Physical Sciences and Mathematics Commons^™

The Response Of The Zooplankton Community In The Western Gulf Of Maine To A Shift In Oceanographic Conditions: 2005-2017, Emma Cecile Dullaert

Electronic Theses and Dissertations

The Gulf of Maine (GoM) harbors a productive ecosystem that supports a wide variety of marine life, providing services upon which local communities rely. The GoM ecosystem supports many important commercially harvested species, including the American lobster (Homerus americanus) which is the most valuable fishery in the US, Atlantic herring (Clupea harengus) and a variety of groundfish. The GoM is also home to the critically endangered North Atlantic right whale (Eubalaena glacialis), which has historically been known to feed in the eastern GoM and Bay of Fundy during the summer and fall months. In …

Supramolecular And Covalent Crosslinking Of Organic Semiconductors, Audithya Narasimha Nyaychavadi

Electronic Theses and Dissertations

Organic semiconductors are a class of materials that are uniquely positioned to be the platform for next generation technologies that possess properties that transcend the limitations of silicon materials such as inherent biocompatibility, stretchability and degradability, all while being manufactured sustainably and at lower cost. These materials have good electronic properties that arise from their π-delocalized network, which when combined with rational chemical design allow for highly specialized materials for targeted applications and properties. Furthermore, their ability to be solution processed provides an avenue for low-cost, scalable mass production techniques, such as printing and roll-to-roll coating. Despite these advantages, however, …

Mechanistic Studies Of Inert Bond Functionalization By Mono And Polynuclear Ni Complexes, Jun Yang Liu

Electronic Theses and Dissertations

Studies into the mechanism of 8-aminoquinoline-directed nickel-catalyzed C(sp3)–H arylation with iodoarenes were performed. Paramagnetic complexes such as a high spin four-coordinate disphenoidal Ni([AQpiv]-κN,N)2 (where [AQpiv] = C9NH6NCOtBu) and {[AQpiv]Ni(O2CtBu)}2 undergo the key C–H activation step. The ubiquitous base Na2CO3 is found to hinder catalysis and was rate-limiting; replacement of Na2CO3 with NaOtBu gave improved catalytic turnovers under milder conditions but also occurred without carboxylic acid and phosphine additives. Products of C–H activation supported by PPh3 or PiBu3 were isolated. The C–H functionalization reaction orders with respect to 7·PiBu3, iodoarenes, and phosphines were determined. Hammett analysis using electronically different aryl iodides …

Proposing A Measure Of Ethicality For Humans And Ai, Alejandro Jorge Napolitano Jawerbaum

Electronic Theses and Dissertations

Smarter people or intelligent machines are able to make more accurate inferences about their environment and other agents more efficiently than less intelligent agents. Formally: ‘Intelligence measures an agent’s ability to achieve goals in a wide range of environments.’ (Legg, 2008)

In this dissertation we extend this definition to include ethical behaviour and we will offer a mathematical formalism and a way to estimate how ethical an action is or will be, both for a human and for a computer, by calculating the expected values of random variables. Formally, we propose the following measure of ethicality, which is computable, or …

Examining The Effectiveness Of Using Point-Of-View Video Modeling On Mathematics Improvement In Students With Learning Disabilities In Saudi Arabia, Tirad Alsaluli

Electronic Theses and Dissertations

Video Modeling (VM) is one of the most widely used approaches by researchers to improve many skills, such as academic skills in students with Learning Disabilities (LD; Boon et al., 2020). As the incidence rate of individuals with LD in Saudi Arabia increase (Almedlij & Rubinstein-Ávila, 2018), the need for evidence-based math interventions focused on the math development of individuals with LD also increases. Although VM is recognized as an Evidence-based Practice (EBPs), a limited number of studies have implemented VM as an intervention to improve mathematic skills. Implementing VM as a math intervention strategy would explore its effects on …

Indirect Aggression And Victimization: Investigating Instrument Psychometrics, Gender Differences, And Its Relationship To Social Information Processing, Taylor Steeves

Electronic Theses and Dissertations

The study of indirect bullying behaviors, relational aggression and social aggression, has been of theoretical importance and interest to researchers and psychologists within the last few decades. In this investigation, using a convenience sample of 451 late adolescents attending a private university in the mid-Atlantic U.S., I examined the factor structure of two measures of indirect bullying, the Young Adult Social Behavior Scale – Victim (YASB-V) and the Young Adult Social Behavior Scale – Perpetrator (YASB-P). Using confirmatory factor analysis (CFA), I found that the YASB-V comprised a four-factor model, differing from the model that had been identified in the …

