Physical Sciences and Mathematics Commons^™

Predicting Hand Surface Area From A Two-Dimensional Hand Tracing, Myles O'Mara

USF Tampa Graduate Theses and Dissertations

Recent occupational health studies have focused on dermal exposure at the hands, but have been unable to accurately express dose without knowing the HSA. There is no standard method to calculate HSA, though some researchers have derived HSA formulas based on dimensions from a Taiwanese population. This research paper describes a shortcut method to estimate the hand surface area (HSA) of a human hand from a two-dimensional hand tracing, and repeated a Taiwanese HSA study in order to explore the viability of its HSA formula in an American university population. A sample of nine adult men and nine adult women, …

Perceptions Affecting Tree Valuation: An Analysis Of Recently Sold And Leased Properties In Tampa, Florida, Cody R. Winter

USF Tampa Graduate Theses and Dissertations

The urban forest is a structure that is fluid in both species composition and how it is integrated in our cities and suburban areas. Much like the fluidity in its structure, the urban forest provides ecosystem services and disservices in many forms. These services and disservices can often come in the form of temperature regulation, lower crime rates, and even higher property values. The latter, which is associated with the economic value of trees, is a part of the hedonic pricing literature which suggests that there is a disparity in the value associated with trees to house prices. With the …

Packaging Of Genetic Material By Gene Transfer Agents (Gtas) Produced By Marine Roseobacter Species And Their Effect On Stimulating Bacterial Growth, Shahd Bader Aljandal

USF Tampa Graduate Theses and Dissertations

Horizontal gene transfer is one of the most important mechanisms for prokaryotic genome innovation and evolution. Gene Transfer Agents (GTAs) are phage-like particles that package small fragments of the genome of a GTA-producing bacterial cell. GTA chromosomal gene clusters usually contain 15-conserved open reading frames (ORFs) and are present in most of the sequenced marine alpha-proteobacteria genomes. Some marine strains have been shown to produce GTA particles that were biologically active in marine environment.

GTA particles range in size, morphology and the amount of host DNA they package. To date, the characteristics of GTAs are largely based on observations of …

The Role Of High-Elevation Headwater Runoff In Streamflow Generation And Water Supply In The Northern Andes, Colombia, Laura Lotero Lozano

USF Tampa Graduate Theses and Dissertations

Water security requires that sufficient quantities of water be available at critical times. This is particularly challenging for high-intensity urban and agricultural settings. In underdeveloped nations, streamflow is commonly the preferred water source, as it is readily available and delivered cost-free to users. Yet, the sources of these critical streamflows are often unknown. This issue is salient in the Northern Andes, where basic knowledge of controlling factors for the quantity, quality, and timing of runoff is lacking. High-elevation headwaters are the primary catchment areas in the Northern Andes, but the extent of water providing to municipalities in the Northern Andes …

Reef Fish Biodiversity In The Florida Keys National Marine Sanctuary, Megan E. Hepner

USF Tampa Graduate Theses and Dissertations

The biological diversity of reef-fish in the Florida Keys National Marine Sanctuary (FKNMS) from 1999 – 2016 was evaluated in terms of abundance, biomass, species richness, evenness, Shannon diversity, Simpson diversity, and functional diversity, using observations collected by multiple agencies and institutions under the Reef Visual Census (RVC) program. To compare the different diversity indices species richness, Shannon diversity, Simpson diversity, and functional diversity were converted into effective number of species. I examined the seven indices by no-take marine zones, in seven benthic habitat strata, and across the three-distinct geographic subregions in the Florida Keys domain (Upper, Middle, and Lower …

A Geochemical And Petrological Analysis Of The San Rafael Volcanic Field, Utah, Danielle Koebli

USF Tampa Graduate Theses and Dissertations

The San Rafael Volcanic Field, Utah, is a 4.6 Ma extinct monogenetic field that is found in the Northern Transition Zone of the Colorado Plateau. The field has been eroded, leaving the dikes, conduits, and sills visible. Within the sills we see evidences of immiscibility in the form of an intermediate syenite (~50 wt% SiO₂) enclosed in a mafic shonkinite (~48 wt % SiO₂). Field relations indicate that sills were formed due to single events (Richardson et al., 2015), which makes in-situ differentiation the process at the origin of both rock types. Geochemical data supports differentiation …

