Physical Sciences and Mathematics Commons^™

Assessing Commercial Organic And Conventionally Grown Vegetables By Monitoring Selected Heavy Metals Found In Them., Charles Kafui Dotse

Electronic Theses and Dissertations

Commercially available organic and conventionally grown vegetables were studied by quantitative determination of selected metals in them and to determine if any differences found are statistically significant. These findings can help the consumers to determine if the vegetable products are within the recommended maximum limits as proposed by the joint FAO/WHO Expert committee on organic foods designation. Eight edible vegetables were purchased from local stores in both the organic and conventionally grown categories. Samples were digested with concentrated nitric acid and the metals monitored were zinc, copper, lead, iron, cadmium, and nickel using flame atomic absorption. The concentration range for …

Total Domination Dot Critical And Dot Stable Graphs., Stephanie Anne Marie Mcmahon

Electronic Theses and Dissertations

Two vertices are said to be identifed if they are combined to form one vertex whose neighborhood is the union of their neighborhoods. A graph is total domination dot-critical if identifying any pair of adjacent vertices decreases the total domination number. On the other hand, a graph is total domination dot-stable if identifying any pair of adjacent vertices leaves the total domination number unchanged. Identifying any pair of vertices cannot increase the total domination number. Further we show it can decrease the total domination number by at most two. Among other results, we characterize total domination dot-critical trees with total …

A Re-Evaluation Of The Pleistocene Hellbender, Cryptobranchus Guildayi, And An Overview Of Cryptobranchus Remains From Appalachian Caves., Keila Elaine Bredehoeft

Electronic Theses and Dissertations

Cryptobranchus guildayi is described as an extinct species of large salamander that is closely related to the hellbender, Cryptobranchus alleganiensis. The validity of this extinct taxon has been questioned, so an expanded osteological sample of modern hellbenders was used for comparative purposes with the C. guildayi fossil material. Based on this analysis, all supposed distinguishing morphological characteristics used to define C. guildayi can be observed in specimens of C. alleganiensis, or are based on misidentifications. Therefore, Cryptobranchus guildayi is considered to be conspecific with C. alleganiensis and taxonomically should be considered a junior synonym of the latter. The …

Generating Compact Wasp Nest Structures Via Minimal Complexity Algorithms., Fadel Ewusi Kofi Adoe

Electronic Theses and Dissertations

Many models have been developed to explain the process of self organization-the emergence of seemingly purposeful behaviors from groups of entities with limited individual intelligence. However, the underlying behavior that facilitates the emergence of this global pattern is not generally well understood. Our study focuses on different low complexity building algorithms and characterizes how nests are built using these algorithms. Three rules postulated to be functions of wasps' building behavior were developed. First is the random rule, in which there is no constraint per the choice of site to be initiated. The second is the 2-cell rule where only sites …

A Predictive Model For Secondary Rna Structure Using Graph Theory And A Neural Network., Denise Renee Koessler

Electronic Theses and Dissertations

In this work we use a graph-theoretic representation of secondary RNA structure found in the database RAG: RNA-As-Graphs. We model the bonding of two RNA secondary structures to form a larger structure with a graph operation called merge. The resulting data from each tree merge operation is summarized and represented by a vector. We use these vectors as input values for a neural network and train the network to recognize a tree as RNA-like or not based on the merge data vector.

The network correctly assigned a high probability of RNA-likeness to trees identified as RNA-like in the RAG database, …

Late Spring And Summer Phytoplankton Community Dynamics On Georges Bank With Emphasis On Diatoms, Alexandrium Spp., And Other Dinoflagellates, Rachel Gettings

Electronic Theses and Dissertations

Georges Bank is a highly productive continental shelf system in the Northwest Atlantic that has historically supported a rich fishery. Part of that productivity stems from annual spring diatom bloom, which is followed by post-bloom populations of flagellates, including the toxic dinoflagellate Alexandrium spp., responsible for paralytic shellfish poisoning. While the general oceanography of Georges Bank has been well studied, far less is known about phytoplankton community dynamics or even basic species distributions and abundance. This thesis is driven in part by the possible competitive interactions among species of phytoplankton which are thought to influence Alexandrium blooms on the Bank. …

