Physical Sciences and Mathematics Commons^™

Cover Crop Treatment Impacts On Selected Soil Health Indicators In Two Tennessee Long-Term No-Till Corn-Soybean Rotations, Adam A. Zimmerman

Masters Theses

Soil hydraulic conductivity (K_sat) and soil microbial biomass carbon (SMB-C) estimates in Tennessee no-till corn (Zea mays L.) and soybean (Glycine max L.) rotation systems may be changed with cover crops. This study assessed differences in K_sat rates and SMB-C values under common cover crop treatments of two no-till corn and soybean rotation systems in west and middle Tennessee. Wheat (Triticum aestivum L.), cereal rye (Secale cereale L.), wheat/crimson clover (Trifolium incarnatum L.), cereal rye/crimson clover, a five species mix (containing cereal rye, crimson …

Dissolved Organic Carbon And The Potential Role To Stream Acidity In The Great Smoky Mountains National Park, Jason R. Brown

Masters Theses

A substantial societal shift towards environmental awareness has focused research efforts on the impacts of pollution on natural landscapes. Improvements to pollutant regulations and technology have resulted in sizeable reductions of atmospheric deposition of anthropogenic acids, especially nitrates and sulfates, which has altered the role of these ions in the environment. As such, understandings of environmental chemistry dynamics have required regular updating.

Through the National Park Service Vital Signs monitoring program, increases in precipitation pH observed in Great Smoky Mountains National Park (GRSM) has been attributed to the reduction of inorganic acid concentrations. Unfortunately, these improvements have not been uniformly …

Algal Alterity : A Study Of Florida's Algae-Crisis-Culture, Katelyn Flood

Masters Theses

This research critically engages with the ecology of media discourse surrounding Florida’s “harmful algae crisis” . It uses a content analysis of online news media articles to address how the presence and unique processes of aquatic algae organisms are entangled with people and cultural practices. Specifically, this work grapples with the dynamic relationship between algae organisms and the cultural production of meaning through visual imagery/stimuli. It examines both visual and textual representations of algae in mass media communications covering the harmful algae crisis or “red tide crisis” of 2017 and 2018: an extreme period of aquatic algae proliferation and hazardous …

Application Of Titrations For Verification Of Small Molecule Interaction In Relation To Amidoximated Fibers For Uranium Extraction From Seawater, Kc Michael Mote

Masters Theses

Nuclear energy is a promising substitute for fossil fuels due to possessing low carbon emissions and providing scalable base-load power. However, one major drawback of using nuclear fuel as an energy source is that it needs a steady source of uranium. While the most economical method of obtaining uranium is through conventional terrestrial mining of the ore uranite, mining uranium ores is both harmful to the environment and limited by the terrestrial uranium supply, which is estimated at only 100 more years. However, more than 1000× more uranium is dissolved in seawater than is reasonably inferred and assured in terrestrial …

Development Of High Throughput Assays For Identification And Evaluation Of Small Molecule Inhibitors Of Microrna-31 Expression, Jackline A. Onyango

Masters Theses

Dysregulated expression of miRNAs has been linked to numerous cancers. On the other hand, miRNAs are potential drug targets due to the ability of their precursor molecules to fold into ligand binding structures. Small-molecule modulators of miRNAs offers opportunity for the development of new therapeutic agents and tools to further probe the mechanisms of miRNA functions. To facilitate the identification of miRNA modulators, the appropriate screening systems are needed, which would be adaptable for high-throughput applications, and allow for quantitative measurements. In this text, we present a molecular beacon-based assay to identify molecules that inhibit miRNA-31 processing by Dicer and …

Expanding Band Parameter Analysis Methods For Hed Meteorites And V-Type Asteroids, Noah Adm Haverkamp Frere