Comparative Life Cycle Assessment Of Small Vertical-Axis Wind Turbines And Natural Gas Facility At An Urban University, Mary Kate Ranii

Electronic Theses and Dissertations

Fossil fuels generate the majority of the electricity in the United States and generate pollutants that negatively affect public and environmental health. Renewable energy projects serve as an opportunity for low-pollution and low-carbon electricity; small-scale projects, such as vertical axis wind turbines (VAWTs), provide opportunities for generation in urban areas close to consumers. Researchers collected wind speed and directional data from a potential turbine installation site at Duquesne University to better demonstrate the potential benefits in an urban university location. The data was used in a life cycle assessment framework and a social review to better understand the value of …

Modifying The Composition Of A High Temperature Superconductor, Drue Lubanski

Electronic Theses and Dissertations

The purpose of this research was to recreate a known superconductor, YBa₂Cu₃O_x, and modify it in an attempt to raise its transition temperature. A superconductor is any material that excludes magnetic flux from its interior when at a temperature below its transition temperature. A “high temperature” superconductor refers to material that shows superconductivity at or above the temperature of liquid nitrogen temperatures (77.15K).

Here we were successful in reproducing the original YBa₂Cu₃O_x and measuring its critical temperature; However, our efforts at raising the transition temperature have, as of yet, …

Effectiveness Of 2016 Watershed Protection Plan On Bacteria And Nutrient Concentration Loads In The Attoyac Bayou Watershed, Jack Henson

Electronic Theses and Dissertations

In 2004, bacteria and nutrient sampling on the Attoyac Bayou Watershed discovered elevated concentrations of E. coli on five of the main channels key tributary streams. The Attoyac Bayou was then listed on the Texas 303d list of impaired waterbodies and further research was conducted to identify the main sources of contamination in the waterbody. In 2016, the Attoyac Bayou Watershed Plan (WPP) was developed to implement best management practices (BMPs) that would decrease bacteria and nutrient concentrations in the watershed. Educational outreach programs, on-site-sewage facility repair, and livestock management were some of the strategies suggested by the protection plan …

Bioinformatic Analysis Of The Interaction Of Evc And Evc2 Proteins, Md Atikul Islam Mamun

Electronic Theses and Dissertations

Protein to protein interactions are significant to various biological processes, functioning, and the regulation of cells and organisms. Proteins perform essential cellular tasks and often work together in complexes, enabling specific functions like enzymatic activity, signal transduction, DNA replication, and cell division. These interactions are important in signaling pathways, allowing proteins to interact sequentially, leading to specific cellular responses. Some proteins rely on chaperones to fold correctly, and protein to protein interactions enhance stability, preventing degradation.

Researchers at Stanford University School of Medicine discovered that EvC syndrome is related to a malfunction in the Hedgehog (Hh) signaling pathway. They found …

Applications Of Artificial Intelligence To Improve Coastal Ocean Modeling, Dongliang Shen

Electronic Theses and Dissertations

Numerical Modeling (NM) is widely used to simulate and predict hydrodynamic processes and marine particle movements in coastal oceans, particularly during extreme weather events and emergencies. NM offers the capability to realistically simulate multiple state variables and fill gaps caused by scarce observations. However, inherent uncertainties exist in all NMs, primarily arising from the following three factors: 1) insufficient observations leading to uncertain model initial and boundary conditions, 2) inevitable truncation errors due to coarse model resolution, and 3) imperfect physics parameterization schemes for sub-grid processes, especially those related to waves. The consequences of these uncertainties are that 1) even …

Characteristics Of Refractivity And Sea State In The Marine Atmospheric Surface Layer And Their Influence On X-Band Propagation, Douglas Matthew Pastore

Electronic Theses and Dissertations

Predictions of environmental conditions within the marine atmospheric surface layer (MASL) are important to X-band radar system performance. Anomalous propagation occurs in conditions of non-standard atmospheric refractivity, driven by the virtually permanent presence of evaporation ducts (ED) in marine environments. Evaporation ducts are commonly characterized by the evaporation duct height (EDH), evaporation duct strength, and the gradients below the EDH, known as the evaporation duct curvature. Refractivity, and subsequent features, are estimated in the MASL primarily using four methods: in-situ measurements, numerical weather and surface layer modeling, boundary layer theory, and inversion methods.

