaterial dispersions are presented in this dissertation, with an emphasis on illustrating how effective these theoretical techniques are in providing insight on the selection of dispersion additives. To achieve our goals, we employed molecular mechanics based methods, along with semi-empirical methods, and quantum mechanical methods, such as density …

Tuning Pig Liver Esterase Enantioselectivity For The Synthesis Of Unnatural Serine And Tyrosine Analogues, Dale Anthony Rosado Jr.

Dissertations

The synthesis of disubstituted and homologated unnatural amino acids and the development of a mass spectrometry based assay for enantioselectivity are presented here. Disubstituted and homologated unnatural amino acids have proven to be effective for the treatment of diseases and for use as imaging agents. Peptides that contain unnatural amino acids have also proven to be effective treatments for various disease states including cancer. The potential to evaluate such unnatural amino acids for pharmaceutical properties is limited by the available syntheses. No method currently exists that will allow for the synthesis of homochirally similar unnatural amino acids from a common …

The Multilevel Structures Of Nurbs And Nurblets On Intervals, Weiwei Zhu

Dissertations

This dissertation is concerned with the problem of constructing biorthogonal wavelets based on non-uniform rational cubic B-Splines on intervals. We call non-uniform rational B-Splines ``NURBs", and such biorthogonal wavelets ``NURBlets". Constructing NURBlets is useful in designing and representing an arbitrary shape of an object in the industry, especially when exactness of the shape is critical such as the shape of an aircraft. As we know presently most popular wavelet models in the industry are approximated at boundaries. In this dissertation a new model is presented that is well suited for generating arbitrary shapes in the industry with mathematical exactness throughout …

Processing Techniques For Partial Tree-Pattern Queries On Xml Data, Pawel Placek

Dissertations

In recent years, eXtensible Markup Language (XML) has become a de facto standard for exporting and exchanging data on the Web. XML structures data as trees. Querying capabilities are provided through patterns matched against the XML trees. Research on the processing of XML queries has focused mainly on tree-pattern queries. Tree-pattern queries are not appropriate for querying XML data sources whose structure is not fully known to the user, or for querying multiple data sources which structure information differently. Recently, a class of queries, called Partial Tree-Pattern Queries (PTPQs) was identified. A central feature of PTPQs is that the structure …

In-Group / Out-Group Dynamics And Effectiveness In Partially Distributed Teams, Faina Privman

Dissertations

When organizations collaborate they often do so using partially distributed teams (PDTs). In a Partially Distributed Team there exist at least two distinct sub-groups. In addition, at least one of the sub-groups has two or more members that are geographically co-located. Co-located members can meet face to face; chat in the hallway; have lunch together; and otherwise socialize with one another. On the other hand, remote members must rely on technology to communicate and work together. This distinct characteristic of partially distributed teams makes them especially susceptible to the In-Group / Out Group dynamic (Huang and Ocker, 2006). This dynamic …

High Resolution Solar Observations From First Principles To Applications, Angelo P. Verdoni

Dissertations

The expression "high-resolution observations" in Solar Physics refers to the spatial, temporal and spectral domains in their entirety. High-resolution observations of solar fine structure are a necessity to answer many of the intriguing questions related to solar activity. However, a researcher building instruments for high-resolution observations has to cope with the fact that these three domains often have diametrically opposed boundary conditions. Many factors have to be considered in the design of a successful instrument. Modern post-focus instruments are more closely linked with the solar telescopes that they serve than in past. In principle, the quest for high-resolution observations already …

Design Development And Evaluation Of Collario, A Group Support System For Collaborative Scenario Creation, Xiang Yao

Dissertations

In the fields of Emergency Management and Business Continuity Planning, scenarios are a widely used tool for planning, training and knowledge sharing purposes. The ability to create and discuss emergency scenarios in virtual teams can lead to many potential applications, such as discussing emergency scenarios by world-wide experts, conducting on-line exercises, and creating Communities of Practices. Existing scenario creation systems, like NxMsel provided by FEMA, allow distributed groups to create scenarios together. However, collaborative support in these systems is generally limited.

This dissertation explores an innovative solution to provide various types of collaboration support around a knowledge structure and uses …

Reduced Order Models For Fluid-Structure Interaction Systems By Mixed Finite Element Formulation, Ye Yang

Dissertations

In this work, mixed finite element formulations are introduced for acoustoelastic fluid- structure interaction (FSI) systems. For acoustic fluid, in addition to displacement- pressure (u/p) mixed formulation, a three-field formulation, namely, displacement-pressure-vorticity moment formulation (u - p -Λ) is employed to eliminate some zero frequencies. This formulation is introduced in order to compute the coupled frequencies without the contamination of nonphysical spurious non-zero frequencies. Furthermore, gravitational forces are introduced to include the coupled sloshing mode. In addition, u/p mixed formulation is the first time employed in solid. The numerical examples will demonstrate that the mixed formulations are capable of predicted …

Carbon Nanotube Electronic Structures As Anti-Corrosion Coatings, Sreeya Sreevatsa

Dissertations

A new concept of corrosion prevention is considered in this study. Diode-like and transistor-like structures have been fabricated and analyzed in the study of ionic flow through the resulting potential barriers. The structures were made of functionalized carbon nanotubes. Carbon nanotubes are known for many remarkable properties among which is being chemically inert. Taking advantage of this property, a study of corrosion of steel was undertaken.