Analysis Of Discrete Data Under Order Restrictions, Jeff Campbell

Electronic Theses and Dissertations

Strategies for the analysis of discrete data under order restrictions are discussed. We consider inference for sequences of binomial populations, and the corresponding risk difference, relative risk and odds ratios. These concepts are extended to deal with independent multinomial populations. Natural orderings such as stochastic ordering and cumulative ratio probability ordering are discussed. Methods are developed for the estimation and testing of differences between binomial as well as multinomial populations under order restrictions. In particular, inference for sequences of ordered binomial probabilities and cumulative probability ratios in multinomial populations are presented. Closed-form estimates of the multinomial parameters under order restrictions …

Design, Synthesis And Characterization Of New Two-Photon Absorbing (2pa) Fluorescent Dyes And Bioconjugates, And Their Applications In Bioimaging, Carolina D. Andrade

Electronic Theses and Dissertations

The development of new multiphoton absorbing materials has attracted the attention of researchers for the last two decades. The advantages that multiphoton absorbing materials offer, versus their one-photon absorbing counterparts, rely on the nature of the nonlinearity of the absorption process, where two photons are absorbed simultaneously offering increased 3D resolution, deeper penetration, and less photobleaching and photodamage as a result of a more confined excitation. The applications of efficient two-photon absorbing materials have been extensively expanding into the fields of photodynamic therapy, microscopy, and optical data storage. One of the fields where an increased interest in multiphoton absorbing materials …

Black Writing Ink Analysis By Direct Infusion Electrospray Mass Spectroscopy, Christopher M. Moody

Electronic Theses and Dissertations

An optimized method of extraction, an instrumental analysis method and data analysis was proposed for black writing inks based on direct infusion electrospray-mass spectrometry (ESI-MS). The sampling and analysis method is both minimally destructive and able to assess differences in inks from a reference collection of thirty ballpoint, gel, and rollerball inks. The methanol extracts of ink on paper samples were analyzed with three direct infusion (ESI-MS) methods. Each method varied scan voltage negative and positive, ESI fragmentor applied voltage (+120V, +0V, and -120V), and mobile phase additive. Direct infusion ESI-MS analysis, followed by pair-wise comparisons of the observed ion …

Experimental And Theoretical Study Of The Optical Properties Of Semiconductor Quantum Dots, Gero Nootz

Electronic Theses and Dissertations

The aim of this dissertation is to gain a better understanding of the unique electronic structure of lead salt quantum dots (QDs) and its influences on the nonlinear optical (NLO) properties as well as the time dynamics of the photogenerated charge carriers. A variety of optical techniques such as Z-scan, two-photon excited fluorescence and time-resolved pump probe spectroscopy are used to measure these properties. The one-photon as well as the degenerate and nondegenerate two-photon absorption (2PA) spectra are measured and the electronic wave functions from a four-band envelope function formalism are used to model the results. We observe local maxima …

Detection And Approximation Of Function Of Two Variables In High Dimensions, Minzhe Pan

Electronic Theses and Dissertations

This thesis originates from the deterministic algorithm of DeVore, Petrova, and Wojtaszcsyk for the detection and approximation of functions of one variable in high dimensions. We propose a deterministic algorithm for the detection and approximation of function of two variables in high dimensions.

The Fabrication Of Polymer-Derived Sicn/Sibcn Ceramic Nanostructures And Investigation Of Their Structure-Property Relationship, Sourangsu Sarkar

Electronic Theses and Dissertations

Polymer-derived Ceramics (PDCs) represent a unique class of high-temperature stable materials synthesized directly by the thermal decomposition of polymers. This research first focuses on the fabrication of high temperature stable siliconcarbonitride (SiCN) fibers by electrospinning for ceramic matrix composite (CMC) applications. Ceraset™ VL20, a commercially available liquid cyclosilazane, was functionalized with aluminum sec-butoxide in order to be electrospinnable. The surface morphology of the electrospun fibers was investigated using the fibers produced from solvents. The electrospun fibers produced from the chloroform/N,N-dimethylformamide solutions had hierarchical structures that led to superhydrophobic surfaces. A “dry skin” model was proposed to explain the formation of …