The existing refractivity estimation techniques often assume …

Reservoir Characterization Of The Utica Shale Play Using Well Log Data In Columbiana, Ohio, Tyler L. West

Electronic Theses and Dissertations

The Ordovician Utica shale play is rapidly developing throughout the Appalachian Basin. The play is a mixed carbonate-siliciclastic system that grades from primarily carbonates at its base in the Lexington/Trenton limestones into primarily shale within the Utica shale. As of January 2021, it is the third highest-producing dry shale gas play in the contiguous U.S., although it is known to produce wet gas and oil in various parts of the basin. In addition to being an unconventional reservoir, the Utica shale, an informal unit in Ohio where the main fairway is located, is a known source rock for much of …

Age And Paleontology Of The Turin Pit Locality, Monona County, Iowa, Samantha Wright

Electronic Theses and Dissertations

The Turin Pit locality (Monona county, Iowa) has been known to paleontologists since 1908, yet the age of the fauna has been unclear. Early paleontologists considered Turin Pit to date to a pre-Illinoian interglacial (the “Aftonian).” Subsequent researchers suggested it dated to the last glaciation. This study provides a partial list of mammals in the Turin Pit fauna, and together with stratigraphic information, uses the known age ranges of taxa to estimate an age for the assemblage. The presence of Mammuthus, Aenocyon, and Castoroides combined with a magnetically-reversed till located stratigraphically above fossil-bearing deposits, suggest the Turin Pit …

Lightweight Blockchains And Their Network Impact On Vehicular Ad-Hoc Network-Based Blockchain Applications, Edgar Bowlin

Electronic Theses and Dissertations

Vehicular Ad-hoc Networks (VANETs) provide networks for smart vehicles and will enable future systems to provide services that enhance the overall transportation experience. However, these applications require consideration to possible damage to both property and human life. Communication between vehicles requires data immutability and user privacies to provide safe operation of the system. Blockchains can provide these properties and more to create a more secure and decentralized system. However, a chain’s security comes from the chain length. VANETs’ ephemeral connections provide harm limits how much data can be exchanged during vehicle rendezvous. This thesis investigates lightweight blockchains that operate with …

Geometric Morphometric Analysis Of Modern Viperid Vertebrae Facilitates Identification Of Fossil Specimens, Lance D. Jessee

Electronic Theses and Dissertations

Snake vertebrae are common in the fossil record, whereas cranial remains are generally fragile and rare. Consequently, vertebrae are the most commonly studied fossil element of snakes. However, identification of snake vertebrae can be problematic due to extensive variation. This study utilizes 2-D geometric morphometrics and canonical variates analysis to 1) reveal variation between genera and species and 2) classify vertebrae of modern and fossil eastern North American Agkistrodon and Crotalus. The results show that vertebrae of Agkistrodon and Crotalus can reliably be classified to genus and species using these methods. Based on the statistical analyses, four of the …

A Low Cost, Compact Electrochemical Analyzer Based On An Open-Source Microcontroller, Michael Kofi Darko Addo

Electronic Theses and Dissertations

Compared to other instruments for chemical analyses, electrochemical analyzers are relatively simple, inexpensive, easy to miniaturize and require little-to-no maintenance. However, like all commercially available instruments, commercial electrochemical analyzers like potentiostats primarily operate as black boxes with manufacturers providing little or no information about internal circuitry and programming. This practice can limit a researcher’s ability to develop new techniques or adapt an instrument for applications outside its typical use. In contrast, creators of open-source instruments release all the necessary information for reproduction of the hardware and software – minimizing such barriers to innovation in chemical analyses. Here, we report a …

Extraction, Purification, And Characterization Of Potential Bioactive Compounds Produced By Janthinobacterium Lividum Tajx1901, Andy Elorm Agbakpo

