Physical Sciences and Mathematics Commons^™

From Balancing Redox Reactions To Determining Change Of Oxidation Numbers, Pong Kau Yuen, Cheng Man Diana Lau

Faculty Publications

Redox reaction is a core concept in teaching and learning chemistry. This article explores a new method for balancing organic redox reactions that requires the balancing of both atoms and charges. The H+, O, H2O, and e– are used as balanced vehicles in two half reactions. A non-oxidation number approach can be applied to both molecular and ionic equations. The article also provides standard operating procedures and examples. The number of transferred electrons is first determined by balancing a half redox reaction; consequently; the change of oxidation numbers can be calculated. The mathematical equation of Te– = n Te– = …

Effect Of Trigonometric Transformations On The Machine Learning Prediction And Quality Control Of Air Temperature, Andrea Fenoglio [*], Torrey J. Wagner, Paul Auclair, Brent T. Langhals

Faculty Publications

Conducting effective quality control of weather observations in real time is vital to the 14th Weather Squadron’s mission of providing authoritative climate data. This study explored automated quality control of weather observations by applying multiple machine learning techniques to 43,487 surface weather observations from 5 years of data at a single location. Temperature predictors were evaluated using recursive feature elimination on linear regression and XGBoost algorithms, as well as using a neural network hyperparameter sweep. Modeling was repeated after calculating trigonometric transforms of temporal variables to give the models insight into the diurnal heating cycle of the Earth. All models …

Toward Liquid Cell Quantum Sensing: Ytterbium Complexes With Ultra-Narrow Absorption, Ashley J. Shin, Changling Zhao, Yi Shen, Claire E. Dickerson, Timothy Luke Atallah

Faculty Publications

No abstract provided.

Effect Of Connection State & Transport/Application Protocol On The Machine Learning Outlier Detection Of Network Intrusions, George Yuchi [*], Torrey J. Wagner, Paul Auclair, Brent T. Langhals

Faculty Publications

The majority of cyber infiltration & exfiltration intrusions leave a network footprint, and due to the multi-faceted nature of detecting network intrusions, it is often difficult to detect. In this work a Zeek-processed PCAP dataset containing the metadata of 36,667 network packets was modeled with several machine learning algorithms to classify normal vs. anomalous network activity. Principal component analysis with a 10% contamination factor was used to identify anomalous behavior. Models were created using recursive feature elimination on logistic regression and XGBClassifier algorithms, and also using Bayesian and bandit optimization of neural network hyperparameters. These models were trained on a …

Machine Learning Land Cover And Land Use Classification Of 4-Band Satellite Imagery, Lorelei Turner [*], Torrey J. Wagner, Paul Auclair, Brent T. Langhals

Faculty Publications

Land-cover and land-use classification generates categories of terrestrial features, such as water or trees, which can be used to track how land is used. This work applies classical, ensemble and neural network machine learning algorithms to a multispectral remote sensing dataset containing 405,000 28x28 pixel image patches in 4 electromagnetic frequency bands. For each algorithm, model metrics and prediction execution time were evaluated, resulting in two families of models; fast and precise. The prediction time for an 81,000-patch group of predictions wasmodels, and >5s for the precise models, and there was not a significant change in prediction time when a …

Studying The Conditions For Magnetic Reconnection In Solar Flares With And Without Precursor Flares, Seth H. Garland, Daniel J. Emmons, Robert D. Loper

Faculty Publications

Forecasting of solar flares remains a challenge due to the limited understanding of the triggering mechanisms associated with magnetic reconnection, the primary physical phenomenon connected to these events. Studies have indicated that changes to the photospheric magnetic fields associated with magnetic reconnection – particularly in relation to the field helicity – occur during solar flare events. This study utilized data from the Solar Dynamics Observatory (SDO) Helioseismic and Magnetic Imager (HMI) and SpaceWeather HMI Active Region Patches (SHARPs) to analyze full vector-field component data of the photospheric magnetic field during solar flare events within a near decade long HMI dataset. …

Mid-Breton Sediment Diversion (Mbrsd) Assessment – Final Report, Jerry D. Wiggert, Brandy N. Armstrong, M. Kemal Cambazoglu, Sandeep Kalathupurath Kuttan

