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Honors Theses

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Articles 181 - 210 of 2158

Full-Text Articles in Physical Sciences and Mathematics

The Effects Of Dissolved And Suspended Solids On Freshwater Meiofauna, Jessica Cline May 2022

The Effects Of Dissolved And Suspended Solids On Freshwater Meiofauna, Jessica Cline

Honors Theses

Meiofauna include small-sized animals (< 1mm) distributed in all aquatic ecosystems on Earth, where they play fundamental trophic and ecological roles. The biodiversity of marine meiofauna and its links with anthropogenic activities is routinely investigated, however, freshwater communities are less known. This is particularly true for the Southeastern United States, which is greatly investigated and elected a hotspot of biodiversity for larger species but very little is known about the meiofauna. The purpose of this research is to reveal the biodiversity of meiofauna from the Tennessee River and test for potential correlations with anthropogenic activities. As a proxy for pollution, dissolved and suspended solids were considered in this study. The research hypothesis is that meiofaunal biodiversity would be affected by possible changes of dissolved and suspended solids in the water column. Possible mechanisms causing biodiversity shifts could be ascribed to osmotic stresses of animals to cope with variation in dissolved solids or, more indirectly, because different sunlight penetration caused by suspended solids would affect primary production. To test the hypothesis, water samples were collected from nine stations located along the Tennessee River in Hamilton County. Each station was visited three times, and, during each visit, environmental parameters (including dissolved and suspended solids) were measured. Meiofauna biodiversity (estimated as richness, community composition, and phylogenetic diversity) was revealed using a metagenomic approach. Statistical analyses were applied to test for possible correlations between the biodiversity estimates and the measured environmental parameters. Results show a high biodiversity of meiofauna with more than 200 amplicon-sequence variants distributed across 10 metazoan phyla. Environmental conditions are highly variable among stations and statistical analyses show that while both dissolved solids (TDS) and turbidity (suspended solids, NTU) did not significantly affect meiofauna biodiversity in the collected samples, various other water, and sediment metrics were found to be significant predictors of meiofauna biodiversity. In conclusion, the results of this project not only reveal for the first time the meiofauna biodiversity from the Tennessee River, but also suggest that meiofauna could be used as bioindicators for several anthropogenic activities in freshwater ecosystems.

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Synthesis And Characterization Of Organometallic Complexes For Biological Imaging, Emily Stumbo May 2022

Synthesis And Characterization Of Organometallic Complexes For Biological Imaging, Emily Stumbo

Honors Theses

Luminescent transition metal complexes are of interest for biological imaging applications due to their unique photophysical properties including large Stokes shift, long fluorescence lifetimes, and tunable emission. Altering ligand structure is a useful way to manipulate the charge transfer (CT) and mixed character states that give these complexes their photophysical properties. A series of organometallic complexes containing ligands with externally facing nitrogens has been prepared and synthesized. Complexes of the form Pt (II)(tbbpy)(C2-py), Re(CO)3(N^N), Ir(C^N)2(N^N), and Ir(C^N)2(N^O) have been studied for their potential application as biological imaging agents. The goal of this project is to compare the properties of these …

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The Impact Of Water Infrastructure Inequality On Marginalized Communities, Indra Khalsa May 2022

The Impact Of Water Infrastructure Inequality On Marginalized Communities, Indra Khalsa

Honors Theses

America’s current system of water infrastructure poses a threat not only to the environment but also to public health. The water crisis reveals the stark inequalities that exist from both an environmental justice and a social justice perspective. There is a growing concern that without adequate investment from federal resources, the problems related to this issue will only worsen the longer they are neglected. There is little information about how specific environmental and social factors combine with water infrastructure to create long-term infrastructure inequalities. However, this thesis explores the disparities in water infrastructure affordability, vulnerability patterns, and environmental hazards. It …

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Reinforcement Learning In A Quantum Network, Roy Pace May 2022

Reinforcement Learning In A Quantum Network, Roy Pace

Honors Theses

No abstract provided.

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The Effect Of Pesticides And Ultraviolet Radiation On Coastal Invertebrates And The Need For More Research On Multiple Stressors And Predator-Prey Interactions, Chase Robinson May 2022

The Effect Of Pesticides And Ultraviolet Radiation On Coastal Invertebrates And The Need For More Research On Multiple Stressors And Predator-Prey Interactions, Chase Robinson

Honors Theses

No abstract provided.

