Advanced Analysis Of Compounds Of Toxicological Importance By Ice Concentration Linked With Extractive Stirrer (Icecles) Gc-Ms And Rp-Hplc-Esi-Ms-Ms, Joseph K. Dzisam

Electronic Theses and Dissertations

Cyanide and nitrosoamines (NAs) are ubiquitous compounds, found in our food and water, either by natural process or through man-made activities. The toxicity of cyanide is exerted by its ability to inhibit metalloenzymes such as cytochrome c oxidase, causing concomitant cascades of biochemical effects such as lactic acidosis, inhibition of ATP production, respiratory seizure, and potential death. Nitrosoamines, on the other hand, undergo biotransformation (metabolic activation in cytochrome P450) in the body to produce unstable intermediates that alkylate DNA, causing mutations, and leading to carcinogenesis. In order to further the advancement of a promising cyanide, cobinamide (Cbi), an LC-MS-MS method …

Diversifying Cornfields By Interseeding Cover Crops: Practical Implications And The Response Of Invertebrate Communities, Michael Bredeson

Electronic Theses and Dissertations

The lack of suitable habitat conditions for beneficial organisms in simplified agroecosystems leads to unstable invertebrate communities and overreliance on chemical control of herbivores. It is possible to manage pest populations without agrichemicals by manipulating farmland so that herbivores are impaired by plant-driven bottom-up and enemy-driven top-down antagonisms. Interseeding cover crops between established crop rows is a method used by farmers to improve habitat suitability for natural enemies and hinder host-finding, feeding and movement by herbivores. Here I address three important research gaps related to interseeding cover crops. A calcium carbonate seed coating, used to improve seed-broadcasting efficiency, was tested …

Effects Of Energy Development On Movements, Home Ranges, And Resource Selection Of White-Tailed Deer In The Western Dakotas, Bailey S. Gullikson

Electronic Theses and Dissertations

Oil and natural gas development has increased in recent years and research is needed to assess potential impacts on white-tailed deer (Odocoileus virginianus) populations. Our objectives were to document movements, home ranges, and resource selection of female white-tailed deer in response to energy development in the western Dakotas. Our study areas included Dunn County, North Dakota, an area with current oil and gas development, and Grant County, North Dakota, and Perkins County, South Dakota, areas without current oil and gas development. We captured and fitted 150 female deer with Very High Frequency (VHF) collars across study sites, and …

Brassica Carinata Growth And Yield Response To Nitrogen And Sulfur Fertilizers And Impacts On Selected Soil Parameters And Ghg Fluxes, Dwarika Bhattarai

Electronic Theses and Dissertations

Carinata (Brassica carinata A. Braun), a non-food oilseed crop and an alternative bio-jet fuel feedstock, has received attention for its potential as a low-input option for production in the semi-arid regions of the Northern Great Plains of USA. The crop has a lower N fertilizer requirement as compared to the other oilseeds, suggesting less negative impact on soils and GHGs emissions. Carinata is a new crop to South Dakota (SD), thus, the best management practices have yet to be developed. In addition, no sufficient research to address the impact of growing carinata on soils and GHG emissions has been …

Investigation Of Narrow Bipolar Events In Mississippi Thunderstorms, Sampath Asiri Bandara

Electronic Theses and Dissertations

In the first part of the study FA and Log-RF data were used to examine low-altitude (<8.0 km) negative NBEs (NNBEs) to see how many -CG flashes were initiated by NNBEs. Out of 686 -CG flashes only 33 (5%) flashes were initiated by an NNBE. These NNBEs occurred at an average altitude of 6.2 km had average amplitude (range-normalized amplitude to 100 km) of 0.4 V/m and had average VHF (Log-RF) power of 130 W. Since the low-altitude NNBEs were substantially weaker than positive NBEs that initiate intracloud (IC) flashes it is hypothesized that -CG flashes are easier to initiate than IC flashes. The second part of the study investigated the properties of 201 positive NBEs (+NBEs). The +NBEs were classified in two ways: into Types A-D [Karunarathne et al. 2015] and into three different groups: Isolated Not-isolated and IC flash-initiator or INBE [Wu et al. 2014]. The average VHF (Log-RF) power of NBEs within the A-D categories were 1.9 4 9.8 and 13.2 kW respectively while the powers for the Isolated Not-isolated and INBE categories were 10.1 4 and 10.1 kW respectively. The third study considered 34 NBEs that occurred close in space and time to each other: 13 pairs of NBEs one group of three +NBEs and one group of five +NBEs. The NBEs were overlaid on radar data of the parent thunderstorms. The data indicate that the individual NBEs in each group initiated in separate intense electric field regions of small extent rather than in a single large-scale electric field region. This dissertation investigates Narrow Bipolar Events (NBEs) which are a type of short-duration (10- 30 µs) lightning discharge. The study primarily used data from NBEs collected in 2016 at seven sensor sites within 50 km of Oxford Mississippi USA. Each sensor site had three electromagnetic antennas called Fast Antenna (FA) dE⁄dt and Log-RF with bandwidths of 0-2.5 MHz 0-1.0 MHz and 186-192 MHz respectively. NBEs are often isolated from other lightning events in thunderclouds but they sometimes initiate negative cloud-to-ground (-CG) and intracloud (IC) lightning flashes or they can occur during these flashes.

