Physical Sciences and Mathematics Commons^™

Sewer System Infrastructure And Stressors On Water Quality In Streams Within The Alplaus Watershed In Upstate Ny, Camryn Ragland

Honors Theses

Healthy aquatic ecosystems require clean water, but many creeks and streams may be impaired by human activity. This study is focused on surface water quality of the Alplaus, and Indian Kill streams located within the Alplaus Watershed in Schenectady and Saratoga Counties (NY). The primary goal of this study is to understand the extent of water quality impairment within the Alplaus and Indian Kill using a range of indicators to understand the impacts of failing infrastructure and stressors to surface water. Sixty-five water samples were collected in the fall of 2021 from six locations in the Alplaus and Indian Kill …

Bootstrapped Fractional Designs Applied To Models With Both Mixture And Process Variables, Laura Vinton

Honors Theses

Mixture variables are unique as the components must sum to 1, causing problems when there is interaction between mixture and process variables. The best model is the fully linearized model, but this can get large quickly. We began by comparing models on multiple data sets. These models include linear and nonlinear models. After seeing that nonlinear models appear to be the best alternatives, we used the systematically selected fractions of each data set in order to obtain an in and out of sample RMSE. This allows us to see if there is evidence of overfitting, how well the model predicts …

External Beam Alignment System For Quantitative Proton Induced Gamma-Ray Emission (Pige) Spectroscopy, Elias Ottens

Honors Theses

The effects of pollution on the ecosystem are paramount in our society, permeating air, soil, and drinking water. One contaminant of concern is per- and polyfluoroalkyl substances (PFAS), also referred to as "forever chemicals", which contains fluorine (F), a potentially harmful element to humans. To investigate pollution in the environment, it is necessary to make accurate measurements of the distribution and concentrations of these PFAS chemicals. To do this, soil samples are collected and analyzed using Particle Induced Gamma-ray Emission (PIGE) via the Union College Ion Beam Analysis Laboratory's (UCIBAL) particle accelerator. A 2.2 MeV proton beam comes into contact …

Corrective Feedback Timing In Kanji Writing Instruction Apps, Phoenix Mulgrew

Honors Theses

The focus of this research paper is to determine the correct time to provide corrective feedback to people who are learning how to write Japanese kanji. To do this, we developed a system that is able to recognize Japanese kanji that is handwritten onto an iPad screen and check for errors such as wrong stroke order. Previous research has achieved success in developing similar systems, but this project is unique because the research question involves the timing of corrective feedback. In particular, we are looking at whether immediate or delayed corrective feedback results in better learning.

Analysis Of Covid-19 And Vaccine Administration In Mississippi, Megan Sickinger

Honors Theses

In this work, we develop a simple mathematical model to observe the spread of COVID-19 and vaccine administration in Mississippi. Based on the well-known Kermack-McKendrick Susceptible-Infected-Removed epidemiological model, the ASIRD−V model has eight ordinary differential equations that split infected populations and recovered populations into vaccinated and unvaccinated populations. After determining that the system is reliable for real-world applications, we investigate and determine the stability and equilibrium points of this system. The system is found to be disease-free when R0 < 1 and endemic when R0 > 1. We use MATLAB to numerically solve the system and optimize the model’s parameters over four short periods, two with the …

Statistical Effects Of Synthetic Template Mismatch With Model Deimos Observations, Christos Kakogiannis

Honors Theses

High-precision kinematics of individual stars in Milky Way satellite galaxies and globular clusters is crucial for studies of galaxy formation, cosmology, alternative gravity models, and dark matter. We tested a rigorous method that matches model DEIMOS observations of such targets with synthetic template spectra that deduces radial velocities and [Fe/H] abundances. We added noise to create a model spectrum with SNR = 30, fitted templates with different parameters to it, and calculated the
best-match velocity and the goodness of the fit. The best fits occur for templates that are close in parameter space to the model spectrum, and the fits …

Fine-Tuning A 𝑘-Nearest Neighbors Machine Learning Model For The Detection Of Insurance Fraud, Alliyah Stout

Honors Theses

Billions of dollars are lost within insurance companies due to fraud. Large money losses force insurance companies to increase premium costs and/or restrict policies. This negatively affects a company’s loyal customers. Although this is a prevalent problem, companies are not urgently working toward bettering their machine learning algorithms. Underskilled workers paired with inefficient computer algorithms make it difficult to accurately and reliably detect fraud.