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Compatible Blends Of N-Type Polymer Semiconductors: Impact On The Morphology And Mechanics Of Flexible Optoelectronics, Zachary C. Ahmad May 2022

Compatible Blends Of N-Type Polymer Semiconductors: Impact On The Morphology And Mechanics Of Flexible Optoelectronics, Zachary C. Ahmad

Honors Theses

Conjugated polymers offer the potential for the development of robust, low-cost electronics, but achieving high mechanical deformability and high charge transport simultaneously in polymer semiconductors remains a significant challenge. In this work, blends of conjugated polymers were investigated to elucidate the influence of compatible conjugated blends on polymer morphology, mechanics, and electrical properties (using a partially conjugated polymer as the soft matrix and a fully conjugated polymer as the electrically active component). This work achieves a fundamental understanding of blend morphology for these similar components by establishing the framework for how they deform with strain. Grazing-incidence wide-angle X-ray scattering (GIWAXS) …

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Comparing Composite Severe Weather Indices Of Thunderstorm Activity On Sea-Breeze And Non-Sea-Breeze Days In The Mobile, Alabama Area, Elizabeth Seiler May 2022

Comparing Composite Severe Weather Indices Of Thunderstorm Activity On Sea-Breeze And Non-Sea-Breeze Days In The Mobile, Alabama Area, Elizabeth Seiler

Honors Theses

Sea breezes (SB) occur frequently from May through October along the U.S. Gulf of Mexico Coast. One reason why SBs interest forecasters is their ability to spawn summertime thunderstorms, which can cause flash flooding, lightning, and hail. However, forecasting the exact timing and location of SB-driven convection can be challenging. This thesis will focus on Mobile and Baldwin Counties in southwest Alabama, which experience two types of phenomena – SBs along the Gulf of Mexico Coast and bay breezes on either side of Mobile Bay. Over the past years, multiple undergraduate students have analyzed Mobile, Alabama radar imagery of past …

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Balancing Data- Vs. Art-Driven Decisions In Video Game Design, Jaden D. Goter May 2022

Balancing Data- Vs. Art-Driven Decisions In Video Game Design, Jaden D. Goter

Honors Theses

Video games, like software, need to be designed. Video game development studios tend to use data-driven or art-driven decision-making to design their games. Data-driven decision-making is where active and passive data is collected in order to make informed decisions about the design of a game. Art-driven decision-making is when designers use their artistic intuition to design games, potentially ignoring player data. This paper elaborates on the advantages and disadvantages of both approaches and provides case studies of games designed under both approaches. Based on these studies, for a game to be successful, a combined approach of data- and art-driven decision-making …

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Synthesis And Characterization Of Silver Thione Complexes, Audrey V. Lawrence Apr 2022

Synthesis And Characterization Of Silver Thione Complexes, Audrey V. Lawrence

Honors Theses

Coordination polymers are repeating units of a coordination complex that have applications as catalysts, conductors, and magnets. In this work, silver (I) was the metal of choice because it behaves similarly to copper (I), which has been studied much more extensively and thione ligands were chosen due to their potential for forming coordination polymers. These coordination complexes with silver were synthesized by combining silver nitrate with thioacetamide, N,N'-diphenylthiourea, and 2-mercapto-1-methylimidazole. These complexes were characterized via IR spectroscopy, elemental analysis, and X-ray crystallography. Silver thioacetamide was determined to form a coordination complex through the sulfur to form a trigonal crystal lattice …

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Synthesis And Study Of Unsymmetrical Bidentate Bis(Phosphino)Pyrrole Ligands And Their Transition Metal Complexes, Julia F. Vidlak Apr 2022

Synthesis And Study Of Unsymmetrical Bidentate Bis(Phosphino)Pyrrole Ligands And Their Transition Metal Complexes, Julia F. Vidlak

