Physical Sciences and Mathematics Commons^™

Multidimensional Feature Engineering For Post-Translational Modification Prediction Problems, Norman Mapes Jr.

Doctoral Dissertations

Protein sequence data has been produced at an astounding speed. This creates an opportunity to characterize these proteins for the treatment of illness. A crucial characterization of proteins is their post translational modifications (PTM). There are 20 amino acids coded by DNA after coding (translation) nearly every protein is modified at an amino acid level. We focus on three specific PTMs. First is the bonding formed between two cysteine amino acids, thus introducing a loop to the straight chain of a protein. Second, we predict which cysteines can generally be modified (oxidized). Finally, we predict which lysine amino acids are …

Electromagnetic Wave-Matter Interactions In Complex Opto-Electronic Materials And Devices, Raj Kumar Vinnakota

Doctoral Dissertations

This dissertation explores the fundamentals of light-matter interaction towards applications in the field of Opto-electronic and plasmonic devices. In its core, this dissertation attempts and succeeds in the the modeling of light-matter interactions, which is of high importance for better understanding the rich physics underlying the dynamics of electromagnetic field interactions with charged particles. Here, we have developed a self-consistent multi-physics model of electromagnetism, semiconductor physics and thermal effects which can be readily applied to the field of plasmotronics and Selective Laser Melting (SLM). Plasmotronics; a sub-field of photonics has experienced a renaissance in recent years by providing a large …

A Complete Characterization Of Near Outer-Planar Graphs, Tanya Allen Lueder Genannt Luehr

Doctoral Dissertations

A graph is outer-planar (OP) if it has a plane embedding in which all of the vertices lie on the boundary of the outer face. A graph is near outer-planar (NOP) if it is edgeless or has an edge whose deletion results in an outer-planar graph. An edge of a non outer-planar graph whose removal results in an outer-planar graph is a vulnerable edge. This dissertation focuses on near outer-planar (NOP) graphs. We describe the class of all such graphs in terms of a finite list of excluded graphs, in a manner similar to the well-known Kuratowski Theorem for planar …

Evaluating Outcomes Of An Immersive-Field-Study Program On Fifth-Grade Students’ Connectedness With Nature, Laleh Talebpour

Doctoral Dissertations

The purpose of this research was to investigate to what extent an immersive-field-study experience influenced fifth-grade students’ connection to nature. Two instruments were used to collect data: Connection to Nature Index (CNI) obtained pre- and postfield study and students’ field journals with prompts.

The coding of the journals was based on the four components of CNI: Enjoyment of Nature, Empathy for Creatures, Sense of Oneness, and Sense of Responsibility. These components were built on the three basic components of nature connectedness described by Schultz (2002) as “cognitive (connectedness), affective (caring), and behavioral (commitment)” (p. 61).

Data were gathered from 317 …

Seismic Anisotropy And The Mantle Dynamics Beneath The Arabian Plate, Saleh Ismail Hassan Qaysi

Doctoral Dissertations

"We investigate mantle seismic azimuthal anisotropy and deformation beneath the Arabian Plate and adjacent areas using data from 182 broadband seismic stations which include 157 stations managed by the Saudi Geological Survey. A total of about 4000 pairs of shear wave splitting parameters are obtained using the transverse minimization technique. The individual XKS (including PKS, SKS, and SKKS) splitting measurements were manually checked to ensure the quality. The well-defined parameters show dominantly N-S fast orientations at the majority of the stations, and NW-SE fast orientations along the Zagras Mountain front. No clear systematic variations of the splitting parameters as a …

Equidimensional Adic Eigenvarieties For Groups With Discrete Series, Daniel Robert Gulotta '03

Doctoral Dissertations

We extend Urban's construction of eigenvarieties for reductive groups G such that G(R) has discrete series to include characteristic p points at the boundary of weight space. In order to perform this construction, we define a notion of "locally analytic" functions and distributions on a locally Q_p-analytic manifold taking values in a complete Tate Z_p-algebra in which p is not necessarily invertible. Our definition agrees with the definition of locally analytic distributions on p-adic Lie groups given by Johansson and Newton.