The goal of this study is to understand the idea of -Nearest Neighbors ( -NN) and to use this classification technique to accurately detect fraudulent auto insurance claims. Using -NN requires choosing a value and a …

Fluid Pathways In Magmatic Fluid-Dominated Hydrothermal System: Upper Resurgent Cone, Brothers Volcano, New Zealand, Esther G. Goita

Honors Theses

The Tonga-Kermadec Arc is an active volcanic arc located between New Zealand and Fiji. The arc expands over an approximate distance of 2530 km. The Kermadec Arc is currently host to over 30 volcanoes, the majority of which are submarine. The magmatic activity along the arc is characterized by the convergence between the Pacific and Australian plates. Brothers volcano is the most active hydrothermal system along the Kermadec arc and hosts two distinct hydrothermal systems, one magmatic fluid dominated, and the other seawater dominated, making the site perfect for studying nascent volcanogenic massive sulfide formation and fluid pathways. The International …

Investigation Of Python Variable Privacy, Joshua Bartholomew

Honors Theses

This study looks at the relative security of Python regarding private variables and functions used in most other programming languages. Python has only grown in popularity due to its simple syntax and developing capabilities. However, little research has been published about how secure Python code and programs compiled from Python code actually are. This research seeks to expose vulnerabilities in Python code and determine what must be done for these vulnerabilities to be exploited by hackers to abuse potentially sensitive information contained within the program.

The proposed methodology includes examining the private variable concept in other programming languages and conducting …

Real Time Call-Flagging System To Respond To Suicidal Ideation In Call Centers, Vishnu Menon, Joseph Carrigan, Charles Floeder, Thomas Walton, Devin Mcguire

Honors Theses

The 2021-2022 Signature Performance Design Studio team developed a live audio call-flagging system that enables faster responses and new response pathways to veteran crises by call service representatives and their management team. Using a custom made deep learning model, live audio streaming server, and Teams broadcasting add-on, the system empowers Signature Performance call service representatives to make quicker and more well informed decisions to provide veteran’s the best care possible.

Analysis Of The Effectiveness Of Different Techniques For Creating Cross-Platform Compatible Software, Michael Westberg

Honors Theses

Creating cross-platform compatible software is a major issue in a world where users utilize a variety of devices and platforms. To ensure that a piece of software is accessible to as many users as possible, software must be cross-platform compatible. There are four main approaches that can be done to achieve this state of being cross-platform compatible, each with both advantages and disadvantages. These methods are: creating the software as separate binaries, using a scripting language with a cross-platform interpreter, compiling to an intermediate language, and creating the software as a web application. This paper will discuss how each of …

A Framework Comparison: .Net And Laravel, Guy Richard

Honors Theses

No abstract provided.

A Study Of Cannabigerolic Acid And Its Derivatives Via Raman Spectroscopy And Density Functional Theory, Trevor Wolfe

Honors Theses

The cannabinoids are a class of molecules endogenous to the cannabis plant. Their scientific relevance has increased in recent years due to the mercurial legal status of marijuana across the United States. Some of the most known are cannabidiol (CBD), δ9-tetrahydrocannabinol (δ9-THC), and δ8-THC due in large part to their widespread use, especially in states where marijuana and related products are legal. However, cannabigerolic acid (CBGA) is arguably the most important cannabinoid; it is enzymatically converted into other acidic cannabinoids, which subsequently undergo non-enzymatic processes (isomerization, thermal decarboxylation, oxidation, etc.) to synthesize further cannabinoids. Although there is a wealth of …

