Physical Sciences and Mathematics Commons^™

Improving Conservation And Recreation In Environments Shared By Humans And Bats, Hannah Shapiro

Masters Theses

White-nose syndrome (WNS) has drastically changed how caves are managed in the United States. This disease has killed millions of bats throughout eastern North America and continues to spread westward. Since the discovery of WNS, The U.S. National Park Service (NPS) has acted to slow the spread of the disease through the development of educational programs and the deployment of decontamination measures. Despite the vast array of research on the biological and ecological aspects of bats and WNS, few studies focus on how visitor attitudes and knowledge of management strategies implemented in response to WNS impact the effectiveness of these …

Late Paleozoic Ophiuroid Biodiversity Based On A Diverse Fauna From The Indian Springs Shale Member Of The Big Clifty Formation, Sulphur, Indiana, Usa, Nicholas Scott Smith

Masters Theses

Ophiuroids (brittle stars and basket stars) are a diverse echinoderm group (i.e. star fish, sea urchins, and sea lilies) found in almost all marine environments and often major components of seafloor communities. Originating in the early to middle Devonian, the group quickly diversified and is today the most species rich echinoderm clade. Unfortunately, our knowledge of their diversity and evolutionary pathways during the Late Paleozoic has been understudied leaving a large gap in our understanding of their true biodiversity. This can be attributed to study methods and a poor understanding of Paleozoic ophiuroid skeletal morphology. Ophiuroid skeletons are composed of …

From Drones To Soil Cores: Comprehensive Ecological Assessments For Enhancing Conservation Management Of Urban Forested Natural Areas, Mia T. Wavrek

Masters Theses

Urban natural areas are vegetated areas within cities that exhibit characteristics of non-urban natural areas in that they have relatively high levels of self-regulation (low or no level of management) of natural ecosystem processes and exhibit high taxonomic, genetic, and structural diversity. When these areas take the form of urban parkland, they are often managed for their social benefits to urban residents, while their ecological potential remains underutilized. Growing interest in enhancing biodiversity conservation in cities has highlighted the importance of improving the ecological planning and management of urban natural areas, particularly forested natural areas. For the variety of agencies …

Synthesis Of Well-Defined Binary Mixed Brushes On 20 Nm Silica Nanoparticles And Asymmetrically End- Functionalized Semicrystalline Poly(Ε-Caprolactone)S, Andrew J. Chancellor

Masters Theses

Well-defined polymers and polymer brushes play an important role in the understanding of their behavior under various conditions and in the fabrication of nanostructured functional materials. This Master’s thesis work focuses the synthesis of two well-defined systems: binary mixed homopolymer brushes grafted on 20 nm silica nanoparticles (NPs) for understanding their microphase separation behavior and asymmetrically end-functionalized semicrystalline poly(- caprolactone) polymers for use in the fabrication of multicomponent polymer brushes on flat substrates with various architectures. While theoretical and simulation studies have revealed intriguing morphologies of mixed homopolymer brushes grafted on nanospheres with a size similar to those of grafted …

Electron Microprobe In Situ Monazite Dating Of The Slide Lake Shear Zone, Jeremy Leierzapf

Masters Theses

The Colorado mineral belt (CMB) shear zone system records Proterozoic deformation episodes documenting the progressive tectonic accretion of Laurentia. Regional fold formation (D₁ & D₂) is coeval with the ca. 1700 – 1600 Ma Yavapai and Mazatzal orogenies, while Mesoproterozoic sub-vertical shear zones (D₃ & D₄) are a response to 1450 – 1300 Ma intracontinental deformation. The Slide Lake shear zone (SLSZ) is a sub-horizontal shear zone located in the Northern Sawatch Range, central Colorado. Aside from its orientation, the SLSZ records similar deformational structures to other shear zones in the CMB, but there …

Agricultural Irrigation Induced Evaporation In A Temperate Study Area: A Stable Isotope Approach, Lincoln Grevengoed

