Physical Sciences and Mathematics Commons^™

Tailoring The Pore Environment Of Metal-Organic And Molecular Materials Decorated With Inorganic Anions: Platforms For Highly Selective Carbon Capture, Patrick Stephen Nugent

USF Tampa Graduate Theses and Dissertations

Due to their high surface areas and structural tunability, porous metal-organic materials, MOMs, have attracted wide research interest in areas such as carbon capture, as the judicious choice of molecular building block (MBB) and linker facilitates the design of MOMs with myriad topologies and allows for a systematic variation of the pore environment. Families of MOMs with modular components, i.e. MOM platforms, are eminently suitable for targeting the selective adsorption of guest molecules such as CO₂ because their pore size and pore functionality can each be tailored independently. MOMs with saturated metal centers (SMCs) that promote strong yet reversible …

Developing A Compiler For A Regular Expression Based Policy Specification Language, Cory Michael Juhlin

USF Tampa Graduate Theses and Dissertations

Security policy specification languages are a response to today's complex and vulnerable software climate. These languages allow an individual or organization to restrict and modify the behavior of third-party applications such that they adhere to the rules specified in the policy. As software grows in complexity, so do the security policies that govern them. Existing policy specification languages have not adapted to the growing complexity of the software they govern and as a result do not scale well, often resulting in code that is overly complex or unreadable. Writing small, isolated policies as separate modules and combining them is known …

Saharan Air Layer Dust Loading: Effects On Convective Strength In Tropical Cloud Clusters, Randall J. Hergert

USF Tampa Graduate Theses and Dissertations

Numerous factors play a role in the development and maintenance of North Atlantic tropical cyclones as they originate and cross the Main Development Region. These factors include sea-surface temperatures (SSTs), relative humidity, vertical wind shear, etc. One key player in many of these factors is the Saharan Air Layer (SAL) which has been a source for study for nearly five decades.

The interplay between dust loading within the SAL and the development of African Easterly Waves (AEWs) has been repeatedly noted in many of the studies in this field. The cumulative indirect effect of the dust on AEWs however remains …

Blindcanseeql: Improved Blind Sql Injection For Db Schema Discovery Using A Predictive Dictionary From Web Scraped Word Based Lists, Ryan Wheeler

USF Tampa Graduate Theses and Dissertations

SQL Injections are still a prominent threat on the web. Using a custom built tool, BlindCanSeeQL (BCSQL), we will explore how to automate Blind SQL attacks to discover database schema using fewer requests than the standard methods, thus helping avoid detection from overloading a server with hits. This tool uses a web crawler to discover keywords that assist with autocompleting schema object names, along with improvements in ASCII bisection to lower the number of requests sent to the server. Along with this tool, we will discuss ways to prevent and protect against such attacks.

A Bat-Guano-Derived Δ15N And Δ13C Record Of Paleoenvironmental Change: Zidită Cave, Romania, Daniel Martin Cleary

USF Tampa Graduate Theses and Dissertations

Because nitrogen isotopes are fractionated along the soil-plant-insect-bat-guano pathway, it may be possible to reconstruct environmental and climatic changes reflected in the nitrogen isotopic composition of guano. A 1.5-m core of bat guano from Zidită Cave (western Romania) provides a record of climatic and anthropogenic influence on the regional nitrogen cycle and paleoenvironmental controls on nitrogen transforming processes. Increasing and decreasing trends of nitrogen isotopic composition (δ¹⁵N values) correspond well with changes in the influence of farming practices, deforestation, and forest expansion. These influences likely had a significant effect on the openness of the nitrogen cycle, resulting in …

Informing The Design And Deployment Of Health Information Technology To Improve Care Coordination, Diego A. Martinez

USF Tampa Graduate Theses and Dissertations

In the United States, the health care sector is 20 years behind in the use of information technology to improve the process of health care delivery as compared to other sectors. Patients have to deliver their data over and over again to every health professional they see. Most health care facilities act as data repositories with limited capabilities of data analysis or data exchange. A remaining challenge is, how do we encourage the use of IT in the health care sector that will improve care coordination, save lives, make patients more involved in decision-making, and save money for the American …

Dissolved Nutrient Distributions In The Gulf Of Mexico Following The Deepwater Horizon Oil Spill, Ashley Ann Parks