Faculty Publications

The purpose of this project is to provide managers at the Mississippi Department of Marine Resources (MDMR) with the scientific information needed to accurately address public concerns regarding the potential effects of the Louisiana Coastal Master Plan / Coastal Protection and Restoration Authority (CPRA) Mid-Breton Sediment Diversion (MBrSD) on the jurisdictional waters and resources of Mississippi. The stated design purpose of the MBrSD is to reconnect and re-establish the deltaic sediment deposition process between the Mississippi River and the Breton Sound Basin through a diversion that will deliver up to 75,000 cfs of sediment-laden freshwater. The report presented herein provides …

The Other Legacy Of Qasim Amin: The View From 1908, Hoda Yousef

Faculty Publications

No abstract provided.

Exploring The Relationships Among Stoichiometric Coefficients, Number Of Transferred Electrons, Mean Oxidation Number Of Carbons, And Oxidative Ratio In Organic Combustion Reactions, Pong Kau Yuen, Cheng Man Diana Lau

Faculty Publications

Combustion reactions, stoichiometry, and redox reactions are some of the basic contents in chemistry curriculum. Although the counting of transferred electrons is critical in redox reactions, assigning mean oxidation number of organic carbons (ONc) is not always easy. Even though the relationship between the oxidative ratio (OR) and ONc is known, the relationship between the number of transferred electrons (Te−) and OR has not been thoroughly studied. The H-atom method has already been developed to balance and deduct organic combustion reactions. It can be used further to help establish the relationships among the stoichiometric coefficients (SC), the number of transferred …

Intercomparison Of Salinity Products In The Beaufort Gyre And Arctic Ocean, Sarah B. Hall, Bulusu Subrahmanyam, James H. Morison

Faculty Publications

Salinity is the primary determinant of the Arctic Ocean’s density structure. Freshwater accumulation and distribution in the Arctic Ocean have varied significantly in recent decades and certainly in the Beaufort Gyre (BG). In this study, we analyze salinity variations in the BG region between 2012 and 2017. We use in situ salinity observations from the Seasonal Ice Zone Reconnaissance Surveys (SIZRS), CTD casts from the Beaufort Gyre Exploration Project (BGP), and the EN4 data to validate and compare with satellite observations from Soil Moisture Active Passive (SMAP), Soil Moisture and Ocean Salinity (SMOS), and Aquarius Optimally Interpolated Sea Surface Salinity …

Splashing Of Large Helium Nanodroplets Upon Surface Collisions, Paul Martini, Simon Albertini, Felix Laimer, Miriam Meyer, Michael Gatchell, Olof E. Echt, Fabio Zappa, Paul Scheier

Faculty Publications

In the present work we observe that helium nanodroplets colliding with surfaces can exhibit splashing in a way that is analogous to classical liquids. We use transmission electron microscopy and mass spectrometry to demonstrate that neutral and ionic dopants embedded in the droplets are efficiently backscattered in such events. High abundances of weakly bound He-tagged ions of both polarities indicate a gentle extraction mechanism of these ions from the droplets upon collision with a solid surface. This backscattering process is observed for dopant particles with masses up to 400 kilodaltons, indicating an unexpected mechanism that effectively lowers deposition rates of …

Salt Marshes As Groundwater Buffers For Development: A Survey Of South Carolina Salt Marsh Basins, Alicia M. Wilson, Meghan Shanahan, Erik M. Smith

Faculty Publications

Salt marshes serve as zones of intense groundwater mixing and reaction between freshwater uplands and estuaries. This raises the question of whether the impacts of upland development on nutrient and carbon species can be transmitted through salt marshes via groundwater, or whether salt marshes can buffer estuarine waters from coastal development. We sampled groundwater from fifteen tidal creek basins in South Carolina to test for compositional differences associated with development and marsh width. Groundwater samples from near creekbanks and below freshwater uplands were analyzed for salinity, total dissolved nitrogen and phosphorus, and dissolved organic carbon. Analyses revealed significantly higher TDN …

