Physical Sciences and Mathematics Commons^™

Cost/Effectiveness Analysis Of Obtaining Operational Estimates Of Reference Evapotranspiration, Peninsular Florida, Usa, Michael G. Kittridge

USF Tampa Graduate Theses and Dissertations

The objective of this study is to conduct a cost/effectiveness analysis of the computation of reference evapotranspiration (ETo) in the peninsular of Florida. A meteorological station on the Fort Meade Mine in Polk County, Florida was used to provide data for the calculation of ETo. Five ETo equations were tested to determine the accuracy and cost/effectiveness to the fully measured ASCE Penman-Monteith (Full ASCE-PM) equation on daily, monthly, and annually time steps. The ETo equations ranged in amounts of parameters from the Full ASCE-PM to the Hargreaves. The energy terms accounted for approximately 90% of the total ETo flux. Solar …

Hydrostratigraphy And Groundwater Migration Within Surficial Deposits At The North Lakes Wetland, Hillsborough County, Florida, Jason J. Laroche

USF Tampa Graduate Theses and Dissertations

A wetland in west-central Florida was studied to characterize the local hydrostratigraphic configuration of surficial deposits overlying more-permeable limestones and conceptualize groundwater recharge. Eight continuous cores were drilled through the surficial deposits and partially into the underlying limestone. A total of 111 samples were extracted from the cores for laboratory sediment analyses and testing. The surficial deposits are roughly eight meters thick and made up of upper and lower clean-sand hydrostratigraphic layers (S1 and S3, respectively) separated by a low-permeability layer of clayey sand (S2). Also, a discontinuous low-permeability layer of clayey sand (S4) lies between S3 and the top …

Functionalization Of Resorcinarenes And Study Of Antimicrobial Activity, Kirankirti Muppalla

USF Tampa Graduate Theses and Dissertations

Cavitands are very important class of compounds in supramolecular chemistry. These molecules contain rigid enforced cavity,and have attracted considerable attention in supramolecular chemistry as building blocks for the construction of carcerands, hemicarcerands, and other host guests complexes. Nearly 40 years ago, Niederl and Vogel laid foundation for the study of such type of condensation reactions. In our laboratory we are involved in synthesis of resorcinarenes with readily available substrates such as resorcinol and aldehydes to form a cyclic tetramer.

Herein, I present detailed studies about the functionalization of the synthesized tetramers and their antimicrobial activity. Octahydroxy resorcinarenes were synthesized and …

Climatic And Structural Controls On The Geomorphology Of Wadi Sana, Highland Southern Yemen, Joshua Michael Anderson

USF Tampa Graduate Theses and Dissertations

Middle Holocene climate change forced significant environmental response and influenced human activities throughout southern Arabia. Climate models and proxy data indicate that climate along the southern Arabian peninsula changed from a moist phase, spanning the early to middle Holocene, to an arid phase, which persisted for the last ca. 5,000 years. A weakening and southward shift of the Southwest Indian Monsoon System, forced by northern hemisphere insolation variations in the precession band and/or glacial boundary conditions, is suggested as the mechanism for the abrupt shift to more arid conditions. Geoarchaeological evidence suggests that agriculture was more widespread and evolved alongside …

Evanescent Field Absorption Sensing Using Sapphire Fibers, Michael Grossman

USF Tampa Graduate Theses and Dissertations

This thesis explores the application of coiled sapphire multimode optical fibers for evanescent wave chemical sensing in both the visible spectrum and the near infrared. As has been suggested in the literature pertaining to silica fibers, bending converts low-order modes to high order ones, which leads to more evanescent absorption and thus a more sensitive chemical detector. By coiling the fiber many times, it was expected that even greater sensitivity would be attained.