USF Tampa Graduate Theses and Dissertations

The Deepwater Horizon (DWH) oil spill in the Gulf of Mexico (GoM) in the spring of 2010 introduced 4.4 million of barrels of oil to the ecosystem. Some biodegradation of the oil occurs when microorganisms, particularly bacteria, metabolize the oil as a carbon source. During this process, the microbes also require nutrients for energy. An introduction of oil at this magnitude has the ability to induce large blooms of microbes, which in turn can affect nutrient concentrations. Microbial petroleum degradation decreases nutrient concentrations, whereas the microbial assimilation and decay of organic matter increase nutrient concentrations. This study assessed whether any …

Ocean Forcing Of Quaternary East Antarctic Ice Sheet Evolution: An Ice-Proximal Sedimentary Perspective, Michelle E. Guitard

USF Tampa Graduate Theses and Dissertations

Antarctica and the Southern Ocean play a critical role in Earth’s climate system. Antarctica’s ice sheets contain enough ice to raise global sea level by ~58 m, and the Southern Ocean distributes climate signals and nutrients to the major ocean basins and the deep ocean. Antarctica’s largest ice sheet, the East Antarctic Ice Sheet (EAIS), was considered stable compared to those in West Antarctica and the Antarctic Peninsula because it was thought to be grounded above sea level. However, subglacial topography now reveals vast submarine basins and measurements of ice velocity in the Pacific sector indicate marine-terminating outlet glacier thinning …

Millennial-Scale Variability Of A Major East Antarctic Outlet Glacier During The Last Glaciation, Michelle Guitard

USF Tampa Graduate Theses and Dissertations

Ongoing retreat of Antarctica’s marine-based glaciers is associated with warm (~2° C) modified Circumpolar Deep Water intrusion onto the continental shelf, suggesting that Southern Ocean temperatures may influence Antarctic ice sheet stability. Understanding past cryosphere response to environmental forcing is crucial to modeling future ice sheet behavior. Of particular interest is the response of the East Antarctic Ice Sheet (EAIS), which stands to contribute ~20 m to global sea level. However, marine sediment sequences recording timing and variability of EAIS fluctuations through the last major climate shift, the Last Glacial Maximum (LGM), are either missing from the margin or have …

The Role Of Community Participation In Water Production And Management: Lessons From Sustainable Aid In Africa International Sponsored Water Schemes In Kisumu, Kenya, Erick Oniango Ananga

USF Tampa Graduate Theses and Dissertations

Few studies have attempted to determine the tenability of Community Participation (CP) theory is explicating Water Production and Management dynamics in Urban Informal Settlements. Consequently, several gaps exist in knowledge of the value of this important theory for efforts to improve water service delivery in such settlements. The main purpose of this study is to contribute to efforts addressed to filling these gaps. Four water schemes established by Sustainable Aid in Africa International in partnership with different communities in the informal neighborhoods of Kisumu Kenya are used as empirical referent. The study is guided by the following three Research Questions; …

Field Observations And Novel Methodologies For Carbon System Assessments In Coastal Waters, Bo Yang

USF Tampa Graduate Theses and Dissertations

Coastal zones receive massive terrestrial inputs of nutrients and organic matter, and play an important role in biogeochemical cycles. The interactions of river inputs, ocean currents, atmospheric exchanges, anthropogenic influences, and biologically active ecosystems make CO₂ system studies in coastal waters highly challenging. This work focuses on improving our understanding of the CO₂ system in coastal waters through (1) development of a new methodology for measurements of CO₂ system parameters in the field; (2) observations of large spatial and temporal CO₂ system variations in coastal waters; and (3) characterization of the influence of organics on CO …

Bio-Photoelectrochemical Solar Cells Incorporating Reaction Center And Reaction Center Plus Light Harvesting Complexes, Houman Yaghoubi

USF Tampa Graduate Theses and Dissertations

Harvesting solar energy can potentially be a promising solution to the energy crisis now and in the future. However, material and processing costs continue to be the most important limitations for the commercial devices. A key solution to these problems might lie within the development of bio-hybrid solar cells that seeks to mimic photosynthesis to harvest solar energy and to take advantage of the low material costs, negative carbon footprint, and material abundance. The bio-photoelectrochemical cell technologies exploit biomimetic means of energy conversion by utilizing plant-derived photosystems which can be inexpensive and ultimately the most sustainable alternative. Plants and photosynthetic …

