Physical Sciences and Mathematics Commons^™

M-Grid : A Distributed Framework For Multidimensional Indexing And Querying Of Location Based Big Data, Shashank Kumar

Masters Theses

"The widespread use of mobile devices and the real time availability of user-location information is facilitating the development of new personalized, location-based applications and services (LBSs). Such applications require multi-attribute query processing, handling of high access scalability, support for millions of users, real time querying capability and analysis of large volumes of data. Cloud computing aided a new generation of distributed databases commonly known as key-value stores. Key-value stores were designed to extract value from very large volumes of data while being highly available, fault-tolerant and scalable, hence providing much needed features to support LBSs. However complex queries on multidimensional …

Evolving Decision Trees For The Categorization Of Software, Jasenko Hosic

Masters Theses

"Current manual techniques of static reverse engineering are inefficient at providing semantic program understanding. An automated method to categorize applications was developed in order to quickly determine pertinent characteristics. Prior work in this area has had some success, but a major strength of the approach detailed in this thesis is that it produces heuristics that can be reused for quick analysis of new data. The method relies on a genetic programming algorithm to evolve decision trees which can be used to categorize software. The terminals, or leaf nodes, within the trees each contain values based on selected features from one …

Privacy Preservation Using Spherical Chord, Doyal Tapan Mukherjee

Masters Theses

"Structured overlay networks are primarily used in data storage and data lookup, but they are vulnerable against many kinds of attacks. Within the realm of security, overlay networks have demonstrated applicability in providing privacy, availability, integrity, along with scalability. The thesis first analyses the Chord and the SALSA protocols which are organized in structured overlays to provide data with a certain degree of privacy, and then defines a new protocol called Spherical Chord which provides data lookup with privacy, while also being scalable, and addresses critical existing weaknesses in Chord and SALSA protocols. Spherical Chord is a variant of the …

Dephosphorylation Of Iqg1 By Cdc14 Temporally Regulates Actin Ring Formation, Daniel Patrick Miller

Masters Theses

"Cytokinesis is the final step in cell division when the cell separates the cytoplasm by contracting a ring composed of filamentous actin (F-actin) and type II myosin. Iqg1, an IQGAP family member, is an essential scaffolding protein in budding yeast (S. cerevisiae) required for actin recruitment to, and contraction of, the actomyosin ring. Actin is recruited by the calponin homology domain (CHD) in anaphase after Iqg1 is localized to the bud neck. Consensus sites for the cyclin-dependent kinase (CDK) Cdc28 were identified flanking the CHD. This led us to the hypothesis that phosphorylation of Iqg1 by Cdc28 negatively regulates actin …

Crime Pattern Detection Using Online Social Media, Raja Ashok Bolla

Masters Theses

"In this research, we show online social networks can be used to study crime detection problems. Crime is defined as an act harmful not only to the individual involved, but also to the community as a whole. It is also a forbidden act that is punishable by law. Crimes are social nuisances that place heavy financial burdens on society. Here we look at use of data mining followed by sentiment analysis on online social networks, to help detect the crime patterns. Twitter is an online social networking and microblogging service that enables users to post brief text updates, also referred …

Characterization Of A Plant Gene Family Expanded In Glycine Max, Lisa Snoderly-Foster

Masters Theses

"Glycine max, commonly named the cultivated soybean, is one of the oldest and most important food crops in the world. The study of the G. max genome provides valuable insight into the molecular mechanisms that govern its reproduction and environmental responsiveness, key factors in maximizing crop yield. Since the complete sequencing of the genome in 2010, the analysis has become faster and easier, especially with the development of numerous web-based, publically accessible bioinformatics tools.