Fabrication Of Functional Nanostructures Using Polyelectrolyte Nanocomposites And Reduced Graphene Oxide Assemblies, Anindarupa Chunder

Electronic Theses and Dissertations

A wide variety of nanomaterials ranging from polymer assemblies to organic and inorganic nanostructures (particles, wires, rods etc) have been actively pursued in recent years for various applications. The synthesis route of these nanomaterials had been driven through two fundamental approaches - 'Top down' and 'Bottom up'. The key aspect of their application remained in the ability to make the nanomaterials suitable for targeted location by manipulating their structure and functionalizing with active target groups. Functional nanomaterials like polyelectrolyte based multilayered thin films, nanofibres and graphene based composite materials are highlighted in the current research. Multilayer thin films were fabricated …

Surface Plasmon Hosts For Infrared Waveguides And Biosensors, And Plasmons In Gold-Black Nano-Structured Films, Justin Cleary

Electronic Theses and Dissertations

Applications of surface plasmon polaritons (SPPs) have thus far emphasized visible and near-infrared wavelengths. Extension into the long-wave infrared (LWIR) has numerous potential advantages for biosensors and waveguides, which are explored in this work. A surface plasmon resonance (SPR) biosensor that operates deep into the infrared (3-11 µm wavelengths) is potentially capable of biomolecule recognition based on both selective binding and characteristic vibrational modes. The goal is to operate such sensors at wavelengths where biological analytes are strongly differentiated by their IR absorption spectra and where the refractive index is increased by dispersion, which will provide enhanced selectivity and sensitivity. …

Accelerating Optical Airy Beams, Georgios Siviloglou

Electronic Theses and Dissertations

Over the years, non-spreading or non-diffracting wave configurations have been systematically investigated in optics. Perhaps the best known example of a diffraction-free optical wave is the so-called Bessel beam, first suggested and observed by Durnin et al. This work sparked considerable theoretical and experimental activity and paved the way toward the discovery of other interesting non-diffracting solutions. In 1979 Berry and Balazs made an important observation within the context of quantum mechanics: they theoretically demonstrated that the Schrodinger equation describing a free particle can exhibit a non-spreading Airy wavepacket solution. This work remained largely unnoticed in the literature-partly because such …

Misalignment Induced Nodal Aberration Fields And Their Use In The Alignment Of Astronomical Telescopes, Tobias Schmid

Electronic Theses and Dissertations

Following the foundation of aberration theory for rotationally symmetric optical systems established by Seidel, Schwarzschild, Burch, Conrady, Buchdahl, and in its most useful form H.H. Hopkins, Shack, Buchroeder, Thompson, and Rogers developed a vectorial form of the wave aberration theory that enables addressing optical systems without symmetry. In this research, a vectorial theory is utilized and extended for the alignment of two- and three-mirror astronomical telescopes, including the effects of pointing changes and astigmatic figure errors. Importantly, it is demonstrated that the vectorial form of aberration theory, also referred to as nodal aberration theory, not only provides valuable insights but …

A Robust Wireless Mesh Access Environment For Mobile Video Users, Fei Xie

Electronic Theses and Dissertations

The rapid advances in networking technology have enabled large-scale deployments of online video streaming services in today's Internet. In particular, wireless Internet access technology has been one of the most transforming and empowering technologies in recent years. We have witnessed a dramatic increase in the number of mobile users who access online video services through wireless access networks, such as wireless mesh networks and 3G cellular networks. Unlike in wired environment, using a dedicated stream for each video service request is very expensive for wireless networks. This simple strategy also has limited scalability when popular content is demanded by a …

Spatio-Temporal Maximum Average Correlation Height Templates In Action Recognition And Video Summarization, Mikel Rodriguez

Electronic Theses and Dissertations

Action recognition represents one of the most difficult problems in computer vision given that it embodies the combination of several uncertain attributes, such as the subtle variability associated with individual human behavior and the challenges that come with viewpoint variations, scale changes and different temporal extents. Nevertheless, action recognition solutions are critical in a great number of domains, such video surveillance, assisted living environments, video search, interfaces, and virtual reality. In this dissertation, we investigate template-based action recognition algorithms that can incorporate the information contained in a set of training examples, and we explore how these algorithms perform in action …