Bayesian Inference On Longitudinal Semi-Continuous Substance Abuse/Dependence Symptoms Data, Dongyuan Xing

USF Tampa Graduate Theses and Dissertations

Substance use data such as alcohol drinking often contain a high proportion of zeros. In studies examining the alcohol consumption in college students, for instance, many students may not drink in the studied period, resulting in a number of zeros. Zero-inflated continuous data, also called semi continuous data, typically consist of a mixture of a degenerate distribution at the origin (zero) and a right-skewed, continuous distribution for the positive values. Ignoring the extreme non-normality in semi-continuous data may lead to substantially biased estimates and inference. Longitudinal or repeated measures of semi-continuous data present special challenges in statistical inference because of …

Photoacoustic Calorimetry Studies Of The Earliest Events In Horse Heart Cytochrome-C Folding, Tarah A. Word

USF Tampa Graduate Theses and Dissertations

The protein folding problem involves understanding how the tertiary structure of a protein is related to its primary structure. Hence, understanding the thermodynamics associated with the rate-limiting steps for the formation of the earliest events in folding is most crucial to understanding how proteins adopt native secondary and tertiary structures. In order to elucidate the mechanism and pattern of protein folding, an extensively studied protein, Cytochrome-c (Cc), was chosen as a folding system to obtain detailed time-resolved thermodynamic profiles for the earliest events in the protein folding process. Cytochrome-c is an ideal system for understanding the folding process for several …

Radial Versus Othogonal And Minimal Projections Onto Hyperplanes In L_4^3, Richard Alan Warner

USF Tampa Graduate Theses and Dissertations

In this thesis, we study the relationship between radial projections, and orthogonal and minimal projections in l_4^3. Specifically, we calculate the norm of the maximum radial projection and we prove that the hyperplane constant, with respect to the radial projection, is not achieved by a minimal projection in this space. We will also show our numerical results, obtained using computer software, and use them to approximate the norms of the radial, orthogonal, and minimal projections in l_4^3. Specifically, we show, numerically, that the maximum minimal projection is attained for ker{1,1,1} as well as compute the norms for the maximum radial …

Dual 7-Degree-Of-Freedom Robotic Arm Remote Teleoperation Using Haptic Devices, Yu-Cheng Wang

USF Tampa Graduate Theses and Dissertations

A teleoperated system of dual redundant manipulator will be controlled in this thesis. The robot used with the dual redundant manipulator in this thesis is Baxter. Baxter’s redundant robot arms are 7-degree-of-freedom arms. The problem that will be solved in this thesis is optimization of the 7-degree-of-freedom robot arms. The control algorithm of the 7-degree-of-freedom robot arms will be discussed and built. A simulation program will be built to test the control algorithm. Based on the control algorithm, a teleoperation system will be created for Baxter. The controller used is Omni, which is a six-joint haptic device. Omni will also …

Nanomechanical And Nanotribological Characterization Of Sub-Micron Polymeric Spheres, Himanshu Kumar Verma

USF Tampa Graduate Theses and Dissertations

Friction between nanoscale objects has been a subject of great interest and intense research effort for the last two decades. However, the vast majority of the work done in this area has focused upon the sliding friction between two rigid, atomically smooth surfaces. Thus the parameter most explored has been the corrugation in the atomic potentials and how this affects the force required to slide one object across another. In truth, many nanoscale objects whose translation force is of practical interest are more spherical in nature. We hypothesize that the factors that determine the translation force will be related, not …

Dead/Live Microbial Culture Technique, Michael Veri

USF Tampa Graduate Theses and Dissertations

New methodology has been utilized to provoke or increase targeted metabolic pathways in microbes. The low hanging fruit of natural products has been discovered over the last 50 years. To continue finding new metabolites to be used as possible drug candidates, methodology development such as those proposed herein are necessary. This methodology uses extracts from known pathogenic bacteria to elicit production of latent biosynthetic pathways from environmental bacterial isolates that may be active against the original pathogenic strains. A new compound, MAV-1 (1) of the diketopiperazine family (Figure 1) was isolated and identified utilizing these techniques. The structure of MAV-1 …