This research effort utilizes these tools to characterize a small, unannotated G. max gene family. Although no definitive evidence was uncovered for the production of a …

A Cloud Brokerage Architecture For Efficient Cloud Service Selection, Venkata Nagarjuna Dondapati

Masters Theses

"The expanding cloud computing services offer great opportunities for consumers to find the best service and best pricing, which however raises new challenges on how to select the best service out of a huge pool. It is obvious time-consuming for consumers to collect the necessary information and analyze all service providers to make the decision. It is also a highly demanding task from a computational perspective, because the same computations may be conducted repeatedly by multiple consumers who have similar requirements. In this paper, we propose a novel brokerage-based architecture in the cloud, where the cloud brokers is responsible for …

An Investigation Of Contaminant Metal Distribution And Mineral Speciation In The Soil Near The Buick Recycling Division Smelter, Iron County, Missouri, Krista Nicole Rybacki

Masters Theses

"Trace metal contamination studies were conducted near the Buick Resource Recycling Division. This study used sequential extraction, total digestion, X-Ray Diffraction (XRD), and Scanning Electron Microscopy-Energy Dispersive Spectroscopy (SEM-EDS) to study trace metals in two soil cores. Sequential extraction analysis of the soil cores revealed that lead was associated with either iron or manganese oxides. Zinc and copper were bound to soil components, extracted mainly from organics, sulfides, and clays. Total digestion results compared favorably to the sum of the sequential extraction results for lead, thus validating the sequential extraction methodology. The highest concentration observed for lead was 4,743 parts …

Time Dependent Density-Functional Theory - Linear Response, Bryan Edman Sundahl

Masters Theses

The formal derivation of the linear response of time-dependent density-functional theory as shown by E. K. U. Gross is presented. The transformation of formal theory to the working linear response equations in the form of Casida's eigenvalue equation is demonstrated, and the results are applied to small monatomic, diatomic and triatomic systems. The application of different operators to the perturbed density is discussed, with the most attention being given to the dynamic polarizabilities. The dynamic polarizabilities and excitation spectra for N₂ [nitrogen gas] are then analyzed. The first excitation energy is noted to be in line with Koopmans' theorem. …

Origin Of High Levels Of Ammonium In Groundwater, Ottawa County, Michigan, Derrick Lingle

Masters Theses

Groundwater from wells located in and around Hemlock Crossing Park in Ottawa County, Michigan has elevated levels of ammonium. High ammonium concentrations in potable water wells are a common indicator of anthropogenic impact, such as landfill leachate or agricultural activity. Ammonium can also occur in groundwater through the decay of natural organic material. Along with the retrieval of a complete glacial sediment core via rotasonic drilling, numerous chemical and isotopic parameters were used to determine the source of ammonium in the impacted aquifer.

Buried organic material, deposited during the Athens subepisode interglacial period, is in contact with groundwater containing elevated …

Stratigraphic Controls On Diagenetic Pathways In The St. Peter Sandstone, Michigan Basin, Stephen A. Zdan

Masters Theses

The Middle Ordovician St. Peter Sandstone in the Michigan Basin is a target for hydrocarbon exploration/production, and carbon sequestration and geologic storage. The St. Peter is predominantly a marine sandstone with four dominant lithofacies. The uppermost facies contains zones of porosity and good reservoir quality. Because of the mostly uniform detrital composition, diagenesis must play a leading role in reservoir quality development. This study tests stratigraphic controls on diagenesis and reservoir quality development. The distribution of diagenetic regimes is believed to result from depositional setting and related geologic processes, including variations in sediment accumulation rate. Early carbonate cements preserve pre-compaction …

Demonstration Of A Targeted Proteome Characterization Approach For Examining Specific Metabolic Pathways In Complex Bacterial Systems, Adam Justin Martin

Masters Theses

Multiple Reaction Monitoring (MRM) is a powerful tandem mass spectrometry (MS/MS) tool frequently implemented in proteomic studies to provide targeted analysis of proteins and peptides. The selectivity that MRM delivers is so strong that it provides the quadrupole mass spectrometers (QQQ), on which it is commonly employed, with pertinence to proteomic studies that they would otherwise lack for their relatively low resolution. Additionally, this increased level of selectivity is sufficient enough to supplant complicated fractionation techniques, additional dimensions of chromatography, and 24 hour long MS/MS experiments in simplistic biological samples. But there is a deficiency of evidence to determine the …

Utilizing Persistent Scatterer Interferometry To Investigate The Nature And Factors Controlling Nile Delta Subsidence, El Hachemi Yousef Bouali

Masters Theses

The Nile Delta in Egypt is being threatened by two continuous and relatively slow hazards: encroachment from the Mediterranean Sea as sea levels rise and land subsidence of the delta itself. The magnitude of sea level rise has been actively monitored, while the subsidence of the Nile Delta has not been adequately quantified spatially and temporally. Instead, all previous studies have either focused on measuring average Holocene subsidence rates or modern subsidence rates on local scales (point- or city-scale).