Mining And Analysis Of Real-World Graphs, Armita Abedijaberi

Doctoral Dissertations

"Networked systems are everywhere - such as the Internet, social networks, biological networks, transportation networks, power grid networks, etc. They can be very large yet enormously complex. They can contain a lot of information, either open and transparent or under the cover and coded. Such real-world systems can be modeled using graphs and be mined and analyzed through the lens of network analysis. Network analysis can be applied in recognition of frequent patterns among the connected components in a large graph, such as social networks, where visual analysis is almost impossible. Frequent patterns illuminate statistically important subgraphs that are usually …

Electrodeposited Epitaxial Cobalt Oxides And Copper Metal, Caleb M. Hull

Doctoral Dissertations

"Electrochemical deposition methods are presented for the deposition of Co(OH)₂ and Cu metal. Paper I shows the deposition of β-Co(OH)₂ on Ti through electrochemical reduction of [Co(en)₃]³⁺ to [Co(en)₃]²⁺ in 2M NaOH. The catalytic properties of the deposited Co(OH)₂ towards water oxidation is found comparable to Co₃O₄, with the surface of the Co(OH)₂ converting to CoOOH during the reaction. Paper II gives the conditions suitable for epitaxial growth of Co(OH)₂ on Au(100), Au(110), and Au(111) following the same reduction mechanism as described in Paper I. …

On Modeling Quantities For Insurer Solvency Against Catastrophe Under Some Markovian Assumptions, Daniel Jefferson Geiger

Doctoral Dissertations

"Insurance companies sometimes face catastrophic losses, yet they must remain solvent enough to meet the legal obligation of covering all claims. Catastrophes can result in large damages to the policyholders, causing the arrival of numerous claims to insurance companies at once. Furthermore, the severity of an event could impact the time until the next occurrence. An insurer needs certain levels of startup capital to meet all claims, and then must have adequate reserves on a continual basis, even more so when catastrophes occur. This work examines two facets of these matters: for an infinite time horizon, we extend and develop …

Aerogels For Energy Storage Applications: From Shape Memory Materials To Thermites And Explosives, Suraj Donthula

Doctoral Dissertations

"Aerogels are three dimensional highly porous solid objects that provide density reduction compared to dense objects. Those materials can have applications in different classes of energy storage and the two types that are focused in this dissertation are mechanical energy and thermal energy storage. Shape memory materials can store and recover elastic deformation energy when triggered by an external stimulus such as temperature. To incorporate those properties, shape memory polymeric aerogels (SMPA) were synthesized from a rigid isocyanurate containing triisocyanate (N3300 A) and four short oligomeric derivatives of ethylene glycol: H(OCH₂CH₂)_nOH (1 ≤ n …

Machine Learning Techniques Implementation In Power Optimization, Data Processing, And Bio-Medical Applications, Khalid Khairullah Mezied Al-Jabery

Doctoral Dissertations

"The rapid progress and development in machine-learning algorithms becomes a key factor in determining the future of humanity. These algorithms and techniques were utilized to solve a wide spectrum of problems extended from data mining and knowledge discovery to unsupervised learning and optimization. This dissertation consists of two study areas. The first area investigates the use of reinforcement learning and adaptive critic design algorithms in the field of power grid control. The second area in this dissertation, consisting of three papers, focuses on developing and applying clustering algorithms on biomedical data. The first paper presents a novel modelling approach for …

Mitigation Of Environmental Hazards Of Sulfide Mineral Flotation With An Insight Into Froth Stability And Flotation Performance, Muhammad Badar Hayat

Doctoral Dissertations

"Today's major challenges facing the flotation of sulfide minerals involve constant variability in the ore composition; environmental concerns; water scarcity and inefficient plant performance. The present work addresses these challenges faced by the flotation process of complex sulfide ore of Mississippi Valley type with an insight into the froth stability and the flotation performance. The first project in this study was aimed at finding the optimum conditions for the bulk flotation of galena (PbS) and chalcopyrite (CuFeS₂) through Response Surface Methodology (RSM). In the second project, an attempt was made to replace toxic sodium cyanide (NaCN) with the biodegradable chitosan …

Lithospheric Layering And Thickness Beneath The Contiguous United States, Lin Liu

