Physical Sciences and Mathematics Commons^™

Electrochemical Studies Of Iron, Cobalt, And Nickel Complexes Of Bidentate Phosphine Thioether Ligands, Robert L. Turner

Masters Theses

The electrochemical behavior of a series of cationic complexes, [Ni(S-P)₂]²⁺, [Fe(S-P)₂(CH₃CN)_2.5]²⁺ and [Co(S-P)₂CH₃CN]²⁺, where S-P= (C₆H₅)₂PCH₂CH₂SCH₂CH₃, has been examined in acetonitrile on mercury and platinum electrodes. The nickel compound was reduced in two reversible diffusion controlled, one-electron transfers. Addition of PPh₃ (Ph=C₆H₅) and S-P caused a positive potential shift in the nickel(I) to nickel(0) wave. An EC mechanism was postulated to account for this …

Lithofacies Analysis Of The Lamotte Sandstone In South Central Missouri, Michael Gerard Kraenzle

Masters Theses

"Based on the analysis of thirty-one cores obtained from the Missouri Department of Natural Resources in Rolla, the upper Cambrian Lamotte Sandstone in South Central Missouri has been divided into six sedimentary facies ranging from alluvial fan and braided stream to open marine.

The Lamotte Sandstone is the basal Cambrian sandstone found throughout most of the state of Missouri. It directly overlies late Precambrian (1.4 to 1.5 billion year old) granites and metasediments. The Lamotte and overlying Bonneterre Formations are generally considered to have been deposited by a transgression which occurred during the Late Cambrian Period (Croixian Epoch).

The Lamotte …

Multilist And Inverted File System Performance Measurements, Ashok Chandramouli

Masters Theses

"This study evaluates the multilist and inverted file systems. It describes the structure of the two file system and then proceeds to investigate the performance. The performance is based on quantitative estimates of space requirements for file system, time to retrieve records, time to insert a record, time to delete a record, time to update a record and time to exhaustively read and reorganize the file system. The study then investigates specific situations in which one file system seems to perform better than the other"--Abstract, page ii.

A Proposed C Language Binding For The Graphical Kernel System-3d, Mark Gerard Bolten

Masters Theses

"This thesis introduces a proposed C language binding definition for the International Standards Organization's draft international standard of the Graphical Kernel System-3D. This work augments the earlier C language binding of the two dimensional version of the Graphical Kernel System commonly known as GKS. The proposed function interface will provide a basis for, if not a final, C language binding for the three dimensional version of the Graphical Kernel System"--Abstract, page ii.

The Synthesis And Characterization Of Polycarbonates Based On 1,1'-Dihydroxyethyl-2,2'-Biimidazole, Judith J. Garces

Masters Theses

"The synthesis of polycarbonates formed by the reaction of 1,1'-dihydroxyethyl-2,2'-biimidazole and diphenyl or diethyl carbonates was investigated and the products formed were characterized. The molecular weights of the polymers were dependent on catalyst, ratio of starting materials, nature of carbonate (aromatic or aliphatic) and method of polymerization. Isolated polymers exhibit a linear structure. They have no well-defined melting points (melting pt. range of 280- 330⁰C) indicating low degree of crystallization, and undergo less than 9% decomposition below 200⁰C"--Abstract, page ii.

Medial Axis Transform Using Ridge Following, Richard Mark Volkmann

Masters Theses

"The intent of this investigation has been to find a robust algorithm for generation of the medial axis transform (MAT). The MAT is an invertible, object centered, shape representation defined as the collection of the centers of disks contained in the shape but not in any other such disk. Its uses include feature extraction, shape smoothing, and data compression. MAT generating algorithms include brushfire, Voronoi diagrams, and ridge following. An improved implementation of the ridge following algorithm is given. Orders of the MAT generating algorithms are compared. The effects of the number of edges in the polygonal approximation, shape area, …

Performance Parameter Measurements Of Generic Files, Sankarraman Subramanian

Masters Theses

"This study discusses the performance parameter measurements of generic files, the pile file, the sequential file, the indexed-sequential file, the indexed file and the direct file. The file performance measurements are compiled in a software package. The study then describes the use of such software package as a simulation tool in a file design environment"--Abstract, page iii.