Thermodynamic And Kinetic Aspects Of Hen Egg White Lysozyme Amyloid Assembly, Tatiana Miti

USF Tampa Graduate Theses and Dissertations

Deposition of protein fibers with a characteristic cross-β sheet structure is the molecular marker associated with human disorders ranging from Alzheimer's disease to type II diabetes and spongiform encephalopathy. Given the large number of non-disease related proteins and peptides that have been shown to form amyloid fibrils in vitro, it has been suggested that amyloid fibril formation represents a generic protein phase transition. In the last two decades it has become clear that the same protein/peptide can assemble into distinct morphologically and structurally amyloid aggregates depending on the solution conditions. Moreover, recent studies have shown that the early stage, oligomeric …

Genetic Identification And Population Characteristics Of Deep-Sea Cephalopod Species In The Gulf Of Mexico And Northwestern Atlantic Ocean, Amanda Sosnowski

USF Tampa Graduate Theses and Dissertations

Nearly all deep-sea cephalopod life history studies have been completed by examination of specimens collected in the wild. Much of this work is like piecing together a puzzle; knowledge of the life history of many species remains fragmented and hence, taxonomically and phylogenetically confused. Molecular approaches and sequencing technologies are powerful tools for deciphering wild-type cephalopod life history and population dynamics. Use of molecular markers offers additional certainty for identifying specimens damaged during deep-sea collections and can elucidate often cryptic, intra- and interspecific diversity. The research presented in this study assessed broad genetic patterns of biodiversity in deep-sea cephalopods from …

Calibration-Free Spectrophotometric Measurements Of Carbonate Saturation States In Seawater, Erin E. Cuyler

USF Tampa Graduate Theses and Dissertations

This work describes efforts to improve methodologies and instrumentation for investigation of the marine CO₂ system. In the first section of my thesis, a method was developed that provides simple, calibration-free measurements of seawater carbonate saturation states (Ω_spec) based solely on the use of a laboratory spectrophotometer. Measurements of pH are made in paired optical cells, one with and one without added nitric acid. The amount of added nitric acid is determined through the direct proportionality between nitrate concentration and UV absorbance. After an initial calibration, the method is calibration-free and requires no volumetric or gravimetric analyses …

More Than Just Empty Space: Integrated Geoarchaeological Investigations Of The Crystal River Site (8ci1) Plaza, Alexander C. Delgado

USF Tampa Graduate Theses and Dissertations

Crystal River (8CI1) is a Woodland period archaeological site on the west-central Gulf Coast of Florida, famous for its diverse suite of exotic artifacts typical of the Hopewell Interaction Sphere, as well as its monumental shell mounds which surround a central plaza. Historically, these plazas are utilized as spaces for cultural expression, daily interactions between members of the community, economic exchanges, and discourse of all types. They also serve as a symbolic space, embodying social and political relations that are critical to the formation and maintenance of cultural identity. These spaces are challenging to study using conventional archaeological techniques since …

Sustainability Of Community-Managed Rural Water Supply Systems In Amazonas, Peru: Assessing Monitoring Tools And External Support Provision, Jacob E. Mangum

USF Tampa Graduate Theses and Dissertations

Globally, there is still a large number of people without access to safe drinking water; a known health risk. In rural areas of countries like Peru, when potable water systems are built the responsibility for maintaining these systems is given to volunteer water committees. Despite its prevalence as a management model, there is a consensus that community management alone cannot ensure sustainable water service. Therefore, the overall goal of this research is to assess the sustainability of community-managed water systems in rural areas of the department of Amazonas, Peru. Specifically, this research examines two mechanisms that have been shown to …

Formation Of Carbon-Carbon And Carbon-Hetero Bonds Through Gold Catalysis, Boliang Dong

USF Tampa Graduate Theses and Dissertations

This dissertation mainly contains two parts: one is C-X (C, O, S) bond formation through gold(I) catalysis, one is new applications via gold(I/III) redox catalysis.