Masters Theses

Vesta and Vesta-like asteroids have been convincingly linked, through visible and near-infrared (VNIR; 0.7 - 2.5 µm [micron]) spectral analysis, to a clan of basaltic achondritic meteorites – howardites, eucrites, and diogenites (HEDs). VNIR reflectance spectra of V-type asteroids and HED meteorites have two absorption features centered near 1 µm (Band I) and 2 µm (Band II) caused primarily by Fe²⁺ [iron] and Ca²⁺ [calcium] cations in pyroxene. Previous studies have shown a correlation between the mol% Fs and Wo with the central wavelengths of Band I and Band II, hereafter called Band I Center (BIC) and Band …

Using Low-Flow Sampling Data To Estimate Hydraulic Conductivity In Aquifers, Joy Kiefer

Masters Theses

Hydrogeologists sample wells to test aquifer water quality and use slug tests to estimate aquifer permeability. Robbins et al. (2009) proposed a more efficient way to obtain the goals of the two tests—the use of low-flow sampling and the use of the resulting flow rate and drawdown data to estimate aquifer hydraulic conductivity (K). The Robbins et al. method calculates K by using the slope of the best fit line from the graph of flow rate vs. drawdown for all low-flow pumping data collected at a well. When the method was applied to low-flow data from four Kalamazoo, MI, it …

Association Between Stream Impairment By Mercury And Superfund Sites In The Conterminous Usa, Karessa L. Manning

Masters Theses

Mercury is a natural element that can cause harm to the brain, heart, kidneys, lungs, and immune system, especially to fetuses developing in the womb. Many natural and anthropogenic factors contribute to mercury in the environment, such as geologic deposits, landfills, gold and silver mining operations, cement production, and atmospheric deposition. Mercury has been identified as a contaminant of concern at many National Priority List (NPL) sites, however, studies on contamination at NPL sites are often only conducted on a local level. This study was to analyze the potential connection between mercury-contaminated NPL sites and the presence of mercury impaired …

Quantum Simulation Using High-Performance Computing, Collin Beaudoin, Christian Trefftz, Zachary Kurmas

Masters Theses

Hermitian matrix multiplication is one of the most common actions that is performed on quantum matrices, for example, it is used to apply observables onto a given state vector/density matrix.

ρ→Hρ

Our goal is to create an algorithm to perform the matrix multiplication within the constraints of QuEST [1], a high-performance simulator for quantum circuits. QuEST provides a system-independent platform for implementing and simulating quantum algorithms without the need for access to quantum machines. The current implementation of QuEST supports CUDA, MPI, and OpenMP, which allows programs to run on a wide variety of systems.

A Novel Palladium Bodipy Photocatalyst For Sonogashira Carbon-Carbon Cross-Coupling, Prahadeesh Nagaretnam

Masters Theses

No abstract provided.

Preclassic Cultural Eutrophication Of Lake Petén Itzá, Lowland Guatemala, By The Early Maya Of Nixtun-Ch'ich', Brooke A. Birkett

Masters Theses

"Paleolimnological evidence indicates the ancient Maya transformed lowland terrestrial ecosystems by felling forest vegetation to construct large civic-ceremonial centers and expand agriculture. The effects of prehistoric Maya land alterations on lake trophic status, however, remain poorly understood. We analyzed a 515-cm-long sediment core from Lake Petén Itzá, lowland Guatemala, to infer paleoenvironmental changes resulting from Maya occupation of the riparian archaeological site of Nixtun-Ch'ich'. Substantial increases in charcoal and fecal stanol concentrations indicate Maya occupation of the Candelaria Peninsula by the late Early Preclassic period beginning ca. 1400 cal yr Before the Common Era (hereafter BCE), despite scant archaeological evidence …

Metal Complexes Of Bis(Pyrazolyl)Methane-Based Ditopic Ligands, Pubudu Nuwan Perera Hapuarachchige

Masters Theses

No abstract provided.

Synthesis And Characterization Of A Two Station Starburst Pseudorotaxane, Janaka Prasad Kaviraj Kavikarage

Masters Theses

Mechanically interlocked molecules (MIMs) are arranged with mechanical bonds. These molecules cannot be separated without breaking the required covalent bonds. There are different kinds of MIMs, such as rotaxanes, catenanes, suitanes, borromean rings, and molecular knots. These MIMs are stabilized by non-covalent interactions such as hydrogen bonds, π-π stacking, and ion-dipole interactions. Dialkylammonium ions, bis(pyridinium)ethane dications, viologen species, and naphthalene diimide π-deficient groups are typical examples of recognition motifs for crown ethers.