Experiments were performed to investigate the sensor response to different solutions and to characterize this response. In the first of three experiments, the large absorption peak of …

Influence Of Evapotranspiration On Patterns Of Ground-Water Conductivity In Small Basins, Ana Jiménez

USF Tampa Graduate Theses and Dissertations

Ground-water conductivity data were obtained from shallow wells in a 12 km2 stream-basin along a 400 m transect, extending from the divide to the stream. The stream, Pringle Branch, is a second-order perennial stream in Hillsborough County, Florida. The shallow stratigraphy consists of 2-3 m of fine sand over a layer of clayey silt and silty clay. Vegetation cover includes grasses on the upper and middle slope, and riparian woodlands on the foot slope and floodplain. Precipitation is about 1.3 m per year. Shallow ground-water conductivity is about 50 uS/cm at the divide. It increases moderately along the mid slope, …

Geophysical Investigations And Groundwater Modeling Of The Hydrologic Conditions At Masaya Caldera, Nicaragua, Richard Eric Macneil

USF Tampa Graduate Theses and Dissertations

Masaya volcano, Nicaragua, has been the site of tremendous Plinian basaltic eruptions. Two eruptions ~6,500 and 2,250 BP formed the 6 kilometer (km) x 11 km, northwest trending Masaya caldera. The present day active Santiago Crater within the caldera is the site of persistent volcano degassing and occasional phreatic explosions. While the mechanism responsible for these phreatic explosions is unclear, one possible explanation is the interaction of groundwater with the shallow magma chamber beneath Masaya. This interaction with meteoric water is supported by the substantial steam discharge from the vent, which is significantly larger than other similar volcanoes in the …

An Investigation Into The Antifungal Activities Of N-Thiolated Beta- Lactams Against Selected Candida Species, Marci Culbreath

USF Tampa Graduate Theses and Dissertations

β-lactam antibiotics have long been a reliable course of treatment for bacterial infections. However, with recent increases in resistance and rising populations of immunocompromised patients new β-lactams have been synthesized and tested. The Turos laboratory has recently discovered novel β-lactams that have a mode of action distinct from penicillin and other β-lactam antibiotics as cell lysis is not observed. In the current investigations, these compounds are shown to also have antifungal properties. The rising incidence and prevalence of invasive fungal infections has become an increasing concern. The most common fungal pathogens involved in these infections are species in the genus …

Impacts Of Rainfall Events On Wastewater Treamtent Processes, Erin K. Mcmahan

USF Tampa Graduate Theses and Dissertations

Current research is revealing that stormwater can carry pathogens and that this stormwater is entering wastewater treatment facilities. During periods of intense rainfall, not only can stormwater carry higher amounts of pathogens, but it also increases the flow rate to the wastewater treatment facility. In many instances, the flow rate exceeds the facilities' treatment capacity and can impact treatment performance. The purpose of this study was to identify whether wastewater treatment is impaired during periods of increased rainfall, and to compare current policies that address this issue. The study was conducted using a case study approach to analyze historical precipitation …

Chemo-Enzymatic Route To Synthesis Of Biodegradable Polymers And Glycolipid Analogs, Surbhi Bhatt

USF Tampa Graduate Theses and Dissertations

New catalytic synthetic methods in organic chemistry that satisfy increasingly stringent environmental constraints are in great demand by the pharmaceutical and chemical industries. Studies over last 15 years have revealed that activity of enzymes can be increased in organic solvents rather than their natural aqueous environment. Because of their ease of use, high selectivity and environment friendliness, enzymes are enjoying increasing popularity in today's synthesis world.

Chapter 1 describes chemo-enzymatic synthesis of various glycolipid analogs. A highly regioselective macrolactonization was achieved using lipase from Candida antarctica as a catalyst. It also describes evaluation of lipases from different source and their …

Evaluation Of Geophysical And Thermal Methods For Detecting Submarine Groundwater Discharge (Sgd) In The Suwannee River Estuary, Florida, Matthew Weiss

USF Tampa Graduate Theses and Dissertations

Submarine groundwater discharge (SGD) represents a significant portion of the total discharge from coastal aquifers through diffuse seepage and point source springs, but can be difficult to locate. SGD is important as it can be a source of nutrients to estuaries and other coastal ecosystems. In an effort to evaluate geophysical and thermal methods for detecting SGD on the Florida Gulf coast, a suite of water-borne surveys were run in conjunction with aerial thermal imagery over the lower Suwannee River and estuary in March and September 2005. Thermal imagery exploits temperature differences between discharging groundwater and surface water. Thermal images …

Dynamic Monitoring Of Cytotoxicity Using Electric Cell Substrate Impendence Sensing, Alfred Brian Wafula