Numerical Computations For Pde Models Of Rocket Exhaust Flow In Soil, Brian Brennan

Electronic Theses and Dissertations

We study numerical methods for solving the nonlinear porous medium and Navier-Lame problems. When coupled together, these equations model the flow of exhaust through a porous medium, soil, and the effects that the pressure has on the soil in terms of spatial displacement. For the porous medium equation we use the Crank-Nicolson time stepping method with a spectral discretization in space. Since the Navier-Lame equation is a boundary value problem, it is solved using a finite element method where the spatial domain is represented by a triangulation of discrete points. The two problems are coupled by using approximations of solutions …

Plasmon Enhanced Near-Field Interactions In Surface Coupled Nanoparticle Arrays For Integrated Nanophotonic Devices, Amitabh Ghoshal

Electronic Theses and Dissertations

The current thrust towards developing silicon compatible integrated nanophotonic devices is driven by need to overcome critical challenges in electronic circuit technology related to information bandwidth and thermal management. Surface plasmon nanophotonics represents a hybrid technology at the interface of optics and electronics that could address several of the existing challenges. Surface plasmons are electronic charge density waves that can occur at a metal-dielectric interface at optical and infrared frequencies. Numerous plasmon based integrated optical devices such as waveguides, splitters, resonators and multimode interference devices have been developed, however no standard integrated device for coupling light into nanoscale optical circuits …

An Assessment Of Sea Turtle Nesting Behavior In Relation To Hurricane- And Restoration-Induced Beach Morphodynamics, Tonya Michele Long

Electronic Theses and Dissertations

Coastal habitats are highly dynamic and vulnerable to landscape-level disturbances such as storms and restoration projects. Along the east coast of Florida these areas are particularly valuable as they provide significant nesting habitat for two sea turtle species, the threatened loggerhead (Caretta caretta) and the endangered green turtle (Chelonia mydas). This coast was heavily impacted by three major hurricanes in 2004 and in some areas by large restoration projects in 2005. Recent remote sensing methods allow for broad evaluation of the shoreline and thus the ability to assess sea turtle nesting habitat at a landscape scale. I collected nesting data …

Laboratory Studies To Field Evaluation : Remediation Of Polychlorinated Biphenyl Contaminated Painted Surfaces Through The Use Of Activated Metal Treatment Systems, Erin Kristen Saitta

Electronic Theses and Dissertations

Polychlorinated Biphenyls (PCBs) are a group of 209 congeners that are regulated under the Toxic Substance Control Act. They enter the environment as a result of industrial processes and can travel long distances. PCBs are environmentally persistent and bioaccumulate in animal populations. Painted surfaces are a common point source for PCBs and there are few options for remediating structures painted with PCB-contaminated paint. Removal of the paint can often spread contamination and disposing or burning of large structures is expensive. Experiments employing reductive dehalogenation through the use of a bimetal have shown that PCBs can be degraded in mild laboratory …

Electro-Optical And All-Optical Switching In Multimode Interference Waveguides Incorporating Semiconductor Nanostructures, Nathan Bickel

Electronic Theses and Dissertations

The application of epitaxially grown, III-V semiconductor-based nanostructures to the development of electro-optical and all-optical switches is investigated through the fabrication and testing of integrated photonic devices designed using multimode interference (MMI) waveguides. The properties and limitations of the materials are explored with respect to the operation of those devices through electrical carrier injection and optical pumping. MMI waveguide geometry was employed as it offered advantages such as a very compact device footprint, low polarization sensitivity, large bandwidth and relaxed fabrication tolerances when compared with conventional single-mode waveguide formats. The first portion of this dissertation focuses on the characterization of …

A Fpga-Based Architecture For Led Backlight Driving, Zhaoshi Zheng

Electronic Theses and Dissertations

In recent years, Light-emitting Diodes (LEDs) have become a promising candidate for backlighting Liquid Crystal Displays [1] (LCDs). Compared with traditional Cold Cathode Fluorescent Lamps (CCFLs) technology, LEDs offer not only better visual quality, but also improved power efficiency. However, to fully utilized LEDs' capability requires dynamic independent control of individual LEDs, which remains as a challenging topic. A FPGA-based hardware system for LED backlight control is proposed in this work. We successfully achieve dynamic adjustment of any individual LED's intensity in each of the three color channels (Red, Green and Blue), in response to a real time incoming video …