In first part, gold(I) catalysts would be introduced and their general applications, then the TA-Au species will be emphasized including the design, synthesis, characters and their application in catalysis. The applications are well developed during the past decade in our group, but here only involves three examples regarding C-C, C-O and C-S bond formations. From these effective applications, the unique stability and reactivity of TA-Au will be studied and explained, which is the reason and …

Stable Isotopes In The Eye Lenses Of Doryteuthis Plei: Exploring Natal Origins And Migratory Patterns In The Eastern Gulf Of Mexico, Brenna A. Meath

USF Tampa Graduate Theses and Dissertations

Stable isotope analysis is an emerging tool to examine trophic pathways and migratory patterns of marine organisms. Squid are widely distributed in coastal and deep water regions of the Gulf of Mexico. Stable isotope ratios of carbon and nitrogen found within cephalopod tissues can provide information on both trophic level and habitat of their food sources. More recently, ontogenetic changes in stable isotope ratios within squid eye lenses have been documented. Concentric layers of crystallin proteins are added to the lens as the squid ages; the center of the lens contains the oldest layer and the youngest layers are on …

Synthesis, In Vitro Characterization And Applications Of Novel 8-Aminoquinoline Fluorescent Probes, Adonis Mcqueen

USF Tampa Graduate Theses and Dissertations

Malaria is a parasitic disease that is caused by the plasmodium parasite. Plasmodium infection has affected man for thousands of years. With advances in drug discovery over the past century, malaria has evolved to possess resistance to most mainline therapeutics. This war of drug discovery vs plasmodium evolution continues to be fought to this very day, with attempts to eradicate malaria worldwide. Frontline treatments such as chloroquine, artemisinin, and atovaquone/proguanil have all seen parasitic resistance in strains of P. vivax as well as P. falciparum. While plasmodium possesses resistance to most classes of anti-malarials, the 8-aminoquinoline (8-AQ) class has …

Healthcare It In Skilled Nursing And Post-Acute Care Facilities: Reducing Hospital Admissions And Re-Admissions, Improving Reimbursement And Improving Clinical Operations, Scott L. Hopes

USF Tampa Graduate Theses and Dissertations

Health information technology (HIT), which includes electronic health record (EHR) systems and clinical data analytics, has become a major component of all health care delivery and care management. The adoption of HIT by physicians, hospitals, post-acute care organizations, pharmacies and other health care providers has been accepted as a necessary (and recently, a government required) step toward improved quality, care coordination and reduced costs: “Better coordination of care provides a path to improving communication, improving quality of care, and reducing unnecessary emergency room use and hospital readmissions. LTPAC providers play a critical role in achieving these goals” (HealthIT.gov, 2013).

Though …

Role Of Viruses Within Metaorganisms: Ciona Intestinalis As A Model System, Brittany A. Leigh

USF Tampa Graduate Theses and Dissertations

Marine animals live and thrive in a literal sea of microorganisms, yet are often able to maintain specific associations that are largely dictated by the environment, host immunity and microbial interactions. Animal-associated microbiomes include bacteria and viruses that vastly outnumber host cells, especially in the gut environment, and are considered to be integral parts of healthy, functioning animals that act as a metaorganism. However, the processes underlying the initial establishment of these microbial communities are not very well understood. This dissertation focuses on the establishment of a well-known developmental animal model, Ciona intestinalis (sea squirt), to study the establishment and …

Enhancing The Internet Of Things Architecture With Flow Semantics, Allen Ronald Deserranno

USF Tampa Graduate Theses and Dissertations

Internet of Things (‘IoT’) systems are complex, asynchronous solutions often comprised of various software and hardware components developed in isolation of each other. These components function with different degrees of reliability and performance over an inherently unreliable network, the Internet. Many IoT systems are developed within silos that do not provide the ability to communicate or be interoperable with other systems and platforms. Literature exists on how these systems should be designed, how they should interoperate, and how they could be improved, but practice does not always consult literature.