Electronic Theses and Dissertations

Underexplored environments such as soil samples continue to be an untapped source of bacterial strains with great potential to produce secondary metabolites for medicinal applications. As a result, these microorganisms represent a broad and yet unknown reservoir of new strains capable of producing these novel compounds. The current research primarily seeks to perform the isolation, purification, and characterization of secondary metabolites from a soil bacterium (Janthinobacterium lividum TAJX1901). The isolated soil bacterium was successfully cultured on rich media agar plates, followed by extraction using methanol and chloroform. The purification methods utilized include flash column chromatography, preparative thin-layer chromatography, and …

Isolation And Structural Determination Of Bioactive Metabolites From The Soil Bacterium, Arthrobacter Sp. Tajx1902, Amonah Arije

Electronic Theses and Dissertations

As antimicrobial resistance persistently disrupts the treatment of microbial infection, natural product chemistry has played a significant role in identifying novel drugs with novel modes of action critical to getting ahead of resistance. The primary goal of this project is to extract and identify potential novel antimicrobial natural products produced by Arthrobacter sp. Although underexplored, Arthrobacter sps. have been known to produce bioactive compounds with versatility; one such is a depsipeptide with quorum-sensing inhibitory activity.¹ In this research, an Arthrobacter sp. TAJX1902, isolated from a soil sample, showed inhibitory activity against a filamentous indicator bacterium and a violacein-producing Janthinobacterium …

Statistical Inference On Lung Cancer Screening Using The National Lung Screening Trial Data., Farhin Rahman

Electronic Theses and Dissertations

This dissertation consists of three research projects on cancer screening probability modeling. In these projects, the three key modeling parameters (sensitivity, sojourn time, transition density) for cancer screening were estimated, along with the long-term outcomes (including overdiagnosis as one outcome), the optimal screening time/age, the lead time distribution, and the probability of overdiagnosis at the future screening time were simulated to provide a statistical perspective on the effectiveness of cancer screening programs. In the first part of this dissertation, a statistical inference was conducted for male and female smokers using the National Lung Screening Trial (NLST) chest X-ray data. A …

Penalized Bayesian Exponential Random Graph Models., Vicki Modisette

Electronic Theses and Dissertations

Networks have the critical ability to represent the complex interconnectedness of social relationships, biological processes, and the spread of diseases and information. Exponential random graph models (ERGM) are one of the popular statistical methods for analyzing network data. ERGM, however, struggle with computational challenges and degeneracy issues, further exacerbated by their inability to handle high-dimensional network data. Bayesian techniques provide a promising avenue to overcome these two problems. This paper considers penalized Bayesian exponential random graph models with adaptive lasso and adaptive ridge penalties to perform variable selection and reduce multicollinearity on a variety of networks. The experimental results demonstrate …

Controllable Language Generation Using Deep Learning, Rohola Zandie

Electronic Theses and Dissertations

The advent of deep neural networks has sparked a revolution in Artificial Intelligence (AI), notably with the creation of Transformer models like GPT-X and ChatGPT. These models have surpassed previous methods in various Natural Language Processing (NLP) tasks. As the NLP field evolves, there is a need to further understand and question the capabilities of these models. Text generation, a crucial part of NLP, remains an area where our comprehension is limited while being critical in research.

This dissertation focuses on the challenging problem of controlling the general behaviors of language models such as sentiment, topical focus, and logical reasoning. …

Ocean Wave-Coherent Temperature And Humidity Near-Surface Vertical Distributions And Their Effect On Radar Performance Over The Ocean, Mathew James Stanek

Electronic Theses and Dissertations

Large knowledge gaps concerning the effect of ocean surface waves on near-surface vertical distributions of temperature and humidity in the marine atmospheric surface layer exist due to practical limitations and sensor fidelity challenges of direct measurements. Wave effects on these distributions between the wave trough and crest are least studied within the literature. These scalar distributions influence atmospheric refractivity, which can lead to anomalous propagation of electromagnetic energy. Measurements of temperature and humidity are classically made using rocket- or radiosondes and fixed weather stations, and can utilize tethered profiling systems. However, these measurement systems have limitations when obtaining measurements near …

Intercalation And High-Pressure Investigations Of Black Arsenic Phosphorus: Unraveling Material Transformations., Dinushika Vithanage