The overall study objective is three-fold: (1) to measure and map the spatial variations in subsidence rates across the entire Nile …

Synthesis Of A Bifunctional Heterogeneous Catalyst For The Conversion Of Lignocellulosic Biomass Into Precursors For Alternative Fuels And Fine Chemicals, Matthew David Dembo

Masters Theses

The overall goal of the research described here is to develop synthetic routes to bifunctional reagents that can be tethered into silicate matrices derived from the tin functionalized cube, Si₈O₂₀(SnMe₃)₈. The critical functional group required for reaction with cubic silicate building block is a chlorosilane, and we additionally wish to incorporate both acid and ionic liquid groups. Once in hand, a crosslinking metathesis reaction will incorporate these reagents into porous silicate matrices derived from the Si₈O₂₀ cube, creating platforms with both acid and ionic liquid groups tethered to their …

Hydrogeology Of The Little River Animal Agriculture Environmental Research Unit And Impacts Of Dairy Operations On Groundwater, Robert Wesley Hunter

Masters Theses

This thesis describes the development of an integrated hydrogeologic/hydrologic site assessment and groundwater/surface water quality monitoring program at the University of Tennessee – Little River Dairy Farm, located near Townsend, TN. Hydrologic/hydrogeologic investigations of streams and groundwater at the site have been underway for more than 5 years, and these are expected to provide background data for assessing impacts of dairy wastes. The lower half of the ~180 ha site consists of low-relief fields used for row crops, which are underlain by 4 – 9 m of alluvial deposits on top of black shale or limestone that include sinkhole features. …

Mapping Spatial Thematic Accuracy Using Indicator Kriging, Maria I. Martinez

Masters Theses

Thematic maps derived from remote sensing imagery is increasingly being used in environmental and ecological modeling. Spatial information in these maps however is not free of error. Different methodologies such as error matrices are used to assess the accuracy of the spatial information. However, most of the methods commonly used for describing the accuracy assessment of thematic data fail to describe spatial differences of the accuracy across an area of interest. This thesis describes the use of indicator kriging as a geostatistical method for mapping the spatial accuracy of thematic maps. The method is illustrated by constructing accuracy maps for …

The Green's Function Method For Solutions Of Fourth Order Nonlinear Boundary Value Problem., Olga A. Teterina

Masters Theses

This thesis has demonstrated that Green’s functions have a wide range of applications with regard to boundary value problems. In particular, existence and uniqueness of solutions of a large class of fourth order boundary value problems has been established. In fact, given any fourth order ODE with homogeneous boundary conditions, as long as the corresponding Green’s function exists and f satisfies an appropriate Lipschitz condition, Theorem 2.1 guarantees such a solution under equally mild conditions. Similarly, Theorem 2.2 also guarantees such a solution under equally mild conditions. These theorems are contrasted with classical ODE existence theorems in that they get …

Linking Stream Sediment Metrics And Aquatic Macroinvertebrate Status In East Tennessee Streams, Grant Thomas Lynch

Masters Theses

Excess sediment is one of the leading causes of impairment of the rivers and streams of Tennessee and in the United States. Sediment acts as a pollutant by degrading the quality of habitat for fish and other aquatic life. The Tennessee Department of Environment and Conservation (TDEC) currently assesses the quality of streams in Tennessee by conducting benthic macroinvertebrate surveys. These surveys use seven biometrics to calculate Tennessee Macroinvertebrate Index (TMI) scores. This method is well tested and reliable, but it has not been shown to directly link changes in stream sediment characteristics to macroinvertebrate status. Finding a stream sediment …

Finite Topological Spaces, Jimmy Edward Miller

Masters Theses

A thesis on some fundamental aspects of Algebraic Topology on Finite Topological Spaces, specifically 4 point spaces.