In the research described here, we synthesized a new axle, based on a combination of benzobis(imidazolium) (BBI) and viologen species. The axle contains two recognition sites: one is …

Cheeger Constants Of Two Related Hyperbolic Riemann Surfaces, Ronald E. Hoagland

Masters Theses

This thesis concerns the study of the Cheeger constant of two related hyperbolic Riemann surfaces. The first surface R is formed by taking the quotient U²/Γ(4), where U² is the upper half-plane model of the hyperbolic plane and Γ(4) is a congruence subgroup of PSL2(Z), an isometry group of U² . This quotient is shown to form a Riemann surface which is constructed by gluing sides of a fundamental domain for Γ(4) together according to certain specified side pairings. To form the related Riemann surface R' , we follow a similar procedure, this time taking the …

Multiple Generations Of Phlogopite In An Alnöite Diatreme: Insights Into The Petrogenesis Of The Avon Alkaline Igneous Province, Missouri, Nathan Gregory Limbaugh

Masters Theses

“Alkaline Ultramafic Carbonatite (AUC) complexes, although rare, are valued for diamonds and REEs, and as windows into subcontinental and mantle processes as recorded by rock fabrics, mineral spatial relationships, and mineral compositions. We report specifically on olivine and phlogopite petrographic relationships and compositions from the Devonian alnoite diatreme-facies of the Avon Alkaline Igneous Province, Missouri. The diatreme alnoite is a mixture of domains of olivine magmaclasts (OM) set in a crystal-rich melilite matrix. OM are highly fractured, serpentinized olivine pseudomorphs with variable amounts of pristine olivine fragments. Larger olivine domains typically exhibit clear crystal faces and irregular “channels” indicative of …

Relationships Among Mineralogy, Geochemistry, And Oil And Gas Production In The Tuscaloosa Marine Shale, Hayley Roxana Beitel

Masters Theses

"The Tuscaloosa Marine Shale (TMS) is an unconventional shale reservoir located in southeast Louisiana and southwest Mississippi. Limited mineralogical and geochemical data for the TMS have been published. The data that do exist indicate that the formation is heterogeneous. Consequently, previous investigators and oil and gas companies have not managed to effectively link mineralogical and chemical changes to oil and gas production in the TMS. These linkages are critical to establish for future exploration efforts. In this study, we attempt to establish these relationships by gathering all existing mineralogical and chemical data in the TMS, including newly acquired data from …

Predator Scent And Presence Alter Mammal Assemblages In The Missouri Ozarks, Usa, Cara Jean Yocom-Russell

Masters Theses

"Species that are vulnerable to predation exhibit a host of behavioral and physiological adaptations toward the avoidance of this outcome: Heightened awareness of surroundings through visual, olfactory, and auditory senses are common ways in which these species avoid detection by predators. While links between direct predator-prey relationships are well established, less is known about how predators can shape overall community structure or the populations of secondary or less frequently consumed prey items. As humans expand into rural areas, the frequency of wildlife conflicts rises. In response, humans look to prevent these events with a variety of methods. One such method …

A Simple Background Elimination Method For Miniaturized Fiber-Optic Raman Probe, Bohong Zhang

Masters Theses

"Raman scattering is called a photonic - molecular interaction based on the kinetic model of the analytic. Due to the uniqueness of the Raman scattering technique, it can provide a unique fingerprint signal for molecular recognition. However, a serious challenge often encountered in Raman measurement comes from the requirements of fast, real-time remote sensing, background fluorescence suppression, and micro-environmental detection.