Extending The Quality Of Secure Service Model To Multi-Hop Networks, Paul M. Simon, Scott R. Graham

Faculty Publications

Rarely are communications networks point-to-point. In most cases, transceiver relay stations exist between transmitter and receiver end-points. These relay stations, while essential for controlling cost and adding flexibility to network architectures, reduce the overall security of the respective network. In an effort to quantify that reduction, we extend the Quality of Secure Service (QoSS) model to these complex networks, specifically multi-hop networks. In this approach, the quantification of security is based upon probabilities that adversarial listeners and disruptors gain access to or manipulate transmitted data on one or more of these multi-hop channels. Message fragmentation and duplication across available channels …

Study Of The Reactions E+E-→Π+Π-ΠΠΠΠΠΠΠΠ And Π+Π-ΠΠΠΠΠΠΗ At Center-Of-Mass Energies From Threshold To 4.5 Gev Using Initial-State Radiation, J. P. Lees, V. Poireau, V Tisserand, E. Grauges, A. Palano, G. Eigen, D. N. Brown, Yu G. Kolomensky, M. Fritsch, H. Koch, T. Schroeder, R. Cheaib, C. Hearty, T. S. Mattison, J. A. Mckenna, R. Y. So, V. E. Blinov, A. R. Buzykaev, V. P. Druzhinin, Milind Purohit, Et. Al.

Faculty Publications

We study the processes e⁺e⁻→ π⁺π⁻π⁰π⁰π⁰π⁰γ and π⁺π⁻π⁰π⁰π⁰ηγ in which an energetic photon is radiated from the initial state. The data were collected with the BABAR detector at the SLAC National Accelerator Laboratory. About 7300 and 870 events, respectively, are selected from a data sample corresponding to an integrated luminosity of 469 fb⁻¹. The invariant mass of the hadronic final state defines the effective e⁺e⁻ center-of-mass energy. The center-of-mass …

Study Of The Process E+ E− → Π + Π − Π0 Using Initial State Radiation With Babar, J. P. Lees, V. Poireau, V. Tisserand, E. Grauges, A. Palano, G. Eigen, D. N. Brown, Yu. G. Kolomensky, M. Fritsch, H. Koch, T. Schroeder, R. Cheaib, C. Hearty, T. S. Mattison, J. A. Mckenna, R. Y. So, V. E. Blinov, A. R. Buzykaev, V. P. Druzhinin, Milind Purohit, Et. Al.

Faculty Publications

The process e⁺e⁻→ π⁺π⁻π⁰γ is studied at a center-of-mass energy near the ϒ(4S) resonance using a data sample of 469 fb⁻¹ collected with the BABAR detector at the PEP-II collider. We have performed a precise measurement of the e⁺e⁻→ π⁺π⁻π⁰ cross section in the center-of-mass energy range from 0.62 to 3.5 GeV. In the energy regions of theω and ϕ resonances, the cross section is measured with a systematic uncertainty of 1.3%. The leading-order hadronic contribution to the …

The Kelvin-Helmholtz Instability From The Perspective Of Hybrid Simulations, Peter A. Delamere, Nathan P. Barnes, Xuanye Ma, Jay R. Johnson

Faculty Publications

The flow shear-driven Kelvin-Helmholtz (KH) instability is ubiquitous in planetary magnetospheres. At Earth these surface waves are important along the dawn and dusk flanks of the magnetopause boundary while at Jupiter and Saturn the entire dayside magnetopause boundary can exhibit KH activity due to corotational flows in the magnetosphere. Kelvin-Helmholtz waves can be a major ingredient in the so-called viscous-like interaction with the solar wind. In this paper, we review the KH instability from the perspective of hybrid (kinetic ions, fluid electrons) simulations. Many of the simulations are based on parameters typically found at Saturn’s magnetopause boundary, but the results …

Basis For Changes In The Disease Burden Estimates Related To Vitamin A And Zinc Deficiencies In The 2017 And 2019 Global Burden Of Disease Studies, Sonja Y. Hess, Alexander C. Mclain Ph.D., Haley Lescinsky, Kenneth H. Brown, Ashkan Afshin

Faculty Publications

Background:

The Global Burden of Disease (GBD) Study provides estimates of death and disability from eighty-seven risk factors, including some micronutrient deficiencies.