Doctoral Dissertations

"The Upper Mississippi Embayment (UME), where the seismically active New Madrid Seismic Zone resides, experienced two phases of subsidence commencing in the Late Precambrian and Cretaceous, respectively. To provide new constraints on models proposed for the mechanisms responsible for the subsidence, we computed and stacked P-to-S receiver functions recorded by 49 USArray and other seismic stations located in the UME and the adjacent Ozark Uplift and modeled Bouguer gravity anomaly data. The inferred thickness, density, and Vp/Vs of the upper and lower crustal layers suggest that the UME is characterized by a mafic and high-density upper crustal layer of ∼30 …

Nanoporous Carbon Scaffolds For Energy Storage Applications, Waruni Jayawardana

Doctoral Dissertations

"Nanoporous carbons (NCs) have become increasingly popular in various fields of research due to their unique properties including tunable pore sizes, higher pore volumes and higher surface areas, as well as being able to produce controlled nanostructures. The work presented here uses NC scaffolds with as active hosts for (1) Li-ion battery electrodes and (2) confined metal hydrides (MH) for hydrogen storage applications. In (1) we investigate the Li diffusion characteristics in hard carbons (HCs) that are important for electrochemical applications. We develop a novel method named Voltage-Relaxation Galvanostatic Intermittent Titration Technique (VR-GITT). Parameters derived from the fitting of electrochemical …

Crustal Structure Beneath The Eastern Margin Of The Tibetan Plateau And Adjacent Areas From Receiver Function Stacking And Gravity Modeling, Yunxin Peng

Doctoral Dissertations

"To provide constraints on the mechanisms responsible for the uplift and crustal thickening of the eastern Tibetan Plateau, the thickness and Vp/Vs values of the Moho beneath 153 seismic stations are obtained by stacking P-to-S converted phases from the Moho and gravity modeling. The resulting crustal thickness generally decreases from the northwest to the south-east, from about 60 km in the Bayan Har Block to 30 km in the Sichuan Basin. The crustal Vp/Vs measurements in the Qinling Orogenic Belt, Bayan Har Block, Chuxiong Basin, and Yangtze Platform indicate an overall intermediate to felsic crustal composition. With a relatively thick …

Security Risk Assessment In Cloud Computing Domains, Amartya Sen

Doctoral Dissertations

"Cyber security is one of the primary concerns persistent across any computing platform. While addressing the apprehensions about security risks, an infinite amount of resources cannot be invested in mitigation measures since organizations operate under budgetary constraints. Therefore the task of performing security risk assessment is imperative to designing optimal mitigation measures, as it provides insight about the strengths and weaknesses of different assets affiliated to a computing platform.

The objective of the research presented in this dissertation is to improve upon existing risk assessment frameworks and guidelines associated to different key assets of Cloud computing domains - infrastructure, applications, …

The Utility Of Geophysical Techniques To Image The Shallow Subsurface In Karst Areas In Missouri, Nathainail Bashir

Doctoral Dissertations

"This dissertation is composed of three papers, which are focused on the utility of geophysical techniques to imaging the shallow subsurface in karst areas in Missouri.

In the first paper, ground penetrating radar (GPR) and time domain electromagnetic metal detector (TDEM-MD) methods were effectively deployed in an investigation of the cemetery with the intent of locating unmarked graves. The outcome of this study is to expand the knowledge of GPR and TDEM-MD methods, to locate unmarked graves in cemeteries. The study concluded that the GPR method is superior than TDEM-MD to locate buried caskets in cemetery investigations.

In the second …

Integrated Study On The Applicability Of Co₂-Eor In Unconventional Liquids Rich Reservoirs, Dheiaa Khafief Khashan Alfarge

Doctoral Dissertations

"Unconventional Liquids Rich Reservoirs (ULR) such as Bakken, Niobrara, and Eagle Ford have become the main target for oil and gas investors as conventional formations started to deplete and diminish in number. These unconventional plays have a huge oil reserve; however, the predicted primary oil recovery is still low as an average of 7.5 %. Unconventional Improved Oil Recovery (UIOR) techniques are still a new concept in the oil industry because there is no commercial project for any IOR technique so far. Injecting carbon dioxide (CO₂) might be the most potential strategy to improve oil recovery in such complex plays. …

Electrodeposited Semiconductor Nanostructures & Epitaxial Thin Films For Flexible Electronics, Naveen Kumar Mahenderkar