Insights Into The Challenges Of Modeling The Atmospheric Boundary Layer, Esa-Matti Tastula

USF Tampa Graduate Theses and Dissertations

This work approaches the topic of modeling the atmospheric boundary layer in four research projects, which are summarized below.

i) The diurnal cycles of near-surface meteorological parameters over Antarctic sea ice in six widely used atmospheric reanalyses were validated against observations from Ice Station Weddell. The station drifted from February through May 1992 and provided the most extensive set of meteorological observations ever collected in the Antarctic sea ice zone. For the radiative and turbulent surface fluxes, both the amplitude and shape of the diurnal cycles varied considerably among different reanalyses. Near-surface temperature, specific humidity, and wind speed in the …

Authentication Via Multiple Associated Devices, Jean-Baptiste Subils

USF Tampa Graduate Theses and Dissertations

This thesis presents a practical method of authentication utilizing multiple devices. The factors contributing to the practicality of the method are: the utilization of devices already commonly possessed by users and the amenability to being implemented on a wide variety of devices. The term “device” refers to anything able to perform cryptographic operations, store data, and communicate with another such device.

In the method presented herein, multiple devices need to be associated with a single user to provide this user an identity in the system. A public key infrastructure is used to provide this identity. Each of the devices associated …

Information Technology & Sustainability: An Empirical Study Of The Value Of The Building Automation System, Daphne Marie Simmonds

USF Tampa Graduate Theses and Dissertations

This study examines the environmental and economic effects of green information technology (IT). Green IT describes two sets of IT innovations: one set includes innovations that are implemented to reduce the environmental impact of IT services in organizations; and the other IT to reduce the environmental impact of other organizational processes. The two sets respond to the call for more environmentally friendly or “greener” organizational processes.

I developed and tested a preliminary model. The model applied the resource based view (RBV) of the firm (Wernerfelt 1984) the stakeholder theory (Freeman 1984) and included four constructs: (1) BAS implementation; environmental …

The Effect Of Urbanization On The Embodied Energy Of Drinking Water In Tampa, Florida, Mark Vincent Eli Santana

USF Tampa Graduate Theses and Dissertations

Increasing urbanization has serious implications for resource and energy use. One of these resources is drinking water. The increased amount of impervious surfaces associated with urban development is responsible for increased runoff during rain events, which may have a negative impact on the quality of nearby bodies of water, including drinking water sources. The growing populations associated with urbanization require a higher water demand. In addition, urban drinking water systems use energy to collect, treat, and distribute a safe reliable effluent to users. Therefore, this study focuses on the degree to which urbanization influences the embodied energy of drinking water …

Investigаtiоn Оf 3d Structures Оf Γ-Aaрeрtide Bаsed Peрtidоmimetics, Qiao Qiao

USF Tampa Graduate Theses and Dissertations

Oligomers which have a tendency to form well-defined secondary structures are called foldamers. They offer an attractive opportunity for the design of novel molecules that mimic the structures and functions of proteins and enzymes including biocatalysis and biomolecular recognition. Herein a new class of non-natural γ-AApeptides and their derivatives are synthesized and studied in our lab. Previous studies of γ-AApeptides have revealed that they are highly resistant to proteolysis, and have virtually limitless potential in functional group diversity. However, to improve the bio-activity and explore new bio-applications, the understanding of the folding conformation of γ-AApeptides are necessary. Thus, NMR spectroscopy …

Spatiotemporal Sensing And Informatics For Complex Systems Monitoring, Fault Identification And Root Cause Diagnostics, Gang Liu

USF Tampa Graduate Theses and Dissertations

In order to cope with system complexity and dynamic environments, modern industries are investing in a variety of sensor networks and data acquisition systems to increase information visibility. Multi-sensor systems bring the proliferation of high-dimensional functional Big Data that capture rich information on the evolving dynamics of natural and engineered processes. With spatially and temporally dense data readily available, there is an urgent need to develop advanced methodologies and associated tools that will enable and assist (i) the handling of the big data communicated by the contemporary complex systems, (ii) the extraction and identification of pertinent knowledge about the environmental …

Environmental Sustainability Of Wastewater Treatment Plants Integrated With Resource Recovery: The Impact Of Context And Scale, Pablo K. Cornejo

USF Tampa Graduate Theses and Dissertations

There is an urgent need for wastewater treatment plants (WWTPs) to adapt to a rise in water and energy demands, prolonged periods of drought, climate variability, and resource scarcity. As population increases, minimizing the carbon and energy footprints of wastewater treatment, while properly managing nutrients is crucial to improving the sustainability WWTPs. Integrated resource recovery can mitigate the environmental impact of wastewater treatment systems; however, the mitigation potential depends on various factors such as treatment technology, resource recovery strategy, and system size.