A new Miniaturized Fiber-Optic Raman Probe (MFORP) for Raman spectroscopy, used especially for eliminating background fluorescence and enhancing sampling, is presented. Its main purpose is to provide an overview of excellent research on the detection of very small substances and …

A Compact Wavelength Meter Using A Multimode Fiber, Ogbole Collins Inalegwu

Masters Theses

“Wavelength meters are very important for precision measurements of both pulses and continuous-wave optical sources. Conventional wavelength meters employ gratings, prisms, interferometers, and other wavelength-sensitive materials in their design. Here, we report a simple and compact wavelength meter based on a section of multimode fiber and a camera. The concept is to correlate the multimodal interference pattern (i.e., speckle pattern) at the end-face of a multimode fiber with the wavelength of the input lightsource. Through a series of experiments, specklegrams from the end face of a multimode fiber as captured by a charge-coupled device (CCD) camera were recorded; the images …

Biochemical Assay Invariant Attestation For The Security Of Cyber-Physical Digital Microfluidic Biochips, Fredrick Eugene Love Ii

Masters Theses

“Due to the devastating global impact that infectious diseases have had, especially in developing countries, the demand for access to adequate resources to combat sickness continues to be a heavy burden. Reliable and affordable diagnostics is a vital first line of defense in fighting outbreaks and providing accurate treatment. Digital microfluidics biochips capable of running multiple diagnostic tests on a single platform are an emerging technology that are increasingly being evaluated as a viable platform for rapid diagnosis and point-of-care field deployment. Although these systems offer many benefits, processing errors are inherent. Therefore, cyber-physical digital biochips are being investigated that …

Neural Network Supervised And Reinforcement Learning For Neurological, Diagnostic, And Modeling Problems, Donald Wunsch Iii

Masters Theses

“As the medical world becomes increasingly intertwined with the tech sphere, machine learning on medical datasets and mathematical models becomes an attractive application. This research looks at the predictive capabilities of neural networks and other machine learning algorithms, and assesses the validity of several feature selection strategies to reduce the negative effects of high dataset dimensionality. Our results indicate that several feature selection methods can maintain high validation and test accuracy on classification tasks, with neural networks performing best, for both single class and multi-class classification applications. This research also evaluates a proof-of-concept application of a deep-Q-learning network (DQN) to …

Values Of Trust In Ai In Autonomous Driving Vehicles, Ru Lian

Masters Theses

“Automation with artificial intelligence technology is an emerging field and is widely used in various industries. With the increasing autonomy, learning, and adaptability of intelligent machines such as self-driving cars, it is difficult to regard them as simple tools in human hands. At the same time, a series of problems and challenges such as predictability, interpretability, and causality arise. Trust in self-driving technology will impact the adoption and utilization of autonomous driving technology. A qualitative research methodology, Value-Focused Thinking, is used to identify the values of trust in autonomous driving vehicles and analyze the relationship between these values”--Abstract, page iii.

The Kitchen Table: Relationships With The People, Food And Land That Sustain Us, Chelsey Frost

Masters Theses

The purpose of this paper is to examine the ways in which interactions with food and around food affect an individual’s sense of self, connection to community as well as to friends and family, and sense of place. Short, personal narrative gives way to discussion of such themes and ideas as home, homemade food and terroir. It becomes clear that acts of celebration of and gratitude for food, particularly in connection with a specific place or line of heritage, play necessary roles in the development of our personal identities and in our search for belonging. These stories are based on …

Mobility Justice And Social Capital In Strawberry Mansion And Kensington, Philadelphia Pa, Rebecca Fruehwald

Masters Theses

This thesis explores the theoretical and practical relationship between mobility justice and social capital. A literature review establishes the theoretical relationship through an overview of history and policy. The relationship is then explored through a case study of Strawberry Mansion and Kensington neighborhoods in Philadelphia. These sections are then connected by considering how they are both impacted by the larger system of capitalism. The real-world example of gentrification is given for how all these elements interact and affect each other, and the practical relationship between mobility justice and social capital is established. Finally, policy implementations and paths for possible future …

Exploring Multimedia Storytelling As A Novel Tool To Inspire Americans To Participate In Wildlife Conservation, Megan Brief

Masters Theses

Human and nonhuman animal lives are intimately entangled. In the age of the Anthropocene, it is imperative to reexamine our proximity and kinship with nature. Human-wildlife conflict can evolve into coexistence through conservation efforts marked by creativity and compassion. To inspire conservation action among North American audiences, we must enact novel ways of disseminating scientifically technical concepts. Multimedia storytelling can encourage equitable involvement among lay participants in conservation spaces. When inclusive of Indigenous knowledges, and conscious of damage narratives, such innovative stories can empathetically communicate wildlife degradation and injustices, as well as animate vulnerable human and nonhuman communities.

