Physical Sciences and Mathematics Commons^™

Design And Analysis Of Asynchronous Adders, Khalid Khanfar

Masters Theses

The aim of this study is to come up with a fast adder suitable for use in self-timed subsystems. 7 adders were evaluated.

The findings from this study indicated that a Conditional Sum Adder (CSA) is the best candidate for high speed addition. One of the two resulting adders was given the name High Speed Conditional Sum Adder (HSCSA) .

A Hydrogeochemical Characterization Of A Glacial-Drift Aquifer System In Southwest Michigan, Patrick G. Barrese

Masters Theses

A hydrogeochemical investigation of the Schoolcraft Aquifer, an unconfined, glacial-drift aquifer located in southwest Michigan, was undertaken to focus on three topics: (1) the geochemical definition of recharge and discharge zones both vertically and laterally along projected flow paths, (2) the description of the carbonate and redox chemical systems, and (3) groundwater degradation associated with excessive nitrate, ammonium, and chloride concentrations.

The results of the study were inconclusive in defining recharge and discharge zones; however, iron and alkalinity concentrations were identified as possible indices for recharge and discharge conditions. The carbonate analysis indicated that the aquifer is saturated with respect …

An Analysis Of Hydrogeologic Factors Affecting Aquifer Vulnerability In Southwestern Michigan, Steven E. Benton

Masters Theses

In southwestern Michigan aquifers are threatened by human activities. Parameter/factor weighting systems are used to rate aquifer vulnerability. Hydrogeologic factors affecting aquifer vulnerability were investigated in this study.

Well records, soil surveys, hydrogeologic reports, and partial chemical analyses were used to obtain data on the aquifers, soil types, glacial sediments, and types of contaminants. Data analysis included comparisons of means and medians, factor analysis, and Pearson and Spearman Correlation analysis.

The results indicate that the aquifers in Kalamazoo County are not protected. Depending on the type of glacial sediment, hydrogeologic factors that protect aquifers are clay thickness and the depth …

Fractures In The Jacobsville Sandstone And The Precambrian “W” Rocks In Eastern Marquette County, Michigan, Leonard Paul Belliveau

Masters Theses

The major fracture systems in the Jacobsville sandstone likely originated by reverse faulting on the Keweenaw fault and by glacially produced thrusting. Fracture orientations, apertures, and spacings are uniform in the Jacobsville sandstone and Lighthouse Point member of the Mona Schist, and are variable in the Lower member of the Mona schist and Compeau Creek gneiss. Fracture sets in the Compeau Creek gneiss exist in domains separated by metadiabase dikes. The metadiabase dikes relieved the strain produced by the Penokean orogeny by fracturing. Fractures present in inclusions, quartz veins, metadiabase and diabase dikes can be used to temporally evaluate the …

Inhibited Spontaneous Emission By Photonic Band Gaps In A Square Lattice Of Periodic Dielectric Medium, Abdullah Al-Ghamdi

Masters Theses

The concepts of band theory for electrons can be employed to describe the behavior of electromagnetic waves propagating in two-dimensional, periodic dielectric structures. These two-dimensional, periodic structures can produce photonic band gaps in which the spontaneous emission by atoms embedded in the structure is prohibited and as a result the performance of many semiconductor devices can be enhanced. The calculations are based on finding the eigenvalues of the algebraic equation for the frequencies of electromagnetic waves moving in a square lattice composed of square dielectric rods with different dielectric constants.

Micellar Catalysis Of Hydrolysis Of Substituted Hydroxamic Acids With Perfluorooctanoic Acid, Zhongyuan He

Masters Theses

The work demonstrated the effects of differently located and substituted phenyl groups, as well as aliphatic groups in the hydroxamic acids, on micellar catalysis with perfluorooctanoic acid as the reactive counterion surfactant in aqueous acetonitrile solution.

Kinetic rate constant-surfactant concentration profiles for the decano-, 2,5-dimethylphenylaceto-, 4-isopropylphenylaceto-, 4-phenylbutano-, and 6-phenyl-hexanohydroxamic acids were examined and analysis on the data obtained were reported.

The pseudo-phase ion exchange (PPIE) model has been satisfactorily applied to explain the observed micellar effects.

