Physical Sciences and Mathematics Commons^™

Kilocycle Range Dislocation Damping In Dilute Magnesium Alloy Single Crystals, Robert Ray Nothdurft

Doctoral Dissertations

"The kilocycle range dislocation damping and Young's modulus of single crystals of magnesium and single crystals of magnesium containing small additions of lithium, zinc, or aluminum have been studied as a function of strain amplitude, temperature, and time during annealing and following a high strain amplitude vibration. The data are compared to the Granato-Lücke theory of dislocation damping, the Granato-Hikata-Lücke theory for the recovery of damping following plastic deformation, and the Yamafuji-Bauer theory for the recovery of damping following a high strain amplitude vibration. Reasonable qualitative agreement is obtained between the Granato-Lücke theory and the observed dependence of the damping …

Magnetic Properties Of The Bifeo₃-Pbtio₃-Pbzro₃ Ternary System, James Ivan Latham

Doctoral Dissertations

"The magnetic susceptibility and spontaneous magnetic moment of the perovskitic, polycrystalline solid solutions of BiFeO₃ with PbTiO₃, PbZrO₃, and [50PbZrO₃·50PbTiO₃] were determined using the Faraday method. Pure BiFeO₃ has a G-type antiferromagnetic structure. Although the perovskite BiFeO₃ exhibits a sharp peak in the susceptibility at the Néel temperature, it does not possess a spontaneous magnetic moment. The solid solutions investigated possessed a spontaneous magnetic moment throughout the multiple cell rhombohedral region of the BiFeO₃-PbTiO₃-PbZrO₃ ternary phase diagram, which extends from pure BiFeO₃ to …

A Theoretical Investigation Of Elastic And Voigt Transient Spherical Waves, And Plane Three-Element Viscoelastic Waves, Edward Hornsey

Doctoral Dissertations

"A mathematical model of explosive generated waves in rock is needed in many areas of engineering endeavor. Investigations to date have been unsuccessful in obtaining a model that satisfactorily represents real wave phenomena at all radial distances and in all of the important characteristics.

In this investigation, spherical waves in elastic and Voigt media were investigated. Series solutions for plane waves in a three-element viscoelastic medium were obtained. A dual exponential pressure pulse, P(t) = P_o (e^-αt-e^-ßt) was assumed because it can exhibit significant features of real pressure pulses while avoiding instantaneous rise time, which …

High Frequency Ferroelectric Properties Of The Bifeo₃-Pbtio₃-Pbzro₃ Ternary System, Robert Travis Smith

Doctoral Dissertations

"High temperature dielectric measurements have been performed on the ferroelectric and antiferroelectric perovskitic polycrystalline solid solutions in the BiFeO₃-PbTiO₃-PbZrO₃ ternary system. The data were taken in the UHF frequency range with the use of a slotted line and specially constructed sample holder capable of operation at temperatures in excess of 800°C.

The Curie points have been found to occur at progressively higher temperatures with the increase of BiFeO₃ content in the solutions except in phase transition regions where minima can occur. The dielectric constants at the Curie temperatures have been found to decrease with …

The Technique Of Lineaments And Linears Analysis And Its Application In The Minerogenic Province Of Southeast Missouri, Hassan A. Etr

Doctoral Dissertations

"Current terminology in the field of lineaments and linears (lineations) analysis was reviewed and quantitative definitions of the common terms offered. A general classification of lineations is herein proposed. Characteristics of drainage and airphoto lineations were reviewed and the procedure used in their analysis discussed.

An area about 1880 square miles was analyzed for lineations based on drainage networks and the resulting patterns showed preferred orientation. These drainage lineations were later compared with the airphoto lineations of the same area and a limited degree of similarity was observed.