Masters Theses

In regions where groundwater is used for irrigation, significant water losses take place due to evaporation. Previous studies demonstrated the utility of stable oxygen and hydrogen isotopes in estimating evaporative water loss experienced during return flow back to an aquifer. Unlike arid regions where the other studies took place, this study examined the region around Kalamazoo, Michigan, the United States, which experiences a more temperate climate. Irrigation in the Kalamazoo area primarily uses center-pivot systems supplied by wells, unlike flood irrigation in previous study areas. Water samples were taken periodically from wells close to center-pivot irrigation systems. Water losses due …

Synthesis And Biological Evaluation Of Azide- Tagged Biomimetic Probes For Global Labeling Of The Saccharomyces Cerevisiae Glycerolipidome, Matthew R. Johnson

Masters Theses

Lipid metabolism is an extremely complex, interconnected process that, when dysregulated, is strongly linked to cellular disease states including cancer. Study of these metabolic processes is complicated by the characteristic intricacy of these systems; nonetheless, it is achievable through metabolic labeling. Visualization of biosynthesis is an advantage offered by metabolic labeling through the incorporation of fluorescent tags. In this technique, synthetic probes bearing a clickable tag such as azide are fed into live cells where they are directly incorporated using the native enzymatic and cellular processes to metabolically label lipid products. These labeled lipid products are capable of being studied …

Towards Development Of A Remote Charting System For Connected Healthcare, Alex Bodurka

Masters Theses

Health Care Providers play a crucial role in a patients well-being. While their primary role is to treat the patient, it is also vital to ensure that they can spend adequate time with the patient to create a unique treatment plan and build a personal relationship with their patients to help them feel comfortable during their treatment. Health Care Providers are frequently required to manually record patient data to track their healthcare progress during their hospital stay. However, with hospitals continuously trying to optimize their workflows, this crucial one-on-one time with the patient is often not practical.

As a solution, …

Confronting Wicked Crypto: Wicked Problems, Encryption Policy, And Exceptional Access Technology, Kevin Nicholas Kredit

Masters Theses

Public debate has resumed on the topic of exceptional access (EA), which refers to alternative means of decryption intended for law enforcement use. The resumption of this debate is not a renege on a resolute promise made at the end of the 1990s “crypto war”; rather, it represents a valid reassessment of optimal policy in light of changing circumstances. The imbalance between privacy, access, and security in the context of constantly changing society and technology is a wicked problem that has and will continue to evade a permanent solution. As policymakers consider next steps, it is necessary that the technical …

Information Theory Problem Description Parser, Gary Brent Hurst

Masters Theses

Data corruption and data loss create huge problems when they occur, so naturally safeguards are usually in place to recover lost data. This often involves allowing less space for data in order to allow space for an encoding that can be used to recover any data that might be lost. The question arises, then, about how to most efficiently implement these safeguards with respect to storage, network bandwidth, or some linear combination of those two things. This work has two main goals for the information theory community: to produce an intuitive-to-use problem description parser that facilitates research in the area, …

An Explicit Asymptotic Approach Applied To Neutrino-Electron Scattering In The Neutrino Transport Problem, Aaron Michael Lackey-Stewart

Masters Theses

This thesis presents results of explicit asymptotic calculations applied to neutrino-electron collisions in the neutrino transport problem; a problem that is generally solved using implicit methods when simulating core collapsed supernovae. It is shown that the explicit asymptotic method provides stable solutions to these stiff systems of equations while also yielding comparative accuracy and time stepping to standard implicit treatments such as Backward Euler, Fixed Point Iteration, and Anderson Accelerated Fixed Point. Because implicit methods are found to be less efficient for large systems of stiff, coupled equations, these results could help cut costs in solving this problem while also …

Random Search Plus: A More Effective Random Search For Machine Learning Hyperparameters Optimization, Bohan Li

Masters Theses

Machine learning hyperparameter optimization has always been the key to improve model performance. There are many methods of hyperparameter optimization. The popular methods include grid search, random search, manual search, Bayesian optimization, population-based optimization, etc. Random search occupies less computations than the grid search, but at the same time there is a penalty for accuracy. However, this paper proposes a more effective random search method based on the traditional random search and hyperparameter space separation. This method is named random search plus. This thesis empirically proves that random search plus is more effective than random search. There are some case …

Investigating The Ecology And Behavior Of The Indiana Bat And Tri-Colored Bat During Fall Swarming And Spring Staging, Mallory E. Tate