Further investigation into more appropriately substituted hydroxamic acids is suggested in order to obtain a more complete set of data and further evaluation.

Location Analysis Of The Recycling Drop Off Program In Knox County, Tennessee, Carol Michelle Donoghue

Masters Theses

This study examines the drop-off recycling program in Knox County, Tennessee, in order to evaluate the convenience of the drop-off site locations. Measures of convenience were distance, level of recycling participation, and location of the site. Surveys were administered to 461 individuals participating in the program at the three Convenience Centers with drop-off recycling facilities. The spatial analysis compared the drop-off locations to the development patterns of the surrounding area.

The survey results indicate that more people are recycling now than before the beginning of the drop-off program. More than half of those surveyed recycle at least once a week …

Eta Photoproduction Via 2H(Γη)2H*, Yan Zhang

Masters Theses

The reaction H(γη)²H^* is studied using the impulse approximation. A recent fit to the H(γη)²H^* elementary amplitude is employed in the calculation. The n-p final state is described by Reid's soft core potentials. The calculation shows very different cross sections for the final isospin 0 and isospin 1 break-up channels. The S₁₁ resonance is demonstrated to dominate the eta cross sections in the 740 MeV photon laboratory energy region. Fermi motion in the deuteron does not significantly spread the effect of the S₁₁ . All these results demonstrate that the reaction H(γη) …

Time Delay Neural Networks And Speech Recognition: Context Independence Of Stops In Different Vowel Environments, Gregory Andrew Makowski

Masters Theses

A series of speech recognition experiments was conducted to investigate time-dynamic speech recognition of stop consonants invariant of vowel environment using data from six talkers. The speech preprocessing was based on previous studies investigating acoustic characteristics which correlate to the place of articulation (Blumstein and Stevens 1979). The place of articulation features were statistically abstracted using four moments and the energy level of the speech sample.

Both statistical and neural network pattern recognition methods were used. Statistical methods included linear and quadratic discriminant functions, maximum likelihood estimator (MLE) and K-nearest neighbors (KNN). The neural network approach used was Time Delay …

Basement Control On The Development Of Selected Michigan Basin Oil And Gas Fields As Constrained By Fabric Elements In Paleozoic Limestones, Robert Thomas Versical

Masters Theses

Hydrocarbon bearing structures in the Paleozoic section of the Michigan basin possess different structural styles and orientations. Quantification of the direction and magnitude of shortening strains by applying a calcite twin-strain analysis constrains the mechanisms by which these structures may have developed. The calcite twin-strain analysis and fracture orientations in Paleozoic rocks indicate that the mean direction of compression controlling structural development ranged from SE-NW to nearly E-W. This direction of compression nearly parallels the majority of structures in the basin, and provides insight into their origin.

The structural geometries of fields considered in this study can be explained by …

A Valence Quark Model, Tony A. Forest

Masters Theses

A quark model of the baryons has been developed for calculating properties of nucleons which can be useful in nuclear interactions. A Hamiltonian, motivated by QCD, was diagonalized in a harmonic oscillator basis. In addition to predicting the proton charge radius and Delta-Nucleon mass difference, this work also yields a value of the axial vector coupling constant which compares well with experiment. Electric and magnetic form factors represent the major success of this model. The electromagnetic transitions predicted by this model compete well with other models but are not able to reproduce experimental results completely. The advantage of this model …

Double Ionization Of Helium By Intermediate To High Velocity He+ Projectiles, Jun Forest

Masters Theses

Ionization of helium target atoms by He⁺ projectiles colliding with helium at energies of 0.125 to 3.0 MeV/u is investigated. Cross sections for single and double ionization, and ratios o f double-to-single ionization are determined for each outgoing projectile charge state, and are compared to previous studies. For the lowest energies investigated, the ratios are consistent with the two-step mechanism in which the projectile interacts separately with each target electron. At the highest energies, the ratios reach nearly constant values indicating approach to the high velocity limit. At these high energies, however, the ratios are all higher than the …

Facies Analysis And Diagenesis Of The Lower Engadine Group And The Manistique Group In Manistee, Mason And Oceana Counties, Michigan, Karen S. Mater

Masters Theses

Three lithofacies in the Lower Engadine Group, and four lithofacies in the Manistique Group were identified. Facies patterns suggest a transgression during deposition of the Manistique Group and Lower Engadine Group.