Amidst these challenges, this research seeks to investigate the environmental sustainability of wastewater treatment plants (WWTPs) integrating resource …

Effects Of Disorder And Low Dimensionality On Frozen Dynamics In Ca3co2-Xmnxo6, Brian Wesley Casas

USF Tampa Graduate Theses and Dissertations

Complex oxides represent an intersection of play grounds for the existence of exciting new fundamental physics and materials with potential technological implications. The realization of many exciting properties of these systems rely on the coupling of electronic, structural and magnetic degrees of freedom. Additionally, competing interactions within each type of coupling discussed previously lead to theoretically diverse ground states, which under the application of an external perturbation, can be tuned and probed.

Ca3Co¬2-xMnxO6 represent a quasi-one dimensional Ising spin chain system oriented in an antiferromagnetic triangular lattice. The exotic behavior of the undoped compound Ca3Co2O6 has inspired work on continuing …

Reconstructing Paleoenvironments Of The Plio-Pleistocene Tamiami Formation Of Florida With Benthic Foraminifera, Heather Bender

USF Tampa Graduate Theses and Dissertations

There is general agreement that a range of paleodepths and environments are represented in the individual shell units of the middle Pliocene to earliest Pleistocene Tamiami Formation of southwest Florida, but maximum depths remain poorly constrained. Here, benthic Foraminifera abundances are used as a paleoenvironmental proxy to compare the upper Tamiami from quarries in Sarasota, Florida to Recent modern coastal, bay, and reef habitats of Florida, the Grand Cayman Islands, and Puerto Rico, ranging in depth from 0 to 55 meters. I used: (1) ordination techniques, including detrended correspondence analysis (DCA) and cluster analysis, to compare upper Tamiami foraminiferal assemblages …

Development And Application Of Web-Based Open Source Drug Discovery Platforms, Yuri Pevzner

USF Tampa Graduate Theses and Dissertations

Computational modeling approaches have lately been earning their place as viable tools in drug discovery. Research efforts more often include computational component and the usage of the scientific software is commonplace at more stages of the drug discovery pipeline. However, as software takes on more responsibility and the computational methods grow more involved, the gap grows between research entities that have the means to maintain the necessary computational infrastructure and those that lack the technical expertise or financial means to obtain and include computational component in their scientific efforts. To fill this gap and to meet the need of many, …

Application And Development Of Computational Methods In Conformational Studies Of Bio-Molecules, Aleksandra Karolak

USF Tampa Graduate Theses and Dissertations

The work presented in my dissertation focuses on the conformational studies of bio-molecules including proteins and DNA using computational approaches. Conformational changes are important in numerous molecular bioprocesses such as recognition, transcription, replication and repair, etc. Proteins recognize specific DNA sequences and upon binding undergo partial or complete folding or partial unfolding in order to find the optimal conformational fit between molecules involved in the complex. In addition to sequence specific recognition, proteins are able to distinguish between subtle differences in local geometry and flexibility associated with DNA that may further affect their binding affinities. Experimental techniques provide high-resolution details …

Use Of Assessments In College Chemistry Courses: Examining Students' Prior Conceptual Knowledge, Chemistry Self-Efficacy, And Attitude, Sachel M. Villafañe-García

USF Tampa Graduate Theses and Dissertations

Students' retention in STEM-related careers is of great concern for educators and researchers, especially the retention of underrepresented groups such as females, Hispanics, and Blacks in these careers. Therefore it is important to study factors that could potentially influence students' decision to stay in STEM. The work described in this dissertation involved three research studies where assessments have been used in college chemistry courses to assess students' prior content knowledge, chemistry-self-efficacy, and attitude toward science. These three factors have been suggested to have an influence on students' performance in a course and could eventually be a retention factor.

The first …