Training For The Airland Battle With Modeling And Simulation On The Microcomputer, David Dean Holmes

Masters Theses

"This paper describes a methodology for modifying a combat training simulation model to include a comprehensive data structure and computer software, to allow the model to be implemented on a microcomputer. It begins by developing a topology for combat simulation models and proceeds to define a data structure suitable for describing military units and facilitating the varied aspects of the simulation. An eclectic approach to the development of the model and the implementing software is followed throughout. Appropriate aspects of a number of models are incorporated into a single model suitable for training military commanders and their staffs. PASCAL, a …

Ethernet Performance: Design And Implementation Study, Michael M. Chaney

Masters Theses

"General concepts concerning local area network designs, functions and topologies will be presented. Ethernet as a multipoint bus topology local area network will be presented in detail. The Carrier Sense Multiple Access/Collision Detect (CSMA/CD) method of fairly regulating access to the shared network bus is studied. The Ethernet Network in relation to the Open Systems Interconnect (OSI) is reviewed, but only the layers pertaining to Ethernet are discussed throughout the majority of the paper. The specifications as described by Xerox, Digital and Intel are presented to help the designer understand the network's physical limitations. Analytical models are used to predict …

Lily: A Parser Generator For Ll(1) Languages, Timothy Topper Taylor

Masters Theses

This paper discusses the design and implementation of Lily, a language for generating LL(1) language parsers, originally designed by Dr. Thomas J. Sager of the University of Missouri--Rolla. A method for the automatic generation of parser tables is described which creates small, highly optimized tables, suitable for conversion to minimal perfect hash functions.

An implementation of Lily is discussed with attention to design goals, implementation of parser table generation, and table optimization techniques. Proposals are made detailing possibilities for further augmentation of the system. Examples of Lily programs are given as well as a manual for the system.

A Paleoenvironmental Study Of The Salem Limestone In The Vicinity Of St. Louis, Missouri, Douglas J. Van Brunt

Masters Theses

“The Salem Limestone (Meramecian) of Mississippian age in the vicinity of St. Louis, Missouri is composed of a variable sequence of limestones deposited in shallow waters adjacent to scattered positive elements. This unit varies in thickness from zero up to 160 feet.

A medium to coarse-grained calcarenite is the dominant rock-type of the thesis area and is most abundant in the central and southwest regions. Stratigraphic sections in the northern region are more dolomitic, increasingly brecciated, and contains numerous secondary features. The southeast region is thinly bedded and composed of greater amounts of micrite formed by algal activity or direct …

The Implementation Of A Compiler Targeted To A Multiprocessor Environment, R. Dwight Schettler

Masters Theses

"This research is an application of the techniques which have been developed for the detection and exploitation of implicit parallelism. A system has been developed based on Intel 86/12A single board computers utilizing dual-port RAM for communication. The compiler system accepts the source code of a simple block structured language and generates parallel programs to be executed on the Multibus system. The techniques used for detection of parallelism are stressed"--Abstract, page ii.

A General Design Tool For Computer Directories, Edward J. Peeler

Masters Theses

The primary objective of a directory is to organize information for efficient retrieval. There are many techniques that can be applied to the design of a directory. One particularly useful technique employs the use of inverted files on range attributes. The technique provides an effective directory for a variety of applications and for very large databases. This paper examines the technique and describes the implementation of a general design tool based on these principles.

Horizontal Fragmentation And Allocation In A Distributed Database For Cost Minimization With Reliability And Space Constraints, Elmo Loren Ivey

Masters Theses

In this paper a method for horizontal fragmentation of a relational database is presented. A method is given for calculating the benefit or cost savings obtained by allocating a given fragment to a site, independently for each site.

To obtain optimal benefit each fragment is allocated to all sites where there is a positive benefit. This may result in the allocation of some fragments to multiple sites.

Finally a method is given for removing or reallocating certain fragments from sites with insufficient storage. Also, a method is given for allocating fragments to multiple sites to meet constraints on the required …

A Hydrogeologic Investigation Of The Balkema Wetland, Daniel V. Fronczek

Masters Theses

The Balkema wetland, located In southwestern Kalamazoo County, Michigan, represents complex biological and hydrologic Interaction between surface water and a two-aquifer hydrologic system. Situated on the southeastern flank of the Kalamazoo moraine, the glacial geology of the area plays a key role in the understanding of the hydrogeologic function of the wetland. A two-aquifer system, an upper unconfined, and a lower confined, Interact In the vicin ity of the wetland where the c la y /till aqulclude dividing the two systems 1s absent. Various parameters, both hydrologic and geochemical, were measured In the study area, Including specific conductance values of …

Determination Of Phenomenological Optical Model Parameters For Neutrons On 208Pb From 4 To 150 Mev, Randy L. Schutt

Masters Theses

Phenomenological o p tic a l model parameters for neutrons incident on ²⁰⁸Pb have been determined for neutron energies from 4 to 150 MeV using the code SNOOPY-8. Neutron total cross sections from 4 to 150 MeV and angular distributions for elastic scattering from 13.5 to 40.0 MeV were utilized. Analyses of total and differential cross sections were performed at a number of energies to determine energy dependent expressions for the real strengths of the central potential, imaginary surface potential, and imaginary volume potential. These energy dependent expressions for V, W_d, and W_S were found to …

High Performance Liquid Chromatographic Determination Of Thromboxane B2 In Human Serum As A Methoxime-Panacyl Ester Derivative, Robert H. Pullen

Masters Theses

No abstract provided.