In the first case study, successive layers of functionalized carbon nanotubes were deposited to form p-n junctions on steel substrates. It was demonstrated that the corrosion was indeed impeded by the potential barrier formed …

Probing The Complex Magnetic, Electronic And Structural Properties In Correlated Manganese Oxides, Peng Gao

Dissertations

Rare-earth Manganese Oxides (RMnO₃) exhibit two distinct structural phases: the orthorhombic structure and the hexagonal structure. The doped orthorhombic phase exhibits a metal to insulator transition, charge ordering and a strong response of electron transport properties to magnetic fields (colossal magneto-resistance). At low temperatures, this system may also exhibit a finite polarization which couples to external magnetic fields. The hexagonal phase is known to have a large spontaneous polarization at high temperatures which couples to the low temperature magnetic order. These materials are important from the basic point of view of understanding strong electronic correlations and …

Photoionization Of Rare Gas Clusters, Huaizhen Zhang

Dissertations

This thesis concentrates on the study of photoionization of van der Waals clusters with different cluster sizes. The goal of the experimental investigation is to understand the electronic structure of van der Waals clusters and the electronic dynamics. These studies are fundamental to understand the interaction between UV-X rays and clusters. The experiments were performed at the Advanced Light Source at Lawrence Berkeley National Laboratory. The experimental method employs angle-resolved time-of-flight photoelectron spectrometry, one of the most powerful methods for probing the electronic structure of atoms, molecules, clusters and solids.

The van der Waals cluster photoionization studies are focused on …

Topology Control Using Joint Power And Beam-Width Control In Hybrid Rf/Fso Mesh Networks, Osama Awwad

Dissertations

Most wireless networks are deployed strictly in the radio frequency (RF) domain, since RF channels provide natural support for radial broadcast operations. However, the downside of RF channels is that they introduce many limiting externalities that make providing scalable quality of service (QoS) support difficult, if not intractable. These well-known technical challenges include bandwidth scarcity, lack of security, high interference, and high bit error rates.

Faced with such daunting obstacles to QoS, the use of Free Space Optics (FSO) for wireless communications has been proposed in which it has the potential to support higher link data rates compared to present …

Entanglement Perturbation Theory For Antiferromagnetic Spin Chains, Lihua Wang

Dissertations

In this dissertation, we use the recently developed Entanglement Perturbation Theory (EPT) to solve antiferromagnetic spin chain problems, for both spin 1/2 and spin 1. We firs use EPT-g (EPT algorithm for ground state) to get the ground state properties. We calculated precisely energies, magnetization and spin-spin correlations. The precision of the long range spin-spin correlation functions for spin 1/2 chains is unprecedented. Due to its special structure, we also use EPT-g to calculate the firs excited state properties for spin 1 chains. Hence we plotted the phase diagram for spin 1 xxz chains. Also a generalization of EPT (EPT-e) …

Test Procedures For Equality Of Two Variances In Delta Distributions, Jezaniah Kira Sarion Tena

Dissertations

Statistical literature on testing equality of variances is very broad, encompassing a great number of distributional variations. However, the case of a zero-inflated nonnegative continuous random variable has not yet been considered. Such distribution is specified by a positive probability that the variable assumes a true zero value, together with a conditional distribution for the positive values of the variable.

This study considers the special case, delta distribution, where the positive values come from the lognormal distribution. Test procedures were developed using a statistic based on Gini's Mean Difference. Since the asymptotic distribution of the test statistic was shown to …

Statistical Procedures For Bioequivalence Analysis, Srinand Ponnathapura Nandakumar

Dissertations

Applicants submitting a new drug application (NDA) or new animal drug application (NADA) under the Federal Food, Drug, and Cosmetic Act (FDC Act) are required to document bioavailability (BA). A sponsor of an abbreviated new drug application (ANDA) or abbreviated new animal drug application (ANADA) must document first pharmaceutical equivalence and then bioequivalence (BE) to be deemed therapeutically equivalent to a reference listed drug (RLD). The Average (ABE), Population (PBE) and Individual (IBE) bioequivalence have been used to establish the equivalence in the pharmaco-kinetics of drugs.

The current procedure of PBE uses Cornish Fisher's (CF) expansion on small samples. Since …

Meta Analyses Of Multiple Baseline Time Series Design Intervention Models For Dependent And Independent Series, Oluwagbohunmi Adetunji Awosoga

Dissertations

Most wireless networks are deployed strictly in the radio frequency (RF) domain, since RF channels provide natural support for radial broadcast operations. However, the downside of RF channels is that they introduce many limiting externalities that make providing scalable quality of service (QoS) support difficult, if not intractable. These well-known technical challenges include bandwidth scarcity, lack of security, high interference, and high bit error rates.