A Performance Analysis Of The Belle Ii Detector, John Stacy

Honors Theses

The Belle II experiment has recently (2018) started data taking at the SuperKEKB electron-positron collider in Tsukuba, Japan. Detector performance studies are necessary to understand early data and prepare for more complex analyses. This study of the proton detection efficiency of the Belle II detector compares real and simulated data to find discrepancies with the intention to provide useful information for detector and calibration experts to better gauge detector performance. It also attempts to improve the characterization of proton identification efficiency at low momenta, which performs poorly under the current fitting model. This helps analysts exploring final states that include …

Lifetime Measurement Of The Xi_C^+ Using Belle Ii Monte Carlo, Paul Gebeline

Honors Theses

This analysis uses simulated data from the Belle II experiment to measure the lifetime of the Xi_c^+ baryon. Three different decay modes are investigated to explore the feasibility and accuracy of such measurements at Belle II. The Xi_c^+ lifetime is measured using one of these modes after reducing backgrounds from sources other than the decay of interest. The final result is 464 +/- 15 fs, which is consistent with the expected result of 442 fs within uncertainty. This result shows that Belle II can make competitive measurements of particle properties and decays.

Synthetic Investigations In Chemical Probe Development Part 1: Design And Synthesis Of Novel Triton X-405 Adenosine Conjugates; Part 2: Synthesis Of 2,8-Dihydroxychrysene, Rachel Irene Hammond

Honors Theses

Although not drugs themselves, chemical probes are a necessary tool in biomedical research for the interrogation of biological systems. In the present synthetic investigation, two chemical probes were developed – a Triton X-405 adenosine conjugate (TX-405A) and 2,8-dihydroxychrysene. The designed TX-405A conjugate was generated in four steps through tosylation and amination of TX-405 such that EDC-coupling of TX-amine with 2’,3’-Isopropylidene adenosine-5’-carboxylic acid afforded TX-405A following acetonide deprotection. The development of TX-405A represents the first report of the synthesis and utilization of a detergent-linked dosimeter. The synthesis of 2,8-dihydroxychrysene provided an in-depth exploration on the unique reactivity of chrysene. The desired …

Ab Initio Study Of The Rotation Of The C≡C Group In Benzvalyne, Advait Praveen

Honors Theses

For benzvalyne, we have characterized the minima and transition states of the molecule using the B3LYP, MP2, and M06-2X methods and aug-cc-pVTZ basis set. This was done by calculating the energy of the molecule while rotating the alkyne bond contained within it. After the initial rotation, optimized parameters for the molecule are found. Following this, imaginary frequencies were attempted to be found at the local maximum produced by the graph of the Energy v. rotation angle. Should the negative frequencies be found, the energy of the molecule will be characterized by the CCSD (T) method and aug-cc-pVQZ basis sets. This …

Lc-Ms Identification Of Serum Proteins Adsorbed Onto Ionic Liquid-Coated Nanoparticles, Anh M. Hoang

Honors Theses

Nanocarriers are promising candidates for drug delivery due to their size and tunable surface characteristics. However, when they are intravenously injected, few particles make it to their designated location. This is because upon entering the bloodstream, the serum in the blood, which is rich with a diversity of proteins, adsorbs onto the particles’ surfaces forming a protein corona. Many of the attached proteins trigger the mobile immune system and are removed by macrophages, and many particles are then filtered out by the liver and kidneys. Ionic Liquids (ILs), which consist of asymmetric, bulky components that are liquid

Computational Investigations Into Astrochemical Inorganic Oxides, Ammonia Borane, And Genetic Algorithms, E. Michael Valencia