The Stratigraphy, Petrology, And Depositional Environments Of The Maryville Limestone (Middle Cambrian) In The Vicinity Of Powell And Oak Ridge, Tennessee, Michael Glenn Kozar

Masters Theses

The Maryville Limestone (Middle Cambrian) is part of the nearly 600 meter thick Conasauga Group, which crops out along a series of northeasterly trending strike belts in the Valley and Ridge Province of the southern Appalachians. The interlayered limestone, shale, and dolostone comprising the Conasauga result from the interfingering of the Conasauga Shale to the west and northwest and the Honaker Dolomite to the east and southeast. Apart from detailed lithologic and paleoenvironmental work concerning Conasauga strata in southwestern Virginia and northeasternmost Tennessee, few studies have examined the Maryville in detail in east Tennessee.

In the study area, a total …

A Structural Investigation Of A Basement-Involved Thrust System In Southern Sphinx Mountain Quadrangle (Madison Range) Southwestern Montana, Jeffrey Scott Brown

Masters Theses

The Madison Range is the eastern limb of the Laramide Rocky Mountain foreland Madison-Gravelly Arch. The main segment of the Madison thrust system in the map area is the basement-involved Scarface thrust which dips westward, trends north-northwest, and places Archean rocks onto an overturned footwall of Cambrian through Cretaceous rocks. Foliation of Archean rocks in the footwall is folded with overlying sedimentary rocks.

The Shedhorn Mountain thrust splays from the Scarface thrust. It is exposed north and south of the Shedhorn Mountain anticline, but is blind beneath it. The Taylor fault, an east-dipping back thrust, is inferred to be associated …

Experiment Module For Microprocessor Based Data Acquisition And Speech Processing, Namazi Bin Azhari

Masters Theses

This project involves microprocessor applications to the acquisition of physical data. The experiment module developed here will help the physics teacher and the scientist demonstrate the uses and advantages of digital techniques to students. Specific examples of data acquisition and processing are illustrated using speech and repetitive waveforms. The project centers on a module that is programmed to perform a number of types of data recordings and processings.

Stratigraphic And Sedimentologic Analysis Of The Middle Devonian Filer Sandstone, John Charles Rodwan

Masters Theses

The Filer Sandstone, a multistory assemblage o£ lenticular sand bodies, is a member of the Middle Devonian Amherstburg Formation of the Detroit River Group in the subsurface of the western and central portion of the Michigan Basin. It is distinguished from the reworked eolian and nearshore marine sand facies of the underlying Sylvania Sandstone by recognition of its barrier island facies relationships and stratigraphic position within enclosing carbonates unique to the Amherstburg Formation. Lithologically, the Filer ranges from a fine-grained, carbonate-cemented, supermature quartzarenite at its upper shoreface facies, to a texturally-inverted sandy carbonate at its lagoonal facies. Facies distribution was …

Reactive Counterion Surfactant Catalysis Of Hydroxamic Acid Hydrolysis With Perfluorooctanoic Acid, Mohamed El-Sayed Ayoub

Masters Theses

A micellar effect upon the rate of hydrolysis of hydroxamic acids in aqueous perfluorooctanoic acid has been demonstrated for hydroxamic acids with chain lengths of six , eight, and ten carbons. In this system the counterion, hydrogenion, is a catalyst. Typical rate constant-surfactant concentration profiles for micellar catalysis were obtained. The results for these hydrolyses are consistent with the pseudo-phase model for micellar effects.

In addition the Arrhenius activation energies were determined for the reaction of octanohydroxamic acid at surfactant concentrations above and below the critical micelle concentration of the surfactant. The activation energy is lower for reaction in the …

Further Studies On Purification Of A Mannitol Binding Protein: Use Of Ph Gradients For Elution From Cation Exchange Resin, Kristyne Ann Baumgarten

Masters Theses

Studies on the purification of a mannitol binding protein (MBP) from Pseudomonas aeruginosa PAO were performed. Utilizing the alkaline isoelectric point (pi 8.3) of MBP, pH gradients were used to elute MBP from carboxymethylcellulose cation exchange resins. Purification of MBP was monitored by sodium dodecyl sulfate-polyacrylam ide gel electrophoresis (SDS-PAGE). Only one protein band was seen on SDS-PAGE from MBP fractions elutedat pH 7-8 and 8 .2. Although pH gradients appear to give good purification from cation exchange resins, these procedures lead to loss of MBP activity.