Objectives:

To review methodological changes that led to large differences in the disease burden estimates for vitamin A and Zn deficiencies between the GBD 2017 and 2019 Studies.

Methods:

GBD publications were reviewed; additional information was provided by GBD researchers.

Results:

Vitamin A deficiency prevalence is based on plasma retinol concentration, whereas the estimate for Zn deficiency prevalence uses dietary adequacy as a proxy. The estimated global prevalence of vitamin A deficiency for children aged 1–4 years in …

Nutrient Intake And Dietary Inflammatory Potential In Current And Recovered Anorexia Nervosa, Olivia Patsalos, Bethan Dalton, Christia Kyprianou, Joseph Firth, Nitin Shivappa Mbbs, Mph, Ph.D., James Hébert Scd, Ulrike Schmidt, Hubertus Himmerich

Faculty Publications

Anorexia nervosa (AN) is characterised by disrupted and restrictive eating patterns. Recent investigations and meta-analyses have found altered concentrations of inflammatory markers in people with current AN. We aimed to assess nutrient intake in participants with current or recovered AN, as compared to healthy individuals, and explore group differences in dietary inflammatory potential as a possible explanation for the observed alterations in inflammatory markers. We recruited participants with current AN (n = 51), those recovered from AN (n = 23), and healthy controls (n = 49). We used the Food Frequency Questionnaire (FFQ), to calculate a Dietary …

Fungal Community And Functional Responses To Soil Warming Are Greater Than For Soil Nitrogen Enrichment, Mark A. Anthony, Melissa A. Knorr, Jessica A. M. Moore, M. Simpson, Serita D. Frey

Faculty Publications

Soil fungi are key regulators of forest carbon cycling and their responses to global change have effects that ripple throughout ecosystems. Global changes are expected to push many fungi beyond their environmental niches, but there are relatively few studies involving multiple, simultaneous global change factors. Here, we studied soil fungal diversity, community composition, co-occurrence patterns, and decomposition gene responses to 10 years of soil warming and nitrogen addition, alone and in combination. We specifically examined whether there were fungal community characteristics that could explain changes in soil carbon storage and organic matter chemistry in chronically warmed and fertilized soil. We …

Search For Lensing Signatures In The Gravitational-Wave Observations From The First Half Of Ligo–Virgo's Third Observing Run, Ligo Scientific Collaboration, Virgo Collaboration, Tiffany Z. Summerscales

Faculty Publications

We search for signatures of gravitational lensing in the gravitational-wave signals from compact binary coalescences detected by Advanced Laser Interferometer Gravitational-wave Observatory (LIGO) and Advanced Virgo during O3a, the first half of their third observing run. We study: (1) the expected rate of lensing at current detector sensitivity and the implications of a non-observation of strong lensing or a stochastic gravitational-wave background on the merger-rate density at high redshift; (2) how the interpretation of individual high-mass events would change if they were found to be lensed; (3) the possibility of multiple images due to strong lensing by galaxies or galaxy …

Single-Variable Porous Nanomaterial Series From Polymer Structure-Directing Agents, Morgan Stefik

Faculty Publications

Block polymer structure-directing agents (SDA) enable the production of porous nanoscale materials. Most strategies rely upon polymer equilibration where diverse morphologies are realized in porous functional materials. This review details how solvent selectivity determines the polymer SDA behaviors, spanning from bulk-type to solution-type. Equilibrating behavior of either type, however, obscures nanostructure cause-and-effect since the resulting sample series convolve multiple spatial variations. Solution-type SDA behaviors include both dynamic and persistent micelles. Persistent micelle templates (PMT) use high solvent selectivity for kinetic entrapment. PMTs enable independent wall thickness control with demonstrated 2 Å precision alterations. Unimodal PMT pore size distributions have spanned …

Search For Lensing Signatures In The Gravitational-Wave Observations From The First Half Of Ligo-Virgo's Third Observing Run, R. Abbott, T. D. Abbott