The airphoto lineations of an area approximately 7000 sq. mi. covering the …

Study Of Resonance Effects In Allenic And Related Systems, Robert Andrew Steinkamp

Doctoral Dissertations

"In order to investigate the possibility of resonance effects through a non-coplanar substituted acetylene, synthesis of bis-(2,5,8-trimethyl-l-naphthyl)-acetylene was attempted. Condensation of acetylene with 2,5,8-trimethyl-l-tetralone to yield an acetylenic glycol followed by dehydration and dehydrogenation was expected to yield the desired non-coplanar acetylene. Comparison of its ultraviolet spectrum with that of di-l-naphthyl-acetylene would have suggested the true nature of the acetylene pi cloud. The acetylene condensation was unsuccessful, however.

Substituted allenes, which contain one sp hybridized carbon atom, were then successfully synthesized for a similar analysis of potential resonance effects. A series of para-substituted 4-phenyl-2-methylbutadienoic acids were synthesized and their pKa's …

A Calorimetric Study Of The Effects Of Surface Energy In A Type Ii Superconductor, Robert Rex Rice

Doctoral Dissertations

"A calorimetric study of the effects of the interphase surface free energy has been conducted on ellipsoidal samples of first and second kind superconductors. The measurements were performed using a specially designed magnetization calorimeter by two different techniques. The measurements were made on lead, tin, lead-4at%thallium, and tin-6at% indium. The results confirm the existence and experted sign of the surface energy in a well annealed lead-4at%thallium sample, and indicate that the interphase surface energy in lead and tin is too small to be directly detected by this method. The measured latent heats of transition of lead and tin agree well …

Theory Of The Lunar Photoelectron Atmosphere, Hal Emerson Mccloud Jr.

Doctoral Dissertations

"By considering the mechanics of an electron projected into an arbitrary potential field together with Poisson's equation it is possible to set up a differential equation for the electrostatic potential. The equation may be integrated and the photoelectron density found as a function of height for four approximate models. A simple model based upon monoenergetic photons and monoenergetic electrons ejected vertically upward yields rough estimates of the parameters of interest. Another model takes into account the fact that the photoelectrons are ejected at all angles. A general model takes into account the illumination of the lunar surface by solar (black …

Diffusional Drop Growth In A Supersaturated Atmosphere, John C. Carstens

Doctoral Dissertations

"The effect which a growing droplet has on the supersaturated atmosphere surrounding it is analyzed by assuming a macroscopic diffusional growth mechanism involving both heat and vapor. The problem is solved, for cloud-chamber conditions, first for very short times assuming a fixed radius, and then for longer times assuming the establishment of "quasi" steady-state conditions. Knowledge of the way in which droplet growth affects supersaturation is important in the evaluation of nucleation rates"--Abstract, page ii.

Cenozoic And Recent Lunulitiform Bryozoans Of The Gulf And Atlantic Coasts, Ronald Greeley

Doctoral Dissertations

"Free, cup-shaped colonies of cheilostomatous bryozoans, equipped with vibracula, are termed lunulitiform bryozoans. This group is found in sandy and calcareous Cenozoic deposits of the Gulf and Atlantic Coastal Plains. Cupuliform bryozoans are taxonomically distinct from, but in many ways similar to, lunulitiform bryozoans; the two groups are frequently found together.

Known lunulitiform genera of the Gulf and Atlantic Coastal Plains are diagnosed and their species described: Lunulites Lamarck, fifteen species, one new; Oligotresium Gabb and Horn, six species, two new; Discoporella d'Orbigny, two species; Cupuladria Canu and Bassler, two species; Selenaria Busk, one species; Otionella Canu and Bassler, four …

Dynamics Of Disordered Harmonic Lattices, Daniel N. Payton Iii

Doctoral Dissertations

"Extensive numerical and analytic studies of vibrational spectra, normal modes, thermodynamic properties, and dynamical properties of harmonic systems with varying degrees of substitutional disorder have been made. The effects on observable properties of random mixtures of two or more species of atoms with differing masses and differing couplings to nearest-and next-nearest-neighbors have been investigated. Using the IBM-7030 digital computer, spectra for linear chains of 100,000 atoms have been obtained. Calculations in two and three dimensions have been limited to arrays of approximately 1000 atoms. Varying composition, mass ratio, and order affect the spectra in two and three dimensions in ways …