Environments of deposition were determined by analysis of facies found in the Lower Engadine and Manistique Groups using available cores, petrophysical logs, and well cuttings. The diagenetic sequence of events was identified using thin sections.

Diagenesis has greatly altered original fabric and porosity. Hydrocarbon accumulation in these units is dependent on facies distribution, diagenesis, and structural features.

Resonant Electron Transfer And K-Shell Excitation Of FQ+ (Q=6,8) In Collisions With Neutral He And H2 Targets, Konstantinos E. Zaharakis

Masters Theses

Measurements of resonant transfer and excitation (RTE) were conducted for 16.5-38 MeV F⁶⁺ (Li-like) ions colliding with H₂. In the RTE process electron capture and projectile excitation take place simultaneously due to the electronelectron interaction. In previous work, for the same collision system, at the Oak Ridge National Laboratory (Oak Ridge, TN) , the magnitude of the measured RTE cross sections was found to be nearly a factor of two smaller than theory. In order to investigate RTE in F⁶⁺ H₂ collisions more completely, we undertook measurements at Western Michigan University using the EN tandem …

Reactivities Of Some Aromatic Compounds At Supercritical Water Conditions, Chun-Cheng Tsao

Masters Theses

The goals of this study are the removal of nitrogen from the extraction products of coal by Supercritical Water and the development of an understanding of the reactions leading to this removal. Six model compounds with structures similar to the intermediates of the coal liquefaction processes were studied. Benzylamine generated toluene through hydrogen abstraction after the C-N bond rupture. To a lesser extent, the oxidation of the benzylic carbon took place leading to benzene formation. Both reaction pathways occurred with equal probability for benzylidenebenzylamine, producing comparable yields of benzene and toluene. Benzaldehyde generated benzene through the oxidation/decarboxylation sequence. Benzyl alcohol …

Two Lithotectonic Boundaries In Western North Carolina: Geologic Interpretation Of A Region Surrounding Sylva, Jackson County, Michael Joseph Quinn

Masters Theses

Understanding the geology of any region begins with the construction of high-quality geologic maps. As maps for a specific region are revised in greater detail, geologic understanding is improved. This study involved detailed geologic mapping (at the scale of 1 : 24,000) of a portion of the southern Appalachian Blue Ridge that was previously only mapped by reconnaissance. It is hoped that the research herein will add to the present understanding of the Blue Ridge province and of the entire Appalachian orogenic belt.

During the course of field mapping, three lithotectonic units were divided, each separated from the others by …

The Effects Of Urbanization On A Portion Of The Portage Creek Watershed: A Case Study On Surface Water And Groundwater Quality, Susan E. Rezek

Masters Theses

The surface water and groundwater quality in the study area of the Portage Creek watershed was analyzed to determine the possible effects of urbanization. Dry weather and wet weather surface water and groundwater samples were collected from June 1986 to November 1986 at selected stations in the watershed.

Water samples were analyzed for 26 inorganic and organic parameters. Most concentrations were below analytic method detection limits. The analytical data indicate that sodium and chloride are the principal contaminants resulting from urbanization. The probable source of the contamination is deicing salt applied to the City of Portage, Michigan streets.

Overall, the …

Diagenesis In The St. Peter Sandstone, Michigan Basin, Carl E. Lundgren

Masters Theses

The petrographic evolution of authigenic minerals in the St. Peter formation consists of: early marine cement, syndepositional dolomite, quartz overgrowth cement, pervasive dolomite replacement of precursor carbonate, dissolution of framework grains and carbonate cements, and late formation of authigenic chlorite and illite.