Faced with such daunting obstacles to QoS, the use of Free Space Optics (FSO) for wireless communications has been proposed in which it has the potential to support higher link data rates compared to present …

Self Similar Flows In Finite Or Infinite Two Dimensional Geometries, Leonardo Xavier Espin Estevez

Dissertations

This study is concerned with several problems related to self-similar flows in pulsating channels. Exact or similarity solutions of the Navier-Stokes equations are of practical and theoretical importance in fluid mechanics. The assumption of self-similarity of the solutions is a very attractive one from both a theoretical and a practical point of view. It allows us to greatly simplify the Navier-Stokes equations into a single nonlinear one-dimensional partial differential equation (or ordinary differential equation in the case of steady flow) whose solutions are also exact solutions of the Navier-Stokes equations in the sense that no approximations are required in order …

Predictive Decoding Of Neural Data, Yaroslav O. Halchenko

Dissertations

In the last five decades the number of techniques available for non-invasive functional imaging has increased dramatically. Researchers today can choose from a variety of imaging modalities that include EEG, MEG, PET, SPECT, MRI, and fMRI.

This doctoral dissertation offers a methodology for the reliable analysis of neural data at different levels of investigation. By using statistical learning algorithms the proposed approach allows single-trial analysis of various neural data by decoding them into variables of interest. Unbiased testing of the decoder on new samples of the data provides a generalization assessment of decoding performance reliability. Through consecutive analysis of the …

Autonomous Migration Of Vertual Machines For Maximizing Resource Utilization, Hyung Won Choi

Dissertations

Virtualization of computing resources enables multiple virtual machines to run on a physical machine. When many virtual machines are deployed on a cluster of PCs, some physical machines will inevitably experience overload while others are under-utilized over time due to varying computational demands. This computational imbalance across the cluster undermines the very purpose of maximizing resource utilization through virtualization. To solve this imbalance problem, virtual machine migration has been introduced, where a virtual machine on a heavily loaded physical machine is selected and moved to a lightly loaded physical machine. The selection of the source virtual machine and the destination …

A Bioinformatics Framework For Rna Structure Mining, Motif Discovery And Polyadenylation Analysis, Mugdha Khaladkar

Dissertations

The RNA molecules play various important roles in the cell and their functionality depends not only on the sequence information but to a large extent on their structure. The development of computational and predictive approaches to study RNA molecules is extremely valuable. In this research, a tool named RADAR was developed that provides a multitude of functionality for RNA data analysis and research. It aligns structure annotated RNA sequences so that both the sequence as well as structure information is taken into consideration. This tool is capable of performing pair-wise structure alignment, multiple structure alignment, database search and clustering. In …

Discreet Dynamical Population Models : Higher Dimensional Pioneer-Climax Models, Yogesh Joshi

Dissertations

There are many population models in the literature for both continuous and discrete systems. This investigation begins with a general discrete model that subsumes almost all of the discrete population models currently in use. Some results related to the existence of fixed points are proved. Before launching into a mathematical analysis of the primary discrete dynamical model investigated in this dissertation, the basic elements of the model - pioneer and climax species - are described and discussed from an ecological as well as a dynamical systems perspective. An attempt is made to explain why the chosen hierarchical form of the …

Road-Based Routing In Vehicular Ad Hoc Networks, Josiane Nzouonta-Domgang

Dissertations

Vehicular ad hoc networks (VANETs) can provide scalable and cost-effective solutions for applications such as traffic safety, dynamic route planning, and context-aware advertisement using short-range wireless communication. To function properly, these applications require efficient routing protocols. However, existing mobile ad hoc network routing and forwarding approaches have limited performance in VANETs. This dissertation shows that routing protocols which account for VANET-specific characteristics in their designs, such as high density and constrained mobility, can provide good performance for a large spectrum of applications.

This work proposes a novel class of routing protocols as well as three forwarding optimizations for VANETs. The …

Numerical Detection Of Complex Singularities In Two And Three Dimensions, Kamyar Malakuti

Dissertations

Singularities often occur in solutions to partial differential equations; important examples include the formation of shock fronts in hyperbolic equations and self-focusing type blow up in nonlinear parabolic equations. Information about formation and structure of singularities can have significant role in interfacial fluid dynamics such as Kelvin-Helmholtz instability, Rayleigh-Taylor instability, and Hele-Shaw flow. In this thesis, we present a new method for the numerical analysis of complex singularities in solutions to partial differential equations. In the method, we analyze the decay of Fourier coefficients using a numerical form fit to ascertain the nature of singularities in two and three-dimensional functions. …

Enterprise Information Technology Organizational Flexibility : Managing Uncertainty And Change, Karen Prast Patten

Dissertations

Chief Information Officers (CIOs) lead enterprise information technology organizations (EITOs) in today's dynamic competitive business environment. CIOs deal with external and internal environmental changes, changing internal customer needs, and rapidly changing technology. New models for the organization include flexibility and suggest that CIOs should create and manage an enterprise IT organization that is more flexible in order to manage change and prepare for uncertainty, but they do not define what is meant by flexibility.

The first objective of this exploratory and ethnographic research study was to understand how uncertainty and unexpected change are currently managed by CIOs. The second was …