Honors Theses

Our laboratory has reported the synthesis and characterization of a broad library of unsymmetrical bidentate bis(phosphino)pyrrole (BPP) ancillary ligands for use in nickel-catalyzed cross-coupling reactions. The electronic and steric properties of nickel complexes bearing these ligands are examined, and our data support the hypothesis that these ligands produce nickel complexes with electron-deficient metal centers. The syntheses of (BPP)Ni(o-tolyl)Cl precatalysts for utilization in nickel-catalyzed Buchwald-Hartwig Amination are described, and preliminary reactivity studies reveal that (BPP)Ni(o-tolyl)Cl precatalysts are effective in promoting C–N cross-coupling reactions. Finally, we report steric measurements and electronic properties obtained from computed (BPP)NiCl2 and (BPP)Ni(CO)2 complexes, respectively. Additional reactivity …

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Collision-Induced Dissociation And Ion Mobility Mass Spectrometry Of Au30(S-Tbu)18 Nanoclusters, Christopher Hood Apr 2022

Collision-Induced Dissociation And Ion Mobility Mass Spectrometry Of Au30(S-Tbu)18 Nanoclusters, Christopher Hood

Honors Theses

Collision Induced Dissociation (CID) and Ion Mobility Mass Spectrometry (IM-MS) are methods used to understand the structural arrangement and stability of large molecules. In this study, the gold nanocluster Au30(S-tBu)18 was dissociated at varying Trap collision energies, and drift time vs mass spectrometry data was plotted to determine the order of cluster fragmentation. Comparing Au30(S-tBu)18 data to that of Au25(SCH2CH2Ph)18, the only current nanocluster published with IM-MS data, two distinctly different dissociation patterns were seen. Unlike the linear CID fragmentation of Au …

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Synthesis And Characterization Of Redox-Active Multidentate Ligands For Catalytic C-H Bond Oxidation And Carbon Dioxide Reduction, Caroline Hodge Apr 2022

Synthesis And Characterization Of Redox-Active Multidentate Ligands For Catalytic C-H Bond Oxidation And Carbon Dioxide Reduction, Caroline Hodge

Honors Theses

This thesis focuses on two research projects. The first project reported in Chapter 1 involves the synthesis and application of a tetradentate ligand (2-(1,1-di(pyridin-2-yl)ethyl)-1,10-phenanthroline, PhenPY2Me) that is metalated with iron to give a catalyst capable of carbon-hydrogen (C-H) bond oxidation. C-H bond oxidation provides a method that may allow some transformations in organic syntheses to be streamlined. The mononuclear iron complex supported by PhenPY2Me was found to dimerize in the presence of O2 in a non-coordinating solvent. These iron complexes and a previously reported system were assessed and compared in C-H bond oxidation with model substrates using the sacrificial …

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Targeting Platelets Using Ionic Liquid Coated Nanoparticles, Karen Mun Wong Apr 2022

Targeting Platelets Using Ionic Liquid Coated Nanoparticles, Karen Mun Wong

Honors Theses

Platelets are key players in our body’s inflammatory processes upon activation, which can create physiological problems. Researchers are actively seeking solutions by targeting platelets with therapeutics. The objective of the research in this thesis was to investigate a new and potentially less invasive drug delivery platform using nanoparticles. The topic of the project was to explore the world of ionic liquids and their abilities, when coated on nanoparticles, to bind to platelets. A library of choline carboxylic acid-based ionic liquids (ILs) was first synthesized via salt metathesis while PLGA-based nanoparticles were simultaneously being synthesized via the nanoprecipitation method. The ionic …

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Fast Photochemical Oxidation And Footprinting Of Proteins Via Trifluoromethyl Radical Chemistry, Elaine Morrow Apr 2022

Fast Photochemical Oxidation And Footprinting Of Proteins Via Trifluoromethyl Radical Chemistry, Elaine Morrow

Honors Theses

Fast photochemical oxidation of proteins (FPOP) is a useful tool in proteomics because of the ability for modifications to occur on the scale of microseconds which reduces the modifications to tertiary and quaternary structure allowing for more accurate labeling of the protein. Labels for FPOP are generated from various radicals in our experiments which include hydroxyl radicals and trifluoromethyl radicals. Hydroxyl radicals are easily generated by using an excimer laser (KrF laser, 248 nm) or a UV flash lamp (as a part of the Fox™ System) by the photolysis of hydrogen peroxide. Trifluoromethyl radicals, however, need hydroxyl radicals to be …

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A Fractal Geometry For Hydrodynamics, Jonah Mears Apr 2022

A Fractal Geometry For Hydrodynamics, Jonah Mears

Honors Theses

Experiments have shown that objects with uneven surfaces, such as golf balls, can have less drag than those with smooth surfaces. Since fractal surfaces appear naturally in other areas, it must be asked if they can produce less drag than a traditional surface and save energy. Little or no research has been conducted so far on this question. The purpose of this project is to see if fractal geometry can improve boat hull design by producing a hull with low friction.