Geochemical And Petrological Study Of The Precambrian Iron Metallogenic Province Of Southeast Missouri, Geza Kisvarsanyi

Doctoral Dissertations

"The general purpose of this dissertation was to investigate and establish petrological and geochemical relationships, if any, between the Precambrian iron deposits and associated host rocks. A more specific objective was to determine the distribution of some significant minor elements in the rocks and mineral deposits and to include specific mineralogical and petrological studies of the iron deposits and country rocks important to a better understanding of the genetic and geochemical relationships ... A primary task in the investigation was the study of the trace element population of individual iron deposits and establishment of differences, if they exist, between the …

Re-Evaporation Nuclei And Evaporation In A Wilson Cloud Chamber, James G. Smith

Doctoral Dissertations

"Experimental techniques are developed for observing droplet evaporation in the submicroscopic size range. An expansion-compression cloud chamber with an atmosphere of tank helium saturated with water vapor is employed. This work was undertaken with the aim of examining submicroscopic droplet behavior and the existence of re-evaporation nuclei, a form of memory effect.

The theories of evaporation and nucleation on submicroscopic drop residues were re-examined, and alterations which appear to be consistent with the results of this work were incorporated into the evaporation theory.

The observed continually decreasing evaporation rate with diminishing droplet size confirms the existence of re-evaporation nuclei, but …

Some Geological And Magnetic Characteristics Of Buried And Resurrected Precambrian Hills Of Southeastern Missouri, James Edward Palmer

Doctoral Dissertations

"PURPOSE AND SCOPE OF INVESTIGATION The major purpose of this investigation was to determine by a comprehensive study various geological and magnetic characteristics of buried and resurrected Precambrian hills of the Central Ozarks. A second important objective was the determination of characteristics which might aid in the location of buried Precambrian hills. A final objective was the testing of the magnetic surface integration method for identification and determination of depth of buried Precambrian hills.

This investigation is limited to buried and resurrected Precambrian hills of the Central Ozarks. It is concerned primarily with the structure and stratigraphy of sediments adjacent …

An Investigation Of The Control Of Hydraulic Fracturing Through The Inclusions Of Prefractures, William Joseph Kabeiseman

Doctoral Dissertations

"Among the methods for determining the in-situ state of stress within the earth’s crust, hydraulic fracturing has been and is receiving much attention. This method, in principle, measures stress directly with no delicate electronic equipment required nor knowledge of the elastic modulus of the material.

This dissertation investigates experimentally whether or not control of fracture orientation can be achieved by the introduction of circular and elliptical prefractures along with sand inclusions into cast hydrostone blocks which are hydraulically fractured. A mathematical model is presented and analytically solved for the stress condition associated with a circular crack containing fluid pressure with …

Calculated Cohesive Energy Of The Ordered Copper-Gold Alloy Cu Au I, Richard W. Hannum

Doctoral Dissertations

"The ordered alloy CuAu is the fifty atomic per cent alloy in the copper-gold system. It was observed by Johansson and Linde(1) and was one of the first ordered alloys to be studied by x-ray diffraction methods(Z, 3). Two ordered superlattices of CuAu are observed. CuAu I exists below 380° C and has a tetragonal structure which is a slight distortion of the face- centered cubic. It is very highly ordered, with all copper and all gold atoms in alternate (002) planes, as shown in Figure 2. CuAu II, which exists between 380° and 415° C, is orthorhombic in structure(4) …

Structure Of The Northern Portion Of The Dumplin Valley Fault Zone In East Tennessee, Robert Dean Hatcher Jr.

Doctoral Dissertations

(From the Introduction) The purpose of this investigation is to study, synthesize, and interpret the structure of the Dumplin Valley family of faults and associated folds. The ultimate objective of the investigation is to present a clear, concise hypothesis for the origin of the structure. Finally, the writer has tried to relate the fault to other structures in East Tennessee, and to determine if the interpretation as formulated fits the regional tectonic picture.