Honors Theses

The formulations of quantum mechanics in the early 1900s were exciting theoretical discoveries, but were not practical to apply until the advent of computers and the subsequent computational methods in 1951. With the introduction of tractable simplifications, procedures such as Hartree-Fock allowed for determination of properties of non-trivial systems. Presently, huge leads of computational power have allowed for extremely precise, quantitative work that can be applied to the human body, synthesis, or even astrochemical processes. This thesis presents works concerning 1) the history of quantum mechanics; 2) a brief primer on computational chemistry and its methods; 3) inorganic oxides in …

The Sustainability Rhetoric Among The Spanish Fashion Companies Involved In The Rana Plaza Collapse Of 2013, Keegan Lyle

Honors Theses

Over the last century, fashion has evolved to become a commodity that is rapidly changing and easily available. The processes that have led to this accessibility of fashion, however, have proven to be harmful to the environment and, most recently, proven to be potentially fatal for the people making the clothing. In 2013, a garment factory in Bangladesh, housing production for major global fashion brands, like Zara and The Children’s Place, collapsed following a series of negligence. The event has sparked years of awareness-raising in the public dialogue of fast fashion. As a part of the newly-developing research in sustainable …

Increasing Perceived Realism Of Objects In A Mixed Reality Environment Using 'Diminished Virtual Reality', Logan Scott Parker

Honors Theses

With the recent explosion of popularity of virtual and mixed reality, an important question has arisen: “Is there a way to create a better blend of real and virtual worlds in a mixed reality experience?” This research attempts to determine whether a visual filter can be created and applied to virtual objects to better convince the brain into interpreting a composite of virtual and real views as one seamless view. The method devised in this thesis is being called 'Diminished Virtual Reality'. The results found in this study show that when presented with a scene composed of a combination of …

Monte Carlo Study Of Lepton Flavor Universality Violation In B Decays With Belle Ii Simulation, Sakul Mahat

Honors Theses

Belle II, the first super B-Factory experiment, is designed to make precise measurements of weak interaction parameters and search for New Physics beyond the Standard Model of particle physics. The Standard Model of particle physics is a theory that classifies all known elementary particles and describes three of the four known fundamental forces in the universe. Physics beyond the Standard Model that addresses the theoretical developments needed to explain the deficiencies in the Standard Model is often referred to as New Physics. One of the assumptions of the Standard Model is that the couplings of particles that mediate the weak …

The Use Of Time-Lapse And Still Photographs To Document The Effects Of Seasonality On Dune Morphodynamic Evolution In Corolla, Nc., Briar Ownby-Connolly

Honors Theses

With climate change altering established seasonal and weather phenomena, understanding the physical behavior of barrier islands and the processes driving such physical changes, specifically within their dune zones, is crucial in promoting their resiliency. With ecosystem services provided by dunes to coastal economies and wildlife habitat, promoting dune conservation serves to advance the benefits of these systems, within a changing climate. Current findings by the Army Corps of Engineers Field Research Facility in Duck, NC, suggest the significance of local aeolian sediment transport in interplay with storm intensity in effecting dune stability, and that anthropogenic impacts, like the installment of …

The Design Of A Pcr-Based Assay To Detect And Isolate The Serine Palmitolytransferase Gene From Environmental Bacteria, Lana Taylor

Honors Theses

Sphingolipids are a natural class of lipids that function as structural elements of cell membranes and signaling molecules for important cellular activities such as cell growth, differentiation, apoptosis, recognition, and adhesion. These lipids can be found universally in eukaryotic cells as well as some species of bacteria, such as those found in the human gut microbiome and in the environment in soils. Though sphingolipid production is rare in bacteria, both eukaryotic and prokaryotic sphingolipid biosynthesis begin with the condensation of serine and palmitoyl CoA into 3-ketodihydrosphingosine catalyzed by the enzyme serine palmitoyltransferase (SPT). In recent years, several studies have shown …

The Efficacy Of The Covid-19 Vaccine In Mississippi, Ilyse Miriam Levy

Honors Theses

The Efficacy of The COVID-19 Vaccine in Mississippi

(Under the direction of Dr. Xin Dang)