Application And Refinement Of Molecular Ecology Techniques For Amphibian Conservation, Stephanie Marie Burgess

Electronic Theses and Dissertations

Wildlife conservation has become increasingly difficult due to habitat loss habitat fragmentation and land use change. Thus conservationists have embraced advances in molecular ecology such as landscape genetics and microbial bioinformatics that employ genetic techniques to further understand the relationship between individuals and their environment. In landscape genetics model inferences can be used to identify features that facilitate or resist gene flow providing a framework for anticipating the impacts of land use changes on a species’ ability to disperse. However the factors that affect the transferability of landscape genetics inferences are poorly understood and little is known about the effect …

Probing Atypical Noncovalent Interactions Using Electronic Structure Theory, Katelyn Mae Dreux

Electronic Theses and Dissertations

Some of the most important topics in modern chemistry involve noncovalent interactions in a variety of ways, from pharmacological processes to materials design. Due to the comparatively weak nature of these interactions, they can be difficult to investigate experimentally. Beyond what might be considered the ‘typical’ noncovalent interactions such as hydrogen bonding or London dispersion, there are less well known noncovalent interactions such as coordinate covalent, dihydrogen, and nonconventional hydrogen bonding, which have been the focus of much of this research. Through the use of electronic structure theory, fundamental information about the structure, energetics, and molecular properties of noncovalently bound …

Quadratic Reciprocity: Proofs And Applications, Awatef Noweafa Almuteri

Electronic Theses and Dissertations

The law of quadratic reciprocity is an important result in number theory. The purpose of this thesis is to present several proofs as well as applications of the law of quadratic reciprocity. I will present three proofs of the quadratic reciprocity. We begin with a proof that depends on Gauss's lemma and Eisenstein's lemma. We then describe another proof due to Eisentein using the $n$th roots of unity. Then we provide a modern proof published in 1991 by Rousseau. In the second part of the thesis, we present two applications of quadratic reciprocity. These include special cases of Dirichlet's theorem …

Electrochemical Studies Involving Co2 Reduction With Rhenium-Based Catalysts And For Guanosine Monophosphate Oxidation, Kayla A. Milano

Electronic Theses and Dissertations

The following chapter of this thesis will cover the oxidation of guanine monophosphate (GMP). GMP has been linked to numerous conditions when it is oxidized or damaged. There have been two oxidation pathways suggested in association to the oxidation of GMP: EPT and MS-EPT. The ideal conditions for GMP’s oxidation is still be studied and collected. The study focuses on the acetate versus phosphate buffer, varying base concentration in phosphate buffer, and the varying concentration of ruthenium complex, a redox mediator.

Beta Invariant And Variations Of Chain Theorems For Matroids, Sooyeon Lee

Electronic Theses and Dissertations

The beta invariant of a matroid was introduced by Crapo in 1967. We first find the lower bound of the beta invariant of 3-connected matroids with rank r and the matroids which attain the lower bound. Second we characterize the matroids with beta invariant 5 and 6. For binary matroids we characterize matroids with beta invariant 7. These results extend earlier work of Oxley. Lastly we partially answer an open question of chromatic uniqueness of wheels and prove a splitting formula for the beta invariant of generalized parallel connection of two matroids. Tutte's Wheel-and-Whirl theorem and Seymour's Splitter theorem give …

Manifoldlike Causal Sets, Miremad Aghili

Electronic Theses and Dissertations

The content of this dissertation is written in a way to answer the important question of manifold likeness of causal sets. This problem has importance in the sense that in the continuum limit and in the case one finds a formalism for the sum over histories, the result requires to be embeddable in a manifold to be able to reproduce General Relativity. In what follows I will use the distribution of path length in a causal set to assign a measure for manifold likeness of causal sets to eliminate the dominance of nonmanifold like causal sets. The distribution of interval …

Zeros Of The Dedekind Zeta-Function, Mashael Alsharif

Electronic Theses and Dissertations

H. L. Montgomery proved a formula for sums over two sets of nontrivial zeros of the Riemann zeta-function. Assuming the Riemann Hypothesis, he used this formula and Fourier analysis to prove an estimate for the proportion of simple zeros of the Riemann zeta-function. We prove a generalization of his formula for the nontrivial zeros of the Dedekind zeta-function of a Galois number field, and use this formula and Fourier analysis to prove an estimate for the proportion of distinct zeros, assuming the Generalized Riemann Hypothesis.