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Study Of Deexcitation Intensities To The K-Shell In Iron 55, Eric Helgemo Apr 2022

Study Of Deexcitation Intensities To The K-Shell In Iron 55, Eric Helgemo

Honors Theses

55Fe radioactive sources are used for x-ray calibration due to the long half-lives of 2.73 years and the optimal energies of the peaks. The source used in the experiment was generated using Western Michigan University’s Tandem Van de Graff accelerator to produce a 6 MeV proton beam which induced a 55Mn(p, n)55Fe reaction on a 10 μm 55Mn target. The emissions from this target were then measured using a silicon lithium drift x-ray detector to determine the number of instances of deexcitation through kα and kβ modes. The preliminary data discussed showed a lower relative deexcitation rate of 6.67 between …

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Sandworms And Computer Worms: An Assessment Of American Critical Infrastructure Cyber Vulnerabilities And The Russian Federation's Growing Offensive Capabilities, Spencer Johns Apr 2022

Sandworms And Computer Worms: An Assessment Of American Critical Infrastructure Cyber Vulnerabilities And The Russian Federation's Growing Offensive Capabilities, Spencer Johns

Honors Theses

Bottom Line Up Front: It is highly likely that the Russian GRU has the capability, resources, and intent to execute cyberweapon attacks against American critical infrastructure in times of heightened tensions, either as a warning or a first strike. I also assess that much of current American critical infrastructure is not secure enough to withstand a coordinated assault by the GRU, and very likely has numerous severe vulnerabilities known by the GRU.

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Relative Energy Comparison For Various Water Clusters Using Mp2, Df-Mp2, And Ccsd(T):Mp2 Methods, Qihang Wang Apr 2022

Relative Energy Comparison For Various Water Clusters Using Mp2, Df-Mp2, And Ccsd(T):Mp2 Methods, Qihang Wang

Honors Theses

The study of water clusters is an important area of research in many disciplines, such as biology, physical chemistry, and environmental studies. However, due to the difficulty in studying larger water clusters, such as clathrate hydrates, it is beneficial to obtain accurate descriptions of smaller water clusters to use as models for larger systems via computational methods. By starting with small water clusters, such as (H2O)6, and moving into larger systems it is possible to build up data on various water structures that can determine the energetics of the various geometries within a certain number of water molecules. …

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Classifying Pretzel Links Obtained By Strong Fusion, Jonathan Homan Apr 2022

Classifying Pretzel Links Obtained By Strong Fusion, Jonathan Homan

Honors Theses

A link is a collection of circles embedded into 3-dimensional space. Pretzel links are an important family of links which comprises those links that fit a general form that includes many of the most common links. The strong fusion of a link joins two components of the link via a band and adds an unknotted circle about the band [4]; this naturally arises in the study of concordance and has been used to model biological phenomena such as site specific recombination in DNA [2]. Here we present a complete and original classification of those pretzel links which can be obtained …

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Observing Reactive Events At The Aqueous Graphene Oxide Interface Using Deep Neural Network Potentials, Lukas Kim Apr 2022

Observing Reactive Events At The Aqueous Graphene Oxide Interface Using Deep Neural Network Potentials, Lukas Kim

Honors Theses

No abstract provided.

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Observing And Exploring Intrinsic Characteristics Of Type Ia Supernova, Connor Langevin Apr 2022

Observing And Exploring Intrinsic Characteristics Of Type Ia Supernova, Connor Langevin

Honors Theses

No abstract provided.

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Mathematica Assessment Of Spatial Reasoning Development After Virtual Reality Collaboration, Arthur Odenheimer Apr 2022

Mathematica Assessment Of Spatial Reasoning Development After Virtual Reality Collaboration, Arthur Odenheimer

Honors Theses

No abstract provided.