Fast-Response Liquid Crystal Displays, Meizi Jiao

Electronic Theses and Dissertations

After about five decades of extensive material research and device development, followed by massive investment in manufacturing technology, thin-film-transistor liquid-crystaldisplay (TFT-LCD) has finally become the dominant flat panel display technology. Nowadays, LCD performances, such as viewing angle, contrast ratio, and resolution, have reached acceptable levels. The remaining major technical challenges are response time, light efficiency, and sunlight readability. Fast response time is desired to reduce motion blur and to enable field sequential color displays using red (R), green (G), and blue (B) LEDs (light emitting diodes) without noticeable color breakup. Sequential RGB colors would eliminate the commonly used spatial color …

Survey Of Meteorite Physical Properties Density, Porosity And Magnetic Susceptibility, Robert J. Macke

Electronic Theses and Dissertations

The measurement of meteorite physical properties (i.e. density, porosity, magnetic susceptibility) supplements detailed chemical and isotopic analyses for small samples (thin sections or ~300 mg portions) by providing whole-rock data for samples massing in the tens of grams. With the advent of fast, non-destructive and non-contaminating measurement techniques including helium ideal-gas pycnometry for grain density, the Archimedean ―glass bead‖ method for bulk density and (with grain density) porosity, and the use of low-field magnetometry for magnetic susceptibility, all of which rely on compact and portable equipment, this has enabled a comprehensive survey of these physical properties for a wide variety …

A Wearable Head-Mounted Projection Display, Ricardo F. Martins

Electronic Theses and Dissertations

Conventional head-mounted projection displays (HMPDs) contain of a pair of miniature projection lenses, beamsplitters, and miniature displays mounted on the helmet, as well as a retro-reflective screen placed strategically in the environment. We have extened the HMPD technology integrating the screen into a fully mobile embodiment. Some initial efforts of demonstrating this technology has been captured followed by an investigation of the diffraction effects versus image degradation caused by integrating the retro-reflective screen within the HMPD. The key contribution of this research is the conception and development of a mobileHMPD (M-HMPD). We have included an extensive analysis of macro- and …

Freeform Reflector Design With Extended Sources, Florian Fournier

Electronic Theses and Dissertations

Reflector design stemmed from the need to shape the light emitted by candles or lamps. Over 2,000 years ago people realized that a mirror shaped as a parabola can concentrate light, and thus significantly boosts its intensity, to the point where objects can be set afire. Nowadays many applications require an accurate control of light, such as automotive headlights, streetlights, projection displays, and medical illuminators. In all cases light emitted from a light source can be shaped into a desired target distribution with a reflective surface. Design methods for systems with rotational and translational symmetry were devised in the 1930s. …

Real-Time Cinematic Design Of Visual Aspects In Computer-Generated Images, Juraj Obert

Electronic Theses and Dissertations

Creation of visually-pleasing images has always been one of the main goals of computer graphics. Two important components are necessary to achieve this goal --- artists who design visual aspects of an image (such as materials or lighting) and sophisticated algorithms that render the image. Traditionally, rendering has been of greater interest to researchers, while the design part has always been deemed as secondary. This has led to many inefficiencies, as artists, in order to create a stunning image, are often forced to resort to the traditional, creativity-baring, pipelines consisting of repeated rendering and parameter tweaking. Our work shifts the …

Development Of Reductive Metal Systems For The Degradation Of Energetic Compounds (Tatp, Tnt, And Rdx), Rebecca L. Albo

Electronic Theses and Dissertations

Triacetone triperoxide (TATP), a cyclic peroxide explosive, is frequently used by terrorists and amateur chemists due to the ease of synthesis and the availability of reagents. TATP is extremely sensitive to shock, heat, and friction thus a safe and rapid method for treating TATP is needed. The major objective of this dissertation was to develop in situ methodologies that could safely degrade TATP in various field situations. Initial studies focused on using zero-valent metals and mechanically alloyed metals to decompose TATP samples in both aqueous and organic solutions. The metal systems tested included zero-valent iron, magnesium, and magnesium bimetal, Mg/Pd. …