Sensuous Knitting: Making Practice That (Re)Members Ecological Entanglement, Sarah Manion

Masters Theses

Conceptualizing the climate crisis as a system of broken relationships calls for a broader understanding of entangled ecological interrelationality. Developing deep and effective responses relies on a stamina for complexity grounded in a recognition and acknowledgement of the way ecological entanglements are revealed to us. Within this frame, practice may provide unique opportunity for the development and promotion of this attuned awareness. To explore this possibility, the personal practice of sensuous knitting is used in this thesis as a way to demonstrate the intersections between intellectual modes of understanding and embodied forms of knowing. Using elements of autoethnographic narration of …

Growing Quelites In The City: Exploration On Memory And Food Sovereignty In Mexico City, Paola Valeria Ramirez Ensastiga

Masters Theses

In Mexico, as in the world, the number of people living in urban areas is increasing. In addition, urbanization directly generates a fragmentation of the natural habitat and causes the loss of biodiversity. Native edible crops are also being threatened by a constant decline in biodiversity, causing negative ecological, economic and even cultural impact. Until now, the main guardians of the edible biodiversity have been indigenous peoples. Several authors agree that the way in which indigeous people relate to nature may shed some light on how to face the ecological and climate crisis that we are experiencing today. I argue …

Carbon Metabolism In Cave Subaerial Biofilms, Victoria E. Frazier

Masters Theses

Subaerial biofilms (SABs) grow at the interface between the atmosphere and rock surfaces in terrestrial and subterranean environments around the world. Multi-colored SABs colonizing relatively dry and nutrient-limited cave surfaces are known to contain microbes putatively involved in chemolithoautotrophic processes using inorganic carbon like carbon dioxide (CO₂) or methane (CH₄). However, the importance of CO₂ and CH₄ to SAB biomass production has not been quantified, the environmental conditions influencing biomass production and diversity have not been thoroughly evaluated, and stable carbon and nitrogen isotope compositions have yet to be determined from epigenic cave SABs. …

Conservation Of Terrestrial Salamanders Through Hemlock Woolly Adelgid Management In Eastern Hemlock Forests Within Great Smoky Mountains National Park, Jonathan Lawrence Cox

Masters Theses

Hemlock woolly adelgid (Adelges tsugae; HWA), an invasive aphid-like arthropod, was first documented on the east coast of the United States in the 1950s. HWA is an herbivore which primarily feeds at the needle base of hemlock tree species (Pinaceae: Tsuga). With no evolutionary defenses and few biotic controls, the eastern and Carolina hemlock (Tsuga canadensis and Tsuga carolinensis) serve as the primary diet of HWA in eastern North America. The invasive pest began to spread rapidly throughout the hemlock’s range causing defoliation and death of the trees within 4 – 10 years. With the …

Utilization Of Raman Spectroscopic Techniques For Forensic Science Applications, Alyssa Rose Daniel

Masters Theses

In the field of forensic science, it is important to have reliable, accurate, and nondestructive testing methods for evidence collection and testing. Current methods, such as gas chromatography-mass spectrometry (GC-MS) and high-performance liquid chromatography (HPLC), are destructive to evidence and require lengthy sample preparation. Because of its nondestructive nature, specificity, and portability, Raman spectroscopy has been increasingly improving forensic science. The goal of this work is to expand on the growing pool of knowledge of forensics related Raman applications.

One problem that has plagued forensic scientists for years is how to accurately identify the time since death, or post-mortem interval. …