Variations in the diagenetic sequence were templated by variations in primary mineralogy related to depositional facies. Early intergranular carbonate cement, common in shelf facies, precluded early quartz cementation. Subsequent dissolution of dolomite and detrital grains may be temporally and chemically related to the precipitation of authigenic clay in dissolution pores. In peritidal facies, pervasive quartz cementation was locally …

A Regional Study Of Ground-Water Quality In Barry County, Michigan, Margene K. Brewer

Masters Theses

A regional study of ground-water quality in Barry County, Michigan was conducted using a computerized database from the Science for Citizens Center at Western Michigan University in Kalamazoo, Michigan. The database, initiated by the Michigan Groundwater Survey, consists of residential well logs and chemical analyses of samples collected from residential wells by the Barry County Health Department. Qualitative and statistical analyses of the data indicate that the glacial drift aquifer is recharging the bedrock aquifer throughout most of the county. Groundwater quality appears to be controlled mainly by the open-system dissolution of carbonate minerals. The water chemistry is also influenced …

Sedimentology Of The Bedford-Berea Sequence (Early Mississippian), Williams Field, Michigan, David Alan Balthazor

Masters Theses

The Berea Sandstone has produced in excess of 1.6 million barrels of oil in the Williams field since discovery in 1980. Seven lithofacies are identified from conventional core in the Bedford-Berea sequence. These facies are interpreted as deltaic deposits comprising prodelta (Bedford Shale), delta front, destructive marine shale, abandoned distributary channel-fill, interdistributary bay-fill, transgressive marine sandstone, and marine shale (Sunbury Shale) facies. Passive channel-fill facies truncate reservoir sandstone bodies and compartmentalize the field NW-SE across the trend of the northwestplunging anticline.

The two reservoir facies in the Williams field are the delta front and transgressive marine sandstones. The sandstone framework …

Effects Of Capillarity On Dnapl Thickness In Wells And In Adjacent Sands, Timothy V. Adams

Masters Theses

Physical model experiments were used to investigate the behavior of dense non-aqueous phase liquids (DNAPLs) in various geologic media.

The objectives of the laboratory investigations were to (a) compare DNAPL thickness in wells to thickness in adjacent sands, (b) observe and interpret dyed DNAPL migration in unsaturated and saturated sands, and (c) study DNAPLs' effects on clay layers.

Two cylindrical glass columns fitted with various well screens were filled with sand, clay layers, water, and dyed DNAPLs in four experiments. Columns were packed with fine or coarse sand and clay layers. Coarse hydrophobic sand was also used.

At equilibrium, DNAPL …

An Analysis Of Dissolved Organic Compounds And Their Contribution To Iron Complexation In The Shallow Leachate Plume Of The West Kl Landfill Kalamazoo, Michigan, Eric Fahle

Masters Theses

High concentrations of dissolved iron are present in downgradient groundwater samples adjacent to the western border of the West KL Landfill. Analysis by Rudder (1988) of groundwater samples indicates oversaturation of selected iron oxides, iron sulfides and siderite in monitoring wells TW-4 and M3.

Previous research suggests that pyrogallol, gallic acid, tannic acid and similar organic compounds may retard the oxidation of ferrous iron in the shallow leachate plume of the West KL landfill (Rudder, 1988). Present research utilizing solid phase extraction, reverse phase high performance chromatography, Fourier transform IR spectrophotometry, UV/Visible spectrophotometry, and gas chromatography/mass spectroscopy indicate that pyrogallol, …

Sedimentological, Structural, And Organic Geochemical Controls On Natural Gas Occurrence In The Antrim Formation In Otsego County, Michigan, Timothy M. Dellapenna

Masters Theses

The prolific Antrim Formation natural gas reservoir in Otsego County, Michigan, has been examined using core descriptions, X-ray diffraction, petrographic, and geochemical analyses. New stratigraphy nomenclature is proposed for the Antrim and Ellsworth Shales. The Antrim Shale contains two distinctive lithofacies: (1) a fractured, non-bioturbated, silica-rich, organicrich black shale lithofacies; and (2) sparsely fractured, bioturbated, carbonaterich, organic-poor gray-green shale. Gas production comes from the Black shale facies.

Rock-Eval analysis demonstrates that the organic matter is a mixture of types I and II material. Low Tmax (435°C) and vitrinite reflectance (0.41-0.46%) values indicate a submature thermal maturation level. Del 13 carbon …

Flotation Data Sampling Strategies In Archaeological Research: An Experiment At The Elam Site (20ae195), Allegan County, Michigan, Brian David Deroo

Masters Theses

Studies of prehistoric Native American subsistence patterns have benefited greatly from data recovered through the technique of flotation, which allows investigators to recover small scale organic remains which would otherwise be missed using standard excavation procedures. Using data recovered through flotation researchers have been able to more fairly evaluate the role of plant foods, both wild and cultivated, in the aboriginal diet.