Masters Theses

White-nose syndrome has devastated bat populations across North America since 2005. Due to declines in Indiana bat (Myotis sodalis) and tri-colored bat (Perimyotis subflavus) populations across the eastern United States, management prescriptions need to consider all seasons of these species annual cycles. However, data is severely lacking on the two seasons surrounding winter hibernation. These include fall swarming, a time period when bats are mating and preparing for hibernation, and spring staging, when bats are emerging from hibernation and preparing for spring migration. Both periods are critical for successful reproduction and survival following white-nose syndrome infection. …

High-Resolution Timeseries Analysis Of Dynamic Geochemistry: A 27-Well Survey Of Contaminated Groundwater Downstream Of The Former S-3 Ponds, Oak Ridge, Tennessee, Emma Dixon

Masters Theses

Spatiotemporal variability of geochemistry of contaminated groundwater has large implications on overall water quality and ability to respond to remedial applications. Gaining knowledge of how geochemistry changes over time in an area can help establish response trends to changing external conditions like weather and level of contamination. In this study, a spatiotemporal survey was performed on 27 wells at the Y-12 Complex in Oak Ridge, Tennessee. This was completed to measure diurnal fluxes in geochemistry from seasonal changes and extreme weather conditions in three areas of historically different contamination levels from a single point contamination source. Measurements were gathered over …

Experimental Study Of The Alteration Of Basalt On The Surface Of Venus, Hannah Teffeteller

Masters Theses

Venus is the second planet from the sun, distinguished by its thick atmosphere which prevents visible observations of the surface. Our understanding of its surface is therefore dominated by surface interactions with electromagnetic radiation (e.g. radar, visible-to-infrared, and X-ray wavelengths) which have been collected by a series of missions including the Soviet’s Venera missions, the National Aeronautics and Space Administration’s (NASA) Magellan mission, and the European Space Agency’s (ESA) Venus Express orbiter (Barsukov et al. 1982; Head et al. 1992; Smrekar et al. 2010). The atmosphere of Venus is composed almost entirely (~97%) of CO2 gas with trace amounts of …

Influence Of Living Plant Roots And Mycorrhizal Hyphae On Soil Hydraulic Properties, Katelyn M. Marcacci

Masters Theses

The interrelationships between vegetation, soil, and water are fundamental in evaluating the projected impacts of global climate change. Many predictive models require soil hydraulic parameters as inputs. As most hydraulic parameter datasets are for repacked soil, the influence of vegetation on hydraulic parameters is not thoroughly understood. Living roots and mycorrhizal fungi cause physicochemical alterations in soils. Quantifying how vegetation influences soil hydraulic parameters is necessary to more accurately simulate soil water dynamics in climate models.

Laboratory experiments were conducted to test if the presence of roots and roots inoculated with mycorrhizal fungi have a significant effect on the saturated …

A Privacy Evaluation Of Nyx, Savannah A. Norem

Masters Theses

For this project, I will be analyzing the privacy leakage in a certain DDoS mitigation system. Nyx has been shown both in simulation and over live internet traffic to mitigate the effects of DDoS without any cooperation from downstream ASes and without any modifications to current routing protocols. However it does this through BPG-poisoning, which can unintentionally advertise information. This project explores what the traffic from Nyx looks like and what information can be gathered from it. Specifically, Nyx works by defining a deployer/critical relationship whose traffic is moved to maintain even under DDoS circumstances, and I will be evaluating …

Analysis Of Interdunal Wetlands And Ecosystem Dynamics Using Uas And Obia In Ludington State Park, Michigan, Claire Gilbert

Masters Theses

The Great Lakes sand dunes are the world's largest freshwater dune complex. There is a functional relationship between coastal wetlands and freshwater sand dune, referred to as interdunal wetlands. Interdunal wetland systems are highly dynamic and change dramatically seasonally and annually. Using geographic information systems (GIS) and unoccupied aerial systems (UAS), this thesis project is focused on understanding the spatial distribution of sparse and dense vegetation, and abiotic influence such as distance to coast, slope, and aspect influence interdunal wetland stability within a Great Lakes shoreline dune system. Object-based image analysis (OBIA) classification results extracted meaningful vegetation densities of growth …