The work brings together a proposed reference architecture for the IoT …

Statistical Analysis And Modeling Of Ovarian And Breast Cancer, Muditha V. Devamitta Perera

USF Tampa Graduate Theses and Dissertations

The objective of the present study is to investigate key aspects of ovarian and breast cancers, which are two main causes of mortality among women. Identification of the true behavior of survivorship and influential risk factors is essential in designing treatment protocols, increasing disease awareness and preventing possible causes of disease. There is a commonly held belief that African Americans have a higher risk of cancer mortality. We studied racial disparities of women diagnosed with ovarian cancer on overall and disease-free survival and found out that there is no significant difference in the survival experience among the three races: Whites, …

Lung Ct Radiomics: An Overview Of Using Images As Data, Samuel Hunt Hawkins

USF Tampa Graduate Theses and Dissertations

Lung cancer is the leading cause of cancer-related death in the United States and worldwide. Early detection of lung cancer can help improve patient outcomes, and survival prediction can inform plans of treatment. By extracting quantitative features from computed tomography scans of lung cancer, predictive models can be built that can achieve both early detection and survival prediction. To build these predictive models, first a detected lung nodule is segmented, then image features are extracted, and finally a model can be built utilizing image features to make predictions. These predictions can help radiologists improve cancer care.

Building predictive models based …

Viruses In Marine Animals: Discovery, Detection, And Characterizarion, Elizabeth Fahsbender

USF Tampa Graduate Theses and Dissertations

Diseases in marine animals are emerging at an increasing rate. Disease forecasting enabled by virus surveillance presents a proactive solution for managing emerging diseases. Broad viral surveys aid in disease forecasting by providing baseline data on viral diversity associated with various hosts, including many that are not associated with disease. However, these viruses can become pathogens due to expansion in host or geographic range, as well as when changing conditions shift the balance between commensal viruses and the host immune system. Therefore, it is extremely valuable to identify and characterize viruses present in many different hosts in a variety of …

Essays On Crowdfunding: Exploring The Funding And Post-Funding Phases And Outcomes, Onochie Fan-Osuala

USF Tampa Graduate Theses and Dissertations

In the recent years, crowdfunding (a phenomenon where individuals collectively contribute money to back different goals and projects through the internet) has been gaining a lot of attention especially for its socio-economic impact. This dissertation explores this phenomenon in three distinct but related essays. The first essay explores the nature and dynamics of backers’ contributions and uses the insights generated to develop a forecasting model that can predict crowdfunding campaign outcomes. The second essay investigates how creators’ crowdfunding campaign design decisions impact their funding and post-funding outcomes. Interestingly, the essay highlights that certain crowdfunding campaign design decisions have differential effects …

Magnetic Nanostructure Application In Sers Detection Of Melatonin And Resonance Raman Characterization Of Binding Of Catechol Moieties With Antibiotic, Siqi Sun

USF Tampa Graduate Theses and Dissertations

Raman spectroscopy provides characteristic peaks of the target molecules that can be observed with appropriate laser, spectrometer and detector. These characteristic peaks can reveal ‘fingerprint’ information of a molecule even in a myriad of cases and combinations. It makes Raman spectroscopy a highly sensitive and selective analytical technique. Raman spectroscopy has a variety of chemical, environmental and biological applications. In this dissertation, modified Raman method are applied in life sciences and pharmaceutical studies.

The major challenge against development of Raman spectroscopy is how to improve the intensity of Raman signal. Surface Enhance Raman Scattering (SERS) and resonance Raman(RR) are utilized …

Chemical Investigations Of Fungal Natural Products For Drug Discovery, Danielle H. Demers

USF Tampa Graduate Theses and Dissertations

Natural products have, historically, played an important role in drug discovery. Nevertheless, drug resistance, pathogen evolution, and global climate change threaten human health and nearly all current anti-infective treatments on the market today. It is undeniable that new drug discovery efforts are needed with increasing urgency.

Bolstered by a rich history of discovering treatments in the world around us, natural products chemists continue to look to the environment with increasing understanding and emerging technologies that allow efficient, effective isolation of new chemical entities. This thesis will describe one such endeavor.