A common method of obtaining a flotation sample is to define a column through the center of the cultural feature or midden and removing a specified volume of soil matrix (usually 10 liters) from this column. This thesis …

The Paleoethnobotany Of Schwerdt (20ae127): An Early Fifteenth Century Encampment In The Lower Kalamazoo River Valley, Gregory R. Walz

Masters Theses

Carbonized macrobotanical remains from the Schwerdt Site, an Upper Mississippian sturgeon fishery in the Lower Kalamazoo River Valley are identified and analyzed in terms of their implications for localized subsistence-settlement systems operating during the Berrien Phase in southwestern Michigan. The exploitation of wild plant foods at this limited-activity, spring sturgeon fishery and the environmental composition of the site environs are reconstructed from their representation in flotation samples derived from excavated feature and midden contexts.

Botanical data indicate a strong wetland-aquatic orientation in plant procurement, with aquatic tubers being the primary plant resource exploited at the site. Data from several sites …

Anderson Localization Effects In The Light Transmitted Through A Rough Thin Metal Film, Naimah Mohd. Shafie

Masters Theses

The theory of Anderson localization is used to study transmission enhancements in the diffusely transmitted light through a rough thin metal film. These transmission enhancements arise due to phase coherent effects associated with Anderson localization of surface polaritons and are manifested as a well-defined peak in the angular distribution of the intensity of the diffuse component of the transmitted light for light moving opposite to the specularly reflected beam.

The dependence of the widths and heights of the localization related transmission peak is investigated with computer programming and calculations by McGurn and Maradudin (1989). The peak is found to depend …

A Study Of Periphyton, Sediment And Diatom Community Structure As Monitors Of Heavy Metal Pollution In The Embarras River And Brushy Fork, David L. Vaultonburg

Masters Theses

The purpose of this study was to evaluate periphyton (diatom) and sediment heavy metal content and diatom community structure as potential monitors of heavy metal pollution in the upper reaches of the Embarras River system. The study was initiated due to recent industrialization in the area which could potentially contribute to the present heavy metal burden of Brushy Fork and the Embarras River. These streams are already subject to agricultural runoff, wastewater plant effluent, landfill leachate and other miscellaneous urban and highway runoff. The Embarras River system drains an area of approximately 2800 square miles in 11 east-central Illinois counties …

Development Of Ruthenium Vinylbipyridine Modified Electrode Surfaces For Use In Chemiluminescence-Based Detection Systems, Matthew F. Piescinski

Masters Theses

Based upon the chemiluminescent properties of [Ru(bpy)₃]²⁺ and the proven analytical applications of that complex in the detection of easily reduced anions in solution, a chromatographic detection system was designed utilizing an immobilized form of the Ru(ll) complex. The objective was to create, by electropolymerization, a regenerative chemiluminescent surface on a working electrode. Reductive electropolymerization was accomplished by the use of a [Ru(bpy)₃]²⁺ analog containing the ligand vinylbipyridine. Two analogs, [Ru(vbpy)₃][PF₆]₂ and [Ru(phen)₂(vbpy)][PF₆]₂ were polymerized on platinum, glassy carbon and indium-doped tin oxide working …

A Comparison Of Ancient Mathematical And Calendrical Systems, Karen Schlauch

Masters Theses

No abstract provided.

Spatial And Temporal Variations Of Synthetic Organic Compounds In The Contaminant Plume Emanating From The Kl Landfill, Lynn Diane Broede

Masters Theses

Thirty-one synthetic organic compounds have been detected in samples collected from the KL Landfill contaminant plume from March, 1980 to March, 1986. Two groups of organic compounds have been delineated based on their occurrence, concentrations, and persistence throughout the 7-year monitoring period.

Changes in plume geometry and concentration have been studied relative to time, and concentration variations have been related to selected inorganic plume parameters, distance from the landfill, and precipitation. The spatial and temporal distribution of the organic compounds are attributed to biodegradation, three biotransformation sequences, physical properties of the organics and other factors. Three abbreviated anaerobic biotransformation sequences …