A Study Of Classical Elastic Scattering For Heavy-Ion Nuclear Reactions, John C. Orrison

Masters Theses

Numerical computer programs were developed to calculate the classical elastic scattering orbits, deflection functions and differential scattering cross-sections for a heavy-ion nuclear reaction model.

Critical points of the deflection functions and differential scattering cross-sections were examined.

Semiclassical modifications were developed for future study to account for the phase relation between independent orbits that lead to the same scattering direction.

Hydrodynamic Character Of The Dundee Limestone In The Central Michigan Basin, Ann Carol Little

Masters Theses

The Middle Devonian Dundee Limestone underlies most of the Lower Peninsula of Michigan. A potentiometric surface constructed of the formation, utilizing pressure data was compared to local and regional structure, permeability trends, specific gravity of the brines, oil accumulations, and surficial topography.

The data were distributed mainly in the central basin area, with information becoming more sparse around the basin margins. This created difficulties in the determination of the extent of control imparted by each of the factors, in flow direction. Surficial topography, on a regional scale, is likely the most influential of the controls, with the Dundee Limestone brines …

An Investigation Into The Numeric Solution Of Linear Recurrence Relations, Dennis Lee Kapenga

Masters Theses

This is an investigation of the use of some techniques from numerical linear algebra in solving linear recurrence relations.

The classic methods of Oliver and Lozier are compared with several alternatives. These alternatives center on using advances in the theory of numerical linear algebra, computer software, and raw computer performance which have been made in the 15 years since the original research into linear recurrence relations was done.

A set of test examples is presented to provide a basis to compare solution methods. This set of examples was selected to allow experiments associated with the Poincare class of recurrence relations. …

Late-Quaternary Vegetational And Geomorphic History Of The Allegheny Plateau At Big Run Bog, Tucker County, West Virginia, Peter A. Larabee

Masters Theses

Paleoecological analysis of a 2.3 m sediment core from Big Run Bog, Tucker County, West Virginia (39° 07'N, 79° 35'W), provides an integrated and continuous record of vegetation change for the Allegheny Plateau of the central Appalachians for the past 17,000 yr from the full-glacial conditions of the Wisconsin through Holocene. Big Run Bog (980 m elevation) is high-elevation wetland within the Allegheny Mountain section of the Appalachian Plateaus physiographic province.

From 17,040 yr B.P. to 13,860 yr B.P. the plant communities surrounding the site were a mosaic of alpine tundra dominated by sedges (Cyperaceae) and grasses (Gramineae) with total …

Characteristics Of Thrust Fault Imbrication Along The Western Margin Of The Blue Ridge Structural Province Buffalo Mountain, Tennessee, Mark Morgan Duddy

Masters Theses

The Buffalo Mountain thrust sheet, located along the western margin of the Blue Ridge structural province in northeastern Tennessee, provides an excellent opportunity to examine transitional structural styles and deformational mechanisms between the Valley and Ridge and Blue Ridge.

The Buffalo Mountain sheet is composed of a sequence of Lower Cambrian Chilhowee Group elastics that have been thrust over Upper Cambrian Conasauga Group shales and Cambre- Ordovician Knox Group carbonates. The entire stack has been imbricated into four interleaved thrust slices and is folded into a northeast trending doubly plunging syncline.

Field mapping and indirect examination of thrust plane orientations …

Medium Modified Proton Densities Deduced From Electron Scattering Experiments, Steven Paul Deryke

Masters Theses

Recently two fundamental problems in nuclear physics have been resolved by applying the concept of nucleon size increases over that of free nucleons. These successes have encouraged the use of medium-modified proton densities to explain the differences between Hartree-Fock calculations and experimental charge densities. These differences constituted a long standing problem in nuclear physics.

The covariant soliton model of density dependent nucleon form factors was employed to explain these differences. This model predicts a non-linear relationship between point proton densities and charge densities. This work was able to provide a self-consistent proton density for ²⁰⁸Pb by inverting this relationship. …

A Model Of Syntax-Directed Transduction Of Unrestricted Grammars Using 2pda With Multisymbol Matching Production Rules, Steven William Cooke

Masters Theses

Syntax-directed transduction of unrestricted grammars is modeled by 2PDA automata with multisymbol matching production rules. Syntax-directed transduction normal form grammars (SDT) are constructed for unrestricted grammars. Transduction of sequences of derivation directives to sequences of derivation steps is defined for SDT grammars. E2PDA, a superset of 2PDA with input, output, and multi-symbol matching production rules, is formalized. The class of languages generated by unrestricted grammars. E2PDA syntax-directed transducers are conducted for SDT grammars.