Assessing The Robustness And Versatility Of Nanojars For Anion Binding, Mia Lily Ann Jawor

Masters Theses

Supramolecular chemistry is a field in chemistry that focuses on intermolecular bonds in a “host-guest complex” or supramolecular assemblies. Nanojars are supramolecular assemblies of the formula [anion⊂{Cu(μ-OH)(μ-pz)}_n] (n = 27‒33) which incarcerate kosmotropic anions, such as carbonate (CO₃^2‒), sulfate (SO₄^2‒) and hydrogen phosphate (HPO₄^2‒). Nanojars consist of three [Cu(μ-OH)(μ-pz)]_x (x = 6‒14, except 11) rings that are assembled similarly to Matryoshka dolls, where the top and bottom rings act as guests for the central ring. The larger central ring is bound to the two smaller rings by multiple …

A Framework To Support Automatic Certification For Self-Adaptive Systems, Ioannis Nearchou

Masters Theses

Presently, cyber-physical systems are increasingly being integrated into societies, from the economic sector to the nuclear energy sector. Cyber-physical systems are systems that combine physical, digital, human, and other components, which operate through physical means and software. When system errors occur, the consequences of malfunction could negatively impact human life. Academic studies have relied on the MAPE-K feedback loop model to develop various system components to satisfy the self-adaptive features, such that violation of the safety requirements can be minimized. Assurance of system requirement satisfaction is argued through an industrial standard form, called an assurance case, which is usually applied …

Investigating The Effects Of Tethered, Axial Lewis Base Coordination On Rhodium(Ii) Paddlewheel Complexes, William A. Sheffield

Masters Theses

Dirhodium(II) paddlewheel complexes are highly renowned for their use in diazo decomposition to form a metallic-carbenoid species. This species has been used for a diverse range of chemical transformations including cyclopropanation, cycloproprenation, C-H functionalization, and X-H (Si, S, O, N) insertion reactions. Modulation of these catalysts traditionally involve the exchange of bridging ligands which have profound effects on the catalyst's reactivity, chemo, and enantioselectivity. Recent interest has turned towards to modifying the axial sites present in the complex as an additional means of modulating catalytic activity. These sites normally serve as the active site of the catalyst, but coordination of …

Empirical Modeling Of Used Nuclear Fuel Radiation Emissions For Safeguards Purposes, Amanda M. Bachmann

Masters Theses

For nuclear nonproliferation safeguards, the ability to characterize used nuclear fuel (UNF) is a vital process. Fuel characterization ^allows for independent verification by inspectors of operator declarations of the special nuclear material flow and nuclear related activities within a facility, and an estimation of fissile material remaining in a fuel assembly. Current methods to verify this information rely heavily on non-destructive assay techniques, such as gamma spectroscopy and neutron detection measurements. While these measurements are effective tools for estimating a specific characteristic of the fuel, such as burnup or cooling time, they often require an accurate estimation of a select …

Improving Convolutional Neural Network Robustness To Adversarial Images Through Image Filtering, Natalie E. Bogda

Masters Theses

The field of computer vision and deep learning is known for its ability to recognize images with extremely high accuracy. Convolutional neural networks exist that can correctly classify 96\% of 1.2 million images of complex scenes. However, with just a few carefully positioned imperceptible changes to the pixels of an input image, an otherwise accurate network will misclassify this almost identical image with high confidence. These perturbed images are known as \textit{adversarial examples} and expose that convolutional neural networks do not necessarily "see" the world in the way that humans do. This work focuses on increasing the robustness of classifiers …

Sustained Release Of Persulfate And Iron(Ii) Ions From Inert Inorganic Materials For Groundwater Remediation, Peter Pham

Masters Theses

Contamination of groundwater, initiated from years of human negligence, continues to persist despite major advancements in water remediation technologies. The generated groundwater plumes can continuously replenish contaminants such as dense nonaqueous phase liquids (DNAPLs) through the aid of slow-moving water. Thus, long- term treatment of this flow system has proven to be problematic. A selection of sophisticated sustained diffusion technologies is needed to help prevent further damage to this prominent freshwater source. Here, a novel in-situ chemical oxidation (ISCO) method was designed to incorporate persulfate into silica mediums such as zeolite, diatom, and silica flour for the treatment of groundwater …