X-Ray Crystal Structure Of Au36(Sph-Pch3)24 Nanomolecules, Vigneshraja Ganeshraj

Electronic Theses and Dissertations

Au36(SR)24 is one of the most comNanomolecules (NM) in gold NM field and crystal structures of Au36(SR)24 with different thiolate protecting ligand such as tert-butylbenzene thiol, thiophenol and cyclopentane thiol have been reported. It has been predicted that aromatic thiol protected Au36(SR)24 NM have same core structures like the other reported Au36(SR)24 NMs. Due to the steric and electronic conjugation effects the staples on the gold core exhibit minor changes in the bond length without affecting the gold core. By varying the Gold:Thiol ratio the NM size can be controlled. Herein, we report the synthesis, isolation and characterization of two …

X-Ray Fluorescence Analysis Of Tuscaloosa Marine Shale Cuttings From Horizontally Drilled Wells, Xiaotian Wang

Electronic Theses and Dissertations

The Upper Cretaceous Tuscaloosa Marine Shale (TMS) is a gray to black fissile marine shale deposited at depth of between 10,000 and 20,000 ft near the ancient Gulf of Mexico. The TMS has been gradually developed as a hydrocarbon reservoir in the past several decades. But there are rare researches evaluating geochemical properties based on chemostratigraphy of the TMS. The objective of this research is to spatially evaluate geophysical properties and chemostratigraphy of the TMS, to characterize elemental changes along well paths and to evaluate the effect of basic sample clean on XRF results. The data available for this study …

An Approach To Semi-Autonomous Indoor Drone System: Software Architecture And Integration Testing, Shobhan Singh

Electronic Theses and Dissertations

To address these problems, we establish a semi-autonomous functionality by removing the RC transmitter, and remotely connecting the Drone System to track status and executing user-based input commands. In order to resolve the limitation in hardware connections on the Flight Controller, we integrated the sonar sensor into a companion computer, from where the data is continuously fed to an embedded system through MAVLink (Micro Aerial Vehicle Link) network communication protocol. In this study, we also implemented a modular architecture which enables scalable integration of sensor modules into the Drone System to streamline the process of development, deployment, testing and debugging.

Ni And Au Transition Metal Complexes In The Photocatalytic Co2 Reduction Reaction, Shakeyia Davis

Electronic Theses and Dissertations

The production of renewable fuels by the conversion of solar energy into chemical energy is a challenge. Photocatalytic and electrocatalytic conversion of CO2 to usable fuel precursors are approaches to overcoming this challenge. The two-electron reduction of carbon dioxide to carbon monoxide is an appealing process because CO can be used as a commodity chemical in industrial processes. Many molecular CO2 reduction catalysts have been reported and commonly use expensive late transition metals. These systems are inspired by natural photosynthesis and generally combine a photosensitizer, a catalyst, and a sacrificial electron donor. This work focuses nickel and gold complexes as …

Acoustic Radiation Force On A Fluid To Fluid Boundary By Phase Plate Focused Ultrasound, Robert Lee Lirette

Electronic Theses and Dissertations

In this study, the physics and applications of the ultrasonic radiation force at the interface between two immiscible fluids were investigated. These studies were performed using low-profile discrete-stepped lenses to the modify the phase of the incident radiation generating multiple field morphologies. In its first application to acoustics, a fraxicon lens was developed to approximate the field generated by an axicon. This type of lens creates a minimally diffractive Bessel beam and long depth of focus that is useful in ultrasonic imaging, therapy, and non-destructive evaluation techniques. Fields modified by fraxicon, Fresnel, and axicon lenses were characterized experimentally by scanning …

The Synthesis Of New Donor-Sigma-Acceptor Compounds As Potential Current Rectifiers, Trey Gautier Vaughan

Electronic Theses and Dissertations

The zwitterionic D-σ-A’s are characterized by having an anionic donor, a cationic acceptor, an intervening sigma-bond bridge, and an aliphatic tail. The aliphatic tail is of such length as to impart greater solubility in organic solvents since the formal charges on the donor and acceptor lead to poor solubility. Additionally, the aliphatic tail is required for Pockels-Langmuir deposition to facilitate the favorable van der Waal’s packing when combined to form dense monolayer registries. These monolayers may then be suitable for measuring the bulk electrical properties.