USF Tampa Graduate Theses and Dissertations

Electric cell-substrate impedance sensing (ECIS) pioneered by Giaever and Keese is suitable for continuous, automatic and real-time cell attachment analysis. ECIS is a novel electrical method to study, in real time, many of the activities of animal cells when grown in tissue culture. These include morphological changes, cell locomotion, and other behaviors directed by the cell's cytoskeleton. One of the most direct ECIS measurements is that of the attachment and spreading behaviors of cells. These measurements allow one to study and quantify the interaction of cultured cells with extracellular matrix (ECM) proteins and other macromolecules continuously and in real time. …

Coastal Processes And Anthropogenic Factors Influencing The Geomorphic Evolution Of Weedon Island, Florida, Jeanne Lambert

USF Tampa Graduate Theses and Dissertations

Weedon Island, a peninsula located on the western inner shoreline of Tampa Bay, Florida, is the location of a collaborative geological and archaeological project that aims to relate the present day geomorphology to natural processes and human occupational activity during the middle to late Holocene. The area is known for extensive archaeological sites, which were originally investigated in the 1920s, although they have received relatively little scientific attention during most of the last century. We hypothesize that activities associated with pre-historic human occupation of Weedon Island at various times during the last ca. 5,000 years influenced the geomorphic evolution of …

A Modular Onboard Processing System For Small Unmanned Vehicles, Richard D. Garcia

USF Tampa Graduate Theses and Dissertations

This work describes the design and implementation of a generic lightweight onboard processing system for miniature Unmanned Vehicles (UVs) that is computationally powerful and highly adaptable. First, several classical approaches to giant scale and full size UV onboard processing systems are described along with their corresponding limitations. Second, a detailed study is presented that describes the key characteristics of an onboard system along with associated limitations. Next, an implementation of a generic onboard system capable of vision processing and servo based control is presented along with detailed hardware specifications and implementation software. Last, experimental data, both laboratory and field, are …

Stochastic Methods For Evaluating The Potential For Wetland Rehydration In Covered-Karst Terranes, Christian David Langevin

USF Tampa Graduate Theses and Dissertations

Augmentation with reclaimed water is one method for rehydrating wetlands damaged by water-level declines. Augmentation with reclaimed water has been proposed for rehydrating a wetland in the covered-karst terrane of west-central Florida. There is concern because reclaimed water may contain harmful agents that could flow from the wetland 1.4 km to a municipal wellfield that withdraws 30,000 m³/day. Estimates of groundwater flow velocities were calculated from the results of detailed field studies at the wetland. Results indicate that groundwater flows downward in the surficial aquifer at rates of 0.1 to 0.2 m/day and horizontally in the Floridan aquifer …

Geophysical And Hydrogeological Effects Of Astorm-Water Retention Pond On The Floridan Aquifer, Hillsborough County, Florida, Abdullah M. Alamri

USF Tampa Graduate Theses and Dissertations

An integrated geologic, hydrologic, and geophysical investigation was conducted to determine the effect of a storm-water retention pond on the Floridan aquifer. Surface DC resistivity surveys were used to delineate the hydrostratigraphy. There are four distinct geoelectric layers: (1) Layer 1, high resistivity, 3 meters thick, fine to very fine unsaturated sand; (2) Layer 2, moderate resistivity, 1 to 2.5 meters thick, saturated sands and silts; (3) Layer 3, lower resistivity, 4 to 10 meters thick, silt and clay; (4) Layer 4, moderate resistivity, argillaceous limestone. Two fracture zones are defined by resistivity lows and marked by deep, V-shaped depressions …

The Growth And Toxicity Of The Florida Red Tide Organism, Gymnodinium Breve, Marion Tilton Doig Iii

USF Tampa Graduate Theses and Dissertations

Mass mortalities of marine organisms in the Gulf of Mexico have been associated with blooms of the unarmored dinoflagellate, Gymnodinium breve. This investigation concerns the factors affecting the growth of G. breve and the properties of a toxin produced by the organism.

A modification of the Flask Test of the Provisional Algal Assay Procedure of the Joint Industry/Government Task Force on Eutrophication was used to determine the response of G. breve to various natural waters and enrichments. The growth-promoting potential of natural waters obtained from areas where outbreaks of G. breve frequently occur was greater than that of waters …