Physical Sciences and Mathematics Commons^™

Hindered Rotation Of Dihydrogen On Synthesized Metal Oxides, George Houston Rouvelas

Masters Theses

A MATLAB program was written to calculate the hindered rotational energies of the hydrogen and deuterium molecules interacting with an anisotropic potential, which may be thought of as a potential energy surface of a metal oxide substrate. It was found that an increase in the hindering potential of the rotation about the azimuthal angle lifted the degeneracy of the j = 1,mj [magnetic quantum number] = plus or minus 1 states. A better understanding of how the rotational states of these systems change as a function of the hindering potential can help to explain features in rotational inelastic neutron scattering …

A Gis-Based Multi-Objective Optimization Of A Lignocellulosic Biomass Supply Chain: A Case Study In Tennessee, Zidong Wang

Masters Theses

To achieve an economically and environmentally sustainable lignocellulosic biomass (LCB)-based biofuel industry sector, the design and location of a sustainable LCB supply chain is important. In this study, a multi-objective optimization model integrated with high-resolution geographical data was developed to examine the optimal switchgrass supply chain for a potential biorefinery in Tennessee, specifically evaluating the potential tradeoffs between the objectives of minimizing plant-gate cost and GHG emissions from the switchgrass supply chain. The key findings of this study are as follows: both plant-gate feedstock cost and GHG emissions were sensitive to the type of land converted into switchgrass production, the …

Theoretical Modeling Of Near-Threshold Shape Resonance Behaviour In Photodetachment Experiments, Laurentiu Dan Dumitriu

Masters Theses

This thesis attempts to better understand the results obtained from photodetachment experiments of Fe-, made by the Western Michigan University experimental atomic physics group at the Advanced Light Source (ALS), Lawrence Berkeley National laboratory.

After a relevant description of the quantum mechanics and theoretical atomic physics concepts and formulas involved in this subject, a physically realistic model, based on the square well potential, is developed. Based on this model, the theoretical photodetachment cross section is computed in order to reproduce the qualitative behavior of the experimental photodetachment cross section measured at ALS.

This development, involving programming in Fortran and numerical …

The Geology Of The South Antelope Pass Area Of The Southern Peloncillo Mountains, Hidalgo County, New Mexico, John A. Yellich

Masters Theses

Volcanic activity during the middle and late Tertiary has been recorded in the mountain ranges of the southwestern United States and northern Mexico and the two provinces of prominent volcanic activity, the Sierra Madre Occidental and the Mogollon Plateau, dominantly rhyolitic in composition, are connected by the Peloncillo Range. The predominant rock chemistry of the south Antelope Pass area is “rhyolitic”; however, lava rock types dominate over welded tuff rock types of the two provinces. There is a limited pre-Tertiary rock record of limestones and sandstones in the northeastern part of the study area. The rest of the study area …

Chemical Characterization And Anion Exchange Properties Of A West Tennessee Loess Soil, Jessica Lynn Ottinger

Masters Theses

Loess soils of west Tennessee may potentially contain large amounts of subsoil metal oxides (Fe, Al, and Mn) which may retain and restrict the movement of conservative anions, such as nitrate (NO₃). The potential utilization of large quantities of flue gas desulfurization (FGD) gypsum on these soils may displace subsoil NO₃, releasing it to adversely impact sensitive aquatic environments. This research examines the depth distribution of Fe-, Al, and Mn-oxyhydroxides, pH, particle size distribution, and of the cation and anion exchange capacity and exchange phase composition to identify depths that have the greatest potential for anion …

The Fine-Tuning Of Nomic Behavior In Multiverse Scenarios, Max Lewis Edward Andrews

Masters Theses

The multiverse hypothesis (the view that there is not just one world or universe in existence, bur rather that there are many) is the leading alternative to the competing fine-tuning hypothesis (the laws of physics and constants are fine-tuned for the existence of life). The multiverse dispels many aspects of the fine-tuning argument by suggesting that there are different initial conditions in each universe, varying constants of physics, and the laws of nature lose their known arbitrary values; thus, making the previous single-universe argument from fine- tuning incredibly weak. The position that will be advocated will be that a form …