Physical And Chemical Trace Evidence From 3d-Printed Firearms, And Use Of A Quadcopter For Targeted Sampling Of Gaseous Mercury In The Atmosphere, Oscar Beauchamp Black

Electronic Theses and Dissertations

My forensic research resulted in the first peer-reviepaper to address the forensic challenges presented by 3D-printed polymer firearms. The work involved a systematic approach to the analysis of evidence stemming from 3D-printed firearms filling a critical void in current forensic knowledge. We used DART-MS to characterize the polymer evidence left behind by 3D-printed firearms as well as an evaluation of pre-existing firearm and toolmark techniques and fingerprint analysis. We demonstrated that 3D-printed firearms leave behind characteristic polymer residue on cartridge cases bullets and the receiving surface which can be identified using DART-MS. The culmination of the work includes a database …

Effects Of Increasing Temperature And Acidification On The Growth And Competitive Success Of Alexandrium Catenella From The Gulf Of Maine, Drajad Seto

Electronic Theses and Dissertations

The increases in ocean temperature and pCO2 due to climate change are projected to affect the growth and future prevalence of Harmful Algal Blooms (HABs) in nearshore waters, but systematic studies on the effects these climate drivers have on harmful algal species are lacking. In particular, little is known about how future climate scenarios will affect the growth of the toxic dinoflagellate Alexandrium catenella, which produces the toxins responsible for paralytic shellfish poisoning (PSP) that threaten the health and economy of coastal communities in the Gulf of Maine. I examined growth responses of A. catenella and two other naturally co-occurring …

Investigations Into The Advancement Of Cryptotephra Geochemical Fingerprinting, Laura Hartman

Electronic Theses and Dissertations

The primary purpose of this work is to advance new sample preparation and analytical methods for ice core tephrochronology. When a volcanic source can be accurately identified using volcanic glass particle geochemistry, it may provide a robust time reference for the ice core’s timescale. The presence of an identifiable tephra layer may also suggest atmospheric pathways at the time of deposition, or assist in reconstructing volcanic forcing of climactic state for a specific event. One of the perpetual challenges in ice core based tephrochronological work is measuring the geochemical composition of ultra-fine particles (<10 >μm). Not only is it difficult …

Stream Dynamics In The Headwaters Of Post-Glacial Watershed Systems, Brett Gerard

Electronic Theses and Dissertations

This dissertation summarizes research examining watershed processes across Northern New England, with an emphasis on the Central and Coastal regions of Maine. The research presented here focuses on the linkages between watershed geomorphic conditions, climate, and surface flow regimes driving stream channel hydraulic conditions and bed dynamics governing channel geometry. The geologic and human history of the landscape provides the context in which earth surface processes are examined within the dominant physiographic settings in Maine to describe vulnerabilities to climate change. Results are summarized to support the development of sustainability solutions for forecasted watershed management problems by natural resource management …

Remote Sensing Of Icebergs In Greenland's Fjords And Coastal Waters, Jessica Scheick

Electronic Theses and Dissertations

Increases in ocean water temperature are implicated in driving recent accelerated rates of mass loss from the Greenland Ice Sheet. Icebergs provide a key tool for gaining insight into ice-ocean interactions and until recently have been relatively understudied. Here we develop several methods that exploit icebergs visible in optical satellite imagery to provide insight on the ice--ocean environment and explore how iceberg datasets can be used to examine the physics of iceberg decay and parent glacier properties. First, a semi-automated algorithm, which includes a machine learning-based cloud mask, is applied to six years (2000-2002 and 2013-2015) of the Landsat archive …

Controls On Phosphorus Export From An Agricultural Watershed: Amsden Brook, Fort Fairfield, Maine Usa., Gregory J. Mcdonald

Electronic Theses and Dissertations

This study explores the sources and mechanisms of phosphorus (P) mobilization during base flow within the Amsden Brook watershed, Fort Fairfield, Maine, USA. Amsden Brook is an agriculturally dominated watershed drained by a spring-fed and perennial first- to second-order stream. We characterized the P concentrations within the watershed to investigate connections between soils, stream sediment, surface water, and groundwater. Waters were monitored monthly during the 2017 snow-free period for temperature, pH, dissolved oxygen, conductivity, soluble reactive P (SRP), total P, strong acid anions, strong base cations, dissolved organic carbon (DOC), Al, Fe, and Mn. Phosphorus speciation within soils and sediment …