Doctoral Dissertations

"Single-crystal Si is the bedrock of semiconductor devices due to the high crystalline perfection which minimizes electron-hole recombination, and the dense native silicon oxide which minimizes surface states. To expand the palette of electronic materials beyond planar Si, an inexpensive source of highly ordered material is needed that can serve as an inert substrate for the epitaxial growth of grain boundary-free semiconductors, photonic materials, and superconductors. There is also a need for a simple, inexpensive, and scalable fabrication technique for the growth of semiconductor nanostructures and thin films. This dissertation focuses on the fabrication of semiconducting nanowires (polycrystalline Ge & …

Modeling And Characterization Of Thermo-Oxidative Behavior Of Bismaleimide Composites, Rafid Muhammad Hussein

Doctoral Dissertations

"High-temperature polymer matrix composites (HTPMCs) are susceptible to thermo-oxidation, which accelerates the composites' degradation and reduces the service life. Mechanical properties of HTPMCs deteriorate due to coupled thermo-oxidation and cross-linking mechanisms. Bismaleimides (BMIs) are commonly used high-temperature resins for aerospace applications. This work presents the viability of using experimental weight loss to model the spatial distribution of oxidation when the oxidized polymer matrix is not discernible. Three tasks are introduced: (1) Anisotropic oxidation prediction using optimized weight loss behavior of bismaleimide composites, (2) A multi-scale modeling of thermo-oxidative effects on the flexural behavior of cross-ply bismaleimide composites, and (3) Thermo-oxidative …

Evaluation Of The Redesign Of A Stem Gatekeeper Course, General Chemistry I, Incorporating Active-Learning Strategies And Implementation Of A Student-Choice Model, Travis Rae Mcdowell

Doctoral Dissertations

"The first courses freshman university students typically enroll in are the introductory science and math, courses that bridge from and build upon their prior educational experiences. These introductory courses often have large enrollment lectures coupled with supplemental sessions to teach using traditional educational practices, which may operate counter to the attitudes and culture of the students who take them. To address this, the general chemistry faculty through collaboration with a team of educational specialists initiated a redesign of the general chemistry course, which primarily serves first-year undergraduates. The redesign efforts included changes such as reducing lecture time and placing emphasis …

Characterization Of The Cylinderical Split Internal-Loop Photobioreactor With Scenedesmus Microalgae: Advanced Culturing, Modeling, And Hydrodynamics, Laith S. Sabri

Doctoral Dissertations

"Microalgae are fast growing photoynthetic microorganisms and it have very wide range of industrial applications such as biofuels and wastewater treatment. These cells can be grown in a wide variety of systems ranging from open culture systems (e.g., ponds) to closed culture systems of photobioreactor (e.g., airlift). The open culture systems exist in the external environment, and hence, are not intrinsically controllable. However, the microalgae production in enclosed photobioreactors faces prohibitively high production costs with special difficulty in reactor design and scale-up. The light availability and utilization efficiency in the photobioreactor in terms of design and scale-up consider as the …

Delineation Of A Coal Combustion Residue Landfill And Underlying Karst Subsurface In Southwest Missouri Using Ert And Masw Surveys, Ruobai Zhao

Doctoral Dissertations

"The safe containment of coal combustion residual (CCR) in landfills was addressed by the U.S. Environment Protection Agency (EPA) CCR rule published in 2015. The new rule affects new and existing U.S. based CCR landfills in terms of implementing safeguard systems for safe disposal and contamination control. Electrical resistivity tomography (ERT) and multichannel analysis of surface waves (MASW) data were acquired across and in proximity to a CCR landfill in southwest Missouri, USA, with the intent to identify potential karst features and seepage pathways.

Electrical resistivity tomography data were acquired using an automated 8-channel resistivity meter and multichannel analysis of …

Incremental Proper Orthogonal Decomposition For Pde Simulation Data: Algorithms And Analysis, Hiba Fareed

Doctoral Dissertations

"We propose an incremental algorithm to compute the proper orthogonal decomposition (POD) of simulation data for a partial differential equation. Specifically, we modify an incremental matrix SVD algorithm of Brand to accommodate data arising from Galerkin-type simulation methods for time dependent PDEs. We introduce an incremental SVD algorithm with respect to a weighted inner product to compute the proper orthogonal decomposition (POD). The algorithm is applicable to data generated by many numerical methods for PDEs, including finite element and discontinuous Galerkin methods. We also modify the algorithm to initialize and incrementally update both the SVDand an error bound during the …