Tor Bridge Distribution Powered By Threshold Rsa, Jordan Hunter Deyton

Masters Theses

Since its inception, Tor has offered anonymity for internet users around the world. Tor now offers bridges to help users evade internet censorship, but the primary distribution schemes that provide bridges to users in need have come under attack. This thesis explores how threshold RSA can help strengthen Tor's infrastructure while also enabling more powerful bridge distribution schemes. We implement a basic threshold RSA signature system for the bridge authority and a reputation-based social network design for bridge distribution. Experimental results are obtained showing the possibility of quick responses to requests from honest users while maintaining both the secrecy and …

Stand Dynamics And Fire History Of A Southern Appalachian Pine-Hardwood Forest On Rainy Mountain, Chattahoochee National Forest, Georgia, U.S.A., Alex William Dye

Masters Theses

In the American Southeast, forest managers and conservationists are interested in evaluating how forest composition is changing in response to both human and natural disturbances. This study explored the stand dynamics of a pine-hardwood forest on Rainy Mountain in the Chattahoochee National Forest of Georgia over the last 115 years and analyzed the role fire has had as a disturbance in the forest. Increment cores were collected from trees in 30 plots, each 0.01 ha in area. The cores were used to determine date of establishment of each tree and create age structure charts for each plot and for the …

Emplacement Mechanisms And Magma Driving Pressure Of The Proterozoic Curecanti Pluton; The Black Canyon Of The Gunnison, Colorado, Gordon Leonard Hicks

Masters Theses

There is significant obliquity between the margins of the Curecanti pluton, an internal foliation, a coeval swarm of ~400 pegmatite dikes just west of the pluton, and the host rock foliation. This pluton is a 5 km-long, 3 km-wide, and 0.4 km-thick sheet of monzogranite exposed in the Black Canyon of the Gunnison, CO. The pluton is discordant along most of its length, but has a >100-m-thick root at its western margin subparallel to the foliation in the host rock gneisses. A cordierite + anthophyllite + staurolite + garnet schist from the Vernal Mesa pluton aureole was previously dated (1.4 …

A Study Of Possible Optimizations For The Task Scheduler ‘Quark’ On The Shared Memory Architecture, Vijay Gopal Joshi

Masters Theses

Multicore processors are replacing most of the single core processors nowadays.

Current trends show that there will be increasing numbers of cores on a single chip in the coming future. However, programming multicore processors remains bug prone and less productive. Thus, making use of a runtime to schedule tasks on multicore processor hides most of the complexities of parallel programming to improve productivity. QUARK is one of the runtimes available for the multicore processors. This work looks at identifying and solving performance bottlenecks for QUARK on the shared memory architecture. The problem of finding bottlenecks is divided into two parts, …

Metamorphism, Kinematic Evolution, And Timing Constraints Of The Greenbrier Fault Around The Ela And Bryson City Domes, North Carolina, Remington M. Leger

Masters Theses

Field mapping, microstructural analysis, and electron microprobe analysis were performed on rocks from the Bryson City and Ela domes, North Carolina, to help constrain the tectonic history of the region. The domes are en echelon northeast-trending antiformal structures formed by two perpendicular sets of folds. They are bounded by the Greenbrier fault, which forms a ductile shear zone that juxtaposes the Great Smoky Group in the hanging wall with Grenville basement in the footwall. Isoclinal folds (F2) and axial planar foliation (S2) characterize the regional deformation (D2). Inter- to syn-kinematic porphyroblasts (relative to D2) of kyanite, staurolite, and garnet grew …

Sequence Mining Based Debugging Of Wireless Sensor Networks, Kefa Lu

Masters Theses

Wireless Sensor Network (WSN) applications are prone to bugs and failures due to their typical characteristics, such as extensively distributed, heavily concurrent and resources restricted. It becomes critical to develop efficient debugging systems for WSN applications. A flexible and generic debugger for WSN applications is highly demanded. In this thesis, I proposed and developed a flexible and iterative WSN debugging system based on sequence analyzing and data mining techniques. At first, I developed vectorized Probabilistic Suffix Tree (vPST), a variable memory length model to extract and store sequential information from program runtime traces in compact suffix tree based vectors, based …

Relative And Absolute Quantitation Of Metabolites And Lipids Using Lc/Ms/Ms On The Tsq Quantum Discovery Max, Jesse Lee Middleton

Masters Theses

Two biological systems were studied using LC/ESI/MS/MS on a triple quadrupole operated in SRM (selected reaction monitoring) scan mode. The first bacterium system is aquatic and microscopic in size known as Roseobacter. The second mammalian system is terrestrial and large in size relative to humans known as Holstein cows.