Using Historical Maps For Contaminated Site Identification And Prediction, And Environmental Justice Implications: A Case Study In Grand Rapids, Michigan, Dana Heusinkveld

Masters Theses

As the production of synthetic chemicals has grown in the past centuries to increase production, lower costs, and generally make our lives more convenient, detecting and understanding the environmental impacts of these compounds has lagged significantly behind their mass production and wide-spread use. To combat this trend, sources of these contaminants, especially those that have been removed from the landscape, need to be quickly identified to make mitigation and remediation efforts more effective. In this study, historical Sanborn maps are used to extract and digitize historical site/land use in Grand Rapids during the early 1900s through the practical application of …

An Analysis Of Large Displacement Pneumatic Slug Tests For The Characterization Of Aquifer Parameters – Guidelines For An Alternative Field Procedure, Madison E. Wayt

Masters Theses

Variations in hydraulic conductivity (K) between larger scale aquifer tests and smaller scale slug tests, and within individual aquifer tests, have been linked to method bias and aquifer heterogeneity. The impacts of varying slug sizes on K, which represents K dependence on a smaller scale, is not as well understood. To examine the relationship between K and slug size, a series of slug tests with a range of initial displacements were performed in three intermediate to high K, unconfined aquifers encompassing homogeneous, mildly heterogeneous, and moderate to highly heterogeneous conditions. Slug test estimated K values at Asylum Lake are compared …

Field And Numerical Evaluation Of Nitrogen Transport From Septic Systems In Surfical Aquifer Systems To Charlotte Harbor, Florida, Tanten T. Buszka

Masters Theses

Shallow water tables in coastal surficial aquifers limit effective treatment of septic effluent which can result in excess nutrient loading into nearby surface water bodies. Approximately 45,000 septic systems in Charlotte County, Florida transmit effluent into an under studied surficial aquifer and contribute to harmful algal blooms and outbreaks of E. coli. An undeveloped field site was characterized using standard hydrogeologic methods, including a one-year duration natural gradient tracer test, to obtain representative lithology of the sandy surficial aquifer and estimates of groundwater velocity, flow directions, effective porosity and dispersion. These data were used to support the development of a …

Distribution And Variability In Sulfur Isotopes Within Paleoproterozoic Metasedimentary Strata Of The Michigamme Formation, Upper Peninsula, Michigan, Beau J. Haag

Masters Theses

In the Upper Peninsula of Michigan, the Paleoproterozoic Michigamme Formation is composed of a thick package of metasedimentary rocks derived from foreland basin sediments which were deposited during the 1.8Ga Penokean Orogeny. These rocks contain significant, but variable amounts of texturally distinct sulfide minerals such as pyrrhotite and pyrite. We report a systematic relationship between δ³⁴S values from sulfide mineral occurrences, and their stratigraphic locations regardless of texture and mineral composition. We suggest the sulfide minerals within the Michigamme Formation have inherited δ³⁴S values from early sedimentarydiagenetic sulfides, therefore preserving primary isotopic signatures. The observed stratigraphic …

An Analysis Of Factors Influencing Chemistry Students’ Choice Of Major And Career, Jennifer Marie Ribble

Masters Theses

In recent years there has been a push to increase the number of STEM graduates in the United States in order for the nation to retain its position as a global leader in the sciences. If educators are to address recruitment and attrition issues in STEM fields it is important to understand student perspectives related to choosing both a major and a career in chemistry. The present study explores the decision-making process students utilize to choose chemistry as a major and as a career, their perception of what careers are available to someone with a degree in chemistry and what …

Values Of Artificial Intelligence In Marketing, Yingrui Xi

Masters Theses

“Artificial Intelligence (AI) is causing radical changes in marketing and emerging as a competent assistant supporting all areas of the marketing field. The influences and impacts AI has created in various marketing segments have aroused much interest among marketing professionals and academic scholars. Comprehensive and systematic studies on the values of AI in marketing, however, are still lacking and the existing literature fragmented. This research provides a comprehensive review of the existing literature in the relevant fields as well as a series of systematic interviews using the Value-Focused Thinking approach to understand the values of AI in marketing. This research …