Paleobiogeographical Variation Of Cretaceous Mecaster Batnensis And Mecaster Fourneli (Echinoidea: Spatangoida), Ryan Oliver Roney

Masters Theses

Spatangoids are the echinoid group best represented in the South American Cretaceous fossil record. This study analyzed two Cretaceous spatangoid species of the genus Mecaster (M. batnensis (Coquand, 1862) and M. fourneli (Agassiz, 1847)) found in South America as well as Africa, North America, Asia and possibly Europe (Smith and Bengtson 1991, Smithsonian Collection). This study assessed the paleobiogeographical variation of these species. Specimens from at least eight widely spaced localities were measured for morphometric analysis. Initial observations using length, width, and height data of M. batnensis and M. fourneli populations indicate regional differences in growth trajectories. A comparative …

Phosphatidylinositol 3,4,5–Trisphosphate Probe Synthesis And Microarray Protein Binding Studies To Investigate Multivalency And Detect Proteins Upregulated In Cancer, Benjamin Michael Smith

Masters Theses

Protein–lipid binding interactions control many processes at the cellular level. Many of these biological events between proteins and lipids are often associated with signaling pathway diseases such as cancer and diabetes. Therefore, increasing our knowledge of protein–lipid binding interactions will provide a better understanding of the signaling pathways of living systems. Pursuing this further, the phosphatidylinositol polyphosphates (PIPs) are an important family of signaling lipids that control key biological processes. Thus, the work described in this thesis was aimed at developing methods to validate these types of lipid–protein binding interactions. The goals of these projects were to synthesize the PIP …

Detailed Geologic Studies Of Paleoseismic Features Exposed At Sites In The East Tennessee Seismic Zone: Evidence For Large, Prehistoric Earthquakes, Kathleen Frances Warrell

Masters Theses

The East Tennessee seismic zone (ETSZ) is the second most active in the eastern United States, but recorded earthquakes do not exceed M_w [moment magnitude] = 4.6. Earthquake epicenters are located 5-26 kilometers deep in autochthonous basement, and faults producing these earthquakes do not break the surface. Detailed paleoseismic investigations at sites within the ETSZ include: detailed geological mapping, trenching, aerial photograph reconnaissance, X-ray diffraction (XRD), grain-size analysis, and optically stimulated luminescence dating of alluvium.

Site DL-6 near Dandridge, Tennessee, reveals a complex array of features providing evidence that at least 4‒6 M_w > 6 earthquakes affected the area. …

Surface Complexation Modeling Of Cr(Vi) Absorption On Mineral Assemblages, Ann M. Gilchrist

Masters Theses

Hexavalent chromium (Cr(VI)) is a waste product of many anthropogenic processes. Because it is highly mobile, the improper disposal of Cr(VI) has caused widespread contamination. Because reduction and adsorption reactions may reduce the bioavailability and mobility of Cr(VI) in environmental systems, a better understanding of Cr(VI) adsorption behavior will improve remediation efforts.

Subsurfaces and soils are heterogeneous, however most studies focus on single sorbate/sorbent interactions to develop surface complexation models (SCM) for prediction of heavy metal adsorption. Theoretically, combining the SCMsdeveloped for single sorbate/sorbent systems should yield accurate predictions of adsorption in more complex systems (i.e., the component additivity approach …

An Implementation Of Controller Area Network Bus Analyzer Using Microblaze And Petalinux, Tung-Hsun Tsou

Masters Theses

This paper presents a controller area network (CAN) monitor system created in a Field-Programmable Gate Array (FPGA) board, which is Xilinx SP605. The goals of this research are to let the system demonstrate a reliable CAN bus monitor system, and to show the Xilinx MicroBlaze and PetaLinux design flow. This system can be used to observe the CAN bus messages by means of C program and embedded Linux environment.