By tracking and analyzing fifty-three weeks of COVID-19 data, this thesis analyzes the efficacy of the COVID-19 vaccine within the State of Mississippi. Over the course of these fifty-three weeks, I have also been able to calculate the confidence intervals for vaccination efficacy and the risk reduction due to vaccination by using data regarding the correlations between deaths and vaccination status, provided to me by the Mississippi Office of Epidemiology. My analysis demonstrates that the COVID-19 vaccine is effective not only in Mississippi but also …

Covalent Modification Of Recombinant Protein With Reactive Thiols, Sawyer Dulaney, Bailey Taylor

Honors Theses

Many diseases cause chronic and painful inflammation in different body systems. One of the front-line drug classes to treat such inflammation is Nonsteroidal Anti-Inflammatory Drugs (NSAIDs). Despite the benefits of oral administration of NSAIDs, there are drawbacks to their long-term usage because they can cause detrimental effects on off-target systems in the body such as the liver, kidney, or the lining of the intestinal tract. An alternative to NSAIDs is the usage of hydrogels for targeted drug delivery. Hydrogels can provide drug delivery in a specific portion of the site of inflammation, thus allowing higher doses of medication to be …

Computational And Spectroscopic Studies Of New Sulfur-Containing Dipole-Bound Anions, Nicholas Allen Kruse

Honors Theses

Sulfur and Nitrogen are essential ingredients in both life-supporting and light-harvesting molecules. Their presence also usually leads to the delocalization of electrons and large dipole and quadrupole moments. Such molecules are sometimes able to form negative ions through the electrostatic binding of an excess electron. These so-called multipole-bound (dipole-bound, quadrupole-bound, etc.) anions have been shown to be important in radiation damage in biology and electron transport processes. Here, we present our recent computational and experimental results studying the creation of new multipole-bound anions.

Characterization Of The Initial Explosive Phases Of The 2021 Eruption At La Soufriere, St. Vincent, Sydney Walters

Honors Theses

The Soufriere Volcano on St. Vincent Island, in the Lesser Antilles volcanic arc, is one of the most active subaerial volcanos in the Caribbean, erupting both explosively and effusively at least 7 times in the last 500 years. In December of 2020, the volcano began erupting effusively, showing no evidence of degassing and on April 9^th of 2021, it transitioned to an explosive eruption that continued until April 22, with more than 30 eruptions classified as Vulcanian and sub-Plinian. Scoria samples from three units (U1-U3) erupted in the first 48-72 hours of the explosive eruptive phase were analyzed in …

Studying Suspended Sediment Concentrations In The South Chickamauga Creek Of Chattanooga, Tn Using Satellite Imagery, Digital Image Processing, And Numeric Modeling, Abigail Faxon

Honors Theses

In recent years, Hamilton County, TN has experienced extensive urban growth. According to US Census data, Hamilton County welcomed more than 33,000 new residents in the last decade. There is increased concern about the environmental sustainability of Chattanooga’s urban growth because significant impervious surface development has taken place along the South Chickamauga Creek. This leaves the creek subject to increased urban runoff, which often carries sediments with different municipal pollutants. Thus, monitoring turbidity in the stream water is important to determine the sustainability of urban development in Chattanooga, TN. In this research, we have compared the viability of using different …

Theoretical Studies Of Benzoquinone Reactivity In Acidic And Basic Environments, Natali Majoras

Honors Theses

Quinones are a class of organic compounds containing a six-membered unsaturated ring with two carbonyl groups. They are biologically relevant mostly due to their ability to participate in redox reactions. Prior experiments in our lab showed that quinones can induce protein modifications that are pH dependent. In an acidic environment the modifications were less significant than in a basic environment. Previous computational studies have also been carried out to model, in neutral solutions, the reaction between various quinones and various amines. Various amine groups are used as a model for the amino group of lysine to represent protein modification. The …