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Gl(1|1) Graph Connections, Andrea Bourque Apr 2022

Gl(1|1) Graph Connections, Andrea Bourque

Honors Theses

No abstract provided.

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Opers On The Projective Line, Wronskian Relations, And The Bethe Ansatz, Ty J. Brinson Apr 2022

Opers On The Projective Line, Wronskian Relations, And The Bethe Ansatz, Ty J. Brinson

Honors Theses

No abstract provided.

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Trophic Relationships Between Tadpoles And Other Aquatic Organisms In Sub-Tropical Ponds, Kira Cates Apr 2022

Trophic Relationships Between Tadpoles And Other Aquatic Organisms In Sub-Tropical Ponds, Kira Cates

Honors Theses

No abstract provided.

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Generative Adversarial Networks Take On Hand Drawn Sketches: An Application To Louisiana Culture And Mardi Gras Fashion, Stephanie Hines Apr 2022

Generative Adversarial Networks Take On Hand Drawn Sketches: An Application To Louisiana Culture And Mardi Gras Fashion, Stephanie Hines

Honors Theses

No abstract provided.

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Defining The Leading Edge Of The Marine – Non-Marine Transition In The Pee Dee Basin: Influences, And Dynamic Parameters Of A Highly Dynamic System, Nicole Mchugh Apr 2022

Defining The Leading Edge Of The Marine – Non-Marine Transition In The Pee Dee Basin: Influences, And Dynamic Parameters Of A Highly Dynamic System, Nicole Mchugh

Honors Theses

Among estuaries, there is a large block of co-dependent and independent variables shaping habitat and environmental conditions within a critical area. Historical data proxies and indexes from seven different stations were assessed to consider temporal and spatial variability of the marine and non-marine transition along the South Carolina Pee Dee River Basin. Historical datasets from the upper reaches of Winyah Bay and lower section of the Pee Dee River basin were compiled along with shorter termed deployments of a new instrument station installed near Georgetown, SC. This area is representative of the marine-non-marine transition in drowned river mouth estuaries. Water …

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Microwave-Assisted Synthesis Of Quinoxaline Derivatives, Eric Horsting Apr 2022

Microwave-Assisted Synthesis Of Quinoxaline Derivatives, Eric Horsting

Honors Theses

Quinoxaline and its derivatives have been studied extensively for their relevant biological activity and transition metal selectivity. These compounds are commonly used for their antimicrobial, antifungal, antiparasitic activity, and relevance in the treatment of metabolic diseases [6]. More recently, quinoxaline’s ability to inhibit gram-positive bacterial growth has been found especially in oxygen- containing compounds, yielding promising candidates to prevent cancerous tumor growth [5]. The breadth of quinoxaline makes it a valuable tool within the research community However, its synthesis requires complex solvents, extended reaction times, and often produces a low yield. By using a microwave-assisted synthesis, this novel methodology offers …

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Understanding The Hydrolytic Activity Of Papiliotrema Laurentii On Polyester Polyurethane Coatings, Ariana L. Santos Apr 2022

Understanding The Hydrolytic Activity Of Papiliotrema Laurentii On Polyester Polyurethane Coatings, Ariana L. Santos

Honors Theses

Though plastic polymers such as polyester polyurethanes have many applications from electronics to aircraft coatings, their resistance to natural degradation presents an environmental concern. Therefore, elucidating the mechanism of degradation from microorganisms that were discovered breaking down the coating of a cargo aircraft may offer insights into a method of bioremediation. To explore this, the fungus Papiliotrema laurentii (one microorganism isolated from the consortium) was cultured in several different media types at different pH levels in order to understand how it adjusts its protein secretion patterns to environmental changes. 2D gel electrophoresis, isoelectric focusing (IEF) and a variety of gel …

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Collisions On Campus: Species-Specific Susceptibility Of Resident And Migrant Birds To Window Strikes At Louisiana State University, Jordan A. Mouton Apr 2022

Collisions On Campus: Species-Specific Susceptibility Of Resident And Migrant Birds To Window Strikes At Louisiana State University, Jordan A. Mouton

Honors Theses

No abstract provided.

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