Decay Of Certain Mercury Lines In Argon, Thallium, And Pure Mercury Atmospheres, Edward E. Stepp

Doctoral Dissertations

"Organization of thesis and Hg-A study, The time decay of the intensity of selected mercury lines was examined under three different conditions, Each section of this thesis i s divided into three parts corresponding to these three different conditions, In each section part A concerns the decay of intensity of the 2537, 4079, 4360, and 5462 A mercury lines, following the excitation of the states from which they originate by an Hg-A de discharge, Part B concerns the decay of intensity of 14 mercury lines following the excitation of the originating state of these lines by an intense r-f discharge …

A Study Of Near Surface Elastic-Anelastic Layers, Charles Allen Aldrich

Doctoral Dissertations

"Wave propagation through layered media is of importance in many disciplines. The near surface layers are of special significance, in that most measurements of waves are made within these layers. The purpose of this investigation was to formulate mathematical models with which to analyze the effects of near surface layering"--Introduction, page 1.

Stratigraphy, Sedimentation And Structure Of The Upper Cherokee And Lower Marmaton (Pennsylvanian) Rocks Of Bates County, And Portions Of Henry And Vernon Counties, Missouri, Richard J. Gentile

Doctoral Dissertations

"The major purpose of this dissertation is to describe in detail the stratigraphy of the upper Cherokee and lower Marmaton groups of the Middle Pennsylvanian, Desmoinesian Series in a portion of western Missouri. The stratigraphy of the upper Cherokee and lower Marmaton groups in areas of Kansas west of the project area has been studied by several workers. The most recent contributions have been by Jewett in 1941 and 1945, and by Howe in 1956. Detailed geological mapping also has been completed under the direction of the Missouri Geological Survey in areas to the east of the project area. Most …

Variation In Gold Content Of Minerals Of The Marysville Quartz Diorite Stock, Montana, Erwin Joseph Mantei

Doctoral Dissertations

"The purpose of this thesis was to study the amount and distribution of gold in the minerals of the Marysville quartz diorite stock, Montana. Twenty-eight rock samples were collected from various parts of the Marysville Stock, using a NS-EW grid sample pattern. Thirty additional samples were collected from selected localities and from the vicinity of the gold mines which occur around the periphery of the stock. By use of a hand magnet and a Frantz isodynamic separator, the magnetite, biotite, hornblende, and quartz-feldspar portions of the various rock samples were isolated and purified to between 90-99 percent purity. Eighteen thin …

Pair Distribution For A Cell-Model Liquid, James M. Phillips

Doctoral Dissertations

"The pair distribution function for a cell-model liquid has been derived by Lund in the form of an integral equation which depends upon the cell-center distribution function and the cell model. From this integral equation an approximate integral equation is obtained by substituting a function, which is linearly dependent upon the molecular pair distribution function and a variable parameter for the cell-center distribution function. This approximate integral equation is solved for the molecular pair distribution and the variable parameter is shown to depend upon the difference between temperature and the critical temperature. Although the exact numerical solution of the molecular …

An Investigation Of Current Induced Mass Migration In Solid Metals, Steven Mitchell Kovel

Doctoral Dissertations

"In this investigation of current induced mass transport, the general phenomenological equations will be considered first so as to present a picture of the experimental situation. The theoretical computations are then divided into four sections: (1) the determination of the force on a defect due to electron scattering, (2) a discussion of how the force on the defect might be shared by the surrounding ions, (3) how an external force affects the diffusion frequency of an ion, and (4) what the rate of mass transport is under the influence of an electric field. So as to simplify the discussion and …

A Solution To Einstein's Gravitational Field Equation For A Spherically Symmetrical Static Perfect Fluid, Lionel Donnell Hewett

Doctoral Dissertations

"Given spherical symmetry, Einstein's gravitational field equations are reduced to a single, second order, linear, homogeneous differential equation. The solution of this equation for a homogeneous sphere is identical with Schwarzschild's solution...Values of relative density, interior mass, relative pressure, relative and absolute temperature are obtained as functions of radius, r, and are compared with corresponding values for the homogeneous sphere, and for a model sun"--Abstract, page v.