A Xilinx MicroBlaze soft processor is used to read CAN information from the external CAN bus controller, Microchip MCP2515. Two implementations, a stand-alone system and a Linux system, are built to …

Study Of Feasability For Phase Difference Extraction Using Software Defined Radio In Location Analysis, Paul Miller

Masters Theses

Here is a method for using the phase of an HF radio signal for use in location analysis. This computation is implemented in a software defined radio processing block in the GNU Radio environment. The signals analyzed are received by an Ettus Research USRP SDR. We created a phase analysis system called WMU Rootsync, which compares the roots of a received signal to the roots of a generated reference signal for the phase analysis. This research describes a prototype method for phase analysis only. Future projects may use these ideas differently than presented here. We intend for future projects to …

Using Soil Organic Matter As An Iron Chelate To Enhance The Efficiency Of Modified Fenton Oxidition Of Diesel Fuel In Arctic Soils, Mary K. Sherwood

Masters Theses

Laboratory experiments were conducted to investigate the use of modified fenton chemistry on the treatment of three soils from the Canadian arctic, all with abundant soil organic matter, iron and manganese oxides, and diesel fuel contamination. The purpose of these studies was to (I) to assess modified fenton chemistry as a treatment option for petroleum-contaminated arctic soils, and (2) to evaluate the impact of soil organic matter on the modified fenton treatment of soils. Modified fenton treatment was compared for reactions in which ethylenediaminetetraacetate was added as a chelate vs. reactions in which the native soil organic matter was the …

Activated Carbon Preconditioning To Reduce Contaminant Leaching In Cement-Based Stabilization Of Soils, Renee Elizabeth Crane

Masters Theses

Powdered activated carbon (PAC) is often added with cement to enhance the stabilization and solidification (S/S) of materials contaminated with organic compounds. Adsorption of organic contaminants onto PAC can reduce leaching of organic contaminants. Simultaneous addition of PAC and cement reduces soil handling costs, but cement hydration reactions coat PAC with Ca(OH)2 before contaminants can be adsorbed onto PAC. Laboratory studies were done on four aged, contaminated soils from manufactured gas plant sites to compare the performance of S/S treatment with simultaneous addition of PAC and cement vs. cement addition after preconditioning with PAC to enhance contaminant adsorption. Performance was …

Comparison Of Methods For Estimating Stochastic Volatility, John Parnell Collins

Masters Theses

Understanding the ever changing stock market has long been of interest to both academic and financial institutions. The early attempts to model the dynamics treated the volatility or sensitivity of the price change to random effects as constant. However, in matching the model to real data it was realized that the volatility was actually a random variable, and thus began efforts to determine methods for estimating the stochastic volatility from experimental data.

In this thesis, we develop and compare three different computational statistical filtering methods for estimating the volatility: The Kalman Filter, the Gibbs Sampler, and the Particle Filter. These …

Automated Generation Of Simulink Models For Enumeration Hybrid Automata, David Aaron Heise

Masters Theses

An enumeration hybrid automaton has been shown in principle to be ready for automated transformation into a Simulink implementation. This paper describes a strategy for and a demonstration of automated construction. This is accomplished by designing a data model which represents EHA data and providing a mapping from EHA data points to Simulink blocks.

Kingston Fossil Plant Ash Spill & Corbicula Fluminea: Assessing The Effectiveness Of An Invasive Bivalve As A Biomonitor Of Coal Ash Pollution, Hannah Ruth Johnson

Masters Theses

The goal of this study was to assess the effectiveness of using the invasive Asian clam, Corbicula fluminea, as a biomonitor for trace element bioavailability in the river system affected by the Kingston Fossil Plant coal ash spill of December 2008. I collected Corbicula from five different sites (n=20 per site) and analyzed both the soft body tissues and shells via inductively coupled plasma-optical emission spectroscopy (ICP-OES). I then compared the concentrations of a suite of elements in Corbicula fluminea among sampling sites and examined the correlation between soft tissue and shell concentrations. The multiple analysis of variance (MANOVA) …