Faculty Publications

We search for signatures of gravitational lensing in the gravitational-wave signals from compact binary coalescences detected by Advanced Laser Interferometer Gravitational-wave Observatory (LIGO) and Advanced Virgo during O3a, the first half of their third observing run. We study: (1) the expected rate of lensing at current detector sensitivity and the implications of a non-observation of strong lensing or a stochastic gravitational-wave background on the merger-rate density at high redshift; (2) how the interpretation of individual high-mass events would change if they were found to be lensed; (3) the possibility of multiple images due to strong lensing by galaxies or galaxy …

A Gravitational-Wave Measurement Of The Hubble Constant Following The Second Observing Run Of Advanced Ligo And Virgo (Vol 908, 218, 2021), B. P. Abbott, R. Abbott, T. D. Abbott

Faculty Publications

No abstract provided.

Multi-Scale Feedback And Feeding In The Closest Radio Galaxy Centaurus A, B. Mckinley, S. J. Tingay, M. Gaspari, R. P. Kraft, C. Matherne, A. R. Offringa, M. Mcdonald, M. S. Calzadilla, S Veilleux, S. S. Shabala, S. D. J. Gwyn, J. Bland-Hawthorn, D. Crnojevic, B. M. Gaensler, M. Johnston-Hollitt

Faculty Publications

Supermassive black holes and supernova explosions at the centres of active galaxies power cycles of outflowing and inflowing gas that affect galactic evolution and the overall structure of the Universe(1,2). While simulations and observations show that this must be the case, the range of physical scales (over ten orders of magnitude) and paucity of available tracers make both the simulation and observation of these effects difficult(3,4). By serendipity, there lies an active galaxy, Centaurus A (NGC 5128)(5,6), at such a close proximity as to allow its observation over this entire range of scales and across the entire electromagnetic spectrum. In …

Diving Beneath The Sea Of Stellar Activity: Chromatic Radial Velocities Of The Young Au Mic Planetary System, Bryson Cale, Michael Reefe, Peter Plavchan, Angelle Tanner, Eric Gaidos, Jonathan Gagne, Peter Gao, Stephen R. Kane, Victor J. S. Bejar, Nicolas Lodieu, Guillem Anglada-Escude, Ignasi Ribas, Enric Palle, Andreas Quirrenbach, Pedro Amado, Ansgar Reiners, Jose A. Caballero, Maria Rosa Zapatero Osorio, Stefan Dreizler, Andrew W. Howard, Benjamin J. Fulton, Sharon Xuesong Wang, Kevin I. Collins, Mohammed El Mufti, Justin Wittrock, Emily A. Gilbert, Thomas Barclay, Baptiste Klein, Eder Martioli, Robert Wittenmyer, Duncan Wright, Brett Addison, Teruyuki Hirano, Motohide Tamura, Takayuki Kotani, Norio Narita, David Vermilion, Rena A. Lee, Claire Geneser, Johanna Teske, Samuel N. Quinn, David W. Latham, Gilbert A. Esquerdo, Michael L. Calkins, Perry Berlind, Farzaneh Zohrabi, Caitlin Stibbards, Srihan Kotnana, Jon Jenkins, Joseph D. Twicken, Christopher Henze, Richard Kidwell, Jr., Christopher Burke, Joel Villasenor, Patricia Boyd

Faculty Publications

We present updated radial-velocity (RV) analyses of the AU Mic system. AU Mic is a young (22 Myr) early-M dwarf known to host two transiting planets-P-b similar to 8.46 days, R-b = 4.381(-0.18)(+0.18) R-circle plus, P-c similar to 18.86 days, R-c = 3.5(-0.16)(+0.16) R-circle plus. With visible RVs from Calar Alto high-Resolution search for M dwarfs with Exo-earths with Near-infrared and optical echelle Spectrographs (CARMENES)-VIS, CHIRON, HARPS, HIRES, MINERVA-Australis, and Tillinghast Reflector Echelle Spectrograph, as well as near-infrared (NIR) RVs from CARMENES-NIR, CSHELL, IRD, iSHELL, NIRSPEC, and SPIRou, we provide a 5 sigma upper limit to the mass of AU …