Mercury In Big Cypress Bayou And Caddo Lake Watersheds In Marion And Harrison Counties Texas, Joseph Watkins

Electronic Theses and Dissertations

Caddo Lake has been included on the Texas Commission on Environmental Quality 303(d) list for impairment due to mercury (Hg) content since 1996. One of the primary tributaries, Big Cypress Bayou, flows across Eocene-aged rocks and sediments associated with the Wilcox Group; the Wilcox is of interest because it contains lignite coal, which has a direct link to mercury. Previous research has focused on dry deposition from fossil fuel combustion as the primary source of mercury but has not addressed the potential watershed contribution to mercury concentrations in Caddo Lake.

Big Cypress Bayou flows through Harrison and Marion counties in …

Syntheses Of A Tin (Iv) Meso-Tetra(4-Pyridyl) Porphyrin Dichloride-Tetrachlorobis (Bipy)2 Ruthenium (Ii) Complex And Studies Of Photophysical Properties Of 1-Nitropyrene, Phillip Sharp

Electronic Theses and Dissertations

Development of a photosensitizer that can work in both aerobic and anaerobic environments would increase the robustness of the cancer treatment known as photodynamic therapy. The development of a photosensitizer was first attempted by synthesizing a tin (IV) meso-tetra (4-pyridyl) porphyrin dichloride-tetrachlorobis (Bipy)₂ ruthenium (II) complex. The synthesize of the tin porphyrin was done by a method from literature and had a percent error of 31.58 and 37.31 when comparing the theoretical percentages of carbon (55.39) and nitrogen (12.92) meaning that photosensitizer was not synthesized.

The second type of chromophore that was studied was 1-nitropyrene do determine if it …

Delineation Of Karst Potential Using Lidar And Gis Analyses, Fort Hood Military Installation, Texas, Colby Reece

Electronic Theses and Dissertations

ABSTRACT

Traditional karst surveys require extensive field investigations to completely characterize large areas. They are often time-consuming, requiring up to several years to collect and categorize data. Bias is given to areas that are most easily accessible and false negatives are common. The implementation of geographic information systems (GIS) has aided in the aggregation and standardization of karst data; however, these systems have also been used to develop terrain models that allow the user to remotely delineate sinkholes and other surficial features. The Fort Hood Military Installation is a karst landscape that has been altered significantly for use in military …

Climatic Range Filling Of North American Trees, Benjamin Seliger

Electronic Theses and Dissertations

Understanding the degree to which species distributions are controlled by climate is crucial for forecasting biodiversity responses to climate change. Climatic equilibrium, when species are found in all places which are climatically suitable, is a fundamental assumption of species distribution models, but there is evidence in support of climate disequilibria in species ranges. Long-lived, sessile organisms such as trees may be especially vulnerable to being outpaced by climate change, and thus prone to disequilibrium. In this dissertation, I tested the degree to which North American trees are in equilibrium with their potential climatic ranges using the ‘range filling’ metric, which …

Multispectral Classification Of Gulf Of Maine Surface Waters: Seasonal And Interannual Variability, Brianna M. King

Electronic Theses and Dissertations

Bio-optically, surface waters of the northeastern US continental shelf are strongly heterogeneous, exhibiting highly variable distributions in both time and space of suspended sediment, colored dissolved organic matter (CDOM), and phytoplankton concentration and community structure. These render the standard global NASA satellite chlorophyll algorithm suspect. However, spectral signatures of the water are well quantified by the actual satellite-based multispectral reflectance (Rrs) measurements. Here, we use 6 bands of Rrs measurements from 19 years (1998-2016) of monthly composite SeaWiFS and MODIS data to identify the spectral signatures of dominant water types present over the northeast shelf. A merged multivariate clustering approach …

Physical And Chemical Controls On Suffosion Development In Gypsic Soil, Culberson County, Texas, Jonah Morris

Electronic Theses and Dissertations

In the Gypsum Plain, suffosion processes have encouraged road failure through dissolution and transport of gypsic soils; however, no prior research has been conducted within the Delaware Basin in regard to these processes. These phenomena were evaluated in both field and laboratory settings in order to assess the parameters of suffosion development associated with Ranch to Market (RM) 652 in Culberson County, Texas, where infrastructure extends across Castile and Rustler strata. Field studies simulated surficial ponding in various gypsic soils and correlated suffosion potential with soil composition and thickness. Soluble fractions of gypsic soils were delineated through geochemical analyses, further …