Electronic Theses and Dissertations

Black arsenic phosphorus (b-As_yP_1-y) alloys have emerged as intriguing materials within the realm of two-dimensional (2D) materials, following the discovery of black phosphorus (BP). These alloys possess capability to overcome major limitations of BP and exhibit potential for tunability and enhancement of properties making them promising materials for a wide range of applications, including lithium-ion batteries. Inspired by the intriguing findings obtained for BP, this research focuses on understanding the structural modifications that can be achieved in b-As_yP_1-y alloys through the application of intercalation and high pressure. The initial phase of our investigation …

Evaluating Chatgpt For Recommendation: How Does The Ability To Converse Impact Recommendation?, Kyle Spurlock

Electronic Theses and Dissertations

Recommendation algorithms have become an absolute necessity in the modern world to avoid information overload. However, the interaction between the human and the system is largely superficial and without any real contact. If you are given poor recommendations, you have no choice but to sift through mountains of content on your own until the model learns to accommodate your tastes more. This is bad for business as well as the consumer. Recently, large language models like ChatGPT have seen a significant rise in popularity due to their ease of use and wide range of knowledge. It has now become nearly …

Cannabidiol Tweet Miner: A Framework For Identifying Misinformation In Cbd Tweets., Jason Turner

Electronic Theses and Dissertations

As regulations surrounding cannabis continue to develop, the demand for cannabis-based products is on the rise. Despite not producing the psychoactive effects commonly associated with THC, products containing cannabidiol (CBD) have gained immense popularity in recent years as a potential treatment option for a range of conditions, particularly those associated with pain or sleep disorders. However, due to current federal policies, these products have yet to undergo comprehensive safety and efficacy testing. Fortunately, utilizing advanced natural language processing (NLP) techniques, data harvested from social networks have been employed to investigate various social trends within healthcare, such as disease tracking and …

A Machine Learning Approach To Constructing Ramsey Graphs Leads To The Trahtenbrot-Zykov Problem., Emily Hawboldt

Electronic Theses and Dissertations

Attempts at approaching the well-known and difficult problem of constructing Ramsey graphs via machine learning lead to another difficult problem posed by Zykov in 1963 (now commonly referred to as the Trahtenbrot-Zykov problem): For which graphs F does there exist some graph G such that the neighborhood of every vertex in G induces a subgraph isomorphic to F? Chapter 1 provides a brief introduction to graph theory. Chapter 2 introduces Ramsey theory for graphs. Chapter 3 details a reinforcement learning implementation for Ramsey graph construction. The implementation is based on board game software, specifically the AlphaZero program and its …

Stability Of Cauchy's Equation On Δ+., Holden Wells

Electronic Theses and Dissertations

The most famous functional equation f(x+y)=f(x)+f(y) known as Cauchy's equation due to its appearance in the seminal analysis text Cours d'Analyse (Cauchy 1821), was used to understand fundamental aspects of the real numbers and the importance of regularity assumptions in mathematical analysis. Since then, the equation has been abstracted and examined in many contexts. One such examination, introduced by Stanislaw Ulam and furthered by Donald Hyers, was that of stability. Hyers demonstrated that Cauchy's equation exhibited stability over Banach Spaces in the following sense: functions that approximately satisfy Cauchy's equation are approximated with the same level of error by functions …

Development And Applications Of Novel And Practical Fluorination Reagents., Yuhao Yang

Electronic Theses and Dissertations

The fluorine (F) atom has distinctive properties such as the highest electronegativity, small size, low polarizability, and strong C–F bond strength. Not surprisingly, fluorinated organic compounds have garnered significant attention in the pharmaceutical, agrochemical, and material fields. Since organofluorides are very rare in nature, we need fluorination reagents to help us transfer fluorine into the organic molecules. In past decades, a vast number of fluorination reagents have been developed and many of them are commercially available now. However, there is still much room for the improvement of these reagents. Our target is to develop novel and practical fluorination reagents to …

New Methodologies For Sustainable Organic Synthesis In Water., Sudripet Sharma

Electronic Theses and Dissertations

Water is stable, benign, and green solvent. Its usage as a solvent in organic synthesis is significantly enhanced by micellar catalysis. However, replacing water as a reaction medium in organic synthesis is not sufficient to meet the sustainability challenges—excessive organic solvents are still required for product isolation and purification. Notably, solvents used in syntheses contribute to more than 80% of waste generation. In addition to solvents, the use of palladium in large amounts is also a problem for the future as it is a precious, low-abundance metal, and its supply is dwindling. Therefore, this dissertation highlights the various sustainable protocols …