Paleogene-Early Neogene Palynomorphs From The Eastern Equatorial Atlantic And Southeastern Florida, Usa: Biostratigraphy And Paleoenvironmental Implications, Walaa K. Awad

Doctoral Dissertations

"The transition from greenhouse conditions (Paleocene-Eocene Thermal Maximum, PETM) to icehouse conditions (Early Oligocene) is not well documented in tropical-subtropical regions. One hundred and five samples from Ocean Drilling Program (ODP) Site 959 (Hole 959A and Hole 959D) in the Cote d'Ivoire-Ghana Transform Margin, Alo-1 Well in the northern Niger Delta (Anambra) Basin, Nigeria, and W-17001 in southeastern Florida were studied for their palynological contents. Dinoflagellate cysts were mainly utilized for age refinement and to detect subtle changes in paleoenvironment and paleoclimate during the Paleocene-Early Eocene (ODP Hole 959D and Alo-1 Well) and Late Eocene-Early Miocene (ODP Hole 959A and …

3d Seismic Attribute Analysis And Machine Learning For Reservoir Characterization In Taranaki Basin, New Zealand, Aamer Alhakeem

Doctoral Dissertations

"The Kapuni group within the Taranaki Basin in New Zealand is a potential petroleum reservoir. The objective of the study includes building a sequential approach to identify different geological features and facies sequences within the strata, through visualizing the targeted formations by interpreting and correlating the regional geological data, 3D seismic, and well data by following a sequential workflow. First, seismic interpretation is performed targeting the Kapuni group formations, mainly, the Mangahewa C-sand and Kaimiro D-sand. Synthetic seismograms and well ties are conducted for structural maps, horizon slices, isopach, and velocity maps. Well log and morphological analyses are performed for …

Cox-Type Model Validation With Recurrent Event Data, Muna Mohamed Hammuda

Doctoral Dissertations

"Recurrent event data occurs in many disciplines such as actuarial science, biomedical studies, sociology, and environment to name a few. It is therefore important to develop models that describe the dynamic evolution of the event occurrences. One major problem of interest to researchers with these types of data is models for the distribution function of the time between events occurrences, especially in the presence of covariates that play a major role in having a better understanding of time to events.

This work pertains to statistical inference of the regression parameter and the baseline hazard function in a Cox-type model for …

Disorder At First-Order Classical And Quantum Phase Transitions, Ahmed Khalil Ibrahim

Doctoral Dissertations

"This dissertation studies the effects of quenched disorder on classical, quantum and nonequilibrium phase transitions. After a short introduction which covers the basic concepts of phase transitions, finite-size scaling and random disorder, the dissertation focuses on four separate but related projects. First, we investigate the influence of quenched disorder with long-range spatial correlations on the nonequilibrium phase transitions in the contact process. We show that the long-range correlations increase the probability to find rare atypical regions in the sample. This leads to enhanced Griffiths singularities and changes the universality class of the transition.

Project 2 and 3 focus on disorder …

Fully Differential Study Of Dissociative Capture In P + H₂ Collisions, Basu Ram Lamichhane

Doctoral Dissertations

"In recent years, the key role of the projectile coherence properties has been studied in several ion-atom scattering processes. These studies strongly suggested that cross sections could be significantly affected by the projectile coherence properties, especially for fast, heavy ions. In the present study, we used such coherence effects as a tool to sensitively analyze the few- body dynamics of the scattering process. To this end, we performed three kinematically complete experiments on fragmentation of H₂ by 75 keV proton impacts. A novel approach was used to analyze coherence and interference effects in the observed cross-sections. The idea was …

Evolving Specialization In An Agent-Based Model Without Task-Switching Costs, Shane Robert Meyer

Doctoral Dissertations

"This work examines the possibility of evolving the phenotypic specialization associated with division of labor in an agent-based model without task-switching costs. The model examines two groups competing for vital resources, where members of one group are capable of sharing resources with other agents in their group. Agents attempt to collect resources which allow them to reproduce, with more resources leading to a greater number of offspring by asexual reproduction. Four variants of the model are examined, with combinations of one or two resources and the presence of a foraging risk. The presence of the foraging risk can lead to …