Studies Of Tetrakis (Pyridine Base) Nickel (Ii) Perchlorate And Bisperchloratotetrakis (Pyridine Base) Nickel (Ii) Complexes, Lawrence Edward Moore

Doctoral Dissertations

The stereochemistry of nickel (II) compounds has been one of the most active and controversial fields of research in inorganic chemistry during the last 10 years. The multitude of colorful nickel compounds has intrigued chemists for a much longer time, but only in relatively recent years have such tools as visible and infrared absorptiometry, group theory and quantum mechanics, magnetic measurements, x-ray studies, and conductance measurements been brought to bear effectively to unravel the questions on stereochemistry in metal complexes.

Green's Relations And Dimension In Abstract Semi-Groups, George F. Hampton

Doctoral Dissertations

This thesis originated in an effort to find an efficient algorithm for the construction of finite inverse semigroups of small order. At one stage in trying to devise such a scheme, an attempt was made to construct an inverse semigroup by adjoining two non-idempotent elements to a semi-lattice in such a way that each of them would be D-equivalent to a pair of distinct D-equivalent idempotents. It was noticed taht such adjunction yielded an inverse semigroup only when the elements of the pari were incomparable in the partial ordering of the semilattice, and only when, for each positive integar n, …

Stratigraphy Sedimentation And Petroleum Possibilities Of The Middle Ordovician (Kimmswick-Galena) Rocks Of Missouri, Illinois And Iowa, Krishna Kant Misra

Doctoral Dissertations

"Detailed surface and subsurface studies of the Kimmswick Limestone and the Galena Formation of Middle Ordovician age in eastern Missouri, western Illinois, and southeastern Iowa were conducted in order to examine their stratigraphic relations, geological history, environment of deposition, and petroleum possibilities.

The main objective of this study was to seek a stratigraphic subdivision of the Kimmswick Limestone in Missouri, based on its gross lithology and thin section study, and its correlation with the Galena Formation in Illinois and Iowa. As a result of this study, based on the examination of twelve surface sections and 92 thin sections a three-fold …

A New Determination Of The Homogeneous Nucleation Rate Of Water In Helium, Edward Francis Allard

Doctoral Dissertations

"The object of this investigation is to apply the best known cloud chamber techniques to the study of condensation phenomena, directed mainly toward the development of a precise method for the determination of homogeneous nucleation rates. A secondary object is to investigate the properties of re-evaporation nuclei so that adequate precautions may be taken to eliminate their detrimental effect in the homogeneous nucleation experiments"--Statement of Problem, page 10.

The Origin Of The Bedded Arkansas Barite Deposits (With Special Reference To The Genetic Value Of Sedimentary Features In The Ore), Richard A. Zimmermann

Doctoral Dissertations

"The objective of this study has been to determine the geometric and mineralogic relationships existing between the barite and related sediments in the Stanley Shale in Arkansas and also to establish geometric, mineralogic, petrographic, and geochemical criteria for the interpretation of the origin of the barite and associated minerals. In addition, comparisons with German deposits have been made"--Introduction, Objective and Outline of Study, page [1].

Petrology And Mineralogy Of Certain Portions Of The Fredericktown Deposits, Farouk El Baz

Doctoral Dissertations

"The Fredericktown area is part of the 'Lead Belt' district of southeastern Missouri, the major lead-producing region in the world for fifty years. The district is a typical example of the Mississippi Valley Type deposits. The ores occur in Upper Cambrian sediments overlying Precambrian rocks.

The Fe-Cu-Pb-Zn (-Co-Ni) - sulphide deposits of Fredericktown occur over a few square kilometers in sediments overlying two 'granite knobs'. The sedimentary units lap upon and pinch-out against these buried basement hills.

The basal sedimentary unit, the Lamotte Formation, is a time-transgressive, marine, submature orthoquartzite. It contains a Boulder Bed at the base or at …