Spectroscopic Studies Of The Interaction Between Phosphorus Heterocycles And Cytochrome P450, Dumei Ma, Libo Zhang, Yingwu Yin, Yuxing Gao, Qian Wang

Faculty Publications

P450 fatty acid decarboxylase OleT from Staphylococcus aureus (OleT_SA) is a novel cytochrome P450 enzyme that catalyzes the oxidative decarboxylation of fatty acids to yield primarily terminal alkenes and CO₂ or minor α- and β-hydroxylated fatty acids as side-products. In this work, the interactions between a series of cycloalkyl phosphorus heterocycles (CPHs) and OleT_SA were investigated in detail by fluorescence titration experiment, ultraviolet–visible (UV–vis) and ³¹P NMR spectroscopies. Fluorescence titration experiment results clearly showed that a dynamic quenching occurred when CPH-6, a representative CPHs, interacted with OleT_SA with a binding constant value of 15.2 …

Order And Harmony: Kepler’S Guiding Forces, Dan Broadbent

Faculty Publications

Adapted from the article “Order and Harmony: Kepler’s Guiding Forces” included in “Towards Mysteries of the Cosmos with Johannes Kepler – on the 450th Anniversary of His Birth,” a commemorative volume published by the Obserwatorium Atronommiczne Krolowej Jadwigi Rzepienniku Biskupim (Queen Jadwiga Observatory of Rzepiennik Biskupi Poland) December 2021. Adapted with permission.

As the subject librarian for physics and astronomy at Brigham Young University, the author has had the privilege of handling some of Johannes Kepler’s original books preserved in the university’s archives. One of the most impressive materials in the archive is a large page from Mysterium Cosmographicum that …

Comparison Of Seasonal Foes And Fbes Occurrence Rates Derived From Global Digisonde Measurements, Dawn K. Merriman, Omar A. Nava, Eugene V. Dao, Daniel J. Emmons Ii

Faculty Publications

A global climatology of sporadic-E occurrence rates (ORs) based on ionosonde measurements is presented for the peak blanketing frequency, fbEs, and the ordinary mode peak frequency of the layer, foEs. ORs are calculated for a variety of sporadic-E frequency thresholds: no lower limit, 3, 5, and 7 MHz. Seasonal rates are calculated from 64 Digisonde sites during the period 2006–2020 using ionograms either manually or automatically scaled with ARTIST-5. Both foEs and fbEs ORs peak in the Northern Hemisphere during the boreal summer, with a decrease by roughly a factor of 2–3 in fbEs rates relative to foEs rates without …

Characterization Of The Gut Microbiota Among Veterans With Unique Military-Related Exposures And High Prevalence Of Chronic Health Conditions: A United States-Veteran Microbiome Project (Us-Vmp) Study, Maggie A. Stanislawski, Christopher E. Stamper, Kelly A. Stearns-Yoder, Andrew J. Hoisington, Diana P. Brostow, Jeri E. Forster, Teodor T. Postolache, Christopher A. Lowry, Lisa A. Brenner

Faculty Publications

The gut microbiome is impacted by environmental exposures and has been implicated in many physical and mental health conditions, including anxiety disorders, affective disorders, and trauma- and stressor-related disorders such as posttraumatic stress disorder (PTSD). United States (US) military Veterans are a unique population in that their military-related exposures can have consequences for both physical and mental health, but the gut microbiome of this population has been understudied. In this publication, we describe exposures, health conditions, and medication use of Veterans in the US Veteran Microbiome Project (US-VMP) and examine the associations between these characteristics and the gut microbiota. This …

Survivals Of Two Cooperating Species Of Animals, Joon Hyuk Kang

Faculty Publications

The purpose of this paper is to give conditions for the existence and uniqueness of positive solution to a rather general type of elliptic system of the Dirichlet problem on a bounded domain Ω" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; line-height: normal; font-size: 16.2px; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; position: relative;">Ω in Rn" role="presentation" style="box-sizing: border-box; margin: 0px; padding: 0px; display: inline-block; line-height: normal; font-size: 16.2px; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: …