Focusing on fungal natural products, herein is described the isolation …

Morphodynamics And Sediment Pathways Of The John's Pass-Blind Pass Dual-Inlet System: Pinellas County, Florida, Mark H. Horwitz

USF Tampa Graduate Theses and Dissertations

The morphodynamics of an inlet channel draining an estuary or bay are governed by a complex system of temporally and spatially varying physical processes, including wind, waves, tides, sediment transport, and both tide and wave driven currents. In addition, sediment availability and characteristics in conjunction with underlying geologic framework bear on the morphology and morphologic behavior of an inlet system. This study examines the morphodynamics, sediment transport patterns and time-series morphologic change of John’s Pass and Blind Pass, two structured tidal inlets that collectively make up a dual-inlet system sharing the tidal prism of northern Boca Ciega Bay, in Pinellas …

Towards Violation Of Classical Inequalities Using Quantum Dot Resonance Fluorescence, Manoj Peiris

USF Tampa Graduate Theses and Dissertations

Self-assembled semiconductor quantum dots have attracted considerable interest recently, ranging from fundamental studies of quantum optics to advanced applications in the field of quantum information science. With their atom-like properties, quantum dot based nanophotonic devices may also substantially contribute to the development of quantum computers. This work presents experimental progress towards the understanding of light-matter interactions that occur beyond well-understood monochromatic resonant light scattering processes in semiconductor quantum dots. First, we report measurements of resonance fluorescence under bichromatic laser excitation. With the inclusion of a second laser, both first-order and second-order correlation functions are substantially altered. Under these conditions, the …

A Landscape Of Thermal Inequity: Social Vulnerability To Urban Heat In U.S. Cities, Bruce Coffyn Mitchell

USF Tampa Graduate Theses and Dissertations

A combination of the urban heat island effect and a rising temperature baseline resulting from global climate change inequitably impacts socially vulnerable populations residing in urban areas. This dissertation examines distributional inequity of exposure to urban heat by socially disadvantaged groups and minorities in the context of climate justice. Using Cutter’s hazards-of-place model, variables indicative of social vulnerability and biophysical vulnerability are statistically tested for their associations. Biophysical vulnerability is conceptualized utilizing a urban heat risk index calculated from summer 2010 LANDSAT imagery to measure land surface temperature , structural density through the normalized difference built-up index, and vegetation abundance …

Diversifying Homogenous Au(I)-Catalysis Through New Reaction Discovery, Stephen Motika

USF Tampa Graduate Theses and Dissertations

Homogenous Au(I)-catalysis has become a valuable synthetic tool to activate a host of unsaturated carbon functional groups towards nucleophilic addition. Over the course of the past two decades, many have embarked on new journeys within this field. Notably, the advancements in this field hinge on the development of new ligand systems that impart novel reactivity at the metal. Our group has focused on this area, as we have successfully demonstrated the utility of 1,2,3-triazoles as ligands for gold and a host of other transition metals and Lewis acids. With respect to gold catalysis, these ligands enhance the stability of the …

Bayesian Artificial Neural Networks In Health And Cybersecurity, Hansapani Sarasepa Rodrigo

USF Tampa Graduate Theses and Dissertations

Being in the era of Big data, the applicability and importance of data-driven models like artificial neural network (ANN) in the modern statistics have increased substantially. In this dissertation, our main goal is to contribute to the development and the expansion of these ANN models by incorporating Bayesian learning techniques. We have demonstrated the applicability of these Bayesian ANN models in interdisciplinary research including health and cybersecurity.

Breast cancer is one of the leading causes of deaths among females. Early and accurate diagnosis is a critical component which decides the survival of the patients. Including the well known ``Gail Model", …

Structure And Activity Of Metallo-Peptides, Christian C. Tang

USF Tampa Graduate Theses and Dissertations

Metal ions are ubiquitously found in all living systems and play vital roles in supporting life forms by performing an array of biological activities. Such biological activities include binding and transforming organic molecules, and also acting as active centers and cofactors for catalysis of various acid-base and redox reactions in biological system. The main focus in bioinorganic chemistry is to elucidate the structural and functional roles of metals in biological systems. Among all transition metal ions, Cu²⁺ and Fe³⁺ are especially versatile and important due to their abilities to go through redox efficiently.

This dissertation can be divided …

Patterns In Words Related To Dna Rearrangements, Lukas Nabergall

USF Tampa Graduate Theses and Dissertations

Patterns, sequences of variables, have traditionally only been studied when morphic images of them appear as factors in words. In this thesis, we initiate a study of patterns in words that appear as subwords of words. We say that a pattern appears in a word if each pattern variable can be morphically mapped to a factor in the word. To gain insight into the complexity of, and similarities between, words, we define pattern indices and distances between two words relative a given set of patterns. The distance is defined as the minimum number of pattern insertions and/or removals that transform …