Roseobacter is a clade of marine bacteria abundant in the ocean. Roseophages are viruses that infect Roseobacter and cause viral lysis. Sulfitobacter sp. 2047 was isolated and infected with Roseophages, and the fold change in the metabolic pool relative to a control was studied at discrete time points. The absolute concentration …

Metamorphic Phase Equilibria In A Contact Aureole: Tres Hermanas Mountains, Luna County, New Mexico., Carissa Dawn Snyder

Masters Theses

To characterize the metamorphism in the Tres Hermanas Mountains contact–metamorphic aureole in Luna County, New Mexico, I mapped and collected samples of the Paleozoic strata near the quartz monzonite pluton along the northeast flank of North Peak. Stratigraphy in this area includes the Pennsylvanian undivided unit that is composed of thin-medium interbedded limestone, shale, and sandstone and the Hueco Formation that could be broken out into four members: a pebble–cobble conglomerate marks the base, a medium to massive bedded siliceous limestone is next, followed by a pure limestone member and topped by a breccia bed in places marking the fault …

Vegetation Response To Oak Savanna And Woodland Restoration In The Mid-South Usa, Andrew Lee Vander Yacht

Masters Theses

The decline and degradation of oak savanna and woodland communities throughout the Mid-South underscores the need to develop management techniques capable of their efficient and successful restoration. Therefore, my objectives for this work were to document plant community response to variations in canopy disturbance level, fire seasonality, and herbicide control of hardwood midstories. In Chapter One, I provide a thorough review of the current body of knowledge concerning open-oak communities and their restoration, with specific focus on herbaceous and woody plant response to canopy disturbance, fire, and herbicide midstory management. Chapter Two details the response of herbaceous and woody vegetation …

Adsorption Of Antimony By Birnessite And The Impact Of Antimony On The Electrostatic Surface Properties Of Variable-Charge Soil Minerals, Kalyn Alaine Vergeer

Masters Theses

Antimony (Sb) is a toxin that can be found in high concentrations in the soil due to anthropogenic sources. Antimony exists in soil as Sb(V) in the monovalent antimonate hydroxyanion. The adsorption mechanisms of Sb(V) are not well-characterized. The objective of this study was to further elucidate Sb(V) adsorption mechanisms by examining the impact of adsorption on surface charging characteristics of gibbsite, goethite, birnessite, and kaolinite. Also examined was Sb(V), SO₄ [sulfate], and PO₄ [phosphate] adsorption by birnessite. Electrophoretic mobility and potentiometric titrations were employed to examine the ζ-potential [zeta-potential] and net proton surface charge density as a …

A Search For Volatile Ices On The Surfaces Of Cold Classical Kuiper Belt Objects, Daine Michael Wright

Masters Theses

The surprisingly complex dynamical distribution of small bodies among and beyond the orbits of the planets has changed our understanding of Solar System evolution and planetary migration. Compositional information about the small bodies in the Solar System provides constraints for models of Solar System formation. According to most models, the Kuiper Belt population known as the cold classicals formed at distances far enough from the Sun for these objects to be composed of an appreciable fraction of volatile ices of diverse composition (H₂O, CO₂, CH₄, light hydrocarbons, e.g. CH₃OH) and their orbits …

Quantifying The Relationship Among Ground Penetrating Radar Reflection Amplitudes, Horizontal Sub-Wavelength Bedrock Fracture Geometries, And Fluid Conductivities, Carolyn Morgan Tewksbury-Christle

Masters Theses

Accurate characterization of subsurface fractures is indispensible for contaminant transport and fresh water resource modeling because discharge is cubically related to the fracture aperture; thus, minor errors in aperture estimates may yield major errors in a modeled hydrologic response. Ground penetrating radar (GPR) has been successfully used to noninvasively estimate fracture aperture for sub-horizontal fractures at outcrop scale, but limits on vertical and horizontal resolution are a concern. Theoretical formulations and field tests have demonstrated increased GPR amplitude response with the addition of a saline tracer in a sub-millimeter fracture; however, robust verification of existing theoretical equations without an accurate …

Programming Dense Linear Algebra Kernels On Vectorized Architectures, Jonathan Lawrence Peyton

Masters Theses

The high performance computing (HPC) community is obsessed over the general matrix-matrix multiply (GEMM) routine. This obsession is not without reason. Most, if not all, Level 3 Basic Linear Algebra Subroutines (BLAS) can be written in terms of GEMM, and many of the higher level linear algebra solvers' (i.e., LU, Cholesky) performance depend on GEMM's performance. Getting high performance on GEMM is highly architecture dependent, and so for each new architecture that comes out, GEMM has to be programmed and tested to achieve maximal performance. Also, with emergent computer architectures featuring more vector-based and multi to many-core processors, GEMM performance …

Study Of The Insulin Mimetic Sodium Orthovanadate In Glucosamine Induced Insulin Resistnace In Primary Rat Hepatocytes, Kalan Mcpherson

Masters Theses

Insulin resistance and type II diabetes is a disease state characterized by a lack of sensitivity of insulin to provoke a proper response in insulin sensitive tissues. Currently, we utilize glucosamine to increase flux through the Hexosamine Biosynthetic Pathway (HBP) to induce an insulin resistance like state in primary rat hepatocytes. We tested the effectiveness of the insulin mimetic sodium orthovanadate to determine if it could elicit an insulin-like response under these conditions. Mixed results were obtained on the effectiveness of vanadate as an insulin mimetic in this insulin resistant model.

Development And Evaluation Of An Inquiry-Based Unit For Teaching About Paleoclimate And Climate Change, Steven Barone

Masters Theses

The purpose of this action research study is to develop and evaluate a sequence of four lessons for an introductory earth science course taken by future elementary teachers. Action research is a reflective process of data collection and analysis used by teachers to improve their classroom practice. This study’s goal is to produce a series of lessons that align with the course philosophy of student-driven learning through guided-inquiry and are effective at improving students’ understanding of climate change.

Three data sets were used to evaluate the lessons: 1) student knowledge gains on an objective pre- and post-test, 2) students’ self-reported …

Adsorption Of Hexavalent Chromium On Hydrous Manganese Oxide, Andrew K. Macleod

Masters Theses

Hexavalent chromium is a very common contaminant most often associated with industrial processes, it is quite mobile in the subsurface and a better understanding of its mobility and interactions with soil constituents will help ongoing remediation efforts.

Hydrous manganese oxides (HMO) are a very common soil constituent and thus would be likely to interact with Cr(VI) in contaminated shallow subsurface environments. The goal of this study is to develop a working model that can improve predictions of Cr(VI) mobility in natural systems. A diffuse double layer surface complexation model (DLM) was developed by deriving reaction stoichiometries and stability constants for …

Analysis Of Depositional Facies And Geological Controls On Reservoir Quality In Lower-Middle Devonian Sylvania Sandstone, Midland County, Michigan, Katherine A. Pollard

Masters Theses

The early-Middle Devonian Sylvania “Sandstone” is considered a target for potential CO₂ geosequestration. In order to develop geostatic models for CO₂ injection simulations, controls on reservoir properties must be addressed. The three objectives of this study involve: 1) develop an overview of depositional lithofacies and their vertical stacking relationships, 2) determine fluid sources and controls of diagenesis (dolomitization and silicification), and 3) examine geological controls on the distribution and character of reservoir facies.

The grossly transgressive Sylvania-Bois Blanc interval is a complex lithologic assemblage. Sylvania “Sandstone” strata transition from high energy, subtidal to lower-intertidal mixed carbonate-siliciclastic facies to …

Ethical Ambivalence In Local Television Weathercasting: A Rossian Analysis, Vernon Keith Thompson

Masters Theses

Today’s television weathercasters are being called upon increasingly to go beyond benign weather prognostications to become the “newsroom experts” for science topics. The expectation to act as both scientists and journalists can cause ethical ambivalence (EA), a sociological condition in which, faced with conflicting norms, the subject feels that he/she is being pulled psychologically in two different directions (Jansen & Von Glinow, 1985). This thesis presents a Rossian analysis of climate change in weathercasting, a topic that captures the most important ethical tensions arising from conflicting duties within the weathercaster role, specifically: a) how might the duties of the television …

Creating Sustainable Economic And Ecological Growth In The Congo Basin: Bushmeat Consumption And Biodiversity Protection, Richelle Lynn Warnock

Masters Theses

This research examines the economic and ecological sustainability of bushmeat hunting in the Congo Basin, specifically the Democratic Republic of Congo and the Republic of Congo. Although bushmeat hunting has provided short term gain for individuals in the region, long term solutions focusing on micro and macro level interventions may provide community wide benefits, while protecting Congo Basin wildlife. Research shows that a focus on the development of key economic sectors such as agriculture, mineral resources and hydroelectricity, as well as the growth of infrastructure may provide viable economic gain for the Congo Basin. Ecotourism and improvements to forest management …

Late Mississippian (Chesterian) Through Early Pennsylvanian (Atokan) Strata, Michigan Basin, U.S.A., Shannon M. Towne

Masters Theses

Over 2,000 linear feet of core material was analyzed to evaluate the stratigraphy and basin evolution of Carboniferous strata in the Michigan basin. Rock units were evaluated on the basis of lithofacies type, contact relationships, and existing regional geologic interpretations. The recovery of three distinct pollen and spore assemblages from core confirms the timing of deposition during the Late Mississippian Chesterian and Early-Middle Pennsylvanian Morrowan and Atokan regional stages within the Michigan basin.

The deposition of a marine carbonate succession with significant interstratified quartz sandstone occurred during the Chesterian regional stage. The Bayport interval (Bayport Limestone) is composed of seven …

Integrating Depositional Facies And Sequence Stratigraphy In Characterizing Unconventional Reservoirs: Eagle Ford Shale, South Texas, Seth Jordan Workman

Masters Theses

The Mid-to-Late Cretaceous Eagle Ford Shale of South Texas is a mixed siliciclastic/carbonate, unconventional resource play with considerable oil and natural gas. Characterization of Eagle Ford reservoir quality and potential is made difficult by complex, small-scale heterogeneities.

The limited availability of subsurface data constrains previous subsurface Eagle Ford investigations. As a result, the internal variability of depositional facies and reservoir attributes remain poorly understood for these Eagle Ford rocks.

This investigation incorporates a representative group of four Eagle Ford cores, and core data, from within the current play area in order to: 1) determine facies successions, 2) establish a hierarchal …

Wetting And Drying Cycles And The Fungal Communities On Leaf Litter In Streams, Kele Qwinn Thrailkill

Masters Theses

"Leaf litter is a major source of energy for streams in deciduous forests. Fungi play a critical role by converting the leaves into nutritional material for the rest of the food web. The breakdown of leaf litter and associated biota, including invertebrates and fungi, have been proposed as measures of stream health in systems affected by anthropogenic activity. Rates of leaf breakdown can be depressed in streams affected by acidity, metals, organic contaminants, and other stressors. Climate change may lead to alterations in stream hydrology such that streams experience more frequent floods as well as drying episodes. Fungal communities can …

Broad-Spectrum Antibacterial Properties Of Metal-Ion Doped Borate Bioactive Glasses For Clinical Applications, Megan Ottomeyer

Masters Theses

"Bioactive glasses with antimicrobial properties can be implemented as coatings on medical devices and implants, as well as a treatment for tissue repair and prevention of common hospital-acquired infections such as MRSA A borate-containing glass, B3, is also undergoing clinical trials to assess wound-healing properties. The sensitivities of various bacteria to B3, B3-Ag, B3-Ga, and B3-I bioactive glasses were tested. In addition, the mechanism of action for the glasses was studied by spectroscopic enzyme kinetics experiments, Live-Dead staining fluorescence microscopy, and luminescence assays using two gene fusion strains of Escherichia coli.

It was found that gram-positive bacteria were more …

Comparative Evaluation Of N-Acetylcysteine And N-Acetylcysteine Amide In Acetaminophen-Induced Oxidative Stress, Ahdab Naeem Khayyat

Masters Theses

"Acetaminophen (APAP) is the most widely used pharmaceutical analgesic-antipyretic agent in the world, but its toxicity is a common cause of drug-induced hepatotoxicity. With APAP toxicity, cellular glutathione (GSH) is depleted. This results in the availability of N-acetyl-p-benzoquinone imine (NAPQI), is a toxic metabolite of APAP that binds to cellular macromolecules, which leads to cell necrosis. N-acetyl cysteine (NAC), a GSH precursor, is the only approved antidote for an acetaminophen overdose. It is a negatively charged molecule that diminishes its penetration into the cells, thereby requiring fairly high doses that increase